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By Qing-Yun Huang, Xiao-Yi Zeng, Bing Xie, Hong-Yi Li, Jia-Rong Yan

"In order to utilize vanadium resource in vanadium-titanium magnetite ore efficiently, vanadium distribution ratio between hot metal and slag should be improved during BF process, meanwhile the precipitating of Ti(C,N) in slag must be minimized. Effects of temperature, Ti02 content in the slag and basicity on vanadium distribution between slag and hot metal were investigated by experiment and thermodynamic calculation. The results indicated that high temperature, low Ti02 content and high binary basicity of slag were beneficial to increase the vanadium distribution ratio. The effects of temperature and Ti02 content in slag on vanadium distribution were stronger than that of slag basicity.IntroductionVanadium is an important element that is widely used in industrial fields. Most of vanadium resource is hosted in vanadium bearing titanomagnetite [l]. Vanadium bearing titanomagnetite is thus one of the domainate raw materials to produce the vanadium products. In other words, the comprehensive utilization of vanadium bearing titanomagnetite is beneficial for vanadium resource utilization. Vanadium bearing titanomagnetite sources are abundant in Pan Xi of China [4]."

Jan 1, 2013

By Min Xiaobo

As for treatment of zinc-containing wastewater, traditional SRB (Sulfate Reducing Bacteria) process was used, however, there exist two defects, like toxicity of heavy metal ions and high effluent COD (Chemical Oxygen Demand) value. In this study, a new technique, called ISIS process (Immobilized SRB sludge beads with Inner cohesive carbon Source), in which SRB sludge is embedded in carrier of PVA (Polyvinyl Alcohol) with carbon source that adsorbed on certain material, is put forward for the first time to overcome the two defects existing in traditional SRB process. Furthermore, it has been shown that compared to traditional SRB process, ISIS process increases average zinc removal rate up 30%, average sulfate reduction rate up20%, and decrease average effluent COD value to meet discharge standards. If activated carbon is selected for carbon source adsorption and fixing material, and PVA for immobilization material, the zinc removal rate can reach above 98% under the conditions of 35 and pH 6. Meanwhile, the mechanism of zinc removal has been determinated according to the results from SEM (Scanning Electronic Microscope) and XRD (X-Ray Diffraction).

Jan 1, 2006

By Ravi S. Bellur-Ramaswamy, Daniel A. Tortorelli, Robert Haber, Nahil A. Sobh

We optimize continuous quench process parameters to produce functionally graded aluminum alloy extrudates. To perform this task, an optimization problem is defined and solved using a standard nonlinear programming algorithm. Ingredients of this algorithm include 1) the process parameters to be optimized, 2) a cost function: the weighted average of the precipitate number density distribution, 3) constraint functions to limit the temperature gradient (and hence distortion and residual stress) and exit temperature, and 4) their sensitivities with respect to the process parameters. The cost and constraint functions are dependent on the temperature and precipitate size which are obtained by balancing energy to determine the temperature distribution and by using a reaction-rate theory to determine the precipitate particle sizes and their distributions. Both the temperature and the precipitate models are solved via the discontinuous Galerkin finite element method. The energy balance incorporates nonlinear boundary conditions and material properties. The temperature field is then used in the reaction rate model which has as many as 105 degrees of- freedom per finite element node. After computing the temperature and precipitate size distributions we must compute their sensitivities. This seemingly intractable computational task is resolved thanks to the discontinuous Galerkin finite element formulation and the direct differentiation sensitivity method. A three-dimension example is provided to demonstrate the algorithm.

Jan 1, 2001

By Chen Yongming

In order to eliminate the serious environmental pollution caused by low concentration of sulfur dioxide smoke in antimony smelters, a new smelting process, named as reducing-matting smelting, is proposed in this paper. The effects of technical conditions such as smelting temperature, smelting time, Pyrite cinder addition and the amount of additive on the smelting of stibnite concentrate have been investigated by the method of single-factor experiment. The results show that the optimum conditions are as follow: The amount of pyrite cinder is 1.2 times of its theoretical amount. The addition of soda and sodium sulfate is 15% and 72.6%, respectively, to the amount of stibnite concentrate when the total amount of sodium is 30%. The reducing-matting smelting is conducted at 1100°C for 2h then the smelting temperature is raised to 1200°C for 50min. Under the optimum conditions, the direct and total recovery ratio of antimony can gain 90.99% and 98.87%, respectively, and the fixed ratio of sulfur is higher than 99%.

