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By Duan Baofu, Wang Xuguang, Song Jinquan

In this paper, the model of optimizing selection on preparation of Powdery Emulsion Explosives(PEE) is established by the Neural Net Theory(NNT). On the basis of some data in the study of PEE, the training, prediction and optimizing selection of the Neural Net (NN) model are finished by a compiling procedure. The results indicate that the model is helpful to the preparation of PEE and worthy to extend and apply broadly. KTYWORDS Neural Net Powdery Emulsion Explosives Preparation Optimizing Selection

Jan 1, 2003

The reported values of the standard reduction potentials of the Au(NH3)2+/Au(0) and Au(S2O3)23-/Au(0) couples are reviewed to emphasise the experimental difficulties associated with the measurement of reliable values for these quantities. The standard reduction potential for Ag(I)/Ag(0) in ammonia and thiosulphate solutions measured at ionic strength 0.1 and 25oCis used to predict the following relevant stability constants () for gold complexes based on the linear free energy correlations: Au(NH3)2+2 = 1013, Au(S2O3)23-2 = 1024 and Au(NH3)43+4 = 1033. The equilibrium constant ( 10-11) for the reaction Au(S2O3)23- + 2NH3 = Au(NH3)2+ + 2S2O32- based on these stability constants is in reasonable agreement with the measured value (10-9) based on potentiometric and spectroscopic data when excess ammonia was added to a solution of Na3Au(S2O3)2. This also indicates that the stability constant of Au(NH3)2+ is 9 to11 orders of magnitude less than that of Au(S2O3)23-. Relevant species distribution and Eh-pH diagrams based on the revised data are presented.

Jan 1, 2003

By I. V. Lunkin, E. B. Muhamedzhanov, A. B. Begalinov, B. R. Rakishev

Almost all the ore deposits of ferrous, non-ferrous and rare metals of Kazakstan, are exploiting by the open-cast method, are the complex-structural, multi-component ones. Their rational working requires precise organization of extracting works. In this connection it is necessary to set up the best intercommunications between drilling-blasting, excavating-loading and transport works. This requires the stable functioning of the quarry for dispatch of ore raw material of required quality with minimum of corresponding expenses. For this purpose, proceeding from the quarry’s ore output and the assumed parameters of the exploitation system, the first problem about rational arrangement of excavating-loading equipment in extracting faces is solved. By solving the problem the model with dynamic, adapting properties had been used. It was solved numerically by the method of statistical tests. By setting up the necessary link between type-sizes of excavating-loading and transport equipment, the minimum prime cost of loading and transportation of 1 ton of mining mass from the face to the receiving station was adopted as the criterion of optimality. Depending on the type of excavating-loading equipment, the efficiency function may be different. By using wheel loaders, their displacement between the faces is possible, therefore, the efficiency function of the problem may include expenses for their displacement. By using excavators like power shovel, the problem’s restrictions must exclude its displacement between the faces. The efficiency function consists of minimum expenses for loading, proceeding from set of volumes of extraction from the faces, satisfying required quality. The volumes of extraction from the faces, satisfying required quality of ore in output stream, are determined by the method of statistical tests. Sample range is given, proceeding from the restrictions for maximum productivity of the excavating-loading equipment. Volumes of extraction, not satisfying required quality, are cut off. The efficiency function meaning is then determined and minimized. Keywords: Excavating-loading equipment, its placing in extracting faces, optimal load-carrying capacity, specific expenses for loading and transportation of mining mass.

Jan 1, 2003

By H. Masuda

The lijima Zinc Refinery started operation in 1972, and has today an annual capacity of 200,000t-Zn. The hematite process was employed for the first time and the ideal of waste-free refinery has been pursued for 30 years. In recent years, however, only half of the hematite produced would be sold to the cement industry and hence a reduction of arsenic level has been necessary in order to sell the entire amount produced. The arsenic cementation process with zinc powder, developed through a long time laboratory research was found among some options as the best for the hematite process. The construction work started in 2000 and the facility was put into operation in 2001, As a result in the same year all hematite were sold to the cement industry. The outline of this project, present operations and technical issue are reported in this paper.

