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By Rolfe PR, Ellis BA, Clements RJ

Associated Minerals Consolidated Limited (AMC) is constructing a 112,500 tonne/yr synthetic rutile plant at Narngulu, near Geraldton in Western Australia. Design of the plant is based on the technology developed by AMC and utilised in its two existing plants at Capel in Western Australia. Ilmenite Feedstock for the plant will be sourced from AMC's mine at Eneabba and coal obtained from the Collie deposits. The plant is scheduled to come on stream in the second quarter of calendar 1987. The rationale of the decision to construct the Narngulu plant is examined against the background of the world market for high-Ti02 content feedstocks. Also provided is a detailed description of the plant and an examination of the technology used in process Design.

Jan 1, 1986

By B Shi, Y Li, L Ma, F Zhou

Subsurface fires are a common threat to coal mining, as spontaneous combustion of coal can potentially result in gas combustion and explosion. Fire-proof techniques, such as grouting, foam, or colloid injection, are not in a position to function ideally, due to the limited coverage and stopping the extinguishment substance from reaching the fire location. Liquid nitrogen, as a kind of all-submerged fire prevention or extinguishing method, can rapidly extinguish fires, thus preventing gas explosion and minimising extinguishment time. Injecting liquid nitrogen through boreholes is an important way during the period of mine catastrophe. But liquid nitrogen is not effective enough in infusion; technical issues restrict the development and utilisation of liquid nitrogen fire prevention and extinguishing technology. Immediate infusion of liquid nitrogen is usually associated with ‘air slug’ (the balloons and bubbles in the pipeline which hinder the flow of low-temperature liquid), which blocks pipelines for liquid nitrogen injecting. Another issue is that the pipeline tends to be damaged due to freezing, which undermines the injecting efficiency of liquid nitrogen and its application result. In order to solve the problems of the low efficiency and some other related field issues in liquid nitrogen perfusion, the ground–underground high efficiency liquid nitrogen injection technology were developed. Implementation of liquid nitrogen infusion techniques in Chinese coalmines achieved the goals of fire prevention and air-cooling. The technique presented in this paper is efficient in absorbing heat, and consequently, displacing oxygen and combustible gases. Field tests at Rujigou and Yangchangwan Coalmine justified the efficiency of the technique. By using this technique, there was no waste left behind, which may impede the subsequent production. The presented technique is of great benefit to the social, economic, and environmental aspects of mining operations, and will have broad applications in fire prevention for large-scale coalmines.CITATION:Zhou, F, Shi, B, Li, Y and Ma, L, 2015. Key techniques and engineering applications of stereoscopic liquid nitrogen infusion for coalmine fire prevention, in Proceedings The Australian Mine Ventilation Conference, pp 291–298 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

The performance of the Australian Mining Industry over the past 10 years using key indicators of production, revenue, aftertax return investment, together with key cost elements, market changes and ore reserves is briefly reviewed. The elements of competitiveness are discussed forthe industry and the effects of Government charges and policies relating to existing operations are outlined. There is a demonstrated need for improvements in competitiveness in direct and indirect costs and for improved access to resources for the mining industry to continue to grow and add to Australia's economic growth.

Jan 1, 1987

By M Rafty, C Lane

Managing water is a key aspect of mining, whether a site is in water surplus or water deficit. Water in tailings storage facilities (TSFs) needs to be managed carefully to maximise the density of the solids, maximise the re-use of available water and to minimise the risk of water overtopping the spillway in the event of heavy rainfall. Developing a water balance models is a standard method for monitoring the major flows of water around a site. However, models created by specialist consultants are often overly complex and are not suited to being used by process plant personnel after they have been handed over to the mine operator. Models typically offer information on water management at the time that they are created, but then ‘sit on the shelf’ and offer no further insight or value for operating mines. Advisian has developed a customised water balance model for a mine in Sub-Saharan Africa, which can be adapted to other locations, to assist in managing water at the site and in particular to predict the current and future water level and volume in the TSF under various rainfall scenarios. The model was developed using Microsoft Excel and requires no specialist skills to operate. Site personnel enter in daily production, water transfer and rainfall data and then view the output dashboards to observe the current water level and volume, decant rates, licensed water abstraction and water supply versus demand. The output dashboards were developed in close consultation with the client to ensure that all of the relevant key performance indicators were included, from the perspectives of all the key stakeholders. This modelling approach focusses on the needs of the people who will actually use the model to actively manage TSFs with the need to involve the model developer as part of ongoing operations eliminated. The simplicity of this approach is now being embraced by other mine sites in Africa and Australia. CITATION:Rafty, M and Lane, C, 2018. Water balance management 101, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 485–490 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By I Lamb

