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By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, Z. S. Abisheva

"Phosphorus slag is the most heavy-tonnage waste of yellow phosphorus production, which is stored in the dump fields for many years creating ecological problems in the regions. Despite of the actions taken to utilize the slags, most of them remain in the slag disposal area. One of the relevant and priority directions is rare-earth metals production (REMs), presence of which in the phosphorus slags allows considering the latter as an acceptable raw material source. Phosphorus slags contain about 30–40 wt% of silicon dioxide, therefore they can serve as a source of production of precipitated silicon dioxide highly required in different industries.The purpose of this work is the most complete REMs recovery in the solution while leaching and subsequent processing of siliceous cake. The work shows results of researches on establishment of the chemical and phase compositions of phosphorus slags, determination of the forms of presence therein of REMs compounds, processes of phosphorus slag leaching by nitric acid and processing of produced siliceous cake by NaOH solution.Based on the data of the instrumental and chemical methods of phosphorus slag analysis, it was established that it consists of pseudowollastonite a-CaSiO3 for 90–92%. It was found out that REMs are present in it in the form of carbonate apatite Ca10(PO4)6CO3 or rare earth apatite, and La2S3 compound inclusions.Optimum parameters of phosphorus slag leaching process were selected: HNO3 concentration 7- 7.5 mol/L; L/S ratio = 2.6–3 mL/g; temperature – 50–80o?; duration – 1 h; pulp stirring – 500 rpm. Recovery of SREMs, CaO, Al2O3 and Fe2O3 into the solution were achieved at 98.0, 99.1, 99.0 and 18.8%, respectively. Presence of 10 elements of the rare earths group in the phosphorus slag was established. It was found out that recovery of almost all REMs is within ~92–99%, except for Sc and Lu – ~39% and ~28%, respectively.For the purpose of optimization of siliceous cake leaching by NaOH solution, influence of some physical and chemical parameters was studied: N?O? concentration, L/S ratio, temperature, and duration. Results of the experimental data will serve as a basis for development of the technology of complex processing of the technological waste of phosphorus industry with production of REMs concentrate and precipitated silicon dioxide."

Jan 1, 2016

By L. E. Young

"The Red Dog deposit of the western Brooks Range, Alaska was discovered in the 1970s. Two mineralized areas are present, the Main and Hilltop deposits. With indicated and inferred reserves of 77 million tonnes of 17.1% zinc, 5.0% lead and 82 g/ tonne silver, the Main deposit of Red Dog represents one of the world's largest zinc-lead deposit s. Since serious evaluation by Cominco commenced in 1980, a better understanding of deposit geology has been gained through 10 715m of diamond drilling and concurrent geologic, geophysical and geotechnical studies. The Red Dog deposit is of Mississippian to Pennsylvanian or Early Permian age, and straddles a redox transition in fine-grained and chemical sediments of the Red Dog structural sequence.The Main deposit has been modified by regional Mesozoic thrust faulting and isoclinal folding, resulting in complex interrelationships between silica rock, sulphide rock and barite. Multiple lines of evidence suggest the Main deposit contains both a syngenetic stratiform and a replacement component. Ore fluids were probably derived by regional lateral movement of brines through a coarse clastic footwall aquifer, then upwards along block faults to the site of the Red Dog deposit.Historical PerspectiveThe region in the vicinity of the Red Dog deposit (Fig. 1) was first prospected by J. W. Kelley in the late 1880s (Orth, 1967). The first coordinated inland exploration was conducted by the U.S. Geological Survey in 1910-1911 and 1923-1926 (Smith, 1913; Smith and Mertie, 1930). The earliest reports of zinc-lead mineralization in the region include reference to samples collected at unknown locales by Eskimo prospectors (Anderson, 1944). In 1955 stratiform pyrite was discovered 19 km west of Red Dog by I.L. Tailleur of the U.S. Geological Survey (Tailleur, 1970). The first reported visit to what is known as Red Dog was by I.L. Tailleur in 1968, who was field checking a colour anomaly noted by B. Baker, a local bush pilot (Tailleur, 1970; Moore et al., 1986) ."