Jan 1, 2003

By V. L. Zajakowski, J. D. Gargulak

The current political climate has forced multinational cement manufacturers to consider technology that minimizes GO, emissions. Along with this environmental issue, individual manufacturing facilities are under constant pressure to increase productivity and lower costs. The use of processing or functional additions can help address these difficult demands by maximizing the extender content in blended cements. Recently, cement standards have been modified such that additions can be employed to improve quality. By using these "cement performance enhancers," the cement manufacturer can maximize extender content of cement thus optimizing plant economics, while meeting local quality standards and minimizing greenhouse gas emissions.

Jan 1, 2003

By Y Potvin

Risk assessment in the mining industry is currently a topic of great interest with risk methodologies being increasingly applied beyond the traditional areas of finance and feasibility to analyses of risks due to various physical hazards including chemical, electrical, mechanical and geotechnical sources. The application of risk analysis and evaluation techniques to the management of personnel safety is being promoted by both industry and regulators but, particularly for geotechnical hazards, often there are inadequate databases for a meaningful quantitative calculation of risk. In Western Australia over the decade 1987 - 1997, the annual fatality rate for underground mining has averaged at approximately 1.3 in 1000 employees with rockfalls/rockbursts accounting for over half of these deaths (Prevention of Mining Fatalities Taskforce, 1997). Recent improvements have been made since this time, perhaps halving the annual fatality rate, mainly due to industry improving ground control measures and implementing various recommendations from the Prevention of Mining Fatalities Taskforce (1997). However there still remain a large number of unknowns when trying to address the complex area of geotechnical risk in mining. Risk calculations require information about the source of the hazard, the people or assets exposed to the hazard (the æelements at riskÆ) and the effects on these vulnerable elements if the hazard actually occurs (the potential consequences). To date, little information has been available on the exposure of mining personnel and equipment to underground hazards other than occupational safety studies on chemicals, heat, dust, etc. This paper concentrates on underground geotechnical risks and presents a data collection and rating system for the exposure of both the underground workforce and equipment to rockfalls and rockbursts. The methodology considers exposure times, personnel protection levels and hazard proximities to give exposure ratings for the major underground mining activities and hence rate different locations within a mine. This exposure methodology is then applied to the workforce and production/ development cycles in an actual WA underground mine, creating a snapshot map of differing levels of personnel exposure across the mine.

Jan 1, 2003

By Hiroyuki Matsuura

The effects of P20S or Na20 addition on the reaction rate of CO2 dissociation on the surface of FexO-base molten oxides was investigated at 1773K by isotope exchange methodl-6_ The rate constant decreased with increasing P20S content of molten oxides and the residual rate constant was observed at high P20S content On the other hand, the rate constant increased with increasing Na2O content for FexO-SiO2 melts. The rate constant was evaluated by the composition of oxides and the rate controlling step of CO2 dissociation was discussed.

Jan 1, 2003

By E. Swart

The purpose of this paper is to provide an overview of the current legislative framework for mine closure within South Africa as well as the new requirements in terms of the Mineral and Petroleum Resources Development Act, 2002. The roles and responsibilities of Government, the mining industry and other stakeholders and confusion caused are also highlighted.

Jan 1, 2003

By T. Proietti, L. Mongiovì, L. Simeoni

Reliable estimates of the kinematic characteristics of movements are obtained by using a statistical model SSM. This model represents a useful tool for the management of alert and alarm systems. L'élaboration des données du déplacement médian d'un modèle statistique SSM opportun fournit des estimations fiables des caractéristiques cinématiques du mouvement. Le modèle peut être ainsi utilisé pour la gestion des systèmes d'alarme. Die Bearbeitung von Bewegungsdaten anhand eines geeigneten statistischen Modell SSM ergibt vertrauliche Abschätzungen der kinematischen Eigenschaften der Bewegung. Das Modell kann also für das Management von Alarmsystemen verwendet werden.

