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By J. T. Brown

AS far as could be ascertained, no one had previously investigated the creep strength of silicon poly-crystals. Literature has appeared showing evidence for plastic deformation in silicon single crystals and whiskers.*1"6 Also the fact that germanium, a material of similar crystal structure to silicon undergoes plastic deformation under stress at temperatures above about 60 pct of its melting temperature, has been known for some time.2"4'7 This investigation was performed for the purpose of determining the strength and ductility of silicon polycrystals under creep conditions that would give fairly long times to rupture. PROCEDURE The silicon specimen blanks were obtained by first placing granulated transitor grade silicon (99.999 + pct pure) in a silica crucible. The crucible was surrounded by a graphite susceptor, and induction heating was used for melting the silicon in a vacuum furnace. Blank specimens were formed by freezing molten silicon onto a polycrystalline seed of silicon in a vacuum furnace. The seed was attached to a motor driven revolving rod. As silicon solidified, this rod was gradually withdrawn from the melt. A shape with a contracted center section was obtained by varying the rate of withdrawal from the melt. Specimens for the creep-rupture tests were ground from these "pulled" blanks. Creep-rupture tests were performed in spring loaded machines under constant load at 1800" and 2000° F. RESULTS AND DISCUSSION A test specimen which was sectioned longitudinally is shown in the photomacrograph in Fig. 1. Very little deformation has taken place in the portion of the specimen shown, however, slip lines from several slip systems within the same grain, and deformation band formation was seen. The elongated appearance of the grains is due to the method of growing the specimens. One of the most interesting aspects of the results obtained from the creep-rupture tests was the high strength and the accompanying large amount of ductility. The data obtained is listed in Table I which shows the stress to rupture in 100 hr at 2000°F is between 8000 and 9000 psi. This indicates that silicon's strength at 2000°F is about equal to that of the best commercial super-alloys. It is important to mention that silicon has less than 1/3 the density of iron-, nickel-, and cobalt-base alloys. The usual type alloys for high-temperature applications

Jan 1, 1960

By Carl H. Beal

DURING the latter part of 1915 and the first half of 1916, the writer held the position of geologist in connection with the conservation work instituted by the U. S. Bureau of Mines, on oil and gas land belonging to the Indians of the Five Civilized Tribes in Oklahoma. The duty of the geologist was to correlate formations containing oil, gas, and water, and to determine the relations of these substances in the different formations so that the conservation agents might carry on their work most intelligently. On account of the rapid development of the Cushing field, which lies in the western part of the Creek Nation, much work was done there by the inspection force. In the course of the geologic studies a large amount of information was collected, which, on analysis, has disclosed some interesting facts worthy of publication. The report, of which the following remarks are an abstract, has been prepared and submitted to the U. S. Geological Survey for publication. This report is now (June, 1917) in the press and will doubtless be issued in a few weeks. Methods Used In addition to the structure maps showing the folding of the Pawhuska limestone, which crops out in several places in the Cushing field, separate structure maps of the three most important productive sands—the Lay-ton (Fig. 2)) Wheeler, and Bartlesville—have been prepared. These structure maps were prepared by obtaining the logs of nearly all the wells

Jan 1, 1918

By G. L. Hundley, R. E. Mussler, D. H. Yee, F. E. Block, R. S. Olsen

An anhydrous chlorination process for the recovery of copper from chalcopyrite was investigated. Pelletized concentrate was reacted continuously with gaseous chlorine in a vertical shaft reactor at 550° and 650°C. While the copper was withdrawn with the rest of the metals as molten chlorides from the bottom, 99-x% sulfur was distilled from the top of the reactor. The molten metal chlorides were pulverized and dropped continuously into an upward flowing stream of oxygen. Over 80% of the iron chlorides were converted to oxides in a vertical free-fall reactor at 800° and 900°C while the copper chlorides passed through unoxidized. Copper was recovered in powder form by electrowinning continuously from chloride solutions using a diaphragm cell. The product sloughed easily from a titanium cathode and showed no iron contamination. Current efficiencies and power consumptions averaged 77% and 1.24 kw-hr per lb.

