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By B. R. Davis, Neale R. Neelameggham, R. E. Brown

The element Calcium element has a unique place in the production of etals, intermetallics and other compounds. The unusualness arises from the fact that we have several possible reductants – metallic calcium, calcium carbide, calcium cyanamide and calcium hydride. A review of how metallic calcium is manufactured and utilized is presented. The difficulties involved in producing the metal in large quantities and price implications are noted. . Fundamental thermodynamics of how these act as reductants are shown, along with the historic application of these in metal production during the past century and a half. Alternate applications as to how to control the cost of the reductant is indicated, such as the numerous attempts in making low cost titanium utilizing direct or indirect calcium reductant.

Jan 1, 2014

By Luis Enrique Vargas

En las operaciones a tajo abierto, la generación y control de vibraciones juegan un papel importante en la estabilidad de taludes a lo largo del tiempo. Para mantener un diseño de minado óptimo y seguro en Toquepala, el autor ha contemplado 7 factores (caracterización geotécnica, diseño de malla, diseño de carga, análisis de secuencia de tiempos entre taladros y filas, análisis de vibración tanto en piso como en cara de banco, calidad del precorte y evaluación geotécnica de voladura mediante celdas) al desarrollar esta metodología denominada Evaluación geotécnica integral de voladura. El trabajo incluye conclusiones y recomendaciones precisas.

Sep 20, 2019

By Akira Yazawa

In the field of pyrometallurgy, the equilibrium evaluation has recently become easy by use of thermodynamic software, but it is strongly desired to estimate the amounts of non-equilibrium minor components to simulate practical processes. However, simple physico-chemical technique can not be applied to evaluate practical non-equilibrium components for many reasons. As an engineering solution for postulated equilibrium system, the activity coefficient is modified and introduced as the simulation parameter referred to as the "adjustment coefficient." This modified thermodynamic calculations were adopted to various sulfide roasting processes where many solid phases are participating and the system is not necessarily in equilibrium. Successful simulation was realized by assigning suitable adjustment coefficients for minor components which form a pseudo solid solution in the calcine. Some examples from sulfation roasting and dearsenizing roasting were discussed. In the smelting system, the loss of copper in slag is caused by equilibrium and non- equilibrium reasons, that is, chemical dissolution and entrainment of copper in slag. The total copper content of slag was simulated by use of the adjustment coefficient for entrained copper.

Jan 1, 1998

By Xia Lou, Hossein Dashti

Gas hydrates technology has been considered as an alternative method for carbon dioxide (CO2) separation. A wide range of studies have been reported in the past decade on the improvement of the separation efficiency by using chemical additives. While most of these studies have shown improved kinetics, thermodynamics and/or separation efficiency at the laboratory scale, there has been no quantitative analysis of the energy consumption for viable industrial applications. Comparison of the effectiveness of the chemical additives from separate studies or groups also is impossible. The present work is focused on the modelling of the hydrate-based CO2 separation process and provides a quantitative approach that is new in its analysis of the effectiveness of chemical additives in relation to the energy required and the kinetic parameters involved in the process.

Mar 1, 2018

By G. I. Mathieu

Research and development studies were carried out at the Canada Centre for Mineral and Energy Technology to produce a synthetic forsterite sand from asbestos tailings for Les Sables Olimag Inc. The National Research Council of Canada also supported and collaborated to the project. Theoretically, the technological approach consists of a heat at over 1300°C; however, the process without additive would result in the production of an enstatite-rich product (MgSiO3) having a fusion temperature less than 1600°C. The purpose was to foster the formation of forsterite (Mg2SiO4), a more refractory compound. The fabrication of the forsterite product requires pre-agglomeration of serpentine-MgO with a binder, which is stable at high temperature, to prevent the loss of the powdered magnesium oxide as dust in the kiln off gases and to maintain the mixture homogeneous during the process. Characterization of the end products with respect to mineral composition and thermal resistance are described. The synthetic forsterite in sand form was tested with success under a bath of liquid steel maintained at 1700°C for up to two hours. The advantages of the new sand and its potential applications will be reviewed.

Jan 1, 1992

By L. Filip

The roast-leach-electrowinning (RLE) process for zinc was modified to treat two typical complex concentrates containing zinc, lead, copper, gold and silver. Laboratory testwork results indicated that the optimum roasting temperature ranged from 700 to 800°C, in order to produce acceptable residual sulfur levels. The calcined concentrate was subjected to a three-stage leach sequence. The resulting leach solution was purified by hematitic precipitation and directed to the recovery of copper and zinc by solvent extraction and electrolysis. Alkaline smelting and subsequent electrolytic purification recovered the lead and precious metals from the leach residue. A flowsheet was developed based on the laboratory testwork results, and demonstrated in a large-scale pilot plant. The recoveries produced during the pilot plant operation ranged from 90 to 92% for zinc and copper, 85% for lead and 90% for gold and silver, respectively.