Jan 1, 2003

By Y. H. Hatzor

ABSTRACT: A fully dynamic, two dimensional, stability analysis of a highly discontinuous rock slope is demonstrated in this paper. The studied rock slope is the upper terrace of King Herod’s Palace in Masada, situated on the western margins of the seismically active Dead Sea Rift. The dynamic deformation of the slope is calculated using a fully dynamic version of DDA in which time dependent acceleration is used as input. The analytically determined failure modes of critical keyblocks in the jointed rock slope are clearly predicted by DDA at the end of the dynamic calculation. It is found however that for realistic displacement estimates some amount of energy dissipation must be introduced into the otherwise fully elastic, un-damped, DDA formulation. Comparison of predicted damage with actual slope performance over historic time span window of 2000 years allows us to conclude that introduction of 2% kinetic damping should suffice for realistic damage predictions. This conclusion is in agreement with recent results of Tsesarsky, Hatzor and Sitar (2002) who compared displacements of a single block on an inclined plane subjected to dynamic loading obtained by DDA and by shaking table experiments. Using dynamic DDA it is shown that introduction of a simple rock bolting pattern completely stabilizes the slope. RÉSUMÉ : On présente dans cet article une analyse bidimensionnelle complète de la stabilité d’une pente rocheuse très fracturée. La pente rocheuse étudiée est la terrasse supérieure du Palais du roi Hérode à Massada, située sur la rive Ouest du Rift sismiquement actif de la Mer Morte. La pente est constituée de blocs de dolomite raide présentant une stratification sub-horizontale et des joints sub-verticaux. La déformation dynamique de la pente est calculée en utilisant une version entièrement dynamique de l’Analyse de Déformation Discontinue (DDA) où l’accélération dépendant du temps est utilisée comme donnée. Les modes de rupture déterminés analytiquement des blocs clés dans la pente rocheuse fracturée sont clairement prévus par l’approche DDA à la fin du calcul dynamique. On trouve cependant, que pour obtenir des estimations réalistes du déplacement, il faut introduire un facteur de dissipation énergétique sans lequel la formulation DDA serait totalement élastique et sans amortissement. En comparant l’endommagement prévu avec les caractéristiques de la pente sur une période historique de 2000 ans, nous pouvons conclure que l’introduction d’un amortissement cinématique de 2% suffit pour obtenir de prévisions réalistes. Cette conclusion est conforme aux résultats récents de Tsesarsky, Hatzor and Sitar (2002) qui ont comparé les déplacements d’un bloc isolé sur un plan incliné sous chargement dynamique obtenus avec l’analyse DDA et à partir d’essais sur table vibrante. ZUSAMMENFASSUNG: En utilisant une modélisation DDA dynamique on montre que l’introduction d’un système simple de boulonnage stabilise la pente.In dieser Veroeffentlichung wird eine vollstaendig dynamische, zweidimensionale Stabilitaetsanalyse eines hoechst diskontinuierlichen Steinhangs dargestellt. Der untersuchte Hang ist die obere Terrasse des Herodespalastes in Massada, welche in den westlichen Randgebieten des seismisch aktiven Toten Meer Grabens liegt.Die dynamische Deformation des Berghangs wird mit Hilfe einer vollstaendig dynamischen DDA-Version berechnet, in welcher als Input die zeitabhaengige Beschleunigung eingegeben wird. Die analytisch bestimmten Versagensarten kritischer Schluesselbloecke in diesem zerkluefteten Steinhang werden durch Anwendung von DDA am Ende der dynamischen Berechnung klar vorausgesagt. Es zeigt sich jedoch, dass fuer realistische Dislozierungs-Abschaetzungen ein gewisses Mass an Energieverlust in der sonst vollstaendig elastischen, ungedaempften DDA-Fassung einbezogen werden muss. Der Vergleich des vorhergesagten Schadens mit dem aktuellen Verhalten des Berghangs waehrend einer historischen Zeitspanne von 2000 Jahren erlaubt uns zu schliessen, dass ein Zusatz von 2% kinetischer Daempfung fuer eine realistische Vorhersage des Schadens ausreichen sollte. Diese Schlussfolgerung steht im Einvernehmen mit neuen Ergebnissen von Tsesarsky, Hatzor und Sitar (2002), welche die Dislozierung eines einzelnen Blocks auf geneigter Ebene unter dynamischer Belastung – unter Anwendung von DDA und “shaking table”-Versuchen – verglichen. Mit Hilfe der dynamischen DDA wird gezeigt, dass der Steinhang durch Anwendung einer einfachen Steinschraubenstruktur vollkommen stabilisiert werden kann.

