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By D. Kulchyski, R. Thibault, D. Lamoureux

"Mine tunneling applications are sensitive to the leakage and friction performance of ducting systems. Improvements in performance can help project economics through reduction in drift height, booster fan spacing, fan electrical power requirement, and deferral of ventilation raise construction. Semirigid plastic ducting has enjoyed significant adoption in mine tunneling in recent years. This paper explores technical properties and performance aspects of this relatively new material application.INTRODUCTIONUnderground mining projects are sensitive to mine development cost and schedule to meet first production—both of which are defined to a substantial extent by mine access construction. The very nature of mine access development requires driving accesses into new areas and even mechanized and automated tunneling methods require ventilation. Until underground airways are connected, allowing a flow-through circuit, ducted ventilation is required to establish ventilation within any single-access (i.e.: dead-end) heading. See Figure 1 as an example of ducted ventilation. Improving performance of ducted ventilation systems impacts project cost and schedule in several ways:For drifts whose height is defined by overhead clearance above haul trucks or tall equipment, smaller diameter ducting will decrease heading size.With higher ventilation flows, activities can be less ventilation-constricted; secondary headings can be worked without restriction, which improves schedule.Given the ability to provide more air for a given fan power, blasting gasses can clear the face and mine more quickly so crews can return to work more quickly - allowing higher advance rates.Lower electrical costs – both due to lower power consumed by fans and with the requirement for fewer electrical stations to power booster fans."

Jan 1, 2019

By Samuel O. Akande

"Gold occurs as native metal, in electrum, and in a telluride mineral in quartz carbonate veinlets of three vein systems at the Ross Mine, northern Ontario. The 14 Vein System is made up predominantly of concordant veinlets within layered ankeritic dolomite stratabound by, and conformable with, andesite tuff Individual veinlets contain pyrite, sphalerite, galena, chalcopyrite, tennantite, pearceite, proustite, native gold and electrum in a matrix of quartz, dolomite, ankerite and calcite. The 2B Vein System is made up of both concordant and discordant veinlets within andesite tuffs. The veinlets contain pyrite, chalcopyrite, sphalerite, bornite, tennantite and free gold in quartz, calcite and dolomite. The 18 Vein System is comprised of stockwork veinlets in and around intrusive syenite which has both sharp and gradational contacts with enclosing andesite tuff The veinlets contain pyrite, chalcopyrite, bornite, chalcocite, native gold and calaverite. Sulphide and silicate minerals in veinlets and wall rocks are stable assemblages for the regional metamorphism of greenschist rank. ,The 14 Vein System is interpreted as a metalliferous siliceous carbonate chemical sediment, the components of which were leached from the underlying volcanic rocks by convecting sea water and subsequently deposited on the sea floor between the extrusion of flows and pyroclastic rocks. Subsequent regional metamorphism and intrusions remobilized and redistributed the syngenetic stratabound material into dilatant fractures in adjacent tuff, as in the 2B and the 18 vein systems."

Jan 1, 1982

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By D. M. Baird

ABSTRACT A revised stratigraphic section of Carboniferous rocks which occupy about 700 square miles in southwestern Newfoundland is presented. Gypsum, which outcrops at thirty-five different localities, is found to belong to four principal zones in the section. The newly mapped structure of the region makes the otherwise random occurrences of gypsum appear as systematic outcroppings of the four zones which follow the regional structure. Details of several occurrences are given and those most advantageous for exploitation are pointed out. INTRODUCTION ROCKS of Carboniferous age occupy an area of about 700 square miles in southwestern Newfoundland. They occur in a belt, from 5 to 15 miles wide, which extends from the head of St. Georges bay southwestward for 65 miles to the mouth of Little Codroy river (see Figure 1). Several hundred feet of Pennsylvanian rocks overlie rocks of Mississippian age, which are at least 12,000 feet thick. The rocks of the Carboniferous section of Newfoundland are very similar to those of Nova Scotia and represent a northeastward continuation of the same palaeophysiographic conditions. Mississippian measures of Windsor equivalence include thick gypsum deposits which outcrop at many places and which extend under large areas as indicated by sink-holes and by structural considerations.

