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By Tuula Mäkinen, Lauri Pesonen, Peter Björklund, Jouni Pihlasalo, Mikko Korpi

Outotec Direct Blister Flash Smelting technology has proved to be an efficient and environmentally friendly way to treat copper concentrates from the Zambian Copperbelt at Konkola Copper Mines' (KCM) Nchanga smelter in Zambia. The modeling of slag chemistry and thermodynamics with MTDATA software played a central role in deciding the operation parameters for the smelter. Outotec FSF Online Process Advisor is used to calculate the process parameters and to give valuable information of the process state for the operating personnel. The pre-calculated slag liquidus graphs are also integrated to the Online Advisor.

Jan 1, 2011

By Alper Kirmaci, Taghi Sherizadeh, Kutay E. Karadeniz, Dogukan Guner, Samuel Nowak

Injuries and fatalities resulting from roof falls are still a major concern in U.S. coal mines, and many researchers are focused on developing meaningful approaches to minimize this hazard. In the United States, coal mine roofs can vary widely in composition, geometry, and inherent heterogeneity, leading to a wide array of different roof fall failure types. Researchers frequently employ numerical modeling tools to reproduce this physical phenomenon and provide key guides to engineers regarding roof conditions and control as long as the input data and constitutive relations are appropriately selected. Simulating such complexity requires expertise and constitutive models that adequately simulate roof behaviors. However, the currently available constitutive models have shortcomings in capturing some of the roof fall failure types common in underground coal mines, such as guttering. A new constitutive model is developed to address the shortcomings of constitutive models commonly used for coal roof stability analysis. The constitutive model developed in this study combines the anisotropic-elasticity and nonlinear strain-softening responses. In addition, the developed constitutive model can simulate up to three different joint sets implicitly, allowing for use in both continuum and discontinuum settings, and can be used in both Lagrangian finite-volume and distinct element method codes of Itasca. First, the mathematical expressions of the model are provided. Afterward, the validation phase of the developed model that covers comparisons with analytical solutions and those of existing models (e.g., anisotropic elasticity, ubiquitous-joint, and bilinear strain-hardening/softening ubiquitous-joint plasticity) is presented. Finally, a hypothetical coal mine roadway facing high horizontal stress is simulated. The presented model successfully shows three distinct stages of a cutter roof in a shale roof: (1) initiation of shear cracks at the rib– roof intersection, (2) extension of cracks deeper into the roof (i.e., above the roof bolt length horizon), and (3) cantilevered roof. It is demonstrated that the presented constitutive model has the potential to help future researchers in simulating various roof responses.

Jul 1, 2023

By LINDSAY BOTTOMER, Tassos Grammatikopoulos, Massoud Aghamirian, MARK FEDIKOW

A master composite (Master Comp) sample was prepared from three pegmatite zones from the Zoro Dyke D1 for mineralogical analysis and heavy liquid separation (HLS). The mineralogical examination was conducted on a subsample that was crushed to approximately P80 = 600 μm. The sample consists of spodumene (10.5 percent), quartz (29.3 percent), plagioclase (29.0 percent), K-feldspars (21.3 percent), micas (5.1 percent), tourmaline (2.9 percent) and Fe-Mn-phosphates (0.1 percent). Liberation of spodumene (88 percent) and gangue minerals, including quartz (89 percent), feldspars (94 percent) and micas (83 percent), is very good at this P80 . The average lithium (Li) concentration is 3.7 percent in spodumene, 2,196 ppm in micas, 1,001 ppm in tourmaline and 115 ppm in K-feldspars. Spodumene accounts for 96 percent of the total Li in the sample. The mineralogical data indicate the potential to recover spodumene by flotation with minimal Li losses due to other Li carriers. The HLS was conducted on a subsample that was crushed to smaller than 6.4 mm, with the smaller than 600 µm fraction removed from this test. The HLS results indicate it is possible to produce a high-grade lithium concentrate, with close to 6 percent Li2O, after the rejection of iron silicates with magnetic separation.

