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By T. P. Lim, A. J. Vivyurka, N. K. Davé

Chemical and radioisotope stratification studies were carried out in an abandoned uranium tailings pile at Elliot Lake, Ontario, Canada. The tailings, with an average thickness of 7 m over an area of 16 hectares, were deposited approximately 20 years ago on a layer of black peaty material which overlays deposits of permeable glaciofluvial sands. Geohydro-chemical investigations of this tailings area have been ongoing since 1978. The radioisotope profile study was conducted on three adjacent sites. Solid core samples, collected with a split spoon sampler at various depths, were analyzed for various chemical and radioisotope constituents. The results indicated by 2 distinct zones of stratification; an upper zone, where the constituents were uniformly distributed, and a lower zone, near the peat-tailing interface, which showed increasing concentration with depth. Within the peat layer, the concentration decreased rapidly with no significant levels of contaminant penetration below the peat layers observed, though the samples were limited. The pH profile showed that the top 5 m of the tailings have been oxidized, the average soil pH in this zone was 3.4 compared to 5 .8 underneath it. The groundwater hydrology of the system was observed to be complex showing downward and lateral flow in the dry season and lateral and upward flow during the spring and periods of heavy rainfall. The results are discussed in terms of a model based on the combined segregation and settling process of the tailings fine fraction, and the geohydro-chemical interaction of the solid and liquid phases.

Jan 1, 1981

By Deborah A. Kramer

Although beryllium was initially discovered in 1797, it was not until 1916 that the first significant quantity of beryllium metal ingot was produced in the United States. Before 1940, most of the small quantity of beryllium metal used in the United States was supplied by Germany. Beryllium was not used in its metallic form; it was used as an alloying addition to other metals, mainly copper and nickel. World consumption of beryllium at that time was estimated to be a few hundred kilograms annually. Because of increased tensions in Europe before World War II, imports of metal from Germany ceased in 1940, and domestic production was required to meet the needs of the military. As a result, by 1946, the United States became the principal supplier of beryllium products for the world, a condition that prevails today. Because of beryllium's high strength, light weight, and high thermal conductivity, it has been used in a large number of industrial and defense applications as a metal, alloy, and oxide. The United States is the only country other than China and the former USSR currently producing beryllium products from beryllium ores and concentrates. Bertrandite, mined in Utah, is the principal ore source of domestically produced products. Imported ore, mainly from Brazil, supplements domestic ore supplies. Production and consumption data for the United States is shown in [Figs. 1 and 2]. Production data for 1969-1979 is withheld to avoid disclosing company proprietary data.

Jan 1, 1994

By S. S. Cook, S. E. Paulson

The US Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and Asarco/Freeport Santa Cruz deposit in Arizona to further the understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/L (0.05 to 0.28 oz/gal) copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/L (0.02 to 0.08 oz/ gal) copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration up to 40 g/L - (0.39 oz/gal) while illite and sericite had minimal impact. Biotite, calcium-rich clay, and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentra¬tions increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1990

By Dae S. Young

The Disjunctive Kriging (DK) procedure was developed to estimate ore recovery figures within a deposit/ domain from limited diamond drill hole (DDH) core assay data taken at the exploration stage. Local recovery figures include minable ore tonnage and ore grades within relatively small areas such as stopes or small panels on a pit bench, for a given cut-off grade. The grade and tonnage should be computed based on the true selective mining units, that is, the average grade distribution of selective mining units within a panel. Local recovery figures are critical information for economic and engineering feasibility studies before mine development, as well as for short-term mine planning for operating mines. This kind of information can be provided only by non-linear geostatistical methods including DK and the Multivariate Gaussian Approach (MG) (Journel, 2, Parker, et al, 5).