Jan 1, 2006

By Zhengde Pang, Xue-wei Lv, Guibao Qiu, Chenguang Bai, Zhiming Yan

The viscous behavior of molten slags has played an essential role in determining the performance and productivity of the ironmaking process. In this paper, the viscosity and free running temperature in CaO-SiO2-Al2O3-9 mass% MgO-TiO2 slag has been measured at different content of Al2O3 and Al2O3/SiO2 ratio. In addition, the slags viscous activation energy has also been calculated. The results show that the TiO2 as a basic oxide content from 1 to 5 mass% can reduce the viscosity and free running temperature, and moderate content of TiO2 in high alumina blast furnace slag remains effective for reducing viscous activation energy and free running temperature.

Mar 1, 2018

By M. A. Vera

This paper proposes a simple two-parameter model for the typical inverse relationship between recovery and flotation concentrate grade. The model is based on the mineralogical limitations imposed by the material properties. One parameter (R*) describes the proportion of metal content which is floatable, and the other (b) is the rate at which the fastest floating particles are being contaminated by the other less valuable particles present in the mineral system. One significant feature of the recovery-grade curve is that initial recovery (i. e. R ? 0) is at the purest attainable mineral grade, (but as recovery rises the cumulative grade of the concentrate tends to the feed grade. The ideal recovery-grade curve for a particular mineralogical system can be obtained by release analysis: the release analysis curve determines the maximum or limiting separation efficiency. The model proposed in this work is similar to the linear recovery - cut-off grade model of Dell (1), but has the advantage of describing the whole curve.

Jan 1, 1999

By R. Altman

A Brookfield viscometer fitted with a stainless steel bob was used to measure the viscosity of industrial lead blast furnace slags between 1126 and 1298°c. Slag oxidation state was characterized by first annealing the? slag samples at 750°c in sealed copper tubes in order to precipitate magnetite crystals. The magnetite concentration was then measured on an Outokumpu Saturated Magnetic Analyzer. Using an Arrhenius-type equation, a viscosity model was developed by regression. The equation below accounted for 75% of the variability in the data used to generate the regression coefficients and, on average, could predict viscosity within ± 12% of the measured value. The greatest difficulty encountered in measuring viscosity was due to the occasional presence of solids in the slag which caused, at times, erroneously high viscosity measurements. Precautions to minimize this problem are outlined in the text.

Jan 1, 1985

By Satu Strömberg

Four different nickel concentrates were oxidized in a laboratory scale laminar flow furnace in simulated flash smelting conditions. The major nickel- and iron-bearing minerals in the con- centrates were pentlandite, violarite, gersdorffite, and pyrite and pyrrhotite, respectively. Thermal decomposition, ignition and oxidation behavior of nickel and iron sulfides were examined by using optical and scanning electron microscopy. General reactivity of the concentrates was monitored with sulfur removal which was most effective in violarite-based concentrate. Pentlandite-concentrates needed higher experimental temperatures for complete desulfurization and gersdorffite-based concentrate contained 5 - 10 % of the original sulfur even in the most oxidizing conditions studied (1 100°C, 50 vol-% 02). The reactivity of the iron minerals was found to depend on the other minerals present in the concentrate. In this paper, the observed re- action products and mineralogical changes are presented and preliminary conclusions of possible reaction mechanisms of nickel-bearing minerals are discussed.

Jan 1, 1997

By Shadia Ikhmayies

In this work Thermo-Calc software was used to calculate the phase diagram of the Fe–Si system. The deduced phase diagram includes twenty fields, where three fields represent pure phases; two solid solutions and a liquid phase. There are several fields of two co-existing phases; mixed solid phases, and mixed solid with liquid phases. A set of eutectic and eutectoid points were found, where transformation reactions and temperatures were identified. The results were compared with results in the literature and good agreements with some differences were found. This study is a step to understand the phase diagram of Ca–Fe-Si system for refining metallugical grade silicon (MG-Si).