By The Staff

BEFORE going into detail on the subject to be presented, a brief outline of the Company's earl y history would not be out of place. Prospecting and mining on a small scale was started in 1876 on the site of the present open pit at Thetford Mines. The property was purchased from the Crown in 1878 and Johnson's Company was incorporated in 1885. It is owned and operated today by descendants of the original shareholders. Many employees, through their fathers and grandfathers, have service records dating back three generations. The principal asbestos deposit at Thetford Mines is pear-shaped, with surface dimensions of about 2,200 feet in length by 1,300 feet in maximum . width. Its long axis strikes northeast and the dip is nearly vertical, but irregular in detail. It is known to extend to a depth 1,200 feet below the original surface, but its area at that depth has not been determined. Ownership of this deposit is divided among three active Companies: the Asbestos Corporation, Limited; Bell Asbestos Mines, Limited; and John-son's Company. Johnson's Company owns a section about 1,000 feet in length and 500 feet in width, bounded on the northeast by the King mine of the Asbestos Corporation and on the northwest by the Bell pit. On Johnson ground, there was originally a large outcrop o~ asbestos rock which dipped toward the south below overburden. This was mined until recently by open pit, the overburden being stripped off as far southward from the original outcrop as was economically possible. As the. pit was deepened, within side walls maintained at a maximum safe slope, its floor area, of course, became progressively smaller, and eventually the pit would have wedged out against the Bell property line. It became necessary, there-fore, to introduce some other method of mining before production became seriously curtailed by a shrinkage of the pit area.

Jan 1, 1941

By Thomas B. Douglas

INSTRUMENTATION in the process industries can no longer be regarded as a convenience, but rather an absolute necessity. Although many chemical processes must already be conducted with instruments, every properly designed application of automatic process control will improve operation: 1) the product will be more uniform and of higher quality; 2) the manual labor saved will reduce cost; 3) uniformity of flow and uniform control of process will increase production; and 4) surges will be eliminated, making it possible to operate equipment near ultimate capacity at all times. Industrial instruments fall into two general classifications—those that measure and those that measure and control. The cement industry has been using instruments for a number of years, particularly in the burning process, primarily for indicatlng and recording. Automatic process control makes additional use of these instruments, and others, to control variables. Assisted by the instrument manufacturers, engineers at Ideal Cement Co. achieved considerable progress in determining how well the usual recording instruments could be made to control various phases of cement-making. The results of these experiments were used to make the new plant at Houston as wholly automatic as possible. The original Houston plant, built in 1937 by Gulf Portland Cement Co., consisted of only one 8 x 220-ft kiln and the necessary grinding mills and accessory equipment and had a capacity of 900 bbl per day (300,000 bbl annually). Ideal Cement Co. purchased this plant in 1940 and almost immediately started plans to increase its production. In 1941 a 9 x 220-ft kiln was installed and grinding and storage capacity were increased. The growing demand for cement in the Houston area necessitated a third kiln (9 ft 6 in. x 250 ft) in 1947. This brought the plant up to its present capacity of about 1.3 million bbl per year. Calcium silicates in cement are produced in a burning operation at high temperatures from raw mix of argillaceous and calcareous materials that have been crushed, mixed, and ground to a fine powder. The composition of this mixture must be kept consistent within narrow limits. Raw mixing and grinding may be done either wet or dry, but in both instances the materials must be correctly proportioned, finely ground, and thoroughly intermixed before entering the kiln. As the raw mix passes through a long horizontal rotary

Jan 1, 1959

By E Amini, M Scott

Grade Engineering® involves the planning, integration and operation of coarse preconcentration techniques to reject uneconomic material as early as possible in the mining value chain to improve the quality of ore delivered to mineral processing activities. These preconcentration techniques include screening for natural and induced deportment of grade to finer size fractions during blasting and coarse breakage, sensor-based measurements of grade and mechanised sorting at particle or bulk scales and coarse gravity separation. Over the last decade, the Cooperative Research Centre for Optimising Resource Extraction (CRC ORE), with the support of its participants, has developed a framework for the holistic evaluation of economic and production impacts attributable to these preconcentration techniques. The framework combines the characterisation of preconcentration responses, geostatistical modelling, process modelling and simulation of downstream and upstream production impacts and the optimisation of strategic mine plans to quantify changes in net present value due to different preconcentration strategies. This framework has been applied to evaluate preconcentration techniques at numerous metalliferous operations and can also be used to quantify changes in the environmental metrics for energy, water and steel consumption and emission, tailings and waste rock production. This paper collates the results of these Grade Engineering® studies to show the range and magnitude of economic and environmental impacts attributable to preconcentration. The studies have shown that rejection of uneconomic material prior to mineral processing activities can have a pronounced improvement in energy, water and comminution steel productivity, emission intensity and the profitability of metalliferous mining.