Jan 1, 1982

By Lijun Xu, Jan M. Mutmansky

The purpose of this research was to investigate airborne coal mine dust characteristics in order to assess the possibility of contribution of these characteristics to the incidence of coal workers' pneumoconiosis (CWP). The characteristics studied included physical (mass concentration and size distribution), chemical (elemental composition), and mineralogical (quartz and kaolinite content) variables of the dust. The results are based primarily upon analysis of the characteristics of 99 impactor samples from 18 mines in seven states. Because the eight stages of the impactor span the range of dust sizes up to 20 microns, the characteristics analyzed should represent respirable dust characteristics well and also provide size-dependent representations of the characteristics. In general, the patterns of mass concentration and size distribution in the various mines studied were similar with mass concentrations being high downwind of the continuous miner. The concentrations and size distributions were more variable upwind of the continuous miner, apparently as a result of the variations in the dust conditions in the working section. Significant size effects on the elemental and mineralogical content are shown in the data. Concentrations of most of the elements decrease as size decreases. However, minerals content increases as the dust size decreases. Regional variations of elemental and mineralogical content are also significant. Quartz and kaolinite contents are small in regions with low incidences of CWP. However, the elements of Cu and Zn are high by comparison to their content in high-incidence coal fields and may have the effect of protecting against the disease.

Jan 1, 1991

By A. M. Marabini, G. Belardi, V. Alesse, E. Spaziani

The objective of this investigation was to verify the effectiveness of commercial and synthetic depressing agents in a complex oxidized zinc mineral flotation flowsheet using sodium sulfides and amine. The flotation tests were run on a finely-disseminated calamine ore grading 16.96% Zn and containing smithsonite, hemimorphite, cerussite, calcite, quartz and iron oxide, present essentially in colloidal form. The reagents used in the testing can be grouped into four classes: guar, starch, celluloses and acrylic polymers having various degrees of substitution and molecular weights. The depressants exhibiting the greatest selectivity towards the gangue (considered as a whole) are tripolyphosphate, polycarboxylic acids, methylcarboxylate guars and ethyl hydroxylic starch. In the rougher stage, the Zn recovery ranged from 70% to 80%, and the Zn grade ranged from 27% to 29%. In the Zn-Fe2O3 separation, the compounds ensuring the most efficient separation are the tripolyphosphate and the polycarboxylic acids. In the Zn-SiO2 separation, the compounds that exhibit the best separation efficiency are tripolyphosphate and guar of methylcarboxylic sodium salt. In the case of the Zn-Ca separation, methyl-carboxylic guar exerts the best depressing effect and does not adversely affect the Zn recovery. The separation provided by ethyl hydroxylic guar is also good, although not as good as the preceding reagent. Regarding the Zn-Al separation, the tripolyphosphate, the celluloses and the carboxylate guars are the best depressants. A hypothesis is advanced to interpret the depressing action of the most effective reagents.

Jan 1, 1995

By Jean-Luc Cornet

Advances in conveyor technology over the past decade have enabled the design and erection of very long overland belt conveyors. Such conveyors usually require head and tail drives to lower the belt tension and belt strength required. This paper provides an overview of the problems encountered in controlling the head and tail drives on such conveyors and some of the solutions developed by CDI for several such projects.

Jan 1, 2002

By D. Borrowman

Attrition of activated carbon in either the carbon-in-pulp (CIP) or carbon-in-leach (CIL) method of gold extraction can lead to, at the least, loss of expensive carbon that has to be made up, and at the worst, loss of both the carbon and any gold that was attached to it. Carbon attrition therefore represents a significant factor in both the efficiency and cost of the extraction process, and efforts to reduce attrition through process and equipment selection pay dividends. In evaluating carbon attrition potential, one would note that an individual carbon particle is in jeopardy virtually any time it is in motion. Since the motivators of this motion are primary centrifugal pumps, the purpose of this paper is to review the current styles of these pumps now in use and to examine their performance in minimizing carbon attrition.