Past experience of ground settlement and groundwater monitoring for tunnelling projects in Melbourne has provided an appreciation of the value and importance to owners of establishing a broad baseline monitoring program of the ground surface movements and groundwater movements well in advance of the commencement of any excavation and tunnelling activities. For the Northern Sewerage Project (NSP) tunnels in the northern suburbs of Melbourne, a baseline monitoring network of ground settlement points and groundwater wells was established in early 2006, 18 months prior to the commencement of project construction, and has continued throughout the tunnelling and project construction activities. This baseline monitoring network provides insights into the superposition and interpretation of both tunnelling and non-tunnelling effects, such as seasonal effects, which result in ground settlement.In the case of the NSP the baseline monitoring and construction phase excavations coincided with several years of drought. The reduced rainfall developed overall downward settlement trends project wide that could easily be mistaken at the local site level to be construction effects if the baseline monitoring was not available to show otherwise. There are lessons to be learned from the NSP experience for tunnel projects where there are variable surface soil types and where project-specific settlement criteria are to be established for the protection of property prior to construction.This paper presents examples of the baseline monitoring, how the tunnelling-specific settlement was identified and determined, and what this means in terms of how settlement criteria should be established and set for project consenting and in the construction contract documents.

Mar 8, 2011

By E Rubio, N Morales

A common practice in the mining industry is to decompose the planning process into different tasks, so the overall process and specific schedules can be constructed easily. Nevertheless, currently there are some adverse effects, such as not capturing the real value of a project by not taking into account the construction of several underground drifts and general infrastructure. Then the common practice is to compute mining sequence and cut-off grade profiles over the life of the mine without constitutively integrating the development schedule as a means to measure the constructability of a given mine design and sequence. Thus, the investigation summarised in this paper shows a novel, integrative way of treating an underground mine sequence and production schedule while considering drift development scheduling. Moreover, it is thought that, because of this original model, the whole underground production scheduling exercise must concentrate on combining the development and the production scheduling to compute a robust and a feasible production schedule.In order to quantify the effect of the conventional way of viewing the planning, the concept of the building information model (BIM) needs to be used, which was postulated by Charles Eastman and has been used extensively since the late 1970s. BIM takes other aspects of a project into account, considering at the same time the spatial relationships, quantities and properties of building components, but especially some kind of model visualisation, which is the advantage to be incorporated. This paper presents the basis for an optimisation model that allows for defining the sequence of the mining development so that the production plan can be achieved. For this, the model considers the space dimensions, time, pattern or strategy, cost or benefit, precedence and resources available. Tests were performed considering a block caving and sublevel open stoping method. Finally these tests showed the main conclusion, that production sequence changes when the building capacity is considered.