Jan 1, 1951

By M. Jarvis, D. B. Dreisinger, T. Hitchins

Mineral carbonation (MC) has been extensively researched all over the world since it was found as a natural exothermic process to permanently and safely sequester CO2. In order to accelerate the natural process, various methods for carbonation of Mg-/Ca-silicate minerals and other industrial wastes have been studied. It has been found that the MC efficiency will increase with an increase of CO2 pressure, retention time, temperature, mass ratio of Mg or Ca to Si in minerals, specific surface area, and the slurry concentration in a specific range, and with the introduction of an effective catalysts, for example, 1M NaCl and 0.64M NaHCO3 or carbonic anhydrase. However, there still is not a successful industrial application because of high economic cost and slow reaction rate. It is not economic to exploit Mg- and Ca-silicate minerals deposits or tailings to sequester CO2 by MC, due to the cost of grinding and heat pre-treatment and in some cases the whole sequestration process may result in more CO2 emissions than the amount of CO2 sequestered, due to the requirements of energy inputs. The process however, may be profitable as a whole (with carbon credits). It is suggested to combine MC with recovery of valuable metals from ore deposits in order to reduce the cost for MC by cost sharing for mineral recovery.

Jan 1, 2017

By J. B. Sabey, V. R. Degner, D. MacGillivray

"Hydrodynamics principals are applied to the design of a natural air ingestion flotation machine for coarse solids applications. Preliminary laboratory test data and subsequent operating plant flotation kinetic performance evaluations are reviewed. INTRODUCTIONThe concentration of potash (sylvite, KCI) from halite and other salts using flotation is well understood and practice a with much success. Reagent schemes and plant circuitry for obtaining the desired product recovery and grade have been established with proven performance. These flotation circuits normally process the medium and finer size particles, less than 30 mesh (600 microns).However, often the potash market trends specifically demand a coarse product size. This emphasis, accompanied by the existing high losses of coarse (+30 mesh) potash in flotation circuits, creates the need for development of a flotation machines specifically designed for coarse potash beneficiation.This technical challenge was undertaken by the WEMCO Research and Development Group. The specific objectives of this flotation machine development program were ( l) to achieve an ""Ultra Coarse Flotation Machine"" capable of adequately suspending and transporting particles in the 4 - 30 mesh (4.75 - 0.6 mm) size range at solids concentrations of 30% or greater and (2) ascertain metallurgical performance of this machine.This paper covers the development (both theoretical and mechanical/ hydrodynamic), the field test program and results, a discussion of applicable flotation kinetics, and conclusions of this ""Coarse Potash Flotation Machine"" development project."

Jan 1, 1986

By M. Abdollahi, M. R. Khalesi, Y. Kianinia, A. Khodadadi Darban

High cyanide consumption during the processing of gold ores with high sulphide minerals can make the typical cyanidation uneconomic. Also cyanide is a toxic material and environmental concerns of cyanide compounds are serious. Optimization of cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, the kinetic of their dissolution and estimation of formation of cyanide complexes which consume the free cyanide. In this paper, a methodology to estimate cyanide consumption by modeling the minerals and gold leaching kinetic based on a liberation model and speciation of all possible cyanide related species in the solution is presented. The results showed that this methodology could successfully estimate the cyanide consumption based on mineralogical data with very lower number of parameters compared to empirical models present in the literature, while it offers the prediction of formation of all cyanide complexes which could be used for optimization purposes.

Jan 1, 2017

?NWCC has the highest number of Aboriginal students of any post secondary institution in BC and the region served includes 25 bands ? Chair of the Board of Governors is Irene Seguin (Hagwiloo K?am Saxwhl Giis) from Gitwinksihlkw ? FN council ? 39 First Nations Members * focus is to develop policy recommendations to increase student success rates