Jan 1, 1974

By J. A. Bownocker

The existence of petroleum in the rocks of Ohio and Indiana seems to have been first shown by wells dug for salt. The fuel, however, was objectionable owing to its odor and inflammability. Not until the Drake well was drilled in 1859 did the people appreciate the value of rock oil, and then they at once began plans to secure the coveted fuel. The first successful well in these two states was near Macksburg, in southeast Ohio, where at a depth of 59 ft. (17 m.) oil was found in commercial quantity (1860). A year later this fuel was secured on Cow Run, in the same county, and at about the same time in Noble, Morgan and perhaps other counties in that part of Ohio. The second great step in the production of oil in Ohio and Indiana was taken in 1884 when the reservoir of natural gas in the Trenton limestone of northwest Ohio was tapped, and where a year later oil was secured in the same formation. Petroleum in this limestone was obtained in Indiana in 1889.' The third step in the production of oil in Ohio and Indiana is associated with the Clinton sand of Ohio. Natural gas in large volume was discovered in that rock at Lancaster, in 1887, and the area has been extended until it has become the largest individual producer in the world. The presence of natural gas in such great volume all but demonstrated to the driller that oil lay hidden near by. Soon the search for it was started but not until 1899 was petroleum in commercial quantity found in the Clinton sand, and a large pool was not located in it until 1907. The fourth step in the developrllrnt of the industry was taken in 1913, when the pool in Sullivan County, in western Indiana, was opened. The producing rock is the Huron sandstone, which is the topmost member of the Mississippian system.²

Jan 1, 1921

Phase II of President Nixon's economic game plan will incorporate many top flight metals mining companies. The large corporations must receive approval from the Cost of Living Council before increasing prices and or wages. The theory here is that, with large companies complying with advance approval, smaller firms will be examined more closely by government, and thus will be forced also to comply. Rep. Paul McCloskey (R.-Calif.) called for a moratorium on strip mining for "the few years involved before we adopt a national energy policy and a national land use policy." McCloskey, who is a cosponsor of Congressional legislation that would outlaw strip mining, told a hearing that a "moratorium can scarcely hurt us until national energy and land use policies are adopted."

Jan 1, 1971

By M. M. Fidlar, Ralph E. Esarey

A marked decrease in drilling during 1937 in Indiana seemed to have no undesirable effect upon the oil and gas industry. Instead, production figures for oil showed a small increase over those for the preceding year, although not so much gas was marketed as in 1936. Drilling activity was centered in proven areas, and the proportion of dry holes to the number of wells drilled decreased somewhat. During 1937, including old wells drilled to deeper horizons, 134 wells were completed in Indiana, of which 39 were oil wells, 39 gas wells, and 56 dry holes. Nearly 75 per cent of the holes were drilled in proven areas. Of the 36 wells drilled in wildcat areas, only four found commercial production. Wildcat wells were especially numerous in Vigo, Pike, Perry and Spencer Counties. Exploratory drilling activity in Vigo County resulted in part from the drilling of the discovery well in the new Prairie Creek field. In Pike County, wildcat wells were drilled in the search for new supplies of gas to meet the demand in the southwestern portion of Indiana. Drilling in both proven and wildcat areas in Perry and Spencer Counties continued to be heavy, because of the presence of shallow Missis-sippian sands and the resulting low cost of drilling and equipping. At the end of the year, 42 of the wells started in 1937 were not completed. Only a few locations were drilled in the old Trenton field, but the wells, many of them 40 years old, continued to furnish a small supply of gas for domestic consumption. Oil production in the Jay County portion of the Trenton area was nearly twice that of 1936, owing in part to a vacuum system installed on several leases. The Harrison County (Laconia) gas field is being developed northward to offset water encroaching from the south. This water in the black shale threatens to put an end to the steady production that this field has furnished for many years. During 1937, the Oaktown gas field again furnished more gas than any other field, but production in that area showed a marked decrease over the marketed gas for 1936. During the early months of the year, seven wells were completed in the Oaktown field to bring the total number of producing wells to over 40. At present, all the operators in the area are