Jan 1, 1989

By R. G. Eggert

"A critical element, as the term has come to be used, provides essential properties to a modern engineered material and is subject to supply risk. The rare-earth elements became perhaps the most prominent of the critical elements in recent years because of their important uses in permanent magnets, advanced lighting, and military materials; the geographic concentration of production in China; and the dramatic run-up in prices in 2010-2011 followed by price collapse between 2011 and 2016. Yet criticality extends beyond the rare earths. What is critical depends on your perspective – who and where you are, and when you ask. This paper reviews the many perspectives on, or faces of, critical elements. It compares and contrasts perspectives of industry (General Electric), national or regional manufacturing sectors (Japan, European Union), emerging energy technologies (as seen by U.S. Department of Energy and, separately, Joint Research Centre of the European Commission) and the world as a whole (as evaluated by academics). This comparison reveals a diversity of not only perspectives but also methodologies and time frames of concern.INTRODUCTIONRare-earth elements appeared prominently in the news in 2010 and 2011 because of the dramatic increase in their prices; their important uses in permanent magnets, advanced lighting, and military materials combined with the geographic concentration of production in China, which reduced export quotas significantly. Rare earths became the most prominent of what have become known as critical elements or materials – that is, those that provide essential properties to modern engineered materials and yet are subject to supply risks.Yet criticality, the state of being both essential and subject to supply risks, extends beyond rare earths. What is critical depends on your perspective. This paper begins by reviewing a little history and presenting a general conceptual framework from which to think about critical materials. It then reviews the many perspectives on, or faces of, critical elements – corporate, national, and global, as well several that focus on emerging energy technologies. The paper concludes with thoughts on what to do to mitigate the potentially negative effects of the supply risks associated with criticality."

Jan 1, 2016

By M. Yao, D. Thibodeau

"Selective mining, such as post pillar cut and fill, is used in large, flat, irregularly shaped ore bodies where ground stability is to be maintained. This selective mining is used to open the stope to the full lateral extent of the ore body in order to minimize the dilution and maximise the recovery. For increased mining depth, design of the post pillar becomes more challenging since those pillars will eventually fail as mining progresses upwards. The post pillar should be designed such that failure does not occur at the early mining stage, such as at the first cut. After mining progresses upwards, the post pillars are expected to fail but be confined by backfill. In order to maximise ore recovery, both drift width and post pillar size must be designed adequately with a consideration of all geomechanic parameters. This paper will describe the process used to design post-pillar cut and fill for one of the ore bodies in Vale’s Copper Cliff Mine using a combination of both empirical deterministic and numerical modelling techniques. By utilizing both empirical deterministic and numerical modelling techniques drift width and post pillar size can be effectively designed. Current post pillar cut and fill design in the existing Vale operations are used to validate the design for Copper Cliff Mine. INTRODUCTIONCopper Cliff Mine is located within the Copper Cliff Offset in the limits of City of Greater Sudbury, Ontario, Canada, as shown in Figure 1. The Copper Cliff Offset extends about eight kilometres south from the Sudbury Igneous Complex into the footwall rocks. Until 2008, the current Copper Cliff Mine was operated as two separate mines i.e. North Mine and South Mine. However, as part of restructuring of Vale Ontario Operations, the North and South Mines were merged in 2009 to form the “Copper Cliff Mine”."

