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By P. M. Solozhenkin

The proposed technology of antimony calcine processing includes ferrochloride leaching of calcine, reducing solutions, hydrolysis of hydrochloride solutions with antimony oxochloride isolation, synthesis of antimony trioxide by SbOCl neutralization and its drying, regeneration of hydrolysis solutions. The optimum parameters of separate stage of process has been determined and the chemical character of process has been given. During the leaching of calcine we succeeded to transfer 92.16- 95.66% antimony to solution. On the worked out sheme we attained recovery of antimony to antimony trioxide near 90 .5% Antimony triozide contains 99.5% Sb2O3. The composition of sinter burdens for pigments preparation "Naples Yellow" different colours from brightly-yellow, yellow and lightly yellow has been proposed. Three-sulfuretted antimony-antimonic cinnabar have been prepared by precipitation of antimony solutions by potassium sulfur-bearing solution. The prepared compounds correspond to inorganic pigments for artistic paint. The amorphous antimony-ferrous black we prepared by aluminium cementation of hydrochloric antimony solutions. The ferrous black were used as artistic paints and for coating of metals by antimony.

Jan 1, 1995

By Antti J. Niemi

Radioisotope tracers have so far been used for extraction of residence time distributions of flotation devices. They have also been proven applicable to evaluation of rate coefficients k of industrial flotation. It is now shown how values of k are scaled up on the basis of laboratory data on flotation and chemical conditioning, and of laboratory testing of samples from output of industrial conditioning vessel. Subsequently a model of conditioning and flotation is obtained which may be used for simulation and control of the steady state of the combined process. Discussion extends to modelling, simulation, CAD and opti- mization of flotation plants with re- circulation, and of ore dressing systems which consist of grinding and flotation plants.

Jan 1, 1990

By Thomas H. Koenning, James R. Boulton

The coal mined by Cyprus at the Shoshone mine near Hanna, WY is highly susceptible to spontaneous combustion. Spontaneous heatings have occurred in the gob of several of the longwall panels and, in some cases, following roof falls. Prevention and detection methods have evolved over the years as more has been learned about the occurrences. Seal design and construction have progressed to reduce air leakage into the gob. Pressure balancing has been successful as a supplement to good workmanship in reducing leakage. Early heating detection has improved as knowledge has been gained. Prior methods of detection relied upon thermocouples detecting a temperature change. Later a gas chromatograph was used to analyze gob gas samples. Initially the products of combustion (POC) were relied upon for detection. Most recently, lack of oxygen depletion in the gob has been used as an early warning of problems. Examples are presented to illustrate the evolution of spontaneous combustion control at the Cyprus Shoshone coal mine. Methods have been developed which minimize the oxygen concentration in the gob and reduce the potential for spontaneous combustion.

Jan 1, 1997

By Y. L. Su

This paper describes a case study where solutions were sought to the truck queuing that occurred at a central processing plant. Ore from three production shafts at Falconbridge Limited's Sudbury Opera¬tions is hauled by three trucking contractors to Strathcona Mill. On return trips, the classified mill tailing is carried back to the mines for backfilling. The ore feeder at the mill handles three times the tonnage designed for and the situation is not expected to improve. Excessive truck queuing and consequent mine production interruptions are therefore of great concern. During the study, stochastic models were formulated and programmed for the IBM/AT personal computer. Basic information sought from the models were truck waiting time and ore production interruptions. The existing system was tested, not only to verify the validity of the models, but also to understand the causes of the problem. Several alternatives were simulated and a simple solution selected for implementation.

Jan 1, 1986

By K. E. Kolm, W. H. Langer

Developing natural aggregate resources (sand, gravel and stone) creates environmental impacts. A systems analysis method was designed to characterize the components of the environmental system, identify potential impacts to those systems and evaluate the extent of those impacts. The stepwise method consists of problem definition, data collection, preliminary conceptualization and characterization, additional data collection, data analysis and refinement. The method requires analyzes of various systems making up the environment, including land surface, geomorphic, subsurface and groundwater systems. After system characterization is complete, the method focuses on identifying and evaluating potential environmental impacts to determine acceptable mining strategies.