Jan 1, 1992

By J. A. Hrabik

The feasibility of mining deep phosphate deposits by a borehole mining system was compared with mining by proven conventional techniques. An economic comparison of the borehole mining system with conventional dragline and bucket wheel excavator mining systems was completed at various mining depths and production rates. Hypothetical phosphate deposits, with various overburden thicknesses and reserve tonnages, were defined. Geologic conditions necessary for the application of the borehole system were identified. Discounted cash flow analyses based on derived capital and operating costs were used to generate rates of return and product prices. Borehole mining was found to be more economical where overburden thickness was 46 m (150 ft) or greater. However, at 15- and 30-m (50- and 100-ft) thicknesses, conventional surface mining was more economical. Overburden thickness has a great effect on the economic feasibility of the conventional mining systems but less effect on the economics of borehole mining. Economies of scale are only realized in conventional mining, since larger equipment is used to achieve greater production, whereas increased production from borehole mining is achieved using additional equipment units. A comparison of the environmental effects of borehole and conventional surface mining systems showed that borehole mining is environmentally more desirable.

Jan 1, 1987

By Frank F. Aplan, Edward C. Dowling, Richard R. Klimpel

Several series of time-instantaneous samples were taken on a cell-by-cell basis in the flotation circuits of the Pinto Valley, AZ copper concentrator. These samples were used to calculate mass flow rates throughout the circuit using standard, deterministic metallurgical formulae and also a variety of more statistically oriented techniques. Because of the magnitude of the errors associated with the individual cell samples, the standard metallurgical formulae are not sufficient. Consequently, it is necessary to utilize some type of statistical technique capable of distributing the individual cell sample errors in such a way so as to provide a physically useful mass balance for the entire circuit. This paper explores the use of linear and least squares programming as one technique to providing credible mass balance calculations. For linear programming this was done by distributing the error using two different criteria involving specific linear programming formulations: least absolute sum minimization (which assumes an underlying double exponential distribution error structure) and minimax (which minimizes the maximum absolute deviation and assumes an underlying rectangular distribution error structure). These results were then compared to the more standard formulation of minimization of the sum of least squares which assumes an underlying normal distribution error structure. The least absolute sum approach was particularly attractive due to its simplicity of use and the ease in which repetitive calculations can be done with no user intervention.

Jan 1, 1990

By Christopher J. Hall

It has been known for a long time that summing pressure drops and rises due to friction, shock, fans and natural ventilation is incorrect. In fact, lost works and works should be summed. In spite of this, the traditional method of finding a fan/system operating position has been the H/Q Curve. This paper presents (lost) work/m curves, progressing from a single fan moved around the system to include natural ventilation work, and fans in a series, parallel and series/parallel. The solutions obtained graphically are substantiated by dry air thermodynamic solutions, and the traditional solutions are shown to be in error. This method of solving problems is particularly useful when moving fans around the system, and essential in series/parallel and series situations with substantially different fan densities. The dry air analysis is employed because of its simplicity. Real air, with evaporation and condensation, will react somewhat differently, and one should use real densities (i.e.[l + w +w]/va ) when using this method. One source of error when applying this method to real air, although probably not major, will be investigated in a subsequent paper. Friction and shock losses are proportional to the square of the mass rate of flow, leading to the typical parabolic system curve. However, the unbalanced water stuff potential energy term, on a unit mass basis, is substantially independent of the mass rate of flow. It is possible that this could be handled as a negative natural ventilation work.

Jan 1, 1987

By S. Orr

Flow in heaps and dumps is a two-phase flow phenomenon, though for many applications it could be simplified as unsaturated flow. Unlike saturated flow (typical of ground water flow), where permeability is independent of other hydraulic parameters, unsaturated flow permeability depends on the degree of saturation and/or on capillary pressure. Several recent field studies suggest that flows in heaps and dumps tend to concentrate in preferred pathways, bypassing much of the ore. Different preferential flow phenomena are triggered, promoted and influenced by different heap structures, by pretreatment, by the composition of the leach solution and by application rates and schedules. The structure of heaps and dumps is determined and affected by every stage of their construction -from blasting to crushing to conveying and stacking of the material. History of heap construction and operation combined with monitoring, mapping and certain field tests can reveal patterns of flow and transport in a given heap and can shed light on the physical mechanisms behind it. Such insight can provide a first cut on heap leaching enhancement by either eliminating or bypassing physical barriers to flow and leaching. Based on the understanding of the heap structure, advanced flow and transport models can be constructed and further enhance the insight. This insight is essential for understanding cause and effect and can provide a basis for decision making. Further, based on the physically-based models, an intelligent control agent, such as MRDS1, can learn and build a self-learning representation (or a model) of the complex heap leaching system, followed by dynamic optimization and planning of heap leaching and heap rinsing.