Mar 1, 2018

By Pengfu Tan

A thermo-chemical model of the copper P-S converter and a viscosity model for the converter slag have been developed to predict the behavior of magnetite in the converter slag, amounts of slag and matte, compositions of slag and matte, volume of the bath, bath temperature, slag blow endpoint determination, SEMTECH OPC signals, and the viscosity of converter slags. The predictions of bath temperature, slag and matte compositions, and magnetite content in the slag have been validated by the industrial data. The effects of fluxing strategy, returns and skim charges, oxygen enrichment, and temperature on the magnetite formation in the slag have been predicted and discussed. The effect of oxygen potential, SiO2/Fe in slag, detection of slag blow endpoint, and temperature on Fe3O4 content in converter slag, slag viscosity, liquidus temperature of converter slag and skimming operation has been modeled and discussed as well. Some applications of the industrial operations have been presented.

Jan 1, 2009

By Guan-zhou Qiu, Shui-shi Liu, Yu-feng Guo, Tao Jiang

"The preparation of high-quality synthetic ruitle from electric furnace titanium slag was systematically investigated by activation roasting followed by acid leaching process. The results showed that impurities such as Ca and Mg in titanium slag can be effectively removed and TiO2 grade of the product was markedly improved by the process. High-quality synthetic rutile containing 88.54% TiO2, 0.42% (CaO+MgO) was obtained under the conditions that roasted with 7.5%(wt) H3PO4 at 1000 oC for 2h, followed by two-stage leaching in boiling dilute sulfuric acid for 2h. Mechanism studies showed that anosovite solid solution and silicate minerals were reacted with phosphoric acid in the roasting process. As a result, titanium components in titanium slag turned into rutile (TiO2) and impurities were transformed into acid-soluble phosphate and quartz.IntroductionWith the gradual depletion of natural rutile and the rapid development of titanium industry in China, the natural rutile reserves cannot satisfy the requirement for production of titanium pigment and titanium sponge. Ilmenite is, therefore, becoming main raw material for titanium industry. However, because of its low TiO2 grade, it generally requires preconcentration to titanium-rich material such as titanium slag or synthetic rutile [1-3].Ilmenite resources are extremely rich in Pan-xi area of China, which account for 90.54% of total ilmenite reserves in China [4]. The titanium slag produced by electric smelting of ilmenite concentrate has high contents of Ca and Mg, and is not suitable as a raw material for chloride process and titanium sponge production. Therefore, upgrading titanium slag to prepare raw material suitable for chloride process and titanium sponge production has important significance for the development of China's titanium industry."

Jan 1, 2011

By E. Charles Abbey

Manganese in electrolyte has both beneficial and detrimental effects in Zn electrowinning. Mn oxidizes to form MnO2 on Pb–Ag anodes, cell walls and pipes. MnO2 reduces anode corrosion but also leads to short circuiting and maintenance issues. MnO2 is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Therefore, two sets of 45+ day bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb–Ag anodes. Daily manganese and chloride losses from the electrolyte appeared to be correlated. Increasing the average Mn/Cl− ratio from ∼7:1 to ∼11:1 reduced the anode corrosion rate. Increasing the ratio above 11 did not reduce the corrosion rate further. Anode scales produced with Mn/Cl− ratios at and above 11:1 contained some γ–MnO2 while scales formed with ratios less than 11:1 did not.

