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By Kotaro Ohga, Kiyoshi Higuchi, Zhang Xun Tao

In Japanese coal mines, drivage works of in-seam gate roads are mainly carried out by blasting methods. Changes of methane concentration in gate roads are recorded by centralized monitoring systems in general. To obtain useful information from the recorded data, authors analyzed changes of methane concentration for 3 hours after blastings. As a result, the changes of methane concentration with time can be divided into five distinct patterns. It is thought that appearance of the each pattern depends upon the geological conditions of the surrounding of the headings. Therefore, we attempted to confirm such observations by simulations using mathematical models.

Jan 1, 1989

By D. Moraetis

The present study examines the nutrients and micronutrients availability of uncultivated soils originated from different parent rocks. The study areas include four types of parent rocks with different geological origin, from acidic to ultramafic. The parent rock mineralogy and the nutrients available in soils are in strong relation-ship. Mineralogy, particle size distribution and chemical composition of the soil samples were studied jointly with the nutrient content of soil solution. High magnesium availability in soils of Anogia area is related with the alteration products of the ultramafic rocks. Potassium content of the soils exhibits no relation with the geology of the area. Micronutrients, iron and manganese, shows strong dependence to the bulk chemistry and mineralogy of the parent rock material. In contrast no interrelation detected between zinc and copper availability in soil and parent material.

Jan 1, 2006

By Jonathon M. Hanson, John F. Schatz

A combined theoretical and laboratory test program is described with the purpose of providing a useful model of the multiple radial fracturing process. A non-quantitative conceptual model is developed as the basis for detailed mathematical modeling and test planning. The model includes borehole pressurization, flaw rupture, and gas- driven fracture propagation phases. The laboratory tests are carried out in blocks of scaled rock simulant loaded to a true three-dimension stress state and with miniature propellant/explosive charges in a wellbore as the fracturing energy source. The conceptual model, fracture initiation modeling, and laboratory test setup have been completed and are described. The remaining work is ongoing

Jan 1, 1986

By D. D. Misra

The paper presents a computer simulation package developed for the size¬-reduction circuits of Indian hematitic iron ores. The package is developed by linking independent procedures describing different unit operations like crushing, screening, recycling, etc. Mathematical models are used to quantify the unit operations involved. The models are selected after thorough analytical studies of the samples and data collected from four operating plants. The package developed gives a fairly accurate result with respect to, size and chemical composition of the flow stream and products. The program written in PASCAL can be used to try the flowsheet with various raw ores, as well as different flowsheets with the same raw ore.

Jan 1, 1989

Geopolymerization is a process by which Al-Si minerals undergo dissolution and polymerization in an alkaline solution to form a monolithic material with a high mechanical strength (Davidovits, 1991, 1994). In this study, the factors affecting the geopolymerization of Na feldspar (albite) and K -feldspar (microcline) were investigated. It was found that both Na feldspar and K -feldspar are reactive in geopolymerization with the resultant geopolymers showing a high compressive strength. The leaching ability, the proper molar ratio of Si/Al in the geopolymeric gel phase and the higher average hardness of the undissolved particles remaining in the geopolymers are found to greatly affect the ultimate compressive strength of the formed geopolymers. Key words: Geopolymerization, Mineralogy, Albite, Microcline

Jan 1, 2003

By Alfred W. Hefferan

A longwall face conveyor system serves the primary function as all material handling systems; i.e., to transport material between the source and its destination. However, the conveyor system must provide many other functions as opposed to the traditional belt conveyor system. In this paper, we will attempt to contrast the longwall face conveyor system with a belt conveyor system. In addition, the unique problems encountered along with the solutions to these problems will be covered. Table 1 lists the characteristics required of each conveyor system. The table demonstrates the contrast in the two systems. Both must be designed specifically to encounter its unique problems. The balance of this paper will explain how the longwall face conveyor is designed to address its requirements.

Jan 1, 2000

By R. G. Reddy

Chemical and structural changes occurring during the roasting of refractory gold ores were investigated. Effect of temperature on oxidation behavior of ores was analyzed using TGA, DTA and X-ray diffraction methods. The experimental results showed that the carbon in the ore has to be oxidized to a minimum value before any appreciable oxidation of sulfur occurs. Oxidation rates as a function of temperature were calculated. Optimum conditions under which a successful roasting of the refractory gold ores can be obtained are discussed.

Jan 1, 1990

By S. Finsterle, R. C. Trautz

Numerical modeling studies were performed to investigate water seepage into underground openings excavated in unsaturated fractured rock. Water seepage is an important factor affecting the performance of a nuclear waste repository, such as the one proposed at Yucca Mountain, NV. The amount of water dripping into an underground opening depends on the connectivity and permeability of the fracture network, as well as on the capillarity of individual fractures intersecting the opening. A high-resolution numerical model of an unsaturated fracture network was developed, and the appropriateness of seepage predictions using a fracture-continuum model was examined. Model calibrations to liquid-release tests performed at Yucca Mountain are also discussed.