Jan 1, 1938

By C. A. Stetefeldt

It will be of interest to compare the statistics of the gas-producer plant at Aspen, Colorado (recorded by Mr. W. S. Morse in a paper read at the Montreal Meeting, February, 1893*), with those at the Marsac mill, Park City, Utah, where such a plant was first introduced by the writer in July, 1890. In both mills a Stetefeldt furnace is used for roasting; but the Marsac mill has the old-fidsdshioned revolving dryers, while at Aspen, shelf-dryers are at hand. At Aspen, separate Taylor-producers are provided for the Stetefeldt furnace and the shelf-dryers; at the Marsac mill one 7-foot producer supplies gas to both the furnace and the dryers. Hence, in the latter case, the quantity of coal consumed for each apparatus can only be estimated, based upon the relative consumption of wood before gas was introduced. According to Mr. Wilson's statement, the relative consumption of wood in the Stetefeldt furnace and the revolving dryers was as 3 to 2. In the year 1892 the Marsac mill put through the dryers and the Stetefeldt furnace the following quantities of ore and salt (approximate dry weights) : ore, 22,800 tons; salt, 2262 tons. There were consumed in the Taylor-producer 2,714 tons of Rock Springs coal. We may thus make the comparative estimate as follows: Table Showing the Consumption of Coal per Ton Of Ore and Salt at the Marsac and Aspen Mills. Marsac. Aspen. Difference. Pounds. Pounds. Pounds. Drying ore and salt,.... 86.63 72.22 14.41 Roasting ore,.....142.40 117.44 24.96 Total,.....229.03 189.66 39.37 In making a just comparison a number of items must be taken

Jan 1, 1894

By Frederic P. Dewey

The improvement in leaching introduced by the Russell process has stimulated the development of processes for refining lixiviation-sulphides. In the early days several processes for dealing with the sulphides were proposed, and some of them were tried more or less ; but the business finally settled down to sending the sulphides to the smelters, although this was known to be both troublesome and expensive. In 1891 Mr. C. A. Stetefeldt* introduced at the Marsac mill, Park City, Utah, an unpatented process, built up out of the general fund of information available. It consisted in matting the sulphides, grinding, roasting, grinding again, and dissolving the copper out in diluted sulphuric acid, then melting the silver and crystallizing the bluestone. It did not yield fine bullion, hence the bullion had to be refined as well as parted; besides, there was some loss. This process was thoroughly tried at the Marsac refinery and then a year's run was made, the net result of which was that it did not prove sufficiently better than the sending of the sulphides to the smelters to warrant its substitution for that practice. In 1893 the Dewey-Walter Refining Company undertook the refining of the Daly sulphides in the Marsac refinery by the sulphuric acid process, upon which two United States patents ? have been issued to the writer. Naturally, difficulties were encountered in starting a new process, and most of 1893 was taken up in getting it into smooth working order; but in 1894 a run was started, in which all the regular sulphides produced by the

Jan 1, 1897

Jan 5, 1953

By Stanley M. Miller

The probabilistic nature of appropriate geologic variables can be included in analyzing the stability of potential slope failure modes. Random variables in the two-dimensional plane shear analysis of a specified structural discontinuity include the shear strength and waviness angle of the discontinuity and, in some cases, the rock mass density. Estimated probability density functions that describe these random variables are combined by Fourier analysis to produce an estimate of the safety factor probability density function, which appears to approximate a gamma distribution. The probability that sliding will occur along the specified structure is equal to the area under this density function where the safety factor is less than one.

Jan 1, 1982

By Frank N. Speller

Jan 1, 1934

The regular activities of the Institute are financed mainly by income derived from members' dues, from advertising in MINING AND METALLURGY, and from the sale of publications to the public In addition, collateral activities and special projects are financed each year by means of income from endowed funds controlled and administered by the Institute In the aggregate, the amount of these endowments totals more than $830,000 An active effort is being made to increase the endowment funds of the Institute through a standing committee, of which Harvey S Mudd is Chairman, and