Jan 1, 2015

By J. A. Espinosa-Guillen, J. A. Lopez-Molina, S. García, J. A. Valencia-Quintanar

"The design and implementation of grouting treatments in rock masses are procedures that require continuous adjustment of parameters and criteria to optimize the results. In this proposal we describe a set of tools that enhance decision-making for this type of jobs particularly in dam projects. The methodology is focused on hydrogeological zoning of the site and its constant update combining engineer’s experience with artificial intelligence techniques to integrate the site knowledge; as well as the evaluation of grouting results for different scrutiny scales, with special attention on the relationship between water absorption and grout consumption. INTRODUCTIONSeveral methodologies for design, implementation and evaluation for grouting rock masses have been developed for the solution of specific problems and tested in diverse geological conditions. Each of these methodologies is focused on results evaluation for different scrutiny scales (Table 1) and is employed to assist decision-making before or during the grouting process.Some methods define specifications for grouting each stage of the borehole, making theoretical, semi empirical or experience-based considerations to define basic parameters as maximum pressure, maximum volume, grouting time, flow rate, etc. Ultimately each approach aim to optimize the injection process, adjusting volumes or the grouting time required to obtain satisfactory results, reducing risk of creating new flow paths or unnecessary grout travels, and enhancing the mixture properties to achieve adequate penetrability and long-term behaviour. Some of these criteria have been widely used in dam projects, for example the concept of Grouting Based on Facts to define the maximum pressure and volume (Ewert, 1997), the GIN method (Lombardi & Deere, 1993; El Tani, 2012), or the North American standards based on Apparent Lugeon measures (Naudts, 1995; Bruce 2011); on the other hand, there are relatively new criteria that have shown good results for dam grouting as the Aperture Control Method (Bonin et al., 2012; Carter et al., 2012) or the Real Time Grouting Control Method (Stille et al., 2012)."

Jan 1, 2015

By Adam Turcotte

Mining operations consume a considerable amount of energy, and while reduced energy consumption is desirable, it is not always clear how to achieve this goal. Understanding the opportunities to optimize energy consumption is crucial, and the key to understanding is visualization. One option is the Sankey diagram, which has been used for over 100 years to visualize the flow of energy, materials, or cost through various processes. However, there are drawbacks to this approach that must be addressed. In a Sankey diagram, each flow is represented by an arrow possessing a width proportional to the magnitude of the flow it represents. The diagrams show input flows, how energy is converted and into what form, and also output flows. As per the first law of thermodynamics, the total energy output is equivalent to the total energy input, so any energy that is not transferred to another process is considered to be wasted. These waste flows are depicted in Sankey diagrams and make it straightforward to associate energy sources, sinks and waste flows. Unfortunately, Sankey diagrams do not convey all information required to support practical decision making for redirecting individual energy flows. Based only on a Sankey diagram, it may become evident that a significant flow of waste heat is of the appropriate grade (temperature) and volume to meet an on-site heat demand currently being met with paid-for, possibly carbon intensive fuel. However without augmenting the Sankey diagram with 3D spatial, true geometric analysis, the practicalities of the concept or idea may not be fully appreciated. Another issue with a Sankey diagram is that the magnitude of the energy flowing between processes may have temporal fluctuation or variability on different timescales (diurnal, seasonal, interannual). Currently, Sankey diagrams only provide a static picture of energy conversion and consumption, so that, for example, 4 separate diagrams could have to be prepared for each season. A new energy flow visualization technique which we have called Sankey Trees has been developed. Process locations are defined within a 3D model of the site being studied, and the magnitude of the flow between each pair of processes considered is replaced with a time series. Branches of sustained and diminishing flows are represented through variation of the geometric properties of the branches of the trees. These branches are animated to indicate the direction of flow, and branch joints are used to indicate that a process is transporting one form of energy to multiple processes.