Jan 1, 2003

By D. R. East

Recent experiences within certain sectors of the international mining industry suggest an underestimation of the environmental risks associated with the design of mine waste-management facilities. These experiences show that the technical and managerial challenges of responsible mine waste management is not always fully appreciated. Unfortunately, the image of the mining industry's environmental performance is negatively impacted by a relatively few number of failures. This negative view overrides the many positive contributions made by the majority of mining companies. The fact that these failures continue to occur in developed and developing countries is indeed re¬markable and indicates a degree of risk-taking approaching unacceptable levels. The design requirements for tailings storage facilities are, in many cases, more demanding than those of conventional water dams because seepage of fluids that contain dissolved metals may pose a greater threat than the mere loss of water.

Jan 1, 2000

By Andrew Neale, Ari Supomo, Mike Mular, Rob Perry

A method is presented to measure and correct the performance of regulatory control loops. Freeport Indonesia treats over 220,000 dmtpd of copper-gold ore in a complex of four concentrators. More than 400 regulatory control loops are implemented throughout the operation. The performance of each loop is quantified by an index based on its time in automatic, the deviation of the measurement from the setpoint and a metallurgical assessment of its impact on overall plant operation. Index values are recorded in a plant-wide data acquisition system and analyzed to produce a report of loops requiring attention. Loop statistics are analyzed to show if the problems can be corrected with tuning. The practical application, benefits, management and staffing requirements of this method are discussed.

Jan 1, 2000

By R. C. Ford

The advent of solvent extraction-electrowinning (SX-EW) technology for recovery of copper from low grade oxide ores has extended the operational lives of many historic mines in the western United States, and made many other orebodies economically viable worldwide. Many of these operations are mature and face closure within the next decade, depending on market conditions. Closure of a large copper heap leach operation has not been undertaken, and differs in some important chemical respects from closure of gold leach pads. Challenges for closure include prediction of solution chemistry and draindown characteristics, determining the benefit of cover placement in semi-arid climates and evaluation of solution management strategies once the economics of copper recovery are no longer favorable. This paper discusses issues pertinent to copper heap closure in semi-arid and arid climates, and strategies for their management.

Jan 1, 2000

By C. H. Rawlins

Deep bed media filtration is used as a tertiary treatment step (after hydrocyclones and flotation cells) to remove fine oil droplets and solids from oilfield water before reinjection disposal or to remove particulate material from surface waters used for waterflood injection. Oil and solids injection requirements are typically <5 ppm concentration at <2 micron diameter. The preferred media for produced water filtration is walnut or pecan shell, however the use of this media has evolved by trial & error and the fundamental mechanisms that occur during separation and media cleaning have not been investigated. A project was initiated to fill in this knowledge gap by analyzing the physical, mechanical, chemical, and hydrodynamic properties of six types of granular filtration media (12/20 mesh size): garnet, silica, anthracite, pecan shell, English walnut shell, and black walnut shell. Comparison of bed packing, oil wetting, attrition resistance, particle strength, and fluidization has led to an understanding of the preferred filtration media for separation of fine oil droplets and solids.

Jan 1, 2010

By L. Piga, P. Cipriani, F. Pochetti

High-temperature roasting of alunite in the presence of K2CO3 gives rise to a reaction that results in up to an 80% recovery of its potassium content as K2SO4 by leaching of the roasted mixture. K2SO4 is also generated from the reaction between the added K2CO3 and the SO3 driven off during roasting of the alunite. This limits the environmental and corrosive problems involved in the thermal treatment of this mineral. A solid residue containing mainly aluminum oxide is also obtained. This could be used as raw material for the production of aluminum, as the use of K2CO3 does not introduce different cations than are in the ore. A statistical study was performed on the factors assumed to affect the recovery of potassium, namely, roasting temperature, K2CO3- alunite stoichiometric ratio and leaching temperature.