By Wei Han, Zhenwei Liu, Jianhong Yang, Qingwei Qin, Tiejun Chen, Zili Huang

The preparation of industrial ammonium molybdate from molybdenum concentrate was conducted according to the process of roasting—leaching—purification—precipitation—crystallization. The optimum technological conditions were determined: the roasting temperature was 680 degrees C, the roasting time was 2.5 h; in the leaching process the alkali excess coefficient was 1.2, the reaction temperature was 80 degrees C, the liquid-solid ratio was 3:1, the leaching time was 3 h; the amount of (NH4)2S added into the solution was 1.1 times of the theoretical amount, the temperature was 80-85 degrees C, and the terminal pH was 8.5-9 in the purification process; the density of the solution was 1.4-1.6 g/mL, the pH was 1.5-2 in the precipitation process; temperature of dissolution was controlled at 80-90 degrees C. The recovery of the preparation of ammonium molybdate can reach 85.18%.

Mar 1, 2017

By Rina Kim

There are many factors which affect the gold cyanidation mechanism— mineral composition, free cyanide and dissolved oxygen (DO) concentrations, heavy metal additions, etc. This study combines electrochemistry and surface analysis methods to examine the effectiveness of the above factors on gold cyanidation process. Three gold ore samples were used in this study. Sample 1 was a pyrite concentrate, contained mercury and silver. Sample 2 also contained sulfide minerals, including galena. Sample 3 contained pyrite with sphalerite and galena. In the case of samples 1 and 2, the presence of heavy metals enhanced gold cyanidation kinetics, though the addition of higher DO was not effective on improving the kinetics. Sample 3 showed an opposite behavior: the kinetics was not enhanced by galena, because of its relatively small amount, however, the use of higher DO made improvement in the gold leaching kinetics, likely caused by iron species generated by pyrite oxidation.

By Takashi Miyamoto, Hideo Nakae, Hideki Yamaura, Takeshi Yanagihara

"For the production of partially composed metal matrix composites, namely discontinuous MMCs, using a casting· process, the interpenetrated phase composites with SiC particles were fabricated by pressureless iDfiltration using molten Al-Si alloys. This process is based on a wetting phenomenon, therefore, we discussed the technique based on the reactive wetting. The SiC particles coated by diluted water glass were sintered in a mullite Tammann tube and simultaneously infiltrated with molten Al-Si alloys in air at 1173~1573K. As for the improvement of the wettability between the SiC and the liquid aluminum alloy, Fe3O 4 powder was mixed with the water glass due to the thermit reaction between Fe3O4 and molten aluminum alloy. In some experiments, pure aluminum powder was placed on the sintered SiC to increase the interfacial area and the chemical reaction between the sintered Sic. and the melt. By combining these conditions, we succeeded in the complete infiltration without pressure at 1173K.IntroductionAs is well known, the mechanical properties of metal matrix composites (abbreviated MMCs) are superior than that of ordinary metals. However, their use has not been widely accepted because the production cost is very high due to their poor machinability. Therefore, the production of partially composed, namely discontinuous MMCs, by as the Lanxide process [l,2] has been investigated for many years. The Lanxide process, it takes a long time, sometimes up to 10h, in a nitrogen atmosphere for the infiltration. Therefore, the cost will be higher for common use. On the other hand, a high 'pressure process has been adopted for the production of discontinuous MMCs by the Toyota Motor Corp.[3]."

Jan 1, 2000

By Minna Rämä

Iron containing leach residues like jarosite and goethite from electrolytic zinc production contain many valuable metals and harmful substances. These metals and substances should be removed in order to obtain an acceptable, stable and reusable product, and maximize economic feasibility as well as minimize environmental footprint. In this work, the processing of jarosite leach residue was studied in laboratory scale experiments under oxidizing and reducing conditions at high temperatures. First, the pretreated material was melted and oxidized to produce a melt of metal oxides. Second, the oxide melt was reduced in CO–CO2 atmosphere. Target after the reduction step was to obtain a clean slag and a liquid metal or speiss phase that collects the valuable metals, such as silver. The kinetics of the thermal processing were studied for determining optimal times and conditions for the aforementioned process steps. The preliminary results show that the process is thermodynamically feasible, and the desired phases can be obtained in the experimental conditions investigated.