Nov 10, 2020

By S. H. Lorain

Tin mining on Seward Peninsula, Alaska, has been intermittently active since the early 1900's. Most of the recorded production (over 2,200 short tons of metallic tin) has been obtained from placer deposits, but recent production also has resulted from development of lode deposits associated with intrusive rocks occurring in the western part of the peninsula. Generally, the lode deposits containing tin minerals (principally cassiterite) are found in dikes, in granite masses, and in silicate zones in limestone overlying the granite. Both the placer and lode deposits have been of considerable strategic interest to the Government because of the almost total absence of a domestic supply of tin. The most important tin-lode deposit discovered to date is in the Cassiterite dike at the Lost River mine, on Cassiterite Creek about 85 miles northwest of Nome. This highly altered, rhyolite porphyry dike averages 12 feet in thickness, strikes N. 75° to 85° E., and dips steeply to the south; it can be traced on the surface for about 8,000 feet. Throughout its explored length of about 2,200 feet the dike everywhere contains some tin and tungsten in veinlets and disseminations; economic concentration of the are minerals, however, is confined to definite shoots. The ore minerals include cassiterite, stannite, hulsite, paigeite, wolframite, scheelite, and base-metal sulfides; gangue minerals include fluorite, boron silicates, and lithium-bearing minerals. Some ore minerals also occur in the numerous other dikes and in the granite and intruded limestone in and adjacent to the mine.

Jan 1, 1958

The following is an incomplete list of members and guests who called at Institute headquarters `during the period Aug. 10, 1918 to Sept. 10, 1918. Amil A. Anderson, Hill City, S. D. A. A. Holland. H. G. S: Anderson, Hurley, N. Al. Paul S. King, Wilmington, Del. Louis A. Barton, Capt., Engineers, U. S. A. Herbert G. Officer, Washington, D. C. K. Baumgarten, lst Lieut., U. S. R. A. B. Parsons. Charles W. Boise, Belgian Congo. Robert R. Pollock, San Francisco, Cal. Henry C. Carlisle, The Pas, Manitoba. Frank A. Smith, Edgewood, Md. J. Ross Corbin, Boyertown, Pa. Edward C. Thompson, Kennett, Cal. S. Le Fevre, Forest Glen, N. V. Malcolm M. Thompson, Morsemere, N. J. Harold P. Ford, Cleveland, 0. Lester C. Uren, Berkeley, Cal. William L. Hogg, Waynesboro, Va. Harold W. Aldrich has been appointed assistant general superintendent of the Inspiration Consolidated Copper Co. at Inspiration, Ariz. Capt. Percy E. Barbour, formerly with the New York State Troopers, has been granted a leave of absence from the Department for the period of the war, by the Governor, and has been appointed Captain in the Engineer Corps, U. S. A. He served on the Mexican border in the New York State National Guard. A. C. Barke, formerly with the United States Smelting, Refining and Mining Exploration Co., has accepted a position with the United States Fuel Co. at' Salt Lake City, Utah.

Jan 10, 1918

By W. O. Vanderburg

The leasing or tribute system has been an important factor in the development of our metal-mining industry, particularly in the gold and silver mines of the Western States. It has received its widest application in. the early history of many camps and in the last stages of many mines. The system is especially adapted to mining where the ore's occur in narrow veins or are erratically distributed in small bunches or pockets so that selective mining, hand sorting, screening, or hand cobbing is required to produce shipping or milling-grade ore. The leasing system is also applicable to the development of prospects where the owners are unable or unwilling to assume the risks of searching for ore. The virtue of the system lies in the opportunity it affords miners with little capital to get started; at the same time, it rives owners an opportunity to have their property developed at small cost.