Jan 1, 2003

The design of solvent extraction plants has been generally based on the assumption of steady operating conditions in both the settler and the mixer units. However, recent experience in both large and small plants has shown this not to be the case. Mixer transients include start up aqueous locking and partial phase separation in secondary mixers, which both lead to reduced plant capacity or overflow of upstream mixers. Analysis of the hydraulic pressure profiles has generated new design methods to eliminate the effects of the partial or complete phase separation. Changes to the method of specification and selection of primary and secondary mixers have been made to eliminate the onset of partial separation during operation. The observation of settler operation has shown that it is also a dynamic process, even under "steady-state" conditions. Four transient phenomena have been identified that lead to internal circulating flows, poor disengagement of fine secondary haze and erratic and high entrainment levels in the discharges. A, first approximation analysis has shown that there are significant pressure differentials within settlers, and these change along the length and with the phase separation rates. A technique to control the effects of these transients was developed that allows plant performance to be improved beyond "standard" expectations. The design and selection of the settler internals is described. Key words: Solvent extraction, Mixer-settlers, Phase separation, Entrainment, Mixer transients

Jan 1, 2003

By Peter W. Scott

The Caribbean islands, with their very diverse geology, are a source of several industrial minerals both for their own domestic consumption and for export. The geology of the Greater Antilles, which comprises Cuba, Hispaniola, Puerto Rico, and Jamaica has a Mesozoic or pre-Mesozoic basement overlain by sediments and volcanics, the latter being dominantly island arc in character. Later granitoid intrusions were emplaced. Obduction of ophiolites also occurred variously from the mid- Cretaceous to the Palaeogene. Thick accumulations of limestones surround the older strata, along with Neogene and younger sediments. The Lesser Antilles islands form an arcuate chain, mainly of volcanic rocks of calc-alkali or sub-alkaline affinity with some younger limestones and siliciclastic sediments. Trinidad and Tobago have closer similarities with the South American continent in their geology. Tobago has a metamorphic complex, juxtaposed with a volcanic-plutonic complex, and limestones. Trinidad has very thick Cretaceous to Recent exposed sedimentary sequence. The current exploitation of industrial minerals in the Caribbean is dominated by construction raw materials (mainly sand and gravel, limestone, and cement), although there is extraction of gypsum, silica sand, marble, clay (almost entirely for construction use), pumice, and natural asphalt. Salt is obtained from solar evaporation of seawater. Limestone of high purity and high brightness, gypsum, pumice, and high-density igneous rock have potential for further development of their markets, particularly ex- ports. Potential new and undeveloped industrial-mineral resources include residual and sedimentary kaolin, bentonite, zeolites, magnesite, and talc. Cuba could be a source for many industrial minerals in the future.

Jan 1, 1999

By Jerry M. Whiting, Landy A. Stinnett

The subject of this paper is broad and complex. Secondly, it is near and dear to the authors' hearts. Therefore, it doesn't seem possible to deal with every aspect of it in less space than a good size textbook. Also, if we dealt with all of the basics of feasibility studies and report preparation, we would cover a lot of material available in the literature, and would have to minimize our editorial comments. In view of these limiting realities, we have chosen to discuss selected facets of the subject, and to provide several comments which stem from our personal experiences during the past 20 years. "Think Ahead" hen someone is undergoing training to command a large ship, the following short phrase is engraved in his memory: "Think Ahead." The reason is simple enough. A battleship, aircraft carrier or oil tanker cannot change directions quickly, and if one waits to a what the other ship is going to do, there may be twisted metal and bodies scattered all over the ocean floor. The commanding officer has to use radar, forward rind aft lookouts, experience, common sense, intuition, weather forecasts, and everything else available to him to avoid trouble. Remember the USS Stark, and the fate of its captain? The fact the Stark was hit by a "friendly" missile didn't lessen the damage. How about running into a mine? Is it an excuse that no one thought about the possibility of a minefield ahead of the ship? The point is, relative to feasibility studies, that its prospective authors, and especially the commander of the efforts required to create it, must "think ahead" from the moment of their association with 4 mining activity. They must