Jan 1, 1952

By S. E. Bretherton

Discussion of the paper of S. E. BRETHERTON, presented at. the San Francisco meeting, September, 1915, and printed in Bulletin No. 104, August, 1915, pp. 1595 to1599. ANTON EILERS, Brooklyn, N. Y. (communication to the Secretary*). While the advantages in the use of high-line siliceous slags in lead smelting which Mr. Bretherton discusses in this paper are obvious under certain economical conditions, he gives me credit for the introduction of such slags when it does not belong to me. It is true I did considerable experimental work, off and on, for the purpose of finding such slags, while at the Germania in 1877 and 1878, but I did not have occasion to introduce any such slags for regular work, because I had no ores which fitted the economical conditions for using high silica and high lime, except in isolated cases for very brief periods. On the contrary, the ores I had to treat were mostly very ferruginous and very low in silica, so that, economically, I was compelled to run nearly always on slags, which allowed me to use the abundant flux I had without cost. It was August Raht who first had occasion to establish and use for long periods a slag high in silica and line, and low in iron. This was when he was confronted with the task of smelting the. Horn-Silver ores at the smelting works at Franklin, Utah, with as little expenditure for fluxing material as possible. I was at that time in Leadville, Col., where, in the new works I had built, the Billings and Eilers smelters, I had occasion to use profitably many slags, but never anything as high in the earthy bases and in silica as Mr. Raht had to use.

Jan 12, 1915

By Helmut Thielsch

DURING the last three decades a great many arguments have been presented on the subject of "mosaic" or "block" structures of metals. Apparently because of insufficient evidence, the "block-structure" theories have never been widely understood among the physical metallurgists in this country, and most investigators among the few that have tried to demonstrate the existence of such an inner structure of crystals or grains have failed to recognize also the existence of a lamellar structure. Moreover, little thought has been given to justify the existence of such "lamellar" or "mosaic-block" structures on a theoretical basis. Since properties such as plasticity, ferromagnetism, hardness, diffusion, and others may be explained by structural faults in the lattice network of the crystals, the great importance of a more detailed knowledge of the structure within crystals or grains becomes now evident. Because of the vast extent of the field of submicroscopic structures, it shall be the purpose of this paper only to review the more important of the results obtained by other investigators, especially in Germany, where a great deal of attention has been given to mosaic structure during the last three years. The origin of this mosaic pattern f and effects of cold reduction and recrystallization will be shown in further studies later on. IMPERFECTIONS IN CRYSTALS The many terms used in the literature to denote structural types of crystals are often not clearly defined. To clear up some of the confusion, the meaning of the more important terms will be given here. Ideal, or Perfect Crystals.-Crystals without any structural imperfections are called "ideal crystals," or "perfect crystals," meaning a homogeneous interior structure of atoms, ions or molecules, as the case may be. In other words, at every point in the interior of the crystal exactly the same orientation of the crystallographic axes of the coordinate system would exist. The surface of such a body, if etched with an appropriate etching reagent, would reflect light with perfect uniformity. Crystals of this type are almost nonexistent. Real Crystals.-" Real crystals"' may contain various types of structural defects, which can be classified into: (I) lineage structure, (2) mosaic-block structure, (3) lamellar structure. The inhomogeneities existing in these groups mean that the orientation of the crystallographic axes will not be the same at every point within the interior of a crystal (or grain of a polycrystalline body). Perfect Real Crystals.-The term "perfect real crystals" is generally used to describe crystals with minute structural or thermodynamical inhomogeneities. The former

Jan 1, 1945

By Victor Rudenno

Feasibility studies for mining projects traditionally involve in their final stages a lengthy process of repetitive trial and error discounting, in calculating the discounted cash flow rate of return resulting from the respective yearly after-tax cash flows. Also, probability analysis and sensitivity analysis (in particular) require extensive additional calculations with each change of any project parameter . These inefficient repetitive procedures have two unacceptable results: 1. they are not flexible enough to allow ready analysis of dependent parameters , and 2. they require resort to high-capacity centralised computing facilities with their inherent impersonality, rather than a convenient and available desk calculator - a factor of particular importance to top mining management. Such problems can be overcome if the mining project can be represented by a reasonable straightforward mathematical economic model. The most flexible and appropriate model has been found to be one in which a maximum and minimum value for each of n parameters are supplied to a program which determines a large number of systematic combinations of parameter events and then statistically analyses them to determine the resulting coefficients of the model. In this paper the authors discuss the selection of the most appropriate type of model and outline the steps followed in its development and application.