May 1, 2009

By Leopoldo Gutierrez, Sergio Castro, Lina M. Uribe, Janusz S. Laskowski

"The effect of sulfite and metabisulfite ions on the amyl xanthate flotation of copper-activated pyrite, in distilled water and seawater, has been studied by micro-flotation tests and redox potential measurements. The activation of pyrite was carried out varying copper ions concentration. It was found that in the presence of copper ions in solution, sulfite and metabisulfite are able to depress copper-activated pyrite at neutral or slightly acid pH. After the addition of sulfite or metabisulfite ions the resulting pH is more acidic with metabisulfite ions. A significant increase of the redox potential of the solution was observed as copper ions concentration increased. Then, the initial reducing conditions brought about by sulfite and metabisulfite ions, change abruptly to oxidizing conditions in the presence of copper ions. Under these oxidizing conditions, the metabisulfite showed to be an effective depressant for pyrite mainly in seawater. However, sulfite was a pyrite depressant in both distilled water and seawater. Based on these results, the pyrite depression by sulfoxy-depressants during the flotation of Cu/Mo ores in distilled water and seawater is discussed.INTRODUCTIONDepression of pyrite by sulfoxy-depressants (sulfite and metabisulfite) in the presence of copper ions is an important issue. This is particularly true when pyrite depression in the flotation of Cu/Mo sulfide ores is carried out in seawater. The use of lime in seawater must be avoided because the formation of magnesium hydroxy-complexes and precipitating magnesium hydroxide strongly depresses molybdenite flotation (Castro et al., 2014). In order to solve this problem, one large plant in Chile uses sodium metabisulfite (MBS) instead of lime to depress pyrite in seawater. In plant practice, this also improves molybdenite flotation since with the use of MBS the pyrite depression is carried out at pH 6-7, instead the pH 11-12 usually employed with lime.From a general point of view, pyrite exhibits some natural floatability over acidic pH ranges and may be partially floated without thiol collectors (a coating of sulfur/polysulfides has been claimed). Therefore, pyrite flotation with xanthates is usually high in the acidic pH region, but decreases greatly at alkaline pH (Leppinen, 1990; Fornasiero and Ralston, 1992; Zhang et al., 1997)."

Jan 1, 2016

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By J. M. Cormie

"The orebodies of the East Malarcic mine are interesting from a geological standpoint because of the very small amount of vein quartz, the occurrence of much of the ore in soft greenstone schist, the presence of innumerable bodies of porphyry and diorite, and their obvious relationship to structural features .The property lies in the northeast part of Fourniere township in western Quebec, and within the important fault zone that geological mapping in recent years has shown is traceable wesrward through the Noranda and Kirkland Lake camps and eastward to beyond the Val d'Or region . The claims included in the property were staked by J.P. Norrie and L. K. Coffin in 1932, but gold was not discovered until i934. Production began late in 1938. The total amount of ore milled up to the end of 1945 was 2,837,091 tons from which gold having the value of $16,631,758 was recovered.The region is underlain by an alternating series of Early Precambrian sediments and volcanics cut by innumerable intrusives. These are more fully described in the works of Gunning, Ambrose, and Norman. The East Malanie property is underlain by three formations, which, named from north· to south, are : the Cadillac sediments, the Blake River volcanics, and the Kewagama sediments. In addition, there are countless intrusions of porphyry and diorite, particularly in the greenstone, occurring in all sizes up to those measurable in hundreds and even thousands of feet . These constitute a large proportion of the greenstone in places. In many parts of the ore zone there is more porphyry and diorite than schist. The greenstone itself is not homogeneous but includes peridotite, andesitic lava, and soft talcose schist.Orebodies have been found in both the Blake River volcanics and the Kewagama sediments. They are not known to occur in the Cadillac group. The ore occurs in a zone of pyrite mineralization in which almost no other metallic minerals and very little vein quartz are present. Generally, the grade varies directly with the amount of pyrite. The mineralization is later than all the rocks of the area. Diorite was a particularly favourable rock for mineralization and contains the highest grade of ore, but any rock in the fault zone may be ore-bearing, whereas the same type away from the zone is not."

Jan 1, 1954

By H. D. Goodfellow, R. A. Elliott

"This paper covers the evolution of large mills and autogenous grinding and compares grinding practice in the iron ore industry with that in the base metal industries. Comments on novel methods of grinding are presented for discussion. Recent developments in the field of classification are briefly reviewed. A systems analysis approach to grinding circuits is discussed. Finally, a point is made for establishing a group within the industry with the purpose of developing a comprehensive evaluation of grinding research and development."

Jan 1, 1971

By R P. Douglas

During 1955, Cominco commenced an exploration pro-gram in northern New Brunswick; in the following year, what is now the Wedge mine was discovered. The mineralization is mainly pyrite, with associated chalcopyrite and minor amounts of sphalerite and galena. The property was brought into production at 750 tons per day in early 1962. The ore is trucked 10 miles to the Heath Steele concentrator, where a copper concentrate grading about 19.5 per cent is produced and shipped to the Japanese markets through the port of Dalhousie, New Brunswick. Introduction THE Wedge mine, owned by The Consolidated Mining and Smelting Company of Canada Limited (Cominco), is located in the Newcastle-Bathurst area of New Brunswick. It is 42 miles by road northwest of Newcastle and 37 miles southwest of Bathurst (Figure 1). The mine is located on the north side of the Nipisiquit river in one of the more mountainous areas of the Province, the local relief rising to 1,500 feet above sea level. There is an almost complete forest cover of mixed hardwoods and conifers -the val-leys and hillsides being covered by balsam, spruce and pine, the swamps by cedars and black spruce and the highlands by mixed hardwoods.

