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By Peter T. Chiang

A brief literature review on metal separations by ion exchange and solvent extraction of their thiocyanate complexes which are practiced in analytical chemistry as well as in industries was performed. Owing to the poor stability of free thiocyanic acid in acidic aqueous and organic media, technical and environmental problems which cause high thiocyanate consumptions often arise during the practice of the separation processes. This prompted the conducting of a second and more thorough literature review on the chemistry of thiocyanic acid. The objectives of this undertaking are to compile and interpret literature data on the physical properties and chemical reactions of thiocyanic acid, thus providing a clearer understanding of the causes of these problems and giving options as to how to minimize them. The best answer found for carrying out the separation processes is to keep the temperature, thiocyanic acid concentration and total acidity as low as practical.

Jan 1, 1984

By David Brown, Glen Hall, Ken DeVos, Frank Barone

Dredging and Flooding was completed on the Falconbridge Limited "New Tailings Area" in the period from 1996 through 1998, as part of their site closure measures. Part of the decision making process and closure planning was water quality prediction, including oxidation and diffusion modelling. The purpose of this modeling was to define the potential water quality that would result during and after dredging. A significant body of research on the geochemistry and oxidation kinetics of this site had been compiled. The results of the modeling provide practical insight on the potential water quality that may be expected. Water quality in the pond has steadily improved since flooding was completed with the exception of short term peaks during spring runoff. Aquatic vegetation is appearing through natural recovery and transplanting of local species, and colonies of minnows are now observed in the ponds.

Jan 1, 2000

By James H. Boettcher

In the second quarter of 1979, ASL Inc. inquired whether Crocker National Bank ("CNB") would provide $4 million in term loan financing to help ASL acquire the outstanding shares of the S&S Coal Company in West Virginia. ASL had, prior to approaching CNB, sought financing with the assistance of a financial advisor from a number of commercial banks without success. A summary of the initial terms requested by ASL is shown in Table I compared with the actual terms the transaction closed with. It is not difficult to note that the two sets of terms differ significantly. This is often the case when financing requests based on the expectations and vision of a mine developer are juxtaposed with more pragmatic requirements of a commercial bank. The "art" and fun of structuring financing plans for mining ventures (highly leveraged acquisitions or grass roots) comes in working with mine developers to arrive at a final financial structure that meets their objectives and constraints as well as those of the bank or other financial institution providing much of the financing. This article briefly describes the process we went through with ASL beginning with the terms they requested initially and ending with the ones on which the transaction was finally closed.

Jan 1, 1981

By Stephen H. Stow

The relationships between the amount of light reflected off 21 samples of Florida phosphate and the chemical, composition of the samples were examined. It was found that the reflectivity of a rock is directly related to its chemical composition and that darker phosphates (less light reflectance) have relatively high amounts of iron, organic C and sulfate while lighter-colored rocks were rich in phosphorus, fluorine and aluminum. The use of reflectivity measurements could have economic applications in the phosphate rock industry: color specifications for rock shipments could he met, beneficiations by optical sorting could be performed and semi-quantitative analyses could be made rapidly and inexpensively.

Jan 1, 1971

By Paul T. Allsman, Paul F. Yopes

17.1--CURRENT AND FUTURE STATUS OF SURFACE MINING PAUL T. ALLSMAN AND PAUL F. YOPES 17.1.1--CURRENT The history of surface mining essentially is one of mining coal, copper, iron and aluminum ores, of placer mining gold and tin, and of pits and quarries producing clays, gypsum, phosphate rock, sand, gravel and stone. Table 17-1 is a summary of the estimated world and United States production of crude metallic and non¬metallic ores and coal in 1969. It includes estimates of the quantities produced by surface-mining methods. Two-thirds of the 10 billion tons are mined from the surface, ranging from a third of the coal. 57% of the metallic ores, and nearly all clays, stone, sand and gravel. Production by surface methods in the United States, parallels that of the world with one exception: about 90% of the copper and iron ore is mined from the surface, whereas elsewhere only about half the copper ore is surface mined. In Canada, surface mining of the Athabasca tar-sand deposits is a recent large-scale unique operation. In surface mining of coal and, to a lesser extent, metallic ores, much waste is stripped, but in nonmetallic pits and quarries the ratio between waste and ore usually is small. Assuming that the stripping ratio for surface mining in the

Jan 1, 1973

By H. M. King

A combination of chemical, statistical, geographic, and microscopic analyses reveal that sulfur in West Virginia coals is extremely variable in both form and abundance. Coals in southern West Virginia typically contain less than 1% total sulfur with organic sulfur being the dominant species. Northern West Virginia coals average about 2% total sulfur, mainly contributed by sulfur minerals. In addition to these regional trends, significant variations in sulfur form and abundance exist both vertically and laterally within individual seams. On both regional and local scales, the pyritic sulfur component can vary significantly in mineralogy, particle shape, maceral association, and particle size.

