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By R. L. Bailey

"The Acheson D-3 Pool was discovered in August 1950, and contains 88 producing oil wells on 40 acre spacing. Initial oil-in-place was 118 million stock tank barrels and initial well potentials averaged 2,000 barrels per day.In early 1956 studies of hydraulic interference between the Acheson and Leduc D-3 Pools were conducted on the Carter Petroleum Reservoir Analyzer. These studies indicated that the natural water drive to Acheson would be incapable of replacing reasonable withdrawal rates over the life of the pool. To avoid shrinkage losses a scheme of pressure maintenance by water• injection was therefore instituted in March 1957.This pressure maintenance scheme is notable because pressure is being effectively maintained by high volume injection through one well located on the flank of the pool. Close control on reservoir behaviour is maintained by regular bottom-hole pres-sure surveys and observation of water cuts on producing wells. No evidence of pressure gradients or channelling of the injected water has been observed to date, and the water-oil contact has remained level over the whole field. It is possible to control the average reservoir pressure within very close limits by varying the rate of fresh water injection.Ultimate recovery estimated from the rise of the oil-water contact and calculated water influx to December 31, 1958, is 335 barrels per acre foot, or a total of 91.4 million barrels from the pool. This compares to 217 barrels Per acre foot or a total of 59.4 million barrels indicated from laboratory test data."

Jan 1, 1961

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By J. A. González-Anaya, F. Nava-Alonso, O. Alonso-González, F. Alvarado-Hernandez, A. Uribe-Salas, C. Jimenez-Velasco

"One of the most common hydrometallurgical methods for precious metal extraction is cyanidation. The effluents of this process may contain relatively high concentrations of copper, zinc and iron, which react with free cyanide to form complexes, adversely affecting the efficiency and the economy of the process.This preliminary work studies the use of the solvent extraction technique to remove copper, zinc and iron cyanide complexes from a synthetic solution similar to that of gold mill effluents, in order to allow the recycling of the solution back to the process. For the extraction of these anions (Cu(CN)2 -, Cu(CN)3 2-, Cu(CN)4 3-, Zn(CN)4 2- and Fe(CN)6 3-), trioctyl methyl ammonium chloride (Aliquat 336) was studied as extractant, using nonylphenol as modifier in the organic phase (iso-octane). The experimental results showed that for a synthetic solution containing 450 mg/L total cyanide, 160 mg/L copper, 50 mg/L zinc and 51 mg/L iron, it is possible to extract the 96% of copper, 91% of zinc and 75% of iron when using 0.011 mol/L of Aliquat 336 (organic/aqueous volume ratio (O/A) =1) in the pH range of 9-10."

Jan 1, 2014

By C. E. Lancelle, J. T. Volk, H. F. Wang, D. Fratta

"The Main Injector Neutrino Oscillation Search (MINOS) Near Detector Hall at Fermilab and the Lafarge – Conco Mine are located approximately 100 meters underground in the Galena-Platteville dolomite just below its contact with the overlying Maquoketa shale in Northeastern Illinois, USA. A new cavern was excavated adjacent to the MINOS Near Detector Hall at Fermilab to house the near detector for the Off-axis Neutrino Appearance Experiment (NOvA) program. During this excavation approximately 1150 cubic meters of shale rock were removed. Tiltmeter arrays consisting of a series of hydrostatic leveling sensors (HLS), which are spaced regularly over a total distance of 50-to-100 meters, were used to monitor subsurface deformations. The tiltmeter response in the MINOS Near Detector Hall due to the NOvA cavern excavation is approximately thirteen times the estimated response based on using laboratorydetermined properties. The discrepancy between modeled and measured tilt is likely due to differences in Young’s Modulus in the rock mass versus in a small laboratory sample. Amplitudes of measured solid earth tides differ from the amplitudes of theoretical solid earth tides by up to 40 percent for both arrays. This is likely due to a local heterogeneity or discontinuity.INTRODUCTIONLong baseline tiltmeters have been used to record small earth movements since the early 1900s. One of the first studies using long baseline tiltmeters to measure earth tides was published by Michelson (1914). He used a leveled 152-meter long, 0.15-meter diameter tube half-filled with water connecting two concrete-lined pits. The pipe was trenched 1.75 meters underground in Williams Bay, Wisconsin in a sandy-clay soil. Initially only an east-west line was used, though a north-south line was added after it was seen that viable results were obtained. Measurements were made by hand either hourly or once every two hours depending on the time of day. When compared to 0.7 times the calculated earth tides, the tiltmeter signal matched almost exactly. This excellent result began the use of long baseline tiltmeters to measure small earth movements."