Jan 1, 2000

By R. Fedors, T. Ghezzehei, D. Or

The phenomena of dripping into cavities (e.g., tunnels and drifts) within an unsaturated fractured porous medium under ventilated conditions was studied to improve estimates of dripping rates, drop sizes and the chemical composition of droplets that could affect the integrity of high-level nuclear waste packages placed in drifts. The sensitivity of dripping rates and water chemistry to ventilation was analyzed at various flow rates using analytical expressions linking flow on fracture surfaces to drop formation and evaporation. The model was tested using laboratory experiments involving machined aluminum slabs designed to represent a simplified morphology of a fracture face intersecting a cavity and using natural fracture surfaces from a welded tuff Comparison with ten years of data on dripping in natural caves showed good agreement with model predictions. In particular, for low dripping rates, evaporation due to ventilation leads to larger drop sizes and alters drop chemistry by increasing the concentration of solutes in the drop relative to that in the water flowing on the fracture face.

Jan 1, 2002

By Michael J. Pyrcz, Clayton V. Deutsch

Strategic project decisions are based on the distributions global variables, for example, total mineable resource, or recoverable oil volume. These global variables distributions are very sensitive to the input one point statistic, that is, histogram and rock type proportions. Representivity in the one point statistic retains significance in all spatial models. Spatial sampling bias and nonrepresentative sampling complicate this process of building representative one point statistics. This work outlines the cause of bias, the inability of standard declustering to correct for this bias and two methods for correcting bias in the one point statistics: "trend modeling for debiasing" and "debiasing by qualitative data". An example is presented of each technique based on a poly metallic data set.

Jan 1, 2002

By G. E. S. Valadão

This paper is concerned with studying the dewatering behavior of three samples of iron ore products. The objective is to improve the industrial filtration performance by taking into account the laboratory results. Mineral samples came from the Iron Ore Quadrangle in the state of Minas Gerais, Brazil. These samples represent products from the industrial processing of hematitic ores. The samples have almost the same chemical and mineralogical compositions, but they have different size distributions and different specific surface areas. The filtration tests were performed using a modified Büchner funnel apparatus. The results indicate that size distribution and specific surface area have significant influences on dewatering behavior. For Sample 1, the addition of flocculant and/or surfactant was not essential to improving filtration performance. For Sample 3, the cake porosity and the cake thickness were influenced by the addition of the flocculant. On the other hand, the simultaneous addition of flocculant/surfactant decreased the cake formation time and reduced the cake moisture. For Samples 2 and 3, it was also observed that the industrial operation could be improved by taking into account these laboratory results. Key words: Dewatering, Iron ore, Hematite, Filtration, Flocculation, Surfactant

Jan 1, 2003

By Sigmund J. Sulinski

The following is a progress report on a continuing study being made by the Sanitary District for purposes of developing reliable data for predicting costs and progress on future tunnel contracts. All data available to date on five separate tunnel contracts has been analyzed. All were machine-mined in soft ground, all used steel ribs and wood lagging and finished inside diameters varying from 5&apos;6" to 6&apos;6". Basic data regarding progress per shift, hours mined per shift, hours of downtime per shift, cause of downtime and type of soil mined were reported by the District&apos;s resident engineer at the job site. Figure 1, Weekly Mining Report is an example of the form used. Data regarding manpower and equipment used during tunnelling operations was also supplied by the resident engineer during the course of construction. Soil type being mined was verified by the resident engineer during construction, by visual observation, and compared with data listed on a previously prepared soil profile. The soil profile is a graphic presentation of anticipated soil stratas superimposed on a cross section

Jan 1, 1997

By Menzhans Guo

A coal bunker basically acts as a buffer and regulator to reduce the interruptions between its proceeding production system and succeeding haulage system so as to maximize the availability of the whole system. Although such a role has long been recognized, quantitatively studying it is still rarely seen in the literatures. Its unique characteristics, coupled with numerous transitional states, make it very complex to describe the state transitional process in analytical models and, also very difficult to seek an analytical solution. Moreover, the analytical models inappropriately consider the state of bunker being full or empty as a kind of failure, therefore, by no means can they realistically describe the impact of the difference between rates of coal flowing to and from a bunker on the system availability. In light of this, Monte Carlo simulation methods are suggested to reach an approximate solution. In comparison, simulation methods are simpler and more effective than analytical approaches. Applications of simulation methods to a Northern colliery for determining bunker size from the viewpoint of maximizing system&apos;s availability are discussed. The results are satisfactory.