Jan 1, 1965

By Denis Bois

La Bolivie est un pays en développement qui compte une tradition minière qui précède même l?établissement espagnol en Amérique. Pendant toutes ces années, l?exploitation minière s?est faite sans grands égards pour l?environnement. Au cours des dernières années cependant, le gouvernement bolivien a modifié ses lois afin de rendre nécessaire la prise en compte de l?environnement dans le processus d?exploitation d?une mine. Dans le cadre d?un projet MRN-ACDI1 visant à renforcer le secteur minier en Bolivie et ses retombées pour la population, l?URSTM2 a été mandaté pour développer et mettre en place un programme académique de gestion environnementale minière, basée sur l?expertise canadienne. Ce programme vise à renforcer les institutions académiques boliviennes responsables de la formation en environnement minier en Bolivie ainsi que les ministères et agences gouvernementales concernées.

May 1, 2001

By A. F. Laurin, A. L. Dorr

"Because of its wide areal extent, its numerous lithological facies and its high degree of metamorphism, the Quebec portion of the Grenville province has only partly been explored and prospected. Rock types that are economically among the most interesting in the Grenville are those of mafic and ultramafic compositions, because of their great potential for coppernickel and chromium-platinum. The peculiar mode of occurrence and the distribution of these igneous masses in which copper-nickel mineralization is known to occur indicate' two common geological features: (1) aerial photographs and/or topographic maps strongly' suggest close spatial (and possibly temporal and genetic) association of most of these mineralized mafic and ultramafic intrusions with circular structures; (2) when plotted on a large-scale map comprising the Quebec portion of the Grenville, these circular structures fall along two lines which could correspond to major tectonic features. Even though the genetic links among the mineralized mafic-ultramafic masses, the circular structures and the linear features are not yet fully understood, their associations are believed to be empirically valid and should therefore be used as geological tools by those interested in exploring the Grenville for copper-nickel and possibly chromium-platinum deposits. It should be noted that these mafic and ultramafic bodies do not appear to be spatially related to anorthosite complexes."

Jan 1, 1971

By Alfred C. Lane

WE recently received from Professor A. C. Lane, Emeritus Professor of Geology and Mineralogy, Tufts College, Mass., and a Corresponding Member of this Institute, a very interesting account of some recent developments in radioactive methods of determining the age of minerals and, therefore, of the rocks in which they occur. It deals in particular with studies of the minerals of certain pegmatite dykes on the Huron claims and Bear claims in southeastern Manitoba, which, the results indicate, are among the oldest rocks of the earth's crust. The following article presents a non-mathematical summary of Professor Lane's paper . . It will be noted that he is anxious to obtain suitable samples of certain minerals and rocks for further age studies. We hope some o our members may be able to supply him with the material he needs. It may be well to explain briefly how the age determinations are made. Uranium is continually breaking down, or disintegrating in successive steps through radium, etc., to a final product which is lead (uranium-lead), and the rate at which this change takes place is known. Minerals containing uranium will therefore contain lead also, and the lead-uranium ratio mul-tiplied by a certain factor (approximately 7 ,600) will give the age of the mineral in millions of years. Thorium also disintegrates at a known rate to give lead (thorium-lead) as a final product, and the age of a mineral containing thorium can thus be calculated from the lead-thorium ratio. Thorium breaks down more slowly than uranium. In unit time, one gram of thorium produces about as much lead as 0.36 grams of uranium.-ED.

Jan 1, 1938

By W. G. Millar

Until a fire occurs, insurance and prevention work are often looked on as unavoidable necessities, but as insurance is back of all business credit, it is essential to know that in case of damage money will be available to cover the loss; while the interruption of production, often caused by a fire, brings home the realization that if prevention work avoids such an interruption, it is well worth while. Fire insurance is a legal contract guaranteeing the payment of large amounts to an owner, but it is possible there is no other important contract that receives so little consideration. Although previously carried on elsewhere, it is only of recent years that insurance engineering has been actively followed up in Canada, with inspections of an owner's property carried out for his benefit. Now inspections of this kind are made, advice on fire prevention and protection work ?is available, reports with recommendations with regard to the above are furnished periodically, and with this method applied the owner receives the broadest possible cover and security at the lowest cost. Rates are set by the underwriters by rating schedules which charge for defects in a building and allow credits for protection and other favourable features . These schedules are based on the past record of loss of mining properties as a class, so that a fire in another mining property indirectly affects you, but the amount paid is reduced in proportion as your property is improved. The writer feels, from personal experience, that there is no industry where fire prevention receives more attention than the mining industry, and it is a pleasure to advise that, due to this co-operation, some reduction in the basis rates for mining risks is now being made by the underwriters.