Jan 1, 2015

By C. H. B. Leitch, T. N. MacAuley, R. L. Linnen, A. E. Williams-Jones

"The Trout Lake stockwork molybdenum deposit is temporally and spatially related to the emplacement of a late Cretaceous granodiorite-tonalite stock in southeastern British Columbia and contains an estimated 49 million tonnes grading O.I9% MoS2- No metal zonation patterns are apparent, with the exception of peripheral tungsten skarn, and exploration was guided largely by geological interpretation. It is typical of the granodiorite, or fluorine-poor type of molybdenum deposit. Molybdenite is contained within a quartz-feldspar vein stockwork and coeval dissemination in igneous (and less commonly metasedimentary) hosts. In general, molybdenite is strongly associated with alkali feldspars, but in detail it is intimately associated with incipient muscovite replacement of albite and K-feldspar; veins that lack feldspars are also typically barren of molybdenite. These textures suggest that fe/dspathic alteration (and precipitation in veins) was an important precursor to mineralization, and the occurrence of similar textures elsewhere (e.g. Henderson) suggest that early feldspathic alteration is important to the genesis of molybdenum deposits in general. Molybdenite deposition at Trout Lake was preceded by contact metamorphism, skarn and potassic alteration, and was overprinted by muscovite-ankerite (phyllic) alteration. Only moderate temperature changes are recorded by the metamorphic and alteration mineral assemblages (350°C to 450°C}; however, with time, fluids became increasingly more acidic and enriched in C02- In light of the intimate molybdenitemuscovite intergrowths, the decrease of pH probably exerted a major control on mineralization.IntroductionGranite-hosted molybdenum deposits can be classified in terms of the composition of the related intrusion, e.g., the granodiorite and granite types of Mutschler et a!. (1981), or the calc-alkaline, alkali-calcic, and alkalic types of Westra and Keith (1981). They have also been classified on the basis of their fluorine contents (Theodore and Menzie, 1984) with the fluorine-rich and -poor varieties roughly corresponding to granite- and granodiorite-type deposits, respectively. For economic reasons, most exploration and research has concentrated on the high-grade/large tonnage granite-type of deposit, exemplified by Climax. F1uorine-poor, granodiorite-type deposits are, however, the most common type in Canada and have been mined in the past (e.g., Endako). In this paper, the authors summarize the research that has been carried out on the fluorinepoor Trout Lake deposit (Boyle and Leitch, 1983; Linnen, 1985; Linnen and Williams-Jones, 1987; 1990) and use what has been learned to develop guidelines for the future exploration of fluorinepoor, granodiorite-type molybdenum deposits."

Jan 1, 1995

By John Stoten

"The 1980s have proven extremely difficult years for many resource-based organizations. Mining companies have learned how to weather the negative effects of inevitable economic cycles. However, with some notable exceptions, such as gold mining companies, the mining industry has faced a broader and deeper round of cutbacks than any experienced since the 1930s. Downsizing has been a major issue for many mining companies as they have faced the need for dramatic staffing cost reductions in the recent past.The continuing current rapid rate of change in technology and the marketplace, coupled with increasing merger and acquisition activity, will provide an on-going need for some companies to face major reorganization. This inevitably will involve down-sizing activity in some instances.Given this scenario, it is worth reviewing the industry's past experiences to identify approaches and techniques that could prove of value in handling a future staff downsizing challenge. This paper is based upon a downsizing consultant's experiences with the mining industry and other sectors, and highlights what appear to be key staff reduction planning and process issues.Planning for DownsizingA review of companies' downsizing activities of the last few years reveals four key activity stages which need to be addressed to ensure a successful transition. These stages are:1. organization planning;2. developing cost reduction strategies;3. implementing downsizing; and4. building for the future.A business situation that is severe enough to require drastic staff cuts typically affects all aspects of a company's operations. Most mining companies have reviewed cost efficiencies in many operational areas. However, these reviews often have been short term in focus . As a result, some companies have experienced multiple downsizing; each event a response to an immediate economic threat. This has sometimes resulted in an unstable organizational environment, with severe stresses on staff morale and productivity.In the long term it is more efficient and less stressful to the organization to adopt a more comprehensive and longer-term strategy. Especially in capital intensive mining operations, it makes sense to review all areas of business activity, not just staffing."