Sep 26, 2011

By G Sartor, A Rich, D Grimsey, R Forzatti, M White

An in-depth process model was developed for the pyrometallurgical, off-gas systems and water balance of the Kalgoorlie Nickel Smelter. This model was used to assess plant capacity with changing concentrate grades, increased throughput and tighter environmental emissions under a range of potential future operating conditions. Comparison of modelled results allowed for flow sheet optimisation across a range of metrics including sustainability, processing capacity and costs. Process modelling software, METSIM® (ver 2020.06 by METSIM International), was used to simulate the flash furnace, integrated electric slag cleaning furnace, Pierce-Smith converters, matte granulation, waste heat boiler, hot gas handling equipment, wet gas cleaning plant and acid plant. The METSIM® model was divided into three separate, yet interconnected models: metals, off-gas and water balancing. This allowed for improved modelling efficiency and traceability while minimising manual error. The METSIM® model was supported by inputs from other specialised software. Chemical thermodynamics software, FactSage™ (ver 8.2 by GTT Technologies), was used to establish relationships for the flash furnace fluxing strategy and determine the operating temperature. Arena® (ver 16.0 by Rockwell Automation), a discrete event modelling software, was used to simulate material movements within the aisle as well as Pierce-Smith converter operation, allowing for integration with upstream and downstream systems. A dynamic data exchange (DDE) was used to connect the results of each software package, interfacing through Excel® (version 4203 by Microsoft). The integration between models provided a streamlined approach to test capacity, bottlenecks, water consumption and emissions under a range of operating conditions, enabling a more robust process. Further downstream modelling techniques were used to assess mechanical equipment. METSIM® outputs provided key parameters for combustion assessments using computational fluid dynamics and finite element analysis for the furnace mechanical design.

Aug 21, 2024

By K J. McDonald

All commercially available zircon sands contain radioactivity sourcing from the decay of trace amounts of contained uranium (U) and thorium (Th). The fine particle size zircons of the Horsham area in the Murray Basin region of Victoria, Australia, contain significantly more (about twice) Th+U than those commercial zircon sands. The marketability of these fine-grained zircon sands is likely to rely on the removal of these radioactive impurities. CSIRO Minerals have been working for some time to develop processes for the removal of the radioactive impurities from zircon. It is generally agreed that it is quite impossible to leach U and Th from zircon, however, the Heat and Leach (HL) process, described in detail in Aral and McDonald (1999), reduces the radionuclide levels significantly. The identified (HL) process aims to leach uranium and thorium selectively from a decomposed zircon. The novelty of the process is that a large part of the leached product can be reconstituted to a low radiation zircon by a subsequent heat treatment. The HL process uses a flux mixture of sodium carbonate and calcium borate to decompose the zircon at relatively low temperatures (900 to 1150¦C) and a weak acid (0.5M HNO3; 80¦C/0.5 h; pulp density ten per cent) to leach the radionuclides selectively. The process leaves the major components (ZrO2 and SiO2) behind with little loss. The HL process for example lowers the U+Th content of a Murray Basin zircon from 1000 ppm to 400 ppm U+Th. Among the radionuclides more U progeny is removed than the Th series radionuclides. This is very significant as the radioactivity of U series is 2.5 times more that from the Th series. Therefore the reduction in the radioactivity level of zircon is more than the reduction in Th+U indicated by XRF analysis. A schematic flow sheet of the HL process is shown in Figure 1. Although the HL process successfully lowers the radionuclide levels in zircon sands, the final product contains significant amounts of sodium (up to 14 per cent Na2O) and small amounts of CaO. By comparison, the sodium content of the commercial zircon sands is in general 2O. Zircon is used mainly as an opacifier in tile glazing where the addition of ten to 15 per cent zircon to a translucent base glaze gives the sanitary white colour to the tile surface. Opacification is the result of the refractoriness of zircon particles at the glaze firing temperatures that is generally around 1050¦C.

Jan 1, 2001

The Highlands Region of Papua New Guinea has 3 major national highways. The locations of these national highways are shown in Figure 1. The Highlands Highway begins at Lae City on the coast and passes through the Highlands towns of Goroka, Kundiawa and Mt Hagen. It terminates at Togoba approximately 10km out of Mt Hagen town. The Enga Highway begins at Togoba and passes through the towns of Wapenamanda, Wabag and Laiagam. It terminates at the giant Porgera Gold Mine. The Southern Highlands Highway also begins at Togoba and passes through the major towns of Mendi, and Tari. It terminates at Koroba station, near the Hides Gas Field. Two separate Feeder roads intersecting the main highway service both the Kutubu Oil Project and the Hides Gas Field. These national Highways play a very important role in the development of Papua New Guinea. Goods and services are delivered to the bulk of the population of the Highlands Region using these highways. Heavy machinery and equipment for the mining and petroleum projects of Porgera, Hides and Kutubu are transported using these roads.