Aug 1, 2013

By D. Sharma, A. K. Singh, R. Singh, P. K. Mandal, M. Sarkar

"This paper deals with the stability investigations carried out at the XIVth seam of Jitpur colliery. The study was conducted to investigate the possible causes of roof cavity formation and face spalling at the middle slice face of block-3 longwall panel and to suggest remedial measures. The instrumentation and monitoring work was carried out in the panel over a period of nine months. On the basis of observations, it was found that if the maximum face span was reduced from the existing 4.8 m to 3.6 m, and if the face time schedule cycle was reduced from a maximum of 37 days to about 18 days, this problem could be eliminated. The recommendations of CMRI have been implemented in the middle slice face of block-4 panel with success. IntroductionModerate to steeply dipping, undisturbed seams of uniform thickness are worked by way of inclined slicing parallel to walls. In this method, the seams are treated as a combination of several moderately thick seams dipping parallel to roof and floor. Numerous variations of multislice mining have been used worldwide to get high coal recovery under local conditions of geology, subsidence control, proness to spontaneous combustion, statutes and economics. Multislice mining can proceed either downward descending from the roof or upward ascending from the floor. Ascending methods require backfill behind the working face to provide a base for the next slice. It is also adopted for surface protection against subsidence or mining under a massive roof. This paper presents a scientific study conducted in Jitpur colliery, IISCO where a 9 m thick seam is mined in three slices in ascending order with stowing."

Jan 1, 2002

By G. Morin, F. Chiesa, B. Tougas, B. Duchesne, Jocelyn Baril, N. Giguère

"An aluminum A356 compressor impeller was sand cast using the Low Pressure technique. The casting was limited in size (170 mm in diameter, 1.2 kg in weight) and very intricate in shape thus making 3D mold printing particularly favorable; indeed, producing this part by the traditional pattern-core box route would involve mounting 12 cores inside the mold while stringent dimensional tolerances are required as the impeller blades are only 2 mm thick. Consequently the molds were produce on the X-One MFlex printer of Quebec Metallurgy Center - CMQ. A dozen castings were produced with different casting temperatures and filling times so that it was possible to assess under which conditions complete filling of the mold cavity would be achieved. Filling and solidification modeling allowed predicting misruns and metallurgical properties inside the A356 (AlSi7Mg04) casting.INTRODUCTION Recent advancements in additive manufacturing enable foundries to produce molds without the tooling (pattern and core boxes) necessary when conventional technology is used (Eyad, 2016). This is particularly advantageous when dealing with intricate shapes and/or when a limited number of parts must be produced within a few days rather than in 5 weeks. An additional advantage is gained when producing prototypes (Johnson, 2016) as changes are much less costly and time consuming when made on a numerical 3D drawing rather than on patterns and core boxes. 3D printing is normally economical for a small number of parts; however, if the part is not too big and very intricate in shape such as the part that will be studied in the present work, 3D printing can be economical even for an important number of castings to be produced. On the other hand, low pressure casting is a high integrity casting process in which the mold cavity is filled from the bottom via a transfer tube in which the liquid aluminum rises under the pressure applied at the surface of the melt as illustrated in Figure 1. The filling can thus be precisely controlled, eliminating the turbulence created when the mold is filled from the top (gravity casting). Also, the pressure applied on the melt during solidification results in excellent feeding of the casting when conditions of directional solidification are met. In the present work, the compressor impeller shown in Figure 2 will be sand cast by low pressure."

Jan 1, 2018

By Paul G. Dunn

The planning of underground mines is a complicated process involving geological, engineering and operational constraints. MIRARCO is in the process of developing a 5D Mining Exploratorium where 3D mining models are combined with time (4th dimension) and costs (5th dimension). The mining exploratorium is a collection of external and inhouse software packages specifically geared to help underground mining companies arrive at better mine plans. This paper discusses the progress made in the development of the 5D Mining Exploratorium and a change in mine planning philosophy by conducting frequent audits in a Virtual Reality Laboratory. The development of genetic algorithms for optimising stope sequences is also presented.

May 1, 2003

By L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes (Venkataramani, 2002). Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid startup and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate (Heberlein et al., 2007). Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates.Industrial plasmas can be broadly classified as thermal plasmas and non thermal plasmas. Thermal plasmas are atmospheric pressure plasmas characterized by local thermodynamic equilibrium (Boulos et al., 1994). Thermal plasmas are typically established between any two current conducting electrodes separated by an insulator. A plasma forming gas is blown between the two conducting electrodes resulting in a high temperature plasma plume. A plasma torch generates and maintains an electrically conducting gas column between the two electrodes; a cathode (negative electrode) and an anode (positive electrode) (Camacho, 1988). If both electrodes are housed in a single housing, resulting in an arc enclosed inside the plasma torch, then such plasma generating torches are termed as non-transferred (NT) plasma torches, whereas, if the second electrode is external to the torch, creating an arc transferred between the cathode and the working piece, then such plasma torches are termed as transferred (T) plasma torches. Depending on the source of the electricity which can be either direct current (DC), alternating current (AC) at main network frequency or at radio frequency (RF), the plasma torches are classified as DC, AC or RF plasma torches (Venkataramani, 2002)."