Jan 1, 1989

By J-F. Turgeon, Y. Pépin, G. Hudon

The high temperature hydrochloric acid leaching of titanium slag in the QIT upgraded slag process (UGS) creates a harsh environment for materials of construction. Because of their excellent chemical and heat resistance, furan mortars are a key component in the lining system of the UGS pressure leach reactors. Similar products coming from different manufacturers have however shown unequal performances in service. In some cases, cracking of the brick lining has occurred during curing of the mortar. This study was initiated to investigate the impact of the curing conditions on the properties of carbon filled furan mortars. Laboratory tests were conducted to assess the effects of temperature and exposure to water and HCl solutions on mortar shrinkage and mechanical properties (tensile, compressive and bond strength). Three commercial furan mortars that have been used in the UGS leach reactors were thus characterized. Mortar properties were found to vary significantly among the products tested. Moreover, the curing conditions were shown to have a significant impact on mortar shrinkage and mechanical strength. The experimental findings provide explanations for the unequal performances of the mortars in service and for the problems of brick lining cracking that occurred in the UGS leach reactors. This study demonstrates that excessive mortar shrinkage compromises the integrity of a brick lining system.

Jan 1, 2004

By R. A. Wyman, F. E. Hanes

THE demand for high-quality aggregate is increasing in all phases of the construction industry and in all organizations associated with road building in Canada. The production of aggregate in Canada has increased almost continuously since the end of the war and has quadrupled since 1948. Increases during the past fifteen years can be accounted for by the expansion in all types of construction, particularly that of roads and highways. Total construction in 1959, based on preliminary estimates, has been valued at $7 billion, and an increase fore-cast for 1960 indicates optimism on the •construction horizon (1). Cement produced in Canada in 1959 amounted to 6.3 million tons. This is more than 2.5 times the 1948 production. Increased cement production indicates an increased use of concrete, and thus an increased need for aggregate. Natural sand and gravel deposits are gradually being depleted.

Jan 1, 1962

By Christiaan Zeilstra, Jan van der Stel, Koen Meijer, Gerard Louwerse, Tim Peeters

The steel industry is producing about 5% of the world wide CO2 emission. Therefore the European steel industry has defined a research program to reduce the CO2 emission by 50% per ton: ULCOS. Since its start in 2004 ULCOS has identified four technologies for further development. Two of these technologies which produce liquid hot metal are discussed. The ULCOS blast furnace is based on recycling of decarbonated topgas and the capture and storage of CO2. The concept has been demonstrated during three campaigns at LKAB EBF in Luleå, Sweden. The smelting reduction process HIsarna is a combination of the cyclone-technology and Hismelt. The process has been demonstrated successfully in four campaigns at a pilot installation on the IJmuiden steelmaking site.

Jan 1, 2015

By R. W. Culley

"In many areas of Saskatchewan, known gravel deposits have been depleted or are diminishing rapidly; in other areas, particularly in the north, demands for all-weather highways and access roads are far exceeding the supply of gravel sources with which to surface them. These two problems have made conventional methods of air-photo and ground surveys insufficient for gravel location. In the first case, hauling costs on construction now warrant searching for buried deposits and for smaller, less obvious surficial deposits that may be closer to the project. In the second case, search and access conditions are so difficult and costly that the ratio of successes to failures must be kept very high. The Department of Highways has long been aware of the oncoming scarcity of quality gravel deposits and is continually investigating ways of forestalling it. One of these ways is the use of airborne geophysical methods that permit rapid coverage of large areas and that sense and discriminate between earth properties to a significant depth below ground surface. In 1967, the Department began an investigation of an airborne conductivity survey method called INPUT*, or ""Induced Pulse Transient'', leading to a trial in 1968 and data analysis in 1969. The results of this trial initiated• modifications to the technique to improve its sensitivity for mapping shallow deposits. Part way through this modification in 1970, a decision was made to change to an airborne resistivity survey method called EPHASE*. Trials with this technique were conducted and analysed in 1971. This paper is an explanation of the E-PHASE system and a summary of the results from one of three areas mapped in 1971."