Jan 1, 1986

By Eberhard Stolarski, Michael Tacke

When the oxidized surface gold deposits are mined out, the underlying refractory gold ores become the challenge of treat­ment systems. The size and value ofrefractory gold ore reserves are a function of recovery efficiency and operating cost. The start-up of LURGI's gold roasters at NEWMONT's Carlin site has established whole ore gold roasters as a key to high gold recoveries. The ores from several deposits of the Carlin trend are roast­ed utilizing LURGI / NEWMONT technology, which has achieved gold recoveries approaching 95%. This is in dramatic contrast to the traditional perception that roasting is limited to gold recoveries in the mid 80's. Extensive investigation in pilot scale is required to achieve stable high gold recoveries for most variables in the ore body. The key question for all pilot tests is the classic question of (ROM) run of mine ore roasting or concentrate roasting. All variables are dominated by the leaching/ recovery char­acteristics of the natural ores. The degree ofrecovery improve­ment by roasting / calcining establishes the frame of the eco­nomical conditions. The full range of flexibility is required for the design of the plant to allow for ore variations in heat values, combustible con­tents, agglomeration behavior and off-gas composition. The variables in the ore body influence, therefore, the price of the plant proportionally to its flexibility. Concentrates are usually fairly stable in composition, com­bustion behavior, heat values and particle size since they are a product of the very selective flotation process. Flotation is not the successful process step when the tailings remain high in refractory gold contents.

Jan 1, 1996

By H. Y. Yang, L. L. Tong

Semicontinuous-flow, multistage biooxidation experiments of a Chinese refractory, high-sulfur gold concentrate were conducted with different pulp densities for gold recovery. The maximum iron, sulfur and arsenic oxidation rates of 90.0, 88.8 and 96.4 percent, respectively, were obtained in the experiments with 5 percent pulp density. The highest gold and silver recoveries of 96.1 and 68.9 percent, respectively, were achieved by cyanidation. The negative effect of high pulp density on biooxidation was related to the decrease of free and adsorbed cell concentrations with increasing pulp density. The data of iron oxidation from the semicontinuous biooxidation experiments were best fitted by a shrinking core model in which the chemical reaction controlled the rate. The dissolution kinetics of sulfur and arsenic were therefore analyzed by a shrinking core model in which the internal diffusion controlled the bioleaching rates. For the quantitative description of biooxidation efficiency, two parameters — mass dissolution rate and volume dissolution rate — were proposed. In the first stage, the mass dissolution rates of minerals were negatively correlated while the volume dissolution rates were positively correlated with the actual pulp density. The iron and sulfur mass dissolution rates decreased with increasing actual pulp densities in the third and fourth stage, while linear increasing relationships between the volume dissolution rates of minerals and the actual pulp density were observed from the second to fourth stage. The highest mass dissolution rates of minerals were obtained in the first stage with 5 percent pulp density. The highest volume dissolution rates of minerals were obtained in the first stage with 15 percent pulp density. Compared to the volume dissolution rate, the mass dissolution rate was more intuitive to reflect the negative effect of high pulp density on biooxidation efficiency.

By E. S. Cheney

The sandstone-type uranium deposits of the Gas Hills occur in the arkosic, lower Eocene Wind River formation on the southern edge of the Wind River Basin. The d S34 values of pyrite cement associated with uranium mineralization are-significantly lighter than values for syngenetic-diagenetic pyrite nodules, therefore the H2S responsible for the precipitation of the epigenetic pyrite and uraninite was produced [t]epigenetically. These values are much lighter than the values of H2S from neighboring oil fields. The presence of biogenic pyrite in meta-igneous Precambrian cobbles indicates that these cobbles are not remnants of former; vein-type uranium deposits.

Jan 1, 1964

The exploitation of mineral deposits for economical recovery of the contained minerals has many aspects differing from other industrial or manufacturing operations. However, generally accepted principles of good organization and management applicable to industrial plants are similarly effective for mineral processing plants. A more detailed coverage of organizational structures and management techniques than is possible in this section can be obtained from many good books devoted wholly to these subjects. A few of the more readily available examples are included in the general references at the beginning of this section. The field of mineral processing encompass a wide variety of minerals, processes, flowsheets, equipment, and end products. Mineral deposits, mines, and related beneficiation plants are found in all parts of the globe, often in remote locations with no nearby support for supplies and maintenance. Available labor is frequently unskilled, sometimes primitive, and often untrained without machine and hand tools or heavy equipment experience. Such situations call for well- planned and conducted training programs covering the full range of mining-type job skills. Climates can range from arctic to tropical and from arid to extremes of rain or snow, and the mine and plant sites can be almost anywhere. However, it is often possible and sometimes necessary for