Jan 1, 1992

By C. Strachan

This paper presents an evaluation of the tailings dam incidents included in the 1994 US Committee on Large Dams (USCOLD) Committee on Tailings Dams report. Also, comparisons are made to water storage dam incidents from USCOLD reports, as well as to more recent tailings dam incidents. The evaluation results show that tailings dam incidents result from a number of factors, including overtopping, static and seismic instability, seepage and internal erosion, and foundation conditions. The results also show that no particular type of tailings dam or operational condition is more susceptible to incidents. In addition, the results confirm that tailings dams should be located, designed, operated and reclaimed with a thorough knowledge of site conditions, mill operation, site monitoring and tailings characteristics.

Jan 1, 2002

By David M. Mchaina, Steve Hardcastle, Michel Grenier

An overview of the process employed to assess arsenic exposure levels at a gold mine is provided together with the recommended control measures. Arsenic and its compounds are regulated in Ontario as designated substances in all workplaces except mines and concentrators. There is a proposal to remove the exemption for mine and concentrators. If the exemption is removed, the mining industry will be required to adopt the proposed exposure Limit of 0.01 mg/m over 40 hours. There are many mines in Ontario which will be affected by this new regulation. To determine the extent of which workers are exposed to Levels exceeding 0.01 mg/m , an assessment program was initiated at the mine. The main objective of the program was to determine the effect of the proposed regulation on underground and surface operations in term of compliance if it becomes Law. The data obtained from the assessment program shared that only 1ML of the workplaces monitored for arsenic indicated levels above the proposed limit of 0.01 ,/yard all workplace levels were below the present Limit of 0.2 mg/m .

Jan 1, 1992

The declining grades of surface deposits have re-confirmed the need for greater production rates. Large scale production requires increased investments in expensive and sophisticated equipment. The key to successful operations can depend entirely on proper equipment utilisation and in this program of research at the Department of Mining and Metallurgical Engineering, University of Queensland, much emphasis has been placed on the analysis and improvement of this aspect of a load-haul-dump operation. For a model to be successfully integrated into a mine engineering function and readily accepted by mine operating personnel, it has to offer more than just results. The concepts used in its design and construction must include sufficient detail to enable engineers to apply it usefully and with confidence.

Jan 1, 1979

By M. Takayasu, J. Y. Hwang, F. J. Friedlaender, G. Kullerud

Al unite has been used as raw material for producing alumina and potassium sulfate fertilizer in Russia for many years. In the United States, this mineral has not been commercially processed though reserves of 5 to 10 billion tons of alunite ore have been estimated. Major constituents of these ores are quartz and alunite. The minerals are finely intergrown and liberation occurs below 10 µm. Adequate separation techniques for such ultrafine particles have not been developed. A new method for the beneficiation of al unite ore is proposed in this study. This method utilizes a small amount of fine magnetite upon which the liberated quartz is selectively flocculated. The co-flocculated magnetite and quartz are then separated from the alunite in a high gradient magnetic separator. Clean products, e.g., an al unite concentrate of 90% grade with 80% recovery, has been obtained from Utah ore. Techniques for selective co-flocculation of magnetite and quartz, separation of the carried quartz, and recovery of magnetite after separation are discussed.

Jan 1, 1987

By J. A. Eisele, G. E. McClelland, M. D. Wroblewski

The Bureau of Mines is conducting research at its Reno Research Center to develop a staged agglomeration-heap leaching system and to electrowin the dissolved precious metals from the pregnant leaching solution. For direct electro- winning to be successful, the pregnant solutions generated during the Initial stages of leaching must be higher grade than obtained by conventional heap leaching. The precious metal concentration of the pregnant solution can be Increased by agglomeration pretreatment with cyanide solution which starts the leaching process during the curing period, by leaching with small volumes of solution and by cycling the leaching solution through more than one heap in a staged manner. The resulting pregnant solution is passed directly through an electrowinning circuit. The barren solution from electrowinning is recycled to the leaching circuit. Bench-scale research on the development of the staged leaching system and on the development of an efficient electrowinning cell are described. The Bureau of Mines developed agglomeration- heap leaching technology. This technology was readily adopted by the mining Industry for heap leaching crushed ores and mine wastes. Current research involves the application of this technology to finely ground feed materials such as precious metal-bearing milled tailings. Tailings agglomeration-heap leaching has also been used commercially.

Jan 1, 1984