Jan 1, 1973

This paper describes the results of a laboratory study on the upgrading of Algoma siderite by the amine flotation of silica and silicate gangue. The experiments indicate that a virtually complete removal of silica is possible in a rougher flotation con-ducted in tap water at natural pH, without prior desliming of the ore. Grinding considerably finer than the apparent liberation size is essential for maximum silica rejection. A cationic collector, Aeromine 3037, gave best results when used in combination with a modifier. Of the several modifiers tested, a Dutch potato dextrin, Dextrin 4356, was found to be the most effective. Both iron recovery and the grade of the final iron product are enhanced by floating the pyrite contained in the ore prior to the amine flotation of the silica, and by scalping the magnetics from the silica concentrate. F OR over twenty years, the Algoma Ore Properties Division of The Algoma Steel

Jan 1, 1963

"In many gold deposits, a reasonable amount of the gold that remains in the cyanide leach tailing is associated with pyrite. Some gold plants have found it economical to incorporate gravity circuits on the cyanide leach tailing to recover the gold bearing pyrite before subjecting it to fine grinding, then recycling the ground pyrite back to the cyanide leach circuit. For low grade gold deposits the loss of gold bearing pyrite is exacerbated as the broader process economics normally favour a coarse grind (> 150 ?m). An option that has received attention over the last decade is to recover the gold bearing sulphides in the milling circuit by gravity, similar to the widely-practiced gravity recovery of free liberated gold. The modelling and simulation of a gravity gold circuit in a milling flowsheet is relatively simple compared with a gold bearing pyrite circuit, as the recycle advantages and breakage functions for gold and pyrite are quite different. This current work represents an attempt to simulate the gravity recovery of gold bearing sulphides in a milling circuit that also incorporates fine grinding, using relatively simple simulation models. The simulation results are further explored with reference to the economics of this type of circuit.INTRODUCTION It is well known that gold is associated with pyrite in most sulphide gold deposits and that the amount of gold associated with pyrite will vary from deposit to deposit. Most of the gold associated with pyrite is liberated in the grinding circuit during the processing of a gold ore. However, some gold remains occluded in the pyrite and is lost in the final leach tailings. Little information is available in the literature on methods to enhance gold liberation from pyrite by specifically removing pyrite, either in the grinding circuit or from the final tailings stream, and grinding it finer. One of the earliest record of this approach is described by King (King, 1949) where pyrite present in Witwatersrand gold ores was recovered by circular jigs and Johnson barrels followed by fine grinding of the concentrate prior to cyanide leaching. Dominy et al., 1970, provides information on the use of Yuba jigs to recover pyrite from the discharge end of ball mills. Again, the jig concentrate was ground to a fine particle size before cyanide leaching to recover the liberated gold. Unfortunately, no information is provided in these articles on the additional gold recovery from implementing these circuits in a flowsheet. Martins et al., 1993, provides details of a gravity circuit using Reichert cones and spirals to recover gold bearing pyrite from a cyanide leach tailings followed by fine grinding of the pyrite concentrate in a Tower mill. The ground concentrate returned to the front end of the already installed leach circuit. Overall recoveries were increased by some 2% to 4% depending on the amount of gold and pyrite in the plant feed."