Jan 1, 1997

By A J. Burchell

The introduction reviews the tunnelling carried out in Singapore since the early 1980s. Between 1983 and 1990, Phases 1 and 2 of the mass rapid transit system were constructed. These included some 20 km of bored and cut and cover tunnels together with 18 underground stations. Some particular points of interest in this massive project are briefly commented upon. Reference is also made to other underground or underwater schemes undertaken during this period such as the proposed large caverns project and the submerged tunnel to Pulau Seraya. A description of the subsurface works, now under construction in Singapore, follows. This includes an all underground North-East railway line 20 km long with 16 stations. At a budget of US$ 3 billion, this is a major civil engineering undertaking. Another project is the extension of the railway to Changi Airport which involves 3.5 km of twin tube tunnelling together with a major underground station which is fully integrated into the airport terminals. An on-going program of further major railway extensions over the next 10 to 15 years is in place and an outline is given of some of the most important underground sectors. Other proposed projects such as the underground roads system and the deep level sewers are briefly described. Together they demonstrate the very significant volume of underground construction scheduled for the next century in Singapore.

Jan 1, 1999

Alcoa of Australia's Western Australian bauxite mining operations in the Darling Ranges, southeast of Perth, present major challenges in the control of air blast. The close proximity of rural communities and the face profile make the traditional methods of air blast control difficult.An extensive blast noise monitoring programme has been established. The development of a computerised blast noise prediction model and the establishment of a radiosonde weather balloon facility have reduced blast induced complaints by a factor of ten.The meteorological factors affecting blast noise transmission are discussed and examples are given of adverse weather conditions for the southwest region of Western Australia.

Jan 1, 1983

By E Thomas, L McCallum, G Dale, J Bennett, K Reardon-Smith, S Raine

Sustainable closure of coal mines in Australia to a safe, stable, non-polluting condition remains one of the industry’s biggest environmental and social challenges. A significant proportion of mines in the Bowen Basin of Queensland have dispersive spoil. Based on an estimated area of 20,000ha and a rehabilitation cost of AUD$100,000 to AUD$150,000/ha, the instantaneous rehabilitation liability for the Bowen Basin alone is estimated at AUD$2 to $3 billion.Dispersive spoils present problems in post-mining rehabilitated landforms due to increased potential for surface and tunnel erosion, compromising the ability to achieve fundamental mine closure objectives of a safe, stable, non-polluting and self-sustaining post-mining landform (Minserve, 2004). Dispersion results in clay particles being mobilised and transported in water, even at low flow velocities (So et al., 1998; Minserve, 2004), and blocking of soil pores, resulting in surface sealing, crusting and reduced permeability (DNR, 1997; Vacher et al., 2004) which, in turn, further increases runoff (Dang et al., 2018).CITATION:Dale, G, Reardon-Smith, K, Thomas, E, Bennett, J, McCallum, L and Raine, S, 2018. A process-based approach to mine rehabilitation decision making using Bayesian modelling and risk-based principles for dispersive spoil rehabilitation, in Proceedings Life-of-Mine 2018, pp 106–109 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By C Samuelsson, Q Shu, A Lennartsson, F Gyakwaa, A Andersson, J Isaksson