Jan 1, 1934

By D. Berberick

Hecla?s Lucky Friday Mine is a deep, underground producer of silver, lead and zinc in the Coeur d?Alene mining district of northern Idaho. Main access into, and production from, the mine is via the Silver Shaft, a 5.5-m (18-ft) diameter, concrete lined shaft sunk by J.S. Redpath to an original depth of 1,890 m (6,200 ft) in the early 1980s. The shaft is divided into four compartments (Fig. 1), with sets made of 225 mm x 175 mm (9 in. x 7 in.) hollow structural section (HSS) steel buntons and 150-mm x 150-mm (6-in. x 6-in.) HSS dividers spaced every 4.5 m (15 ft) down the length of the shaft. Two skip compartments on the east side of the shaft are equipped with 125-mm x 150-mm (5-in. x 6-in.) HSS steel guides and 9-t (10-st) skips with three deck trailer cages for men and materials. The west side of the shaft is divided into a manway, and a fourth compartment that was originally designed for a service cage. Shaft services consist of a 250-mm (10-in.) a compressed air line and 150-mm (6-in.) sandfill line along the south side of the shaft, and 250-mm (10-in.) discharge (gray) water and 150 mm (6 in.) fresh water lines on the north wall. The mine?s primary 13.8 kV power lines, as well as communication lines are located on the west wall of the shaft. The production hoist is a 3.7-m (12-ft) diameter, double drum, double clutch, 2,238 kW (3,000 hp), direct current unit equipped, at the time, with thyristor drives. The 30-year-old drives would prove to be problematic during the rehabilitation project, leading to an upgrade to modern ABB drives later in the project, after the shaft rehabilitation was complete. The shaft had been subjected to the typical wear and tear of 30 years of operation, including intermittent sandfill and muck spills, and, in the lower areas, some corrosion. During those 30 years, the west compartment, originally designed for the service cage, could only be accessed from a work deck on top of the skips or from the manway.

By J. D. Miller, C. L. Lin

In general, x-ray computed tomographic (CT) techniques are able to provide 3D images of the internal structure of opaque materials in a nondestructive manner. The unique cone beam geometry allows acquisition of all 2D projections with only one rotation of the sample thus providing for fast data acquisition and better x-ray utilization, as a complete 2-D detector array receives the cone-shaped flux of rays. Thus, an isotropic 3D volume can be reconstructed without the mechanical translation and the stacking of sequential slices as is the case for more conventional CT scanners. In this regard, a state-of-the-art, custom designed xray microtomography facility to provide very detailed 3D spatial analysis of multiphase particles has been installed and is in operation at the University of Utah. The reconstructed 3D tomographic volume allows for an adjustable spatial resolution from 5 to 20 microns for sample dimensions from 10 to 40 mm in diameter, respectively. Utilization of this custom designed cone-beam x-ray microtomography system is discussed. Applications described include: coal washability analysis for the design and operation of coal preparation plants, liberation analysis for evaluation of grinding practice and separation efficiency, mineral exposure analysis for prediction of the ultimate recovery from heap leaching operations, and analysis of the pore structure network of packed particle beds for simulation of flow through such porous structures as encountered in filtration and heap leaching.

Jan 1, 2003

By Harry R. Johnson

Domestic expenditures by the U.S. petroleum industry have exhibited distinctive shifts in emphasis over the past 20 years. From the end of World War II to 1955, expenditures for all phases of the industry expanded. Although over one-half of all expenditures were for production, the relative emphasis was changed after 1956-58 from production toward processing and marketing. The period 1967-69 marked the beginning of a return to emphasis on exploration and production. These trends in expenditure patterns are logical and rational when related to domestic and international economic conditions and to the widespread application of improved production technology. As the immense job of developing the oil resources of Alaska and other regions begins, the petroleum industry will continue to turn to external sources for working capital. Long-term debt will probably be the principal method of external financing through 1970, but a definite shift toward new common and preferred stocks will be made. Higher product prices may be sought by the petroleum industry, but the economics of crude-oil production, changes in the tax structure, and possible changes in the oil imports control program make the price structure of crude oil and crude-oil products unpredictable at the present time.

Jan 1, 1970

Aaby, Alton O , (S'47) Univ of Minnesota, Mimeapolis, Minn Aaby, Waldo S , (S?48) Univ of Minnesota, Minneapolis Minn Aalde, Kaare, (S'48) Univ of Nevada, Reno, Nev Aaring, Floyd D , (S'48) Univ of Oklahoma, Nor man, Oka Aaronson, Hubert I , (S'47) Carnegie Inst of Technology, Pittsburgh, Pa Abbott, Peyton Osborn, (S'46) 1502 Westover, Austin 21, Texas Abel, Malcolm D , (S'47) Univ of Texas, Austin, Texas Aberg, Richard S , (S'47) Univ of Minnesota, Minneipolis, Minn Abrahamson, Guy C , (S'43) 420 W Dennis St , Wilmington, Calif Abrahao, Benjamin, (S'46) Escola Politeenica da Unnersidade, de Sin Piulo, Braizil Achter, Meyer R , (S'46) Carnegie Inst of Tech , Pittsburgh, Pa