Jan 1, 2003

By M A. Harrington-Baker, J M. Trudnowski

Sulfate-reducing bacteria (SRB) have the ability to immobilise dissolved metals by precipitating them as sulfides, provided that a favourable biochemical environment is created. Such an environment includes the presence of sulfate, anaerobic conditions and the availability of organic carbon. If such conditions are engineered within a reactive barrier or field-bioreactor, most metals can be effectively removed. To demonstrate this concept, three passive SRB field-bioreactors were constructed in 1998 at an abandoned mine site in the vicinity of Butte, Montana, USA to treat acid mine drainage with characteristic elevated concentration of metals and low pH. Performance of the field-bioreactors, using aqueous samples, was monitored over 32 months until the project was terminated, field-bioreactors were decommissioned and solid matrix sampling of the reactive matter was performed. The most important analytical results are presented in this paper together with conclusions regarding the appropriateness of the field-bioreactors construction features. Only Zn, Cu, and Cd were being removed as sulfides due to SRB activities. Changes in concentrations of other metals (Fe, Mn, Al, As), which do not necessarily precipitate as sulfide, seemed to be affected by SRB only in an indirect manner by responding to increased pH caused by SRB activity. An innovative cellular containment system used for placing organic matter worked very well in preventing settling of the organic matter and ensuring uniform flow of AMD throughout the entire cross-section of the organic carbon with no preferential flow paths This demonstration was funded by the US EPA and was jointly administered by the EPA and the US DOE under DOE contract number DE-AC22-96EW96405. The project was implemented by MSE Technology Applications, Inc, Butte, Montana, USA.

Jan 1, 2003

By Nickolas J. Themelis

Nearly thirty two million tons of municipal solid wastes (MSW) are combusted annually in over one hundred U.S. Waste-to-Energy (WTE) power plants, thus reducing the use of fuel oil by about 1.6 billion gallons of fuel oil. One of the advanced WTE processes is the 0.9-million ton/y SEMASS facility at Rochester. Mass. Most of the combustion in the three giant combustion chambers occurs while the injected shredded wastes are in suspension, i.e .? in flash combustion mode. The velocity. temperature, and concentration profiles in the SEMASS combustion chamber were simulated by representing the combustible fraction of MSW by the simplified formula C6HIO04 and using the CFD program Fluent to solve the turbulent energy and mass transport equations. After validation against plant data. this model will be used to examine options for increasing the productivity of WTE combustion chambers, such as optimum distribution of primary and secondary air and oxygen enrichment.

Jan 1, 2003

By S. G. Galbraith

We have used the principles of supramolecular chemistry to develop reagents to transport metal salts. These reagents have separated charged "compartments" which recognize a metal cation and its attendant anion(s). They are easy to manufacture as they are structurally related to the commercial hydroxy-oxime extractants for copper. Efficient protocols for loading and stripping of these extractants depend on the novel feature that they bind the metal salt in a zwitterionic form of the ligand. Transfer of the phenolic protons to the pendant amines generates the charged "compartments" to accommodate the metal cation and its attendant anion(s). This paper focuses on how these types of reagent can be used to recover base metals from sulfate and chloride media in flowsheets in which solvent extraction effects separation and concentration operations, interfacing between conventional leach and electrowin/reduction processes. Work on the development of reagents that have high selectivity for metal chloride/sulfate transport, convenient stripping protocols and appropriate hydrolytic stability will be described.