Jan 1, 1999

By Galen G. Waddell

Dilation and contraction of the rock surrounding horizontal access open-ings of a deep mine were analyzed during stope advance to determine what type of measurements, made with relatively inexpensive instrumentation, would best reflect the rock behavior. A variety of instruments, mostly mechanical extensometers, were used. Detailed descriptions are given of Down-the-hole extensometers, floating rockbolt clusters, transit surveys, and other instruments and measuring techniques. Although all of the radial-deformation-rate graphs illustrated useful rock behavior data, the most informative graphs were compiled from data procured with the radial extensometers that penetrated, to various depths, the rock around the access openings. An analysis is given of measurement data on the rock around lateral drifts and across and adjacent to the nearly vertical vein of the Star mine, Burke, Idaho. Several useful relationships were found between the rock deformation rate and the stoping process. Information was produced on the elastic state of rock around an underground opening, effectiveness of stope support, rheology of rock, zone of influence around stopes, effectiveness of rockbolts, axis of maximum strain in a plane perpendicular to the long axis of the lateral, and other phenomena. This information could be of particular value in determining location, design, and support of underground openings.

Jan 1, 1966

By Federick W. Miller

The Bureau of Mines has investigated the availability of columbium from 19 deposits (3 producers and 16 nonproducers) in 7 market economy countries (MEC?s). Brazil has the largest recoverable columbium resource, posessing approximately 2.39 million metric tons Wmt), or 69 pet of the MEC total (3.47 Mmt). The Western Hemisphere countries of Brazil, Canada and the United States contain 3.14 Mrnt of recoverable columbium or 90 pnt of the MEC total. Columbium recovered as a byproduct of tin mining is not included as part of MEC resources in this study. Currently producing mines are Araxa and Catalao in Brazil, and Niobec in Canada, These three mines have 2.42 Mmt of recoverable resources or approximately 69 pct of the MEC total. It is estimated that these mines, operating at full capacity, could satisfy cumulative MEC demand (based on an annual growth rate of 5.1 pct) for the next 20 yr. The United States is totally dependent upon foreign sources for its columbium supply. The majority of U.S. columbium is imported from Brazil in the form of steelmaking- grade ferrocolumbium. Canada has been the sole source of pyrochlore concentrates since Brazil discontinued exports in 1981. The United States also imports small (but important) quantities of columbium as columbite concentrates from Nigeria and Brazil, as columbite contained in tin slags from Thailand and Malaysia, and as synthetic concentrates from the Federal Republic of Germany.

Jan 1, 1986

By Jewel A. Gomes

Keywords: Electrocoagulation, arsenic removal, fuel cell, windmill, energy simulation, combined Fe-Al electrode assembly Arsenic contamination of well-water in different countries has caused signs and symptoms of arsenic poisoning. Although several physicochemical treatments are presently used for the removal of arsenic compounds from drinking water, an electrochemical treatment, electrocoagulation, is a promising processing technology and currently is the most efficient (above 99% removal) and environmentally friendly technique, particularly if combined with alternative energy sources. Wind and fuel cell technologies can be considered the most promising developmental clean power sources. We will discuss new insights into the materials processing mechanisms and show the coupling of electrocoagulation with fuel cells and simulated wind energy sources. Different electrocoagulation plate materials were considered, along varied currents from the fuel cell to produce maximum arsenic removal. Coupling these technologies will remove carcinogenic arsenic from water sources, and will exhibit efficient usage of these energy sources by producing pure water for human and agricultural consumption.