Jan 1, 2012

By Fathi Habashi, Ahmet Deniz Bas

"The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgy researchers in the early 1950s who assumed the formation of intermediate surface complexes that could be neither separated nor identified by physicochemical techniques. The electrochemical theory of leaching introduced in the late 1960s resolved this problem by comparing the leaching process to a corrosion phenomenon similar to the corrosion of metals. Few years later, experimental evidence showed that anodic and cathodic zones are formed on the dissolving mineral although no electric current is imposed on the mineral during dissolution. A discussion of these findings is outlined.INTRODUCTIONIn the early 1950s researchers realized that kinetic studies for leaching ores are as important as thermodynamic calculations. It was also during this period that the concept of species adsorption on mineral surfaces has dominated the interpretation of the mechanisms of most reactions. This may have been due to the fact that many researchers of this period came from the mineral dressing sector and were influenced by flotation theories. However, when the knowledge of lattice defects and the semiconductivity of minerals became known and their importance in extractive metallurgy was realized, there was a need to explain the leaching reactions in light of these modern theories (Habashi, 1969, 1970). Semiconducting minerals of importance in metallurgy are two categories: the sulfides such as those of copper, lead, zinc, and the oxides such as those of uranium."

Jan 1, 2016

By A. Alfantazi, E. Asselin

"The corrosion of commercially pure titanium (CP-Ti) was studied from room temperature up to medium temperature (~160°C) under conditions relevant to medium temperature chalcopyrite leaching processes. The corrosion rates were measured by immersion and electrochemical tests in sulfuric acid. The influences of chloride, cupric and ferric ions on the corrosion rate and behavior were also investigated. Corrosion of the CP-Ti did not account for the total current density measured by linear polarization tests. The corrosion rates of CP-Ti under medium temperature leaching conditions were surprisingly high. The corrosion rate measured in ferric containing solution at 160°C was approximately 20 mm/yr.INTRODUCTIONTitanium exhibits excellent corrosion resistance in many aggressive environments because of the formation of a very chemically stable, highly adherent, and protective oxide film on its surface (Mitsuo et al., 2002). Because titanium is the only metal available at a reasonable cost that resists the high temperature corrosive slurries in many leaching processes, it is often chosen as autoclave liner material where it is subjected to severe conditions of acidity, temperature and pressure (Grauman and Say, 2000).A number of distinctly different hydrometallurgical processes for the pressure leaching of chalcopyrite have been developed and patented by various companies and they can be classified into low, medium and high temperature regimes (McDonald and Muir, 2007). For example, chalcopyrite concentrate may be processed at medium temperatures (115-175°C) and pressures of 800-2200 kPa (Dreisinger, D., 2006; Sahu and Asselin, 2011). The lixiviant may contain 20 to 55 g/L sulfuric acid, 8 to 12 g/L chloride ions, 10-25 g/L Cu2+ (Jones, 1995, 1997, 1999), and less than 1 g/L Fe3+ (Defreyne et al., 2005). The amount of these additions is determined by the grade of the ores and details are shown in Table 1."