Jan 1, 1985

By K. KAKLIS, O. SAUBI, Z. Agioutantis, R. JAMISOLA

Three-point bending (TPB) tests were conducted on prismatic Nestos marble (Greece) specimens. The specimens were instrumented with piezoelectric sensors, and comprehensive recordings of acoustic emission (AE) signals were obtained. Machine learning in the form of artificial neural networks (ANNs) was then applied in an effort to investigate whether specimen load evolution can be predicted as a function of AE signals. A number of ANN models were developed, and the optimum model was selected based on the highest coefficient of determination (CoD) value as well as the lowest root mean square error (RMSE) value that was calculated for each model. The best performing ANN model exhibits accuracy above 99% with an RMSE value below 4%. It can be concluded that ANNs can potentially be applied to predict rock behavior under load especially when such loads lead to failure.

Sep 7, 2022

By Sun K. Kim

Hydrometallurgical processes are not free of environmental regulations. A clear understanding of the regulations under which the minerals industry operates delineates processing requirements at early stages. This paper deals' with federal environmental regulations with emphasis on the hazardous waste regulations promulgated in May, 1980. The procedure of EP toxicity test and an example of the test are described. Brief account is given of the current trend and future outlook of regulations.

Jan 1, 1982

By Brendan Donnelly, Lasitha Piyathilaka, Jung‑Hoon Sul, Sanghyun Jeong, Benjamin Probyn

Premature failure of armoured face conveyor (AFC) chains due to corrosion is a significant proportion of the unplanned downtime experienced on longwall equipment. The AFC chains are constantly in contact with water and wet coal. The premature failure issue of AFC chains has become more prominent since the introduction of longwall top-coal caving with its additional AFC. Reverse osmosis (RO) is a popular water treatment method for reducing salinity and dissolved solids, but its impact on the corrosion of the AFC chains is unclear. This study has been commissioned to investigate the direct effects of RO water on the corrosion of AFC chains. An immersion test was carried out using AFC chain steel submerged in two water samples: untreated dam water and treated water from an RO treatment plant. Elemental analysis was conducted for both water samples, and four corrosion indices were measured for both water samples. The RO water more vigorously dissolves calcium carbonate scales leading to increased corrosion of the AFC chains although the dam water has much higher levels of calcium, chloride, sulphate, sodium, and magnesium. Bicarbonate ions are the main alkaline factor of water that provides the buffering capacity to acids. Decreased alkalinity without balancing other ions in water causes high corrosivity and decreased scaling tendencies.

Oct 16, 2023

By Yuting Xue, Alper Kirmaci, Taghi Sherizadeh, Dogukan Guner, Khaled Mohamed

Rib brows present a significant safety hazard in underground coal mines in the United States. To address this issue, researchers at the National Institute for Occupational Safety and Health (NIOSH) and Missouri University of Science and Technology (MST) are developing a practical tool to assess both the potential of rib brow formation and the stability of any formed brows. As part of this effort, a monitoring study was conducted to assess the potential for rib brow formation in coal pillar ribs. This study was conducted in a room-and-pillar coal mine where coal pillar ribs are prone to developing rib brows. Although no rib brows formed in the instrumented pillar, data from monitoring and visual observations provided valuable insights into the loading mechanisms impacting the instrumented pillar. These findings helped identify factors that may reduce rib brow formation, including the cavability of the roof in mined areas, the applied rib support, the strength of rock partings, and the overall integrity of the coal seam. The scientific findings published in the case study aid in assessing the potential of brow formation, offering additional evidence for the need to improve rib control methods in underground coal mines.

Feb 1, 2025

By Z. H. Xie, D. S. He, W. M. Xie

China has rich phosphate rock resources, but with their continuous depletion, the rich ore resources have become increasingly scarce, which makes the exploration of collophane more important. Medium- and low-grade phosphate rock cannot be utilized until their impurities have been removed through mineral processing. However, due to the similar physical and chemical properties of dolomite and phosphorus minerals, the separation of dolomite from phosphate