Jan 1, 2005

By C. R. Austin

Tan investigation described in this paper deals with the development of high-temperature alloys of the Konel series over a considerable period of time at the Research Laboratories of the Westinghouse Electric and Manufacturing Co. The word "Konel" has been coined to designate a class of alloys which are essentially nickel-cobalt-iron with other elements added, usually in small quantities. Most of these alloys contain titanium, usually about 2.5 per cent. The main consideration related to strength at high temperatures but the thermionic characteristics of the alloys was also of considerable importance. It is, however, with the mechanical properties at elevated temperatures that we are herein concerned. Much attention has also been devoted to their age-hardening characteristics. There is little need to stress the utilitarian aspect of this subject, as it has been discussed frequently. Alloys exhibiting superior properties at normal or elevated temperatures rapidly find many suitable applications. There may be some question, however, as to what constitutes a "superior alloy, " or an alloy that may have good service possibilities at high temperatures. The problem is complex and various means have been employed to predict the useful life that may be expected of a material. In recent years the "creep limit" has been used as the best means of evaluation. Such tests necessarily are prolonged and hence collection of data is very slow. In a general survey of many alloys therefore the creep test is not desirable and recourse must be had to much shorter time tests in order more rapidly to select alloys which appear to show promise. For this reason the present survey has been made using the high-temperature tensile test and a bend test developed by Howard Scott.1 In the tensile test the conditions have been standardized for all tests, so that values obtained are at least comparable, one alloy with another, although the absolute values recorded merely indicate the mechanical properties at the given temperature under a definite rate of loading.

Jan 1, 1931

By Donald W. Mitchell

Studies were made in the Bureau of Mines Experimental coal mine to evaluate the effectiveness of a few extinguishing agents and techniques for controlling a fire on a simulated mining machine. The investigation showed that water containing an alkali-metal salt or a surface-active (wetting) agent was more effective than water alone. For close attack, fog applications was the most effective technique studied; high rates of agent application controlled the fire more quickly than low rates. The ability to control the fire increased as the distance of attack decreased. Dry powders controlled the fire when applied by shovel but not when applied airborne by rock-dust distributor or by hand fire extinguishers. Dry alkali-metal salt powders (potassium and sodium bicarbonates and sodium tetraborate) quenched the fire more readily than limestone dust. In each instance the finer powder, the greater its effectiveness. In an open ventilated entry, smoke and hot gases backed against the air currents. An airspeed of 230 feet per minute was required to permit approach to within 10 feet of the fire. At lower airspeeds, approach could be made by extending the brattice across the bottom two-thirds of the entry, by pushing the smoke ahead with water sprays, or by discharging dust from a rock-dust distributor. In a dead-end entry, the fire was approached to within 30 feet by coursing fresh air along an airtight line brattice; however, it was safer, easier, and less time-consuming to attack the fire from a fresh-air base 100 feet away with a solid stream or by high-expansion foam; the latter method was more effective.

Jan 1, 1961

By Siddhartha Roy, Hemant Agrawal, Ram Madhab Bhattacharjee, Devi Prasad Mishra

Heat stress in underground coal mines is a major threat to the health and safety of the miners. Hence, managing heat and prediction of heat stress in advance is essential for maintaining a safe, healthy, and productive underground mine environment. In this study, an extensive ventilation survey has been carried out in three different deep and mechanized underground coal mines. The ventilation survey data are used to develop 3D simulation models with the VentSim™ software to predict the conditions that could cause heat stress in underground mine workings. The developed 3D models predicted well the wet-bulb globe temperature (WBGT), a recognized indicator of potential heat stress, with a coefficient of determination (R2) of 0.986, 0.994, and 0.993 for Mine-A, Mine-B, and Mine-C, respectively. Moreover, through 3D modelling, the applications of auxiliary ventilation and spot coolers to reduce the wet-bulb globe temperature (WBGT) for improving the underground workplace environment have been explored. The study demonstrated that auxiliary ventilation and spot coolers can help in significant reduction of heat stress conditions in an underground mine environment. By application of auxiliary ventilation, to increase air volumes, and spot coolers, the WBGT index in mining faces is reduced by 1.2–1.4 °C and 3.9–5.4 °C, respectively. Therefore, it is concluded that the spot coolers are more effective in reducing the heat stress conditions in hot and humid underground mine environments in comparison with auxiliary fan that is used to increase the air volume and velocity. This study opens up a new horizon of 3D simulations for heat stress management in underground mines. The outcome of this study will be useful for the researchers, mine operators, and environmentalists understanding the heat stress contributors and their control in underground mine environment.

May 10, 2023

This report, the fourth in an annual series, outlines recent trends and developments in the minerals industry. Discussed are new methods, equipment, techniques, and systems used to more effectively extract and process mineral products. Environmental considerations, health and safety standards, price controls, inflation, material shortages, and more dependence on foreign imports were problems faced by the minerals industry. Although productivity increased for most mineral commodities, the annual rate of increase has slowed in recent years, indicating a maturing technological situation. Growing concern for energy resulted in increased interest and research in alternative fuel sources. The primary concerns of metallurgists were pollution control and improved efficiency and performance of metallurgical processes, especially for reduction of energy consumption.