Jan 1, 2012

By H. J. White

The effect of alloying elements on the mechanical properties and weldability of wrought gamma prime strengthened nickel- base superalloys is well known. An understanding of the basic guidelines concerning alloying additions has led to the invention and development of HAYNES® 282® alloy for applications in aircraft and land base gas turbines and other high-performance high-temperature environments. The alloy combines exceptional high temperature properties with good weldability and fabricability. At high temperatures (~ 900 °C), the alloy is stronger in creep strength than Waspaloy alloy (UNS N07001) and it approaches the creep strength of R-41 alloy (UNS N07041). Because the alloy has better thermal stability, fabricability, and weldability than Waspaloy and R-41 alloys, it is currently being considered as a candidate universal consumable for welding/ repair welding of gamma prime strengthened nickel based superalloys and it is also being considered as a suitable replacement for applications where R- 41, Waspaloy, and 263 (UNS N07263) alloys are currently being used. The alloy was designed to have improved resistance to strain age cracking, a problem common to gamma prime strengthened nickel based superalloys. In this paper, we present (1) results from hot ductility testing of annealed and annealed/aged material; (2) results from Time Resolved X-ray Diffraction (TRXRD) studies during a welding thermal cycle of annealed and annealed/aged material, and (3) gas metal arc (GMA) and gas tungsten arc (GTA) welding of annealed and annealed/aged material.

Jan 1, 2010

By Q. B. Li, B. Gonçalves da Silva, J. T. Germaine, H. H. Einstein, Z. Moradian

"Shale gas and oil production has grown rapidly in recent years, and consequently there are increasing demands to understand the mechanical and microseismic properties of shale. Acoustic emission (AE) monitoring provides useful information on the fracture mechanisms of shale rocks, and provides a basis for interpreting field seismic observations. While there have been attempts for microseismic monitoring of conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted to understand the characteristics of the AE waveforms propagated through Opalinus shale rock in the time and frequency domains. Frequency range, arrival time, first arrival amplitude and other parameters such as counts, duration and energy of the waves generated from artificial and natural sources in the shale specimens were detected and compared with AE characteristics of granite, a brittle rock that has been extensively investigated. The experimental tests showed that there are some important factors that influence the analyses and interpretations of seismic surveys and microseismic monitoring of shale compared to granite. One of these factors is the anisotropic behavior of shale that causes the wave to propagate with different velocities in different directions. Also bedding planes and micro-discontinuities in the shale cause attenuation of the waves. Thus the AE waveforms that arrive at the sensor are a distorted and attenuated versions of the source waveform.INTRODUCTIONMonitoring microseismic activity from hydraulic fracturing of shale provides vital information for mapping injection paths and fluid migration in order to check the effectiveness of the hydraulic fracture stimulation. Analysis of microseismic source locations can be used to identify fracture networks induced or mobilized during the hydraulic fracturing operation (Rotherd and Shapiro, 2003). On the other hand, by monitoring and assessing detected signals from hydraulic fracturing one can evaluate the induced seismic impact of the stimulation operation.While there have been attempts to monitor microseismic events in conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted on Opalinus shale to understand its acoustic emission (AE) characteristics in the time and frequency domains."

Jan 1, 2015

By H. J. McQueen

Pyro-reduction of ores to metal products developed markedly through the industrial revolution into the great depression. Nineteenth century resource and environmental sustainability were haphazardly improved by many process changes, although the motivation was primarily reduction in labor, feed stocks and fuel. Some notable achievements were coke and hot air for blast furnaces (later from waste heat stoves), puddling of wrought iron and steel ingot production with convertors advancing into oxygen use and continuous slab, billet and strip casting. Although advances in one sector were often counteracted by fall-backs in others, there was progress in that the resource consumption and pollution per unit of production was decreased. Improvements in the 2 decades following WW2 were mixed but popular notice of environmental hazards forced governments to legislate pollution controls and initiate steps in resource conservation. The energy crisis of the 1970’s saw an industrial energy-saving campaign and legislation of technology assessment procedures. Up until mid 18th Century, the training of iron masters depended on apprenticeship with some formalized knowledge from medieval books such as those of Biringuccio (1540) and Agricola (1556). The advances were very slow partly due to absence of scientific concepts of the smelting process. Nevertheless, some iron masters succeeded in improving the process and described procedures to instruct others. With the surge of steam power and the reverberatory puddling process for ductile wrought iron (WI), machinery changed from wood (iron strap reinforced) to WI machinery. With the clarification of the reduction and oxidation mechanisms by Cavendish and Lavoisier (~1780), productivity in iron production surged. The mechanical testing and microscopy of Kirkaldy (1862) spurred understanding of processing and properties of WI and steel. The various forms of C in steels were determined by chemists at the end of the 19th Century. It also became possible to control metal and slag chemistry in the open hearth furnace. But understanding of the transformations during heat treatment of steel only came in the first decades of the 20th Century.