Jan 1, 1952

"8.1. IntroductionThe stoichiometry of most named platinum-group minerals (POM) is known (cf. Cabri, 1981b, in Chapter 7), but, because these minerals are subject to a wide range of element substitutions, representative analyses require treatment in a separate chapter (section 8.2). The analyses, in all cases done by electron microprobe, are grouped in sections according to the principal platinum-group element (POE) for each POM, and then follow sequentially with increasing amounts of the principal POE starting with the ideal composition, when known. In order to facilitate reference to specific POM by name, an alphabetical listing is also given (Table 8.1). A range of compositions, in addition to one or several ""representative"" analyses, is given for some POM when more than one analysis has been reported for a particular locality. The tables of POM analyses (Tables 8.2 to 8. 76) include at least one analysis for every locality for which data have been published, to the best of the authors' knowledge. All analyses are referenced for locality and publication source, and include several unpublished analyses (all but one done at CANMET). Most analyses have been rounded off to one decimal place for amounts more than one per cent and their formulae calculated on the basis of an even number of total atoms. In all tables, ''n.d.'' stands for elements sought for but not detected and a dash signifies elements not sought, or when these haven't been specificed in the publication source.Section 8.3 contains tabulated analyses and, in some cases, also includes a critical assessment of POE-bearing minerals in which the POE occur in trace or minor quantities. The organization of the data in this section is by mineral groups; e.g., sulphides, sulpharsenides, silicates, etc. Some of these data are also discussed in Chapter 4 by Crocket (1981) and are discussed briefly in Chapter 6 by Crocket and Cabri (1981)."

Jan 1, 1979

By Atta Ur Rehman, Kwame Awuah‑Offei

This paper evaluates the effectiveness of similitude theory in predicting the draft of a rubber tire loader’s bucket during initial penetration. The work uses 1:16 and 1:8 scale models of an 18-t capacity load haul dump, scaled with the Buckingham Pi Theorem, to evaluate the prediction of draft and penetration under different operating and different dynamic conditions. The authors hypothesize that the observed relationships between draft and longitudinal penetration and the operating and dynamic conditions will hold true for an upscaled model. Similarly, the authors hypothesized that the results of experiments conducted with the smaller scaled model should predict the draft on an upscaled model. The results show that the relationships between draft and longitudinal penetration and operating and dynamic parameters are similar for both scaled models. Similarly, the draft on the upscaled model, predicted by using the experimental results of the small model, is similar to the measured draft on the upscaled model. The mean difference between the two is 1.71 N with 95% confidence interval of [-3.51, 6.93], which is very good given the average draft is approximately 330 N. Thus, the work indicates that both hypotheses are true for draft. However, the work shows that scaling muck pile particle sizes using the Buckingham Pi Theorem is not adequate to ensure good predictions of penetration. This work provides insights that will help design engineers to acquire useful data on scaled models and use it for various analyses on heavy machinery.

Oct 6, 2021

By Manuel Llosa Pautrat

El presente estudio señala la interpretación de los balances de una empresa minera de acuerdo con las disposiciones legales existentes y la práctica establecida en el país. En esta interpretación de balances se ha utilizado ciertos índices como el de balance general, cuenta de ganancias y pérdidas, balance con las ganancias y pérdidas, origen y aplicación de fondos, donde la experiencia resulte de mayor utilidad en el análisis de compañías mineras. Dentro de los índices de balance general están las fuentes del capital, distribución y la inversión del mismo. Entre los índices que analizan la cuenta de ganancias y pérdidas está el control de costo y resultados de la operación. Los índices que relacionan el balance con las ganancias y pérdidas son los coeficientes de rotación, rotación de inventario y distribución de los accionistas. Finalmente, el índice del origen y aplicacíón de fondos, indica la procedencia de los nuevos fondos ingresados en el ejercicio considerado (origen) y hacia dónde se destinan (aplicación).