Jan 1, 1974

In early June, Rio Tinto?s chief executive officer Tom Albanese said that he expected demand for iron ore, aluminum and copper to double in the next 15 years. Driven by global industrialization and urbanization, Albanese said during his company?s annual general meeting that to meet the demand in 2030, the additional supply required will be equivalent to replicating the iron ore output of Australia?s Pilbara region every five years, adding another aluminum production complex the size of Canada?s Saguenay every nine months and developing another copper mine the size of Escondida, in Chile, each year.

Jan 1, 2010

By Andrzej Warczok

Intensive smelting of copper concentrate in Teniente Converter (CT) leads to the production of high grade matte and highly oxidized slag. Smelting slag is processed in Teniente vascular slag cleaning furnace. The slag composition and forms of copper affect the slag cleaning process and final copper content. Converting of high grade matte in Pierce-Smith converter faces some difficulties in proper slagging of iron oxides. Overblowing in copper making stage allows for slag liquidation but leads to high content of copper oxide in converter slag. Converter slag recycling into CT results in the increase of the participation of oxidic copper. Separate treatment of converter slag and its impact on the forms of copper in CT slag has been analyzed. Thermodynamic properties of a system and kinetic limitations pointed out the negative effect of converter slag recycling on the forms of copper and copper recovery in slag cleaning stage. Experimental results of slag cleaning tests in a crucible scale as well as microscopic examination of laboratory and industrial slag samples supported the above analysis and permitted to formulate recommendations of separate processing of converter slag. Keywords: copper, losses, slag, recycling

Jan 1, 2001

By I. M. Ahmed, R. S. Hassan, M. I. Aly

Extraction and separation of La, Sm and Dy ions from acidic sulfate-phosphate solutions was investigated using a cation exchange extractant, bis(2,4,4-trimethylpentyl) phosphinic acid, CYANEX 272, in kerosene. The influence of shaking time, equilibrium pH, extractant, sulfate and phosphate ion concentrations, diluent type and temperature was studied. The extraction was found to be pH-dependent, and increasing the phosphate ion concentration inhibited the extraction which was found to be endothermic. The stoichiometry of the extracted metal species was found to be MOH.H2OHSO4H2A.A2. Aliphatic diluents were found to enhance the extraction compared to aromatic diluents. The results showed that there was a separation mode between the metal ions when varying the hydrogen ion and sulfate ion concentrations, under the used experimental conditions. The investigated process was used for the recovery of La, Sm and Dy from the acid solution resulting from the leaching of low-grade monazite.

By A. A. Remes

High precision on-line particle size distribution measurement of mineral slurries has recently be-come available. It provides new tools for the development of monitoring and optimization methods for mineral grinding and separation circuits. The paper presents the development work at the Kemi chromite concentrator plant of Outokumpu Tornio Works in Northern Finland. The Kemi concentrator processes annually 1.2 Mt of chromium ore. The products are upgraded lumpy ore and metallurgical grade concentrate. The concentrate is produced using gravity separation methods, preceded by a rod mill - ball mill grinding stage. The separation process performance is strongly dependent on the particle size distribution of the grinding product at the Kemi plant. Particle size distribution has a significant effect on the concentrate grade and recovery. Currently a new laser diffraction based on-line particle size analyser is used for monitoring the grinding product. The analyser system allows the measurement of the whole cumulative particle size distribution simultaneously. It provides a wealth of new measurement information for process control. A monitoring and optimization scheme for grinding and gravity separation based on the particle size information is presented. The goal is to minimize the production of fine slime, and subsequently to improve the concentrate quality and minimize chromite recovery losses. Data-based recursively identified linear PLS process models are developed for optimization purposes. The preliminary results of the monitoring system operation in on-line use are presented.