Jan 1, 2003

By K. L. Myers, R. Espell, C. Deringer

Construction of the AA Pad reclamation was completed in the fall of 2000. Seeding of the ET cover began in the late fall of 2000 and continued through May of 2001. On Saturday afternoon, June 1, 2002, a large, very localized thunderstorm struck the reclaimed AA Pad site. Eyewitnesses present at the time described a dark storm cloud parked above the site for less than half an hour. Average rainfall intensity was measured to be 122 mm (4.8 inches) per hour and peak rainfall intensity was estimated to be 213 mm (8.4 inches) to 259 mm(10.2 inches) per hour. At the time of the storm, the construction was less than two (2) years old and the vegetation had only a single season of growth. The entire period from the end of construction until the date of the storm was a drought period with below normal precipitation. Other than a few small snowmelt events, there was no precipitation event large enough to produce any significant flow in the channel network. Therefore, the very first significant runoff event was the extreme event of June 1, 2002. The storm essentially represents a large-scale field test of the design concepts used at the AA Pad site. Shortly after the storm, data was collected and analyzed with the intent of learning as much as possible about the performance of the cover system design with the expectation that the newly acquired knowledge might be utilized in future designs to further improve the performance of similar cover systems during extreme events.

Jan 1, 2003

INAP was formed in 1998 by a number of major mining companies, with a view to sharing acid rock drainage knowledge and experience, and to coordinate global research on the management of sulfidic mine wastes. INAP is now moving to further strengthen its global role by networking with regional organisations that are active in the area of ARD, including MEND 3/NEDEM 3 in Canada, the ADTI in the USA and ACMER in Australia. The INAP-Regional Organisation partnership will be formally launched at the 6th ICARD.

Jan 1, 2003

bauma 2004 will feature a couple of firsts for one of the world’s largest construction and building materials machinery exhibitions. The event is scheduled for March 29 through April 4 of next year at the New Munich Trade Fair Center in Munich, Germany. For the first time, bauma will feature an exhibition area dedicated to mining equipment and technology. Also for the first time, the Commonwealth of Independent States (CIS) will be a partner region of bauma.

Jan 1, 2003

By M. Wright, A. H. Mwale

Opportunities to promote enhanced eco-efficiency (i.e. the simultaneous improvement in economic and environmental performance) for the minerals industry exist across the whole value chain. However, given the current operational models of major companies within the industry, and their focus on refining of primary ore bodies, it is important to understand where such opportunities might lie within minerals beneficiation, as it is here that major environmental pressures are felt. This paper examines the combination of unit technologies in a minerals beneficiation train, and explores the inter-relationship between energy input and water consumption for a given mineralogy and product recovery, as these are two critical environmental issues which affect the overall viability of many minerals plants. In particular, we review constitutive relationships for each of the sub-processes of comminution, flotation, and tailings dewatering, and suggest how these might be integrated into a unified hybrid model, with particle size distribution as the key design variable. Such a model can then be used to explore the trade-offs between different performance objectives (be these technical, economic or environmental) as part of a multiple-objectives optimisation exercise. In this way, it may become practical to envision situations in which concentrate grade and recovery are sacrificed, marginally, in order to reduce energy demand in comminution, and improve overall water recovery. In addition, this work provides a useful baseline against which to analyse the potential for dry processing. This becomes more relevant as the industry commits to advancing the sustainable development agenda in the face of the increasing life -cycle costs and impacts of minerals processing operations, coupled to declining ore body grades, and the desire to maximise recovery of minor and trace elements. Some specific observations for copper are offered, supported by operational data from Zambian copper mines.