Jan 1, 2012

By Jin-Hwa Song

Rolling temperatures and cross rolling ratios were varied to investigate the effect of crystallographic texture of alpha-phase on the anisotropy of mechanical properties in modified Ti-6A1-4V alloy. Hot rolling method was unidirectional and cross rolling, during which the rolling temperature was in the range of 830°C and 920°C. Cross rolling ratios were varied from 0.3 to 1.0 at 875°C. For unidirectional rolling, as the rolling temperature increased texture changed from the mixed basal and transverse texture to the simple transverse texture. Contrary to other work, it was observed that the maximum intensity of transverse components increased with the increase in rolling temperature. For cross rolling, on the other hand, the transverse texture component was almost suppressed at 830°C, giving rise to a symmetrical basal texture. With increasing cross rolling temperature, the transverse texture components developed again. A simple transverse texture, which showed two maxima appearing circularly 90° apart, was observed at 920°C. It was found that unidirectional rolling could not eliminate the transverse texture, which resulted in the anisotropy of mechanical properties. The anisotropy of mechanical properties obtained from tensile and V-notch Charpy test was closely related to the crystallographic texture and its intensity at each rolling condition. To obtain the isotropy of mechanical properties by cross rolling, it is suggested that cross-rolling ratios should be controlled above 0.5. The variation of rolling temperatures and directions has great influence on the anisotropy of impact value rather than tensile strength.

Jan 1, 2004

By T. Niedoba

Coal as an energetic raw material is characterized by many features that determine its quality. The data concerning coal are usually treated as independent values, despite the fact that this kind of approach is not always appropriate. In the paper the dependencies between sulfur contents and volatile components in coal and particle size and density were analyzed. The method of ordinary kriging is applied to experimental data to describe this relationship; this method can be used for particles of any size and density. An example of the application of this technique is presented for energetic coal Type 31, originating from one of the Polish hard coal mines in Upper Silesia. Results from ordinary kriging are in good agreement with experimental results. Similar analyses can be performed for other properties of coal material, such as ash content, Roga number, and moisture. On the basis of the data obtained by ordinary kriging, a more comprehensive multidimensional model is described, which can characterize certain deposits or strata from which the analyzed materials originate. This is superior to basing the model only on experimental data, which often is limited by size of the sample. The results obtained by ordinary kriging applied to various types of coal would allow more precise analysis of individual properties of the studied materials and increase the ability to determine significant differences between them. This method can be also applied to other types of mineral raw materials, such as copper ore.

Aug 1, 2013

By R. L. Christie

"THE ISLANDS lying north of the Canadian mainland, and the large Boothia and Melville peninsulas, form one of the great archipelagos of the world; this sparsely vegetated and nearly unpeopled region extends about 1,500 miles east to west and 1,200 miles from the mainland to the northern tip of the northern-most island. Sea access to most of the islands is restricted by ice to the summer season, and the 'polar pack' ice of the Arctic Ocean presses the year round against the northwest margin of the archipelago. Although the region is remote, the accessibility has greatly increased through a network of weather stations, airfields and air routes connecting with southern centres.The area considered in this paper is that part of the island region underlain mainly by sedimentary rocks. In broad terms, this includes the land and sea areas of the archipelago and the adjacent continental shelf, but excludes the dominantly 'Shield' terrain of Baffin Island, and of Melville and Boothia peninsulas. An impression of the size and potential of this sedimentary region may be gained by comparing some areas: the land area of islands underlain mainly by sedimentary rocks is over 300,000 square miles or about 50,000 square miles greater than the area of Alberta. The total area of the region, including the continental shelf and the inter-island areas, may be double this figure, and may approximate one-seventh of the land area of Canada."