Jan 1, 1928

By Mike D. Riley, Alan V. Bell, Ernest K. Yanful

Acid mine drainage (AMD) research under the MEND program has been ongoing since 1988 at the Heath Steele Mines waste rock piles including sulphide material, outside Newcastle, NB. In 1989 approximately 10,000 mt of waste rock was placed on a prepared sand base with an underlying impermeable membrane. The waste rock pile was heavily instrumented for measuring oxygen concentrations and temperatures. In September 1991, a composite soil cover designed for the Heath Steele climatic conditions, using local soils, was placed over the pile, creating a totally enclosed system. Moisture content and oxygen probes were installed within the composite soil cover to monitor changes within the soils over time, while two large-size lysimeters were installed below the cover to monitor the hydraulic conductivity of the cover. The waste rock site has been monitored on a monthly basis since installation of the cover, for performance of both cover and waste rock. The monitoring shows very clearly that the placement of the composite soil cover has had a major impact on the generation of AMD. Major reductions in temperature and oxygen concentrations within the waste rock pile indicate that the cover has significantly inhibited the oxidation reaction that generates the AMD. Performance data have shown that the cover has maintained its integrity under the climatic conditions of the area.

Jan 1, 1995

By W. S. Szolga, M. Moser, M. D. Soderstrom, L. Cohen

"CYANEX® 272 is a phosphinic acid-based solvent extraction reagent used commercially since the early 80’s to recover and purify cobalt from sulfate solutions. Historically, the design of CYANEX 272 circuits has involved the selection of an optimal pH profile during pilot-scale testing using mixbox pH control. The desired pH profile is required to be carefully controlled in the same manner during commercial operation. To assist operators in the design and optimization of their circuits, Solvay developed CYANEX 272-specific solvent extraction modeling software, which has enabled determination of the ideal pH profile and staging configuration. Solvay’s recent advances in modeling capabilities have allowed the simulation of circuits without direct mixbox pH control. Modeling has indicated that circuits operated without direct pH control can achieve the desired metal separation while simplifying the commercial operation significantly. This paper reviews a number of potential circuit configurations for the use of CYANEX 272 and demonstrates the separations achievable under the right design and operational conditions, some of which have historically been considered too difficult.INTRODUCTION CYANEX® 272 is a phosphinic-acid based reagent designed specifically for the separation of cobalt from nickel by solvent extraction from weakly acidic sulfate solutions (Rickelton, Robertson, & Burley, 1982; Rickelton, Flett, & West, 1984; Rickelton & Nucciarone, 1997). Following commercial introduction in the 1980’s, CYANEX 272 has been used in a number of hydrometallurgical flowsheets for cobalt purification and/or recovery. CYANEX 272 metal extraction occurs by means of a cation exchange mechanism. Extraction of a divalent metal ion M2+ is represented by the following equation where RH represents the CYANEX 272 ligand and MR2 represents the ligand-metal complex."

Jan 1, 2017

By Oberlando Gonzalez, Claudia Serna, Andrea Alzate, Esperanza López, Maria Holuszko

This paper presents a systematic approach on gold recovery from electronic waste (e-waste) using ammonium persulfate. This process was developed as a response to the lack of hydrometallurgical systems capable of separating gold from its metallic substrate without material grinding, with minimum formation of pollutants, and achieving a lower reaction time. Computer memory boards, electronic processors and electronic pins and contacts were analyzed to determinate base metals (Ni, Fe, Cu) and gold (Au) using microwave plasma atomic emission spectroscopy (MP-AES). An aqueous commercial grade ammonium persulfate with oxygen and pressure was used to produce the persulfate anion (S2O82-) and the oxidative sulfate ion (SO42-), which partially oxidized and leached the base metals breaking the Au-Ni-Fe-Cu bonds and allowing gold to be recovered in its original non-leaching state. The influence of the oxidative parameters was evaluated using full factorial (FF) and central composite designs (CCD) with response surface methodology (RSM) and first and second order models were developed. Using RSM allowed to obtain a faster recovery of gold, minimizing the agent consumption. The findings presented suggest that optimized quantities of ammonium persulfate, oxygen, pressure, temperature and liquid solid ratio could be used for selective oxidization of the base metals and to extract more than 96% of gold from e-waste.

Jan 1, 2017