Jan 1, 2017

By T. Feldmann, G. P. Demopoulos

The adsorption of gold complexes on inorganic metal oxides has been mainly discussed in geochemical literature, but it is also of interest to the hydrometallurgical industry. This is so because it could be responsible for valuable metal losses or because it could potentially serve as alternative adsorbent material to activated carbon in certain cases such as from hot and acidic process slurries. This paper constitutes an early investigation into this subject by focusing on the effectiveness of FeOOH, Fe3O4 and Al2O3 as sorbent materials. All tests were done in a batch stirred-tank reactor under atmospheric conditions with synthetic gold(III)-chloride solutions at 23°C and 80°C, in the pH range of 1.6 to 9.0. Detailed kinetic tests were performed at different pH values (3 and 6) on FeOOH and Fe3O4 with solutions having gold concentrations from 5 mg/L to 130 mg/L. The adsorption of gold was found to be best both in terms of kinetics and loading characteristics at 80°C and pH=6. This was explained by a change in Au(III)-Cl speciation from a gold(III)-chloride complex to a gold(III)-chloride-hydroxy complex. By far, magnetite (reagent grade chemical) yielded the best gold adsorption characteristics making it an interesting sorbent material for further development considering that it can be advantageously recovered from slurry streams via magnetic separation. On the other hand, the tendency of gold(III)-chloro complexes to adsorb on metal (hydro) oxides needs to be taken into account to minimize undesirable metal losses in chloride-containing leaching media.

Jan 1, 2015

By R. S. Douglas

THE Granby Consolidated Mining, Smelting and Power Company, Limited, is engaged in the mining and concentrating of copper ores, and, incidentally, in the mining of coal and the production of electric power. The Company has been engaged in these various operations both on the mainland of British Columbia and on Vancouver island for the past forty-five years. This paper will attempt to cover their present operations in the Similkameen mining district of southern interior British Columbia. GENERAL CHARACTER OF THE DISTRICT The Interior Plateau in southern British Columbia ranges in elevation from 3,000 feet to 6,000 feet. In the vicinity of Princet0n, a depression in the Plateau forms a well defined basin which is floored with a series of nearly flat-lying Tertiary sediments containing some workable seams of lignite. From this basin, the upland surface rises gradually t0ward the south, from an elevation of 2,000 feet at Princet0n to 4,000 feet at Copper mountain, and 6,000 feet in the upper parts of the Similkameen basin, where it merges into the rugged and diversified t0pography of the Cascade system, with glacier inhabited peaks rising to over 9,000 feet. The valleys of Similkameen river and its tributaries are wide, having flaring sides and gentle slopes, and are separated one from another by subdued rounded spurs, of which Copper mountain is typical. The drainage of this district is taken care of by Similkameen river and its larger tributaries, such as Pasayten river, and Wolfe, Friday, and Whipsaw creeks. The name Copper mountain is applied to a gently arched, nearly flat-topped spur between the deep valley of Similkameen river to the west and the shallower valley of Wolfe creek tO the east. The mountain is appro-priately named from the number of copper deposits occurring on its sides and summit, some of which have been developed int0 an important producer, known as the Copper Mountain mine.

Jan 1, 1943

By George Wilkinson

"AbstractThe consistent relationship between the availability of electrical energy and our economic wellbeing is well known. As we develop the energy we need to nurture industrial civilization in decades ahead, we will at the same time reduce our reliance on dwindling supplies of oil and gas. Coal and uranium will be developed as our major fuel sources to meet medium-term. energy needs, followed by fusion and solar energy for the long term.IntroductionTHIS PAPER treats the matter of energy in a way that is quite different from that of the crisis-type atmosphere which surrounds so much of it currently in the news media. On the one hand, we lift the whole subject of energy out from its present-day involvement with short-term issues and take an important longer-term look at the solutions which lie before us. On the other hand, we recognize that short-term issues are important and, as we are reading and hearing, many of the right short-term solutions continue to elude our politicians, our policy makers, and even some of those with knowledge and authority in the energy field.A year ago, if you asked people how they would go about conserving energy, they would probably have said turn out the lights. They would probably say the same thing today, but they might also include other things such as driving the automobile more slowly or putting more insulation in the attic. However, their first impulse is still to use less electricity."