Jan 1, 1977

By F. C. von der Weid

THE mining district of São Fidelis, in the northern part of the State of Rio de Janeiro, is situated on the Paraiba River, where it crosses the Serra do Mar (Mountain of the Sea), in the center of a mountainous country having numerous graphitic outcrops. For a long time, these outcrops were irregularly explored by local people, who had little means and no technical advice. A few years ago, the Cia. Brasileira de Mineração de Grafite took over the control of some of the more important outcrops and entrusted to me the task of studying the ores and establishing a flowsheet for a pilot plant to be situated in Sao Fidelis-the ore to be concentrated being mostly of a very high grade. MINERALIZATION AND ORES The rocks of the district are mostly gneiss and crystalline schists, with occasional interstratification of dolomitic limestone belonging to the Archean Brazilian Fundamental Complex. The general direction of the beds is roughly between 60° and 80°E., with variable dip, generally nearly vertical. Mostly, direction and dip of the graphitic outcrops is concordant with the embanking gneisses or schists. These outcrops seem to be aligned in two or three parallel zones (Pádua, São Fidelis, Macabú), the São Fidelis zone being the best known and the most important to date. Two outcrops of the São Fidelis zone, Saudade and São Benedito, are now being exploited. Mining has been carried out, so far, on a small scale. The mineralization consists of a vein of nearly massive graphite in a very compact, partially granitized gneiss, with vertical dip. The vein is most irregular, with nests and lenses irregularly distributed along the fracture plane. The ore consists chiefly (particularly in São Benedito) of massive graphite appearing and disappearing along the main direction of the vein, forming a succession of irregular lenses in a sort of rosary design. The average width is more or less one foot, with variations from zero to 6 feet. The lode minerals are quartz, a little feldspar and garnet (the latter having its origin perhaps in the embedding gneisses), with rare ferruginous clays on the outcrops. In Saudade a little pyrite, pyrrhotite and chalcopyrite is found occasionally, as well as a carbonaceous mineral, very light, black and shiny, with conchoidal fracture, looking like a sort of jet. The composition of this mineral has not yet been established, but it seems to be very complex. The mineralization seems to be hydrothermal at a rather low temperature, perhaps mesothermal. The paragenesis, according to samples from Saudade, seems to be as follows, the earlier minerals being listed first: pyrrhotite, pyrite, chalcopyrite, with quartz concomitant to the three and

Jan 1, 1946

By L. P. Teas

The main facts brought out by the study of the blende-bearing ores examined are as follows: 1. Chalcopyrite as minute triangular or rectangular dots, or as

Jan 1, 1918

By J. J. Marcus

Mineral industry decision-makers are frequently required to select between competing equipment. Various criteria and methods are currently being used, and this writer would like to suggest a method recently tested on two large power shovels in an open pit mine. An initial examination of both shovel A and shovel B indicated that the latter should give the best overall results. since: 1) It swings 13% faster; 2) it carries a dipper with 23%: greater capacity; 3) purchase price is 8.6% lower; 4) shovel weight is 12.5% greater; 5) it has considerably greater bail pull under most operating conditions; 6) the electric controls are of a more modern design. However, shovel B has half the service life. With these points in mind, shovel A was selected by The Buckingham Method, an operations research technique.

Jan 9, 1965

By William E. Ford, Edward Salisbury Dana

1. Normal Class (31) Axinite Type 2. Asymmetric Class (32) Calcium Thiosulphate Type Mathematical Relations of the Triclinic System 216. Crystallographic Axes. - The triclinic system includes all the forms which are referred to three unequal axes. with all their intersections oblique. When orientated in the customary manner one axis has a vertical posi-

Jan 1, 1922

By R. L. Grayson, Y. J. Wang

This paper presents an application of goal programming (GP) to major mining machinery purchases based on historical operating data on mechanical downtime and production. The GP technique, an extension of integer programming, is used to maximize an objective function comprised of deviations away from management-preferred financial goals. Different capital budgeting techniques are used to evaluate capital proposals, and the results of these analyses are combined and weighted in a maximization of profits objective function. The GP method gives an optimal solution to a multiple goal problem. A sensitivity analysis is performed to determine the effect of a variable production improvement condition or a variable budget control con¬dition on proposal selection.

Jan 1, 1984