Jan 1, 2014

By Yuexin Han, Mu. Yufan, Yanjun Li, Peng Gao, Yongsheng Sun

"The objective of this study was to evaluate the effect of reduction temperature, reduction time and binary basicity on the size of metallic iron particles in coal-based reduction products of an oolitic iron ore. The particle size distribution behavior (i.e., cumulative passing percentage and mean size of metallic iron particles) during reduction was investigated in detail. Results showed that the particle size distribution of metallic iron particles was strongly influenced by reduction temperature, reduction time and binary basicity. The cumulative passing percentage and mean size significantly increased with reduction temperature and time in the entire range of the experiments. All curves of cumulative passing percentage versus particle size under different conditions demonstrated a similar trend (continuous increase). The size distribution parameters and mean size slightly increased with increasing binary basicity and significantly decreased when the binary basicity exceeded 1.0. The size of metallic iron particles could be controlled by adjusting the reduction conditions during coal-based reduction.IntroductionThe increasing demand for iron ore coupled with diminishing high-grade iron ore reserves has resulted in the urgent need for innovative technologies in order to use refractory iron ores. Oolitic iron ore is a typical refractory iron ore with tremendous abundance globally. Based on published literature, oolitic iron ore reserves are approximately 140 million tons in Europe, 10 billion tons in China and 66 million tons in Pakistan (Kazmi and Abbas, 2001; Wu et al., 2011; Yu and Qi, 2011; Sun et al., 2013a). Therefore, the efficient exploration and use of oolitic iron ore resources can play a significant role in easing the mineral resource crisis in the iron and steel industry. However, oolitic iron ore cannot be effectively upgraded by traditional beneficiation methods due to its mineralogical characteristics (e.g., low grade of iron, poor liberation of iron minerals and high phosphorus content) (Li et al., 2011b; Sun et al., 2013b).Researchers recently proposed coal-based reduction followed by magnetic separation to recover iron from refractory iron ores (especially oolitic iron ore) and a certain degree of breakthrough was achieved in both theory and practice. In this technology, iron minerals in the ore are directly reduced by coal to metallic iron, which grows into particles of different sizes. After comminution and liberation, metallic iron is concentrated by magnetic separation (Srivastava and Kawatra, 2009; Sun et al., 2013a; Li et al., 2011b; Sun et al., 2013b; Li et al., 2011c; Gao et al., 2013). Sun et al. and Gao et al. used this technology to examine the recovery of iron from oolitic and Bayan Obo iron ores, respectively (Sun et al., 2013a; Li et al., 2011b; Li et al., 2011c). Metallic iron powder with more than 90% iron content was obtained as the final product, which could be used directly in steel production."

Jan 1, 2015

By Nathaniel Arbiter

After almost 60 years of application in this country froth flotation is still by far the most important process for concentrating metallic ores as well as a number of nonmetallic ores including fluorspar, phosphate rock, and potash. Its use on iron ores and coal is increasing. In the metals groups the largest plants and the greatest progress are found in copper and molybdenum mills, and the section of this paper that deals with applications will be found most pertinent to that field. During its long reign the flotation process has passed through several phases of evolution and has achieved progress in economy, efficiency, and simplicity of operation. Much of today's success in the flotation of low-grade ores can be attributed to that progress. Even more important to us than our ability to cope with today's conditions are tomorrow's problems, which we can contemplate with some prescience and confidence. Our annual production of copper, lead, zinc, and molybdenum--to mention only the most important metals occurring in the U.S. as sulphides--must be held at a high level in the face of a declining grade of ore. It is probable that the tonnage of such ores mined and processed will double in this country before the turn of the century. Not only will many of the existing flotation mills be enlarged again and again, but larger mills will be built here and abroad to meet our needs. At this moment, in fact, there are at least three proposed new foreign mills or expansions that envision 100,000 tons daily milling rate on copper ores. Table I (1) shows the trend in copper ore grades in U.S. in recent years:

Jan 1, 1970

By C. R. Austin

THE investigation described in this paper deals with the development of high-temperature alloys of the Konel series over a considerable period of time at the Research Laboratories of the Westinghouse Electric and Manufacturing Co. The word "Konel" has been coined to designate a class of alloys which are essentially nickel-cobalt-iron with other elements added, usually in small quantities. Most of these alloys contain titanium, usually about 2.5 percent. The main consideration related to strength at high temperatures but the thermionic characteristics of the alloys was also of considerable importance. It is, however, with the mechanical properties at elevated temperatures that we are herein concerned. Much attention has also been devoted to their age-hardening characteristics. There is little need to stress the utilitarian aspect of this subject, as it has been discussed frequently. Alloys exhibiting superior properties at normal or elevated temperatures rapidly find many suitable applications. There may be some question, however, as to what constitutes a "superior alloy, " or an alloy that may have good service possibilities at high temperatures. The problem is complex and various means have been employed to predict the useful life that may be expected of a material. In recent years the "creep limit" has been used as the best means of evaluation. Such tests necessarily are prolonged and hence collection of data is very slow. In a general survey of many alloys therefore the creep test is not desirable and recourse must be had to much shorter time tests in order more rapidly to select alloys which appear to show promise. For this reason the present survey has been made using the high-temperature tensile test and a bend' test developed by Howard Scott.1 In the tensile test the conditions have been standardized for all tests, so that values obtained are at least comparable, one alloy with another, although the absolute values recorded merely indicate the mechanical properties at the given temperature under a definite rate of loading.

Jan 1, 1931