Jan 1, 2003

By B Dold

Western Europe is a dynamic region, with an emerging co-operation between the individual nations both politically, economically, technically and scientifically. The European Union, today with 15 member States and with a range of central European States applying for membership, is a catalyst for this Cupertino, using a combination of EU funds, for financing research initiatives, and legislation to enhance development of technology and environmental performance. Europe is a major net importer of metals but with a large potential for own production, in particular in the accession countries. The metals and mining sector is furthermore identified as having a large potential to generate wealth both in todayÆs EU and in the future, widened Union. This paper provides a chart of examples on the many research initiatives presently underway in Europe, addressing environmental issues related to mining. The list of programmes and projects does not claim to be complete; it is rather an illustration on the wideness of the approach, describing various ways for transboundary Cupertino. The approach taken by many of the programmes goes beyond the strict ARD scientific area and therefore only a limited number of the many programmes can be identified as ARD research programmes. Also national programmes, without EU funding, are operating, eg in Sweden, Germany, and UK. The picture is continuously changing with new programmes being commissioned and old ones being completed.

Jan 1, 2003

By P. Amponsah-Mensah

Dilution of ore has a major impact on economics of a mine. The magnitude of dilution depends on mining method, stope dimensions, reef and host rock quality, wall support and drilling accuracy. The main contributing factor is the presence of very weak graphitic shear band of varying thickness in and around the reef. The reef, at Obuasi, is generally steeply dipping and open stoping is the predominant mining method. The stability of the stope walls limits the stope dimensions. Various options for allowing larger stopes for higher productivity and limiting dilution are analysed. The most economic way is to reinforce the walls with systematic cablebolt supports. This option does not only add the support cost but also requires additional cost of access development. These conflicting requirements are continually being optimised at the mine for the economics of dilution control. La dilution du minerai à un impact majeure sur l’économie d’une mine. La quantité de matériel diluant le minerai dépend de la méthode d’extraction, de la dimension des chantiers d’abattage, de la qualité du filon et de la roche mère, du support des épontes et de la précision du forage de production. Le facteur principal qui contribue à la dilution est la présence d’étroites zones cisaillées qui contiennent du graphite ayant différentes épaisseurs à l’intérieur et autour du filon. Le filon, à Obuasi, est généralement à fort pendage et la méthode d’abattage principale est par chantier long-trous. La stabilité des épontes est le facteur qui détermine la dimension des chantiers d’abattage. Differentes options ont été analysées de façon à permettre de plus larges chantiers de manière à augmenter la productivité tout en limitant la dilution. Le moyen le plus économique est de renforcer les épontes avec des cables d’acier cimentés forés de façon systématiques. Cette option n’augmente pas seulement les coûts de support mais aussi les coûts de développement. Ces besoins contradictoires sont continuellement revisés à l’opération afin d’optimiser l’économique par le contrôle de la dilution. Verdünnung des Erzes hat eine spürbare Auswirkung auf die Ekonomie einer Grube. Die Größe der Verdünnung hängt von gewinnenmethode, von den Stopemaßen, von der Reef- und Wirtsfelsenqualität, von der Wandunterstützung und von der bohrengenauigkeit ab. Der beitragende Hauptfaktor ist das Vorhandensein einer sehr schwachen graphitic Scherbandes unterschiedlichen Stärke in und um der Reef. Der Reef, bei Obuasi, taucht im allgemeinen steil ab und geöffnete Aufstemmung ist die überwiegende gewinnenmethode. Die Stabilität der Wand begrenz die Stope grösse. Verschiedene Wahlen für das Erlauben der größeren Stopes für höhere Produktivität und das Begrenzen von Erzesverdünnung werden analysiert. Die ökonomischste Weise soll die Wände mit systematischen Kableankerbolzenunterstützungen verstärken. Diese Wahl addiert nicht nur die Kosten der Unterstützung aber erfordert auch zusätzliche Kosten fuer Zugangsentwicklung. Diese kontroversen Anforderungen werden fortwährend an der Grube analysiert um die Verdünnungkontrolle zu optimieren.

Jan 1, 2003

By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite (CuzS) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical eqUilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003