Aug 20, 1963

By W. P. Sykes

THIS investigation was undertaken primarily to establish the relations existing between temperature and mechanical properties in molybdenum, nickel, and an aluminum-copper alloy. Molybdenum (m.p. 2500° C.) was chosen because it is partly similar to tungsten and partly similar to the common ductile metals. Also it is known to furnish, by proper treatment, a desirable material to use in studying relation of grain size and physical properties. The molybdenum used was of the quality that is drawn into wire 0.003 in. in diameter for use as filament supports in incandescent lamps; chemical analysis shows less than 0.1 per cent. of impurities. Nickel belongs to the same class as iron. Its melting point is 1450° C. and an allotropic change at about 370° C. results in a loss of magnetism above that temperature. This feature made nickel doubly valuable for the purposes of these tests. The nickel used was obtained from the Driver-Harris Co. as 0.090 in. (2.3-mm.) wire, annealed; analysis showed 99.8 per cent. nickel and 0.150 per cent. iron. Aluminum is one of the low melting-point metals. Some tensile tests at elevated temperatures have been reported by Bengough but the possibility of learning more with the low temperature and sensitive apparatus available recommended this metal. The samples marked Al are an aluminum-copper alloy; they contained 3 per cent. copper, 0.42 per cent. iron, and 0.21 per cent. silicon. The presence of the copper somewhat complicates the analysis of the results; but the action of copper in aluminum has been studied so that its influence might have been foretold, in part at least. The material and analyses were furnished by the Aluminum Castings Co. The nickel wire, which was deformed at 400° C., was drawn under a bath of molten lead and through a die, which also was immersed in the bath. A thermocouple was suspended in the molten metal to indicate

Jan 1, 1921

By D. Chakravarty, D. Dutta, B. Samanta, S. Patteti

"This paper presents the mixed spectral behaviour of iron ores from deposits in Gua, India. Spectral signatures of powder samples and their two-component mixtures were generated by spectro - radiometry. Spectra were divided into continuum and absorption components. A modified Gaussian model was used to extract subtle features from the absorption components of the spectra. A linear unmixing model (LUM) applied to estimate minerals from the spectra of mixed powder samples indicated that this model achieved an R2 value of 0.88. The LUM was then applied to estimate the abundance of ores from a hyperspectral satellite image of the deposit area.RÉSUMÉ Le présent article montre le comportement spectral mixte de minerais de fer de gisements à Gua, en Inde. Les signatures spectrales d’échantillons de poudres et leurs mélanges à deux composantes ont été générés par spectroradiométrie. Les spectres ont été divisés en composantes de continuum et d’absorption. Un modèle gaussien modifié a été utilisé pour extraire des caractéristiques subtiles des composantes d’absorption des spectres. Un modèle de démélange linéaire, appliqué pour estimer les minéraux dans le spectre des échantillons de poudres mixtes, indique que ce modèle a atteint une valeur R2 de 0,88. Le modèle de démélange linéaire a ensuite été appliqué pour estimer la quantité de minerai à partir d’une image satellite hyperspectrale du secteur du gisement."

Jan 1, 2015

By J. Bongarra

This report describes the development of the instructional design and content of a training program for shaft construction miners and supervisors. The recommended training approach is based on the results of a needs, task, and competency analysis of the jobs performed by conventional shaft sinking and raise drill personnel. Learning objectives were derived from the task analysis and the appropriate training delivery system was chosen using a selection technique which employed learning algorithms. The training described is aimed at improving the safety and efficiency of constructing shafts by new hire and experienced miners and supervisors. A self-paced, self-teaching, modular approach to training, using criterion-referenced tests was proposed. Recommendation was made to divide the training into three parts: Orientation and Safety; Task Instruction; and Practical Exercise. Training requirements for conventional shaft sinking and raise drilling were described. Training program content was detailed in the form of module and lesson design approaches. In addition, the report recommends a method for developing, implementing and validating the training program. The authors conclude that such an implementation would meet the major objectives of improving the safety and efficiency of shaft construction work operations.

Jan 1, 1979

By Fiona M. Doyle Garner

Hydrolytic stripping is the process whereby metal ions in a loaded solvent extractant are hydrolyzed by water, typically at 130°-200°C. Equilibrium hydrolytic stripping tests were done on Versatic 10 solutions of various metals, singly and in mixtures. Single solutions of Fe, Xi, Cu, Mg, and tin precipitated aFe2O3, Ni(OH)2, Cu2O, Mg(OH) 2 and ?Mn203 respectively during hydrolytic stripping. Several mixtures containing iron precipitated magnetic spinel ferrites, MFe20k. No other combinations formed mixed oxides. It is proposed that the mechanisms for hydrolysis and precipitation of iron in loaded Versa- tic solutions are similar to those for iron hydrolysis in aqueous solutions. Infrared spec- troscopy and thin-layer chromatography of mixed iron-nickel Versatic solutions indicated that mixed Fe-Ni carboxylate complexes are present. Magnetic interactions between mixed complexes are thought to be responsible for the homogeneous nucleation of magnetic mixed oxides in preference to single oxides.

Jan 1, 1984