Jan 1, 1987

By D. C. Mahon, P. G. Sagert, M. R. Legeyt

INTRODUCTION Public opinion, over the effect of industrial development on the environment, has required government to institute guidelines for the protection of the environment both during the development of and after the decommissioning of mines. In no other area of mining has this requirement been more consistently applied in recent times than in the development of uranium mines. Uranium mines have been a focal point because of the very real uncertainties associated with the detrimental effects of radionuclides and the possible hazards of radiation. In order to determine if there is an environmental effect caused by a development or the storage of the mine waste as tailings, it is necessary to know what the quality of the environment was prior to the production of the tailings. This is the reason for baseline data programs. It is neither technically nor economically feasible to completely define the environment in any given region. Therefore, judgement decisions must be made prior to the development as to what aspects of the environment are more likely to be affected by the presence of the tailings, and to what degree. These decisions have evolved over a period of time based on information generated from existing facilities, scientific research, and the development of strong public opinions. This process is not static, but evolves with the growth of information and the technological developments which permit greater control of industrial pollution and waste management. A well-designed baseline program will reflect changes in science, technology and public attitude, even in advance of government regulations to enforce policy changes. RATIONALE FOR PREOPERATIONAL BASELINE STUDIES There are three distinct phases to be considered in the construction of an environmental assessment for a uranium mine tailings containment facility. I. Pre-operational 2. Operational 3. Post-operational (decommissioning and long term).

Jan 1, 1980

By Raja V. Ramani, Wilson Miola

The potential health effects of quartz-bearing airborne dust in mine and mill atmospheres point to the need for the quantification of quartz content in the source material for determining the source-sink relationships and for choosing applicable control measures. While a standard method exists from a regulatory point of view for the sampling of coal mine atmospheres for determining (i) respirable dust concentrations and (i) the amount of quartz in thesamples, there is no generally accepted standard method for quartz analysis in bulk samples of coal and host rocks. Generally, the bulk sample is reduced to a powder for producing quartz analysis samples. Extensive controls are necessary to ensure representativeness of the analysis samples when these are very minute fractions of the bulk samples. Since the amount of analysis sample is not limited, alternative methods for quartz analysis may also be tried. It is, however, necessary to adopt a procedure which will satisfy several statistical requirements to guarantee representativeness of the quartz analysis samples. In this paper, the important factors in the preparation of quartz analysis samples from the host rocks and bulk samples are discussed. The method developed to prepare the analysis samples is outlined. The results of application of the procedures are presented. The procedure developed for quartz analysis sample preparation is based on sound statistical foundations. The procedure has been validated for reproducibility and homogeneity.

Jan 1, 1991

By Bruce K. Cantrell

As part of a continuing study of diesel exhaust aerosol characteristics, the Bureau of Mines has applied Chemical Mass Balance (CMB) model source apportionment analysis to evaluate a size selective sampling method for determining the separate diesel exhaust and coal dust aerosol concentrations in a diesel equipped coal mine. Size selective sampling was used under the premise that diesel exhaust aerosol dominates the submicrometer aerosol size range, while most of the mineral dust aerosol is greater than 1 m. A micro-orifice, uniform deposit impactor (MOUDI) was used as the size selective sampling method. Concurrent samples of mine aerosol were collected using a dichotomous, respirable aerosol sampler. This sampler separated the fine and coarse size portions of its sample at 0.7 m. Trace element concentrations for in-mine aerosol sources and the dichotomous samples used by the CMB model were measured using Instrumental Neutron Activation Analysis. The CMB analysis, applied to both the fine and coarse fractions of the respirable mine aerosol, yielded the mass concentration contributed to each by diesel exhaust and mineral dust aerosol sources. The MOUDI size distribution data were analyzed using nonlinear regression to parameterize the fine and coarse fractions of the sampled aerosol and to estimate the contributions to each fraction from both coal dust and diesel aero- sol sources. For the diesel mine visited, analysis of the MOUDI samples yielded a value for the fraction of the fine aerosol attributable to coal dust of 15[]7% fine fraction coal from analysis of the MOUDI samples versus 25[]4% from the CMB analysis. The remainder of the fine aerosol in the mine was diesel exhaust aerosol. CMB analysis confirms the original premise for such sampling. After correcting for the presence of coal dust in the fine aerosol fraction, analysis of the MOUDI size distributions yielded estimates of respirable mineral and diesel exhaust aerosol concentrations that were accurate to with-in 10% of values determined by the CMB apportionment.