Jan 1, 2002

By Wayne A. Ericson, Kirk S. Davis, Cornelis Winkler

BCI has developed a chemical process known as Ecophos® for the multi-industrial Pine Level Project in DeSoto County, Florida. Approximately 85 percent of the phosphogypsum at Pine Level will be converted to a very clean gypsum. The remaining 15 percent, including impurities plus some quartz tailings sand, constitutes what is termed redigestion solids. BCI has developed an alternative to the practice of disposing phosphogypsum in large above-ground impoundments. The proposed disposal method consists of mixing the redigestion solids with clays and reacting the mixture (leached tailings) with lime prior to disposal into the mine excavations as a reclamation soil material. Leachate water quality testing using lysimeter equipment indicates that the pore water associated with neutralized leached tailings meets maximum contaminant levels set for the drinking water standards of radium and selected primary metals.

Jan 1, 1992

By E. T. Balazs

Share of developing countries in world bauxite resources mining and processing. Technical assistance of the United Nations Industrial Development Organization to the developing world in the field of bauxite evaluation and processing. Review of selected projects of bauxite research and development aimed at creating indigenous capabilities in developing countries: "Assistance to the bauxite aluminium industry of the People's Republic of China". Project activities. UN inputs. Achievements. Follow-up. "Upgrading the scientific and technological capabilities of the Jamaica Bauxite Institute". Project activities. UN inputs. Achievements. Expected follow-up. Assistance to the establishment of an "Aluminium research, development and design centre" in India. Project activities. UN inputs. Achievements. Follow-up. "Establishment of an aluminium institute for research and development in Titograd, Yugoslavia". Project activities. UN inputs. Achievements expected. Second UNIDO group training on bauxite evaluation and processing to alumina October - November 1983 in Budapest, Hungary. Programme and coverage. Show of movie picture on organization and execution (15 minutes). Significance of UNIDO's assistance to the developing world in bauxite research and development. References.

Jan 1, 1984

By A. S. Mallicis, Li Xiawoei, P. W. Weiblen, I. Iwasakl

Platinum group metals (PGM) are often found in close association with arsenide and sulfarsenide minerals in copper-nickel bearing gabbroic rocks. Major losses of platinum in flotation have been attributed to the susceptibilities of the arsenic minerals to oxidation and subsequent losses of their recoveries in cleaner flotation stages. The use of a nitrogen atmosphere in grinding and in flotation, the effectiveness of activation for improving their floatabilities, and the role that electrochemical interactions play not only between grinding media and minerals, but also among different minerals, are discussed.

Jan 1, 1989

By E. D. Goddard, D. S. Murphy

Acid resistance, zeta potential and ESCA (electron spectroscopy. for chemical analysis) experiments were performed on emperador marble and four calcium carbonate samples (onyx calcite, travertine calcite, Iceland spar calcite and aragonite). Six fluorine-containing reagents were used to treat the surfaces of these materials: magnesium hexafluorosilicate, zinc hexafluorosilicate, sodium fluoride, zinc fluoride, strontium fluoride and stannous fluoride. The acid resistance of treated samples proved to be much higher than that of their untreated equivalents. The isoelectric point of treated samples approaches the isoelectric point of fluorite. Also, the fluorine content, as measured by ESCA, of a marble surface treated with magnesium hexafluorosilicate is much higher than that of an untreated sample. The binding energy off of fluorine and calcium the treated marble is consistent with the formation of calcium fluoride.

Jan 1, 1994

By W. D. Hall, M. Norris, J. R. Henke

Dewatering wells producing iron-rich water experience rapid declines in yield and drawdown due to the formation of ferric (Fe3+) hydroxide deposits in well screens, pump intakes and riser pipes. Precipitation is caused by a combination of dewatering-promoted iron oxidation and iron oxidizing bacteria. Physical and chemical well rehabilitation techniques, as well as alternative well-construction and well development techniques, were evaluated in this study. The addition of acid downhole feed systems to dewatering wells that are prone to iron encrustation can, in many cases, prolong their operational lives up to 500% that of unacidified wells.

Jan 1, 1992

By K. N. Han, Y. Guan

The dissolution behavior of silver and copper from silver/copper alloys in ammoniacal solutions was investigated using a rotating disc. Oxygen was used as an oxidant. The effects of the alloy composition, concentration of lixiviants, stirring speed and temperature on the overall dissolution kinetics were studied. Three silver/copper alloys (containing 76.7, 46.9 and 24.1% silver) were used in this study. The rates of dissolution for these alloys were compared to that of pure silver and copper under the same testing conditions. Emphasis was given to the galvanic effect on the overall dissolution rates.