Jan 1, 1977

By J. J. Denny

IN November, 1932, an investigation of silicosis was undertaken at the Mcintyre Porcupine mine, Schumacher, Ont., after a discussion of the p"roblem with Sir Frederick Banting and his staff. As a result, it was decided to carry on dusting experiments with animals at the mine in a manner that would duplicate as far as possible actual industrial conditions. At that time 50 guinea pigs were placed in the crusher house tunnel of the mill where a considerable quantity of fine dust, containing approximately 35 per cent of free silica, was being constantly produced. These animals lived in this atmosphere for periods up to one year, and, while on autopsy large amounts of dust were found in the lungs, not a single case of silicosis had developed. These negative results suggested, among other things, that the mine gases might be a predisposing factor in the production of silicosis, and the results of this investigation (1) led us to undertake the study of the hydrogen-ion concentration of the condensate of the atmosphere, both in the mine and in various sections of the mill. The CO, combining power of blood serum on a series of 400 miners was also studied at this time. While these results were inconclusive, the variation in the hydrogen-ion concentration of the condensate between the surface and underground atmospheres encouraged us to investigate the effect of neutral, weak acid, and alkaline solutions on the solubility of siliceous materials. Gye and Purdy (2) were the first to point out that the chemical reaction, and not the physical presence of siliceous material, was responsible for the production of the fibrosis in silicosis. This work was investigated by Gardner and Cummings (3), who showed that the tissue reaction to quartz was definitely proportional to the size of the particle. They found that 1-3 micron particles of quartz produced an acute proliferative fibrotic response, while the 10-12 micron particles produced only a foreign-body reaction up to a period of three years. It is accepted that the dangerous silica particles retained by the lung are under 5 microns in diameter.

Jan 1, 1937

By R. Blazej

Machinery Systems Division (MSD) in the Institute of Mining Engineering at Wroclaw University of Technology specializes in belt conveying systems analyzing, calculating and design. Within the division operates the certified Laboratory of Belt Transportation (LTT) and Laboratory of Rollers. Since few years, a group of several people have begun work on developing a comprehensive system for the automatic evaluation of condition of conveyor belts working in the mines. Group uses both magnetic devices developed by specialized companies servicing belts and its own machine vision system developed for assessment of belts covers and edges during belt movement (up to 7 m / s) on the specially designed for this purpose the test conveyor. Recently they have got the research grant funded by the National Centre for Research and Development (NCBiR) for development of the system for automatic diagnosing of conveyor belts? condition and aiding of rational belt management. On the basis of previously created diagnostic tool called ABCDE (Automatic Belt Condition Diagnostic Equipment) the five modules: vision-A magnetic-B, preventive-C, forecasting?D, and determining safety factor-E will be developed. They will automatically interpret data about conveyor belts? condition to indicate the extent and timing of repairs, to prevent failures and to select the optimum moments for their replacements. The system will use results of ongoing research & development and planned research concerning modeling of belt wear using evolutionary genetic algorithms. The reached stage of research can not yet allow to start the implementation work by potential users. It is therefore necessary to pursuit research in real scale, the development of new modules (C-E) and intensive testing of the system in working condition with system calibration to optimize the economic effects.

Aug 1, 2013

By J. K. Shaw

The science of low temperature engineering is well entrenched in mining. Uses for common cryogens, including liquid oxygen (LOX), liquid nitrogen (LN2), and liquefied natural gas (LNG) in the gas and minerals industries are reviewed. Potential future applications are discussed within the scope of mining, particularly in refrigeration and ventilation. The second part of this paper focuses on the Linde cycle, which is at the heart of most liquefaction plants. Steady state equations describing the mass and energy flows are presented. The paper concludes by explaining the concept of a wind powered Linde- Hampson cryogenic cycle and assessing, with scoping calculations, the technological feasibility of producing cryogens with an intermittent source of (renewable) energy.

Aug 1, 2013

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

By R. F. Robertson

"Adsorption isotherms of hexyl mercaptan vapour on synthetic sphalerite, zinc sulphide and zinc oxide were de-termined with a gravimetric McBain-Baker micro balance incorporated in the B.E.T. apparatus. Isotherms are given for hexyl mercaptan on synthetic sphalerite at 25°C, 0.5°C and 50°C; on zinc sulphide at 25°C and 1.5°C; and on zinc oxide at 25°C. All these isotherms are sigmoidal, with a definite change in slope at or close to the mono-layer. The amount of mercaptan adsorbed below the monolayer increases almost linearly with relative pressure to P/P0 = 0.8.Above this value, the amount adsorbed increases very rapidly with relative pressure. Hysteresis loops appear in the isotherms for all adsorption-desorption cycles. These loops are completely reversible. It is not possible to desorb the mercaptan monolayer from any of the adsorbents, even at elevated temperatures."

Jan 1, 1966