Jan 1, 1987

By T. Ertekin, R. V. Ramani, W. Sung

The emission of methane in the coal mine working faces has two immediate impacts with regard to coal mine planning. Firstly, at the planning stage, the coal mine ventilation system must be designed such that airflows in the faces keep the concentrations of the gas in faces areas to below one percent. If the concentrations were greater than one percent, the production machine has to be shut down resulting in a loss of productive time. In an extreme case, concentration can reach explosibility limits which may lead to ignitions and explosions. Secondly, in excessively gassy coal seams, several alternatives can be applied to the mine layout configuration, and the mining method to be predicted for the extraction of coal, so as to insure a productive and safe operation. In this study a two-phase, two-dimensional finite-difference model was used to predict the methane emission rates into active mine working area under several methane drainage schemes. The numerical model utilizes a recently developed multi-mechanistic flow theory which describes the flow of methane in an heterogeneous and anisotropic coal seam. Transport of methane in the micropore structure of the coal is described by the Fick's law of dif- fusion under the influence of existing concentration gradient, while flow in the more permeable butt and face cleats (macropore spaces) is formulated by Dar- cy's law under the influence of existing pressure gradient. The desorption of the methane is accounted with the aid of a quasi-steady kinetic sorption model. A series of simulation studies were conducted in a systematic manner by sifting through the parameters associated with the coal seam characteristics and the degasification strategies in order to understand those which most significantly affect the methane emission rates in the face areas during mining. Along these lines, the effects of coal seam properties such as thickness, porosity, permeability, sorption characteristics and scheduling of drainage process against the mining operation have been isolated to understand the role of each individual parameter on the methane emission rates.

Jan 1, 1987

By Maurice C. Fuerstenau

INTRODUCTION The term, chelate, from the Greek for 'claw,' has its origin in the pincer-like representation of more than one atom of a single ligand bonded to the same metal atom, forming a ring-like structure. Depending on how many attachments exist on the sphere of coordination around the metal ion, ligands are referred to as bidentate, tridentate, tetradentate, pentadentate and hexadentate According to Calvin and Martell (1952) and Somasundaran and Nagaraj (1984), chelating agents must contain suitable functional groups, and their location within the ligand molecule must enable ring formation that is sterically possible. Typical structures that meet these requirements have been given by Fuerstenau and Herrera-Urbina (1988) and are listed in Figure 1. As noted, the functional groups of these reagents contain electron donor atoms such as oxygen, nitrogen and sulfur. Basic groups, such as amino (-NH,), are those that contain an atom with a lone pair of electrons. Acid groups are those, such as carboxylic (-COOH) which lose a hydrogen ion and coordinate with the metal atom. Examples of each of these types chelating reagents are given in Tables 1-4. The specificity of chelating agents for various metal ions has long been known and was utilized early in the search for new flotation collectors. In 1927, Vivian used ammonium nitrosophenylhydroxylamine as a collector for cassiterite. Holman (1929) tested dimethylglyoxime as a collector for nickel oxide. He also suggested taurin as a collector for oxidized lead ores. DeWitt and von Batchelder (1939) suggested the use of oximes as flotation collectors. Gutzeit (1946) conducted an extensive investigation on the use of chelating agents as collectors and as depressants for gangue minerals. The depressants are those reagents that form soluble chelates with metal ions that could function as

Jan 1, 2005