The physico-chemical property, viscosity, is essential for pyrometallurgical processes and influences the settling rate of valuable metal droplets in slag, affecting the metal recovery. The copper slag from smelting furnaces typically contains between 1 and 2 wt per cent Cu, which equals to or is higher than in most sulfidic copper ores mined today, meaning the slag is a valuable resource for copper extraction. A low viscosity is desirable for slag-cleaning through a settling furnace where entrained droplets settle under gravity. One approach to control the viscosity is through the slag composition. The literature has limited data on the correlation between viscosity, slag structure, and optical basicity of iron silicate slag with FeO/SiO2, CaO, and Al2O3 as factors. Therefore, the present study evaluated the influence of these factors on viscosity and correlations with slag structure and optical basicity. The FeO/SiO2 ratio (at%/at%) and the CaO and Al2O3 content were altered in two levels, resulting in a two-level full factorial design with three factors. The study was done by synthesising FeO–SiO2–Al2O3–CaO–MgO–Cr2O3 melts, followed by water granulation. The melt structure of the samples was analysed with the help of Raman Spectroscopy. The viscosity was then estimated with a high-temperature rheometer using a Mo spindle and crucible. The results showed a correlation between the optical basicity, FeO/SiO2 ratio, and viscosity, where a high optical basicity and FeO/SiO2 ratio were beneficial for achieving a low melt viscosity.

Jun 19, 2024

By R Thompson, D Tulloch

"Wet-weather or 24×7 wet-trafficability is a commendable design objective for unpaved mine haul roads, but practically often difficult to achieve, due both to the road sheeting material selected, and also its breakdown under the action of traffic and environment. Accidents allied to wet-trafficability issues, either due to rain or often more commonly, over-watering of mine roads, is increasing and especially the loss of control or uncontrolled vehicle movements categorisation. The dominant system failure is that once vehicle control is lost, control cannot be regained.The friction supply, or ‘skid resistance’ of a mine haul road sheeting is critical to the safe operation of the road and data has to be collated concerning the variation of friction supply with sheeting material engineering or indicator properties. In the light of the paucity of data existing in this field, this paper presents the contributory research that informs the development of improved and validated unpaved mine road friction supply estimates, based on a number of mine site evaluations across a range of sheeting material types and characteristic parameters, leading to improved predictive models of friction supply.Results from this preliminary review will enable operators to assess their road sheeting materials, improve and validate unpaved mine road friction supply estimates. This will contribute to improved road design, management and 24×7 operability decisions and contribute to a reduction in heavy vehicle loss of control incidents on gravel-surfaced mine haulage roads.Citation:Thompson, R and Tulloch, D, 2016. What's Stopping You? The Role of Sheeting Material Selection in Safe Haulage Operations, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 253–264 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

By W Liu, S Gao, D Wei, B Cui, Z Guan, Y Shen

Beneficiation of low-grade fine-grained hematite ores becomes increasingly important due to rapid depletion of high quality iron ore resources. However, fine particles, especially ultra-fine particles, make efficient beneficiation of these ores more difficult. Therefore, methods to reduce the influence of fine particles must be considered to achieve better beneficiation performance. Analysis and systematical beneficiation tests were carried out on an ultra-fine-grained hematite ore slime from washing a fine grained hematite ore. Ore particles were found to be presented in loose soil. While some of the ore particles were agglomerated, they were very fine and contained up to 76.5 per cent -0.023 mm material. In this paper, using a single magnetic separation flow sheet with sodium silicate (SS) as a dispersing agent, a concentrate containing 65.05 per cent Fe was obtained at an iron recovery of 68.58 per cent from the hematite ore slime of 56.65 per cent Fe. The single magnetic separation flow sheet was simple and reliable, the agent SS was effective in dispersing ultra-fine particles. The results are believed to be applicable to similar hematite ores.CITATION:Wei, D, Guan, Z, Gao, S, Liu, W, Shen, Y and Cui, B, 2013. Beneficiation study of an ultra-fine-grained hematite ore slime, in Proceedings Iron Ore 2013 , pp 495-500 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By Azizan A

The paper presents the results of chlorination of beneficiated rutile and struverite (a tantalum-niobium bearing, rutile type mineral in alluvial tin deposits) by carbon tetrachloride in the range 623¦K to 773¦K. The chlorination of rutile could reach near completion at 773¦K in about an hour. The process was found to follow a modified pore-blocking law, with the basic reaction constant K varying inversely with the particle size, so that the basic process may be a reaction under interface control (chemical control) as modified by the pore blocking effect. The pore blocking factors for the various experimental conditions were evaluated and the predicted curves showed good agreement with the experimental data. In the case of Struverite, a similar kinetic behaviour was observed but the chlorination process was relatively slower than that in rutile. It was also observed that in struverite, niobium got chlorinated faster, followed by tantalum and titanium, indicating a good possibility of separation by chlorination using carbon tetrachloride.