Jan 1, 1970

By G. A. Young

THE Geological Survey was created in 1842 to aid the development of Canada's mineral resources. Although the institution has been in existence for nearly 100 years and has accomplished an immense amount of work, the need for its services remains as great as ever and, indeed, it is difficult to imagine a time when the country will no longer require a Geological Survey. This is so because of the tremendous effort required to make an adequate geological examination of so large an area as is embraced by Canada and partly because what today may seem an adequate geological examination proves, later on, to be inadequate. The ultimate objective of the Geological Survey is to complete the study of all phases of the geology of Canada, that is, to determine how and when the physical features originated, how and when the soils and other unconsolidated deposits were formed, and how and when the solid rocks and associated deposits were produced and assumed their present conditions. When the study has been completed, any only then, will it be possible to make a reliable estimate of the country's mineral resources. This appraisal embraces more than determining the value of already discovered deposits: it also involves attempting to establish what kinds of undiscovered deposits may be present and where they may occur. The estimating of the potential mineral wealth can be clone only after the geology of the country is known. Not until then will it be possible to forecast what types of valued deposits may occur in a district and what types will almost certainly be lacking. A thorough knowledge of the geology of the country is desirable not only to permit estimating the potential mineral resources but also as an aid in locating and developing mineral deposits whether these are of the nature of a bed of limestone, a seam of coal, a reservoir of petroleum, a vein, an irregular body of sulphides, or any other type of deposit.

Jan 1, 1940

By Jayesh B. Patel, Zhongyun Fan, Hu-Tian Li

"Melt conditioned direct-chill (MC-DC) casting is a novel technology which combines vertical direct-chill (DC) casting with a high shear device directly immersed in the sump for in situ microstructural control. In this paper, the solidification mechanism of DC casting under varying conditions is discussed. The temperature profiles in the sump were measured under the steady state casting conditions by using sacrificing thermocouples. Detailed comparisons of the derived thermal condition are made. The individual role of grain refiner additions, natural thermosolutal convection and forced convection in the sump and the interplay of these factors in determining the solidification structures of DC cast billets are discussed. The MC-DC casting technology can be used to control microstructural constituents and casting defects in DC cast billets/ingots by in situ manipulating of the thermal and fluid flow conditions.INTRODUCTION Direct-chill (DC) casting of aluminium, has been the essential commercial process for producing feedstock suitable for subsequent processing, such as extrusion, rolling or forging. Fine and equiaxed grain structures in the as-cast billets/ingots are required to enable a fine and uniform distribution of second phase particles and microporosity. This leads to higher productivity, more cost-effective homogenisation and more efficient downstream thermomechanical processing. The addition of chemical inoculants has been the standard industrial operation prior to casting for grain refinement of Al alloys. However, it has been established that less than 1% of the grain refiner particles added actually act as heterogeneous nuclei to refine the grain structures, showing a very low grain refining efficiency (Greer, Bunn, Tronche, Evans, & Bristow, 2000). Moreover, the remaining particles from the grain refiner addition in the final casting may cause surface defects during downstream processing. A major issue of the metallurgical quality of large sized ingots/billets is the non-uniformity of microstructures even with chemical grain refiner additions. This is due to the fact that the grain structure formed in the different zones of the billet depends on the local chemical composition and local cooling rate. The local cooling rate can vary from 0.4~1 K/s at the centre of the billet to around 10–20 K/s at its surface zone (Nadella, Eskin, Du, & Katgerman, 2008). The large thermal gradient along radial direction between billet surface and interior of the melt during conventional DC casting induces thermal stress and cold cracking even with grain refiner addition. Therefore the control of casting defects, such as macrosegregation, porosity, cold/hot cracking and distortion of the billets/slabs, etc., is still challenging in industry, causing high scrap rate of DC cast ingots/billets even with grain refiner addition."

Jan 1, 2018