By Stephen H. Partney

Waste clay ponds are a necessary part of phosphate rock beneficiation. They are large, averaging 2.6 km2 (1 sq mile). They are unsightly in that they protrude 6 to 15 m (20 to 50 ft) above natural grade. Stabilization and reclamation is slow and they have had a history of catastrophic failure. Florida has never published a specific rule regarding the configuration or height of these ponds. But it has enforced several policies along these lines. The phosphate industry has been forced to make major monetary decisions that affect mine economics for decades. The Florida Bureau of Mine Reclamation believes that the direction of regulation has been solidified but changes are still anticipated. Phosphate rock has been mined in Florida since 1890 (Fig. 1). Three notable technological changes occurred in the industry that led to major shifts in mining technique and volume. By about 1915, hydraulic mining had been replaced by centralized washers. Hydraulic mines usually started at an outcrop in or adjacent to a stream of the pebble zone. Water was pumped out of the stream through high-pressure monitors and sand and clay were washed away from the pebble. Mobile grizzlies and screens were used in conjunction with animal and human labor to concentrate the pebble and haul it away. Populations were sparse and the clays washed into the stream were considered an acceptable price for the commerce. The clays were not voluminous because the pebble zone typically contained relatively small amounts of them. Machines largely replaced animals by 1910 and provided greater efficiency of production. Centralized washers replaced mobile trommels. They allowed greater ease of access to shipping routes by rail. Some clays were placed in mine cuts from 1915 to 1930. Some were dammed off to increase the capacity of a given site. Some of these also failed, leading to clay plumes that were visible all the way to the Gulf of Mexico. By concentrating the waste clays (slimes) in impoundments, the solids concentration had increased, making plumes persistent for long distances. There were complaints. But there was no litigation against the companies during that time. In 1930, flotation technology allowed the recovery of the phosphate from deeper zones. This was because the "concentrate" size phosphate rock was in the sand-size range and could not be screened out. Centralized beneficiation plants grew into a three-step process - washing and screening, feed preparation and flotation (Fig. 2). Reagent storage, safety and the flotation cell complex made the plants into large capital installations. Larger draglines were required to dig deeper into the matrix. These had dramatically larger production capacities, which were then figured into the overall material balance for a given plant. The number of operators shrank and the production per operator grew. Larger areas were being bermed off for waste clay storage. An economic incentive became apparent for storing as much waste clay as possible in each settling area. At the same time, the population was steadily growing and more eyes were watching the activities of the phosphate mines. Phosphate mining, focused on production and profit, was earning a bad name from its neighbors. When the subject of phosphate mining

Jan 1, 1998

By J. Drelich

The flotation limit of fine particles has been re-examined based on the effect of bubble size on contact angle, and a new surface chemistry-limited relationship describing the minimum particle size which can be floated is proposed. In this analysis the critical value of bubble-solid contact radius (re) for which there is no effective attachment between particle and bubble has to be determined. The values of re determined by extrapolation of our experimental data for contact angle versus bubble-solid contact diameter permit the prediction of the flotation limit of methylated quartz particles, with fraction-al coverage of trimethylsilyl groups from 0.07 to 0.51. The limit of fine particle flotation as determined by this theoretical approach agrees well with experimental data reported in the literature.

Jan 1, 1994

By Dr. Jack M. Gillette

A system of models which simulate surface coal mining operations has been developed for use in mine planning and economic evaluations. Micromodels simulate individual mine operations for equipment selection and mine planning. Macromodels simulate all operations in the complete mine for economic evaluation of reserves. A cash flow analysis model makes a complete discounted cash flow analysis to deter-mine a required coal sales price or return on investment for evaluation of any mining project.

Jan 1, 1978

If the communication/tracking system of an underground mine is severely damaged in a large mine accident or explosion, a surface based seismic system could be the only available tool for locating any trapped miners. This paper documents a field test of a seismic system at a room-and-pillar coal mine in Eastern Kentucky. Testing was performed at 6 different depths (450, 575, 750, 1175, 1525 and 1700 ft) above the mine. For each location underground, the miners pounded a ?set? of 5 ?repetitions? on the roof with each repetition being about one second apart. Over the 3 day field test, 63 sets of underground miners? pounding were detected by the seismic system at depths up to 1175 ft and at horizontal offsets up to 890 ft. Also during the testing, the observed signal strength generated by pounding with a crib blocks was seen to average 180% stronger than the observed signal strength generated by pounding with a sledgehammer. Ultimately, this field test was very successful and definitively demonstrated the ability of the seismic system to detect potential trapped miners? pounding up to a depth of 1175 ft.

Feb 23, 2014

By A. J. Basu

An overview of the evolution of computerized mine planning and design has been given, emphasizing the need for a knowledge-based system for planning and design of underground coal mines. An outline for the development methodology and procedure has been provided. Problem structuring guidelines have been used to incorporate intelligence and integration to the design modules. A skeletal model for a mine planning and design expert system has been prescribed, and the development process has been documented in detail. A feasibility prototype has been developed to test the structure of the skeletal model and to ensure completeness of the design process. The feasibility prototype development and its contribution toward proto typing has been addressed in this paper. At present, prototype development is underway. The prototype is expected to be avail-able for testing and implementation in early 1991.

Jan 1, 1991