By R. Steven Izatt

Green chemistry principles will be discussed, and examples will be given of the use of Molecular Recognition Technology (MRT) to selectively separate specialty metals such as cobalt, nickel, bismuth, rhenium, molybdenum, indium and germanium from various primary and secondary feed streams. Recovery of these metals has numerous advantages including (i) conservation of valuable resources, (ii) prevention of environmental damage, and (iii) elimination of capital and operating expenses due to re-processing or disposal of metal-bearing streams.

By David R. Jessey

An ore microscopic and geochemical study of the nickel-cobalt occurrence in the Southeast Missouri Mining District has revealed several significant relationships. Siegenite [(Ni,Co)3S4] is the dominant nickel-cobalt sulfide in the ores, however, several other members of the thiospi¬nel group (AB2S4) occur: carrollite (CuCo2S4), nickelean carrollite [(Co,Ni,Cu)3S4], fletcherite [Cu(Ni,Co)2S4] and polydymite (Ni 3S4). In addition, bravoite [(Ni,Fe)S2], vaesite (NiS2), millerite (NiS) and gersdorffite (NiAsS) are present. Thiospinel composition varies dramatically within the district. Paragenetic studies have shown that the stratigraphically lowest thiospinels are the most cobalt-copper-rich. A detailed ore microscopic study of the AMAX Lead Company Buick mine has also shown significant changes in mineralogical association, texture and grain size of the siegenite along the north-south strike of the major ore bodies. Siegenite commonly replaces and veins chalcopyrite and is subsequently replaced by sphalerite. Less commonly, siegenite and chalcopyrite are observed to form linear replacements along sphalerite grain boundaries. The grain size of the siegenite varies markedly, but in a predictable north-south pattern that is consistent with a genetic model formulated from geo-chemical data. The compositional as well as textural trends displayed by the thiospinel mineralization could be exploited to optimize recovery of any or all thiospinels of economic interest.

Jan 1, 1981

By Shigehito Deki

"A new wet process has been developed for the synthesis of various kinds of oxide thin films on various kinds of substrates, even which have complex surface morphology, from aqueous solution. The process was named as the LPD, Liquid Phase Deposition, method, which has some advantages over the conventional dry processes. This process can be applied to an on-site synthesis of advanced materials in the thin film technology. In this paper, some current topics on the synthesis of the composite thin oxide films by the LPD method, are presented.IntroductionGenerally, metal oxide thin films have been made by different preparative processes such as r.f. sputtering, chemical vapor depositon, CVD, laser ablation and sol-gel method, etc [1-3]. Each method has it own advantages and disadvantage. In some cases, the process is not suitable for the preparation of thin film on substrate with large surface area or complex surface morphology, and makes the deposition apparatus complicated and expenisve. By using Liquid Phase Deposition, LPD, method which overcomes some of those problems, metal oxide or hydroxide thin film can be formed on the substrate with large surface area and complex surface morphology, which are immersed into the aqueous solution only at ambient temperature and under atmosphere without any special equipments and high energy. And also, multicomponent oxide thin films can be formed readily by mixing solutions containing the objective metal ions, because it is performed in the aqueous solution which is typically a homogeneous mixing system. This process utilizes ligand-exchange, hydrolysis, equlibrium reaction of metal-fluoro complex species, MF x (x-2n>-, and F consumptive reaction. In the aqueous solution, MFx<x-2n>-is hydrolyzed with water to release F ions by a ligand exchange equilibrium reaction as following;"

Jan 1, 2000

By J. Murdoch Mackenzie

Two commercial nickel solvent extraction plants treating laterite leach solutions and using LIX®84-I have been operated in Australia. These circuits employ similar extraction chemistry but differ in their leaching and stripping operations. An alternative process involving elements of both can be conceived. The preparation of the feed solution to solvent extraction plays an important role in nickel extraction using LIX®84-I and the special features of manganese removal and cobalt oxidation in the preparation of the PLS are discussed. This paper compares these three circuit configurations with special reference to the extraction and reductive stripping of cobalt, the transfer of zinc and copper to the strip aqueous, ammonia transfer and sulfur transfer. The potential degradation of the organic and remediation using re-oximation is discussed. Keywords: Nickel, Solvent Extraction, Oxime

Jan 1, 2004