Jan 1, 1996

By R Strand, B Usher

Environmental compliance and mine designs are increasingly including assessment of flows and water qualities as a key driver to decision-making over life-of-mine. Integrated site-wide water quality models linked to dynamic water balances have been used for regulatory submissions, feasibility studies, operating mines and mine closure studies. These models, developed in GoldSim, link aqueous chemistry to the physical system of the site-wide water balance. Geochemical mechanisms included are determined from geochemical characterisation and site water monitoring, depending on the data availability at each site. External geochemical modelling using PHREEQC, version 2 (by D?L?Parkhurst and C?A?J?Appelo) and Geochemists Workbench (GWB), (by C?M?Bethke and The Board of Trustees of the University of Illinois) identifies the most important geochemical processes to be included in the model as a series of geochemical mechanisms which include source term loading rates, pH-buffering and equilibration of water quality. Water balance components include seasonal flow variability; waste facility water storage and system lags; run-off variability; milling processes and tailings production as a function of ore types; simulation of automated and scheduled maintenance of settling ponds; water re-routing for water treatment and freshwater demand, usage and storage.Case studies illustrating the use of these models for regulatory submissions and mine feasibility studies in a variety of climatic and regulatory environments show the utility and applicability of these models. Site-specific examples of these models developed by Klohn Crippen Berger Ltd are currently used at operating mines across the world. One of the larger mines where this is used is a mature poly-metallic mine in South America where the model has aided mine managers in understanding how various planned initiatives and potential water options will result in changes to flows and water quality. It is used regularly to inform water and waste management to minimise impacts to the receiving environment as a consideration of both flows and concentrations. The mine has also used the model in support of water treatment design, regulatory submissions and mine closure planning.Further examples of feasibility and operational/compliance assessment in arid and strongly seasonal environments for planning, regulatory and closure consideration of mine wastes and pits have shown the utility and usefulness of these approaches for a range of mining operations at various stages of mine life.CITATION:Strand, R and Usher, B, ?2014. Integrated site water balances and water quality models for decision-making over life-of-mine, in Proceedings Life-of-Mine 2014 , pp 271–284 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

Between 1966 and 1976, Australia moved from being a non-producer to a position of meeting more than ten per cent of world nickel demand. New mine developments beginning the early-1990s have the promise of more than doubling the country's world market share - from around eight per cent to perhaps close to 20 per cent. This new surge in activity - the so-called `second nickel boom' - has led to several developments which seem likely to have similar economic impacts to those of the late- 1960s and early-1970s. There are, however, some notable differences this time around. The impact of long distance commuting over the past 30 years has changed the regional development scenario. The gold industry is much stronger in Australia than it was in the late-1960s and this helps to place the importance of new nickel discoveries in a more realistic perspective. As potential players have jockeyed to complete feasibility studies and move into construction and production phases of new long-life mines, established suppliers clearly seem to be taking actions to discourage the newcomers. In what appears to be a classic oligipolistic market situation, the heightening of perceived entry barriers to the industry appears to be a particularly visible strategy undertaken. In the current scenario as well, greater vertical integration among producers appears a significant influence on market power.

Jan 1, 1996

By Robinson BW, Walker RK

Using a new highly stable automated electron microprobe analyser, detection limits for gold in arsenopyrite have been improved. Using the AuLA emission tine at 40kV and 500nA, a limit of approximately 10gpt is attained in 10- lSmins. Some unusual features of the background need to be taken into account. Several ores containing different levels of gold in arsenopyrite have been examined, and it has been shown that gold is not evenly distributed between grains (some may contain more than 1%, invisible optically), and that the grains containing gold are often zoned. Gold may be released from the arsenopy rite by weathering or by heating in an inert or slightly oxidising atmosphere.

Jan 1, 1989

By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022