Jan 1, 1995

By J. C. Stankus, J. J. McCaffrey, S. Guo, S. S. Peng

An innovative concept in longwall tailgate support is discussed. This new concept utilizes a high-capacity roof-truss system to replace conventional wooden cribs. The first field test was conducted at the Bailey Mine and was very successful. Similar tests were installed in other mines and seams. An extensive instrumentation plan was designed and implemented in the truss test area. The test data demonstrated that the dynamic roof-truss system effectively controls the various abutment pressures caused by longwall mining. Thus, a stable tailgate entry is maintained

Jan 1, 1997

By Jay Hilary Kelley

A ventilation system is described using dual aircourses: one zone occupied by working personnel, the other at the active working face. The two zones are separated by a partition or Shroud. The occupied zone to the rear of the face zone is ventilated adequately but with considerably less air because little gas, dust, or fumes are present. The face excavating zone is sealed and maintained at slightly more negative pressure preventing dust and gas generating from within to escape. Explosive mixtures within the face zone is rendered non-explosive by the introduction of inert gas therein. Each zone is vented separately to the outside of the mine. Because less total quantity of air is required for human breathing, etc, the total ventilation system can be drastically reduced in tan capacity, development entries, and air shafts, -- a great savings in costs.

Jan 1, 1991

By J. R. Diehl, R. W. Lai, R. W. Hammack, S. U. M. Khan

Cyclic voltammetry (CV), flotation response, evolved-gas analysis (EGA), and X-ray photoelectron spectroscopy (XPS) were employed to evaluate the major differences in the surface property and surface reactivity of a selected coal pyrite and a mineral pyrite. Surface properties of pyrite were evaluated in terms of flotation response in the presence of both an anionic fluorosurfactant and sodium hydrosulfide. The charge transfer adsorption and oxidation potential of sodium hydrosulfide were evaluated using cyclic voltammetry. Drastic differences in the flotation response have been observed between the coal pyrite and the mineral pyrite. Significant differences in the cyclic voltammograms at pyrite surfaces of these two sources were also observed. Measurements by XPS and EGA were used to determine the oxidation products and the rate of oxidation of the coal-pyrite and the mineral-pyrite surfaces.

Jan 1, 1991

By T. Weimer

Gasification of carbonaceous energy carriers with simultaneousCO2 removal is a new and interesting alternative e.g. ZECA [1],HyPr-Ring [2], AER [3]. In the ZECA process lime supported Hydrogen generation from Methane is a basic process unit and the Hypr-RING process investigates Hydrogen generation from hard coal with addition of lime. Here the main objective is a further development of the AER process. High energetic efficiencies for gasification in the range of 90 % can be achieved if the humidity of the energy carrier is already sufficient for steam reforming reaction. The aim of the overall process is upgrading coals and biomass yielding into three valuable products: • A fuel gas ready for power generation • A CO2gas stream containing >95%, ready for transportation to disposal or chemical fixation • A pre-calcined feed for cement clinkering consisting ofCaO and coal ash Thus power generation and gasification are independent. A promising industrial application is the combination of gasification and cement production. Then only one additional reactor is required and the precalcination mass flows have to be increased.

Jan 1, 2004

By G. P. Brahmaprakash, K. A. Natarajan, N. Jyothi, K. N. Sudha

Some important electrochemical aspects involved in the bioleaching of mixed sulfides have been discussed with reference to selective sphalerite dissolution from different binary mineral combinations. Combination potentials and galvanic currents were measured in different binary combinations of sphalerite with other minerals such as galena, chalcopyrite and pyrite in order to under- stand the electrochemical dissolution behaviour of sphalerite when coupled with other minerals. The effect of applied DC potential was also studied with reference to selective sphalerite dissolution from a binary mineral mixture. An application of a potential of -500 mV (vs SCE) was found to enhance bacterial growth as well as selective sphalerite dissolution. Factors influencing bioleaching of sphalerite under a negative applied potential are discussed.

Jan 1, 1989

By V Leus, J. Kallioinen

The large size of the modern flotation cells and the high product flow rate from them has increased the importance of optimal flotation of all the particle sizes and of process control. By treating all the subprocesses of flotation separately a new family of flotation cells and a new concept of optimizing the flotation of coarse and fine particles in separate units but in the same row of flotation cells has been developed. The paper discusses the possibility to enhance coarse particle flotation by varying the froth residence time. A function has been developed between the residence time of the froth, air rate and the froth removal rate of coarse apatite particles. The response of apatite flotation to different control variables has been studied and modelled. The results show that the BPL assay response depends not only on the control variable used but also on the feed assay to the cell. There exists an feed assay dependent region within which the froth assay can be controlled by using the froth residence time as the control variable. These regions can be used to tune a rougher-multistep cleaner circuit to optimal.

Jan 1, 1993