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By R. A. Pindred, M. P. Lam

Cyanide is a conventional lixiviant for gold extraction but its' toxicity is a major concern for the environmentalist. There are many alternative non-cyanide lixiviants, such as thiourea, thiosulphate, chlorine and hypochlorite etc., which may reduce environmental sensitivity. This paper will discuss the leaching characteristics of gold in hypochlorite leaching solutions. The dissolution of gold in a hypochlorite solution not only depends on the concentration of the hypochlorite but also on other variables, such as hydrochloric acid, sodium chloride and temperature. The dissolution rate of gold in hypochlorite solution is much faster than other lixiviants. Due to the interference of impurities, gold extraction from an ore under ambient conditions requires large quantities of reagents. However, refractory gold ores may be successfully pressure oxidized in an autoclave at reasonably low reagent levels. Gold extraction to the pressure oxidation leach solution is rapid and complete in one stage, thus eliminating the need for further cyanidation.

Jan 1, 1990

By B. D. Shah, H. S. Soto

Lack of selectivity in mixed mineral flocculation can be attributed to one or more of the following factors: dissolved ion interference, hetero- coagulation, mechanical entrapment in flocs, and entrainment of fines between flocs. In a study of the apatite-dolomite system, it was determined that dissolved ions do not have a significant effect on selectivity. Heterocoagulation was minimized by choosing proper process conditions and addition of a dispersant. Mechanical entrapment was proved to be insignificant and efforts were made to reduce entrainment by choosing an appropriate method of separation of flocs from fines. A new factor termed "polymer induced entrapment," which occurs due to limited affinity of the polymer to the mineral that is not flocculated, is postulated to be the cause for the loss of selectivity.

Jan 1, 1988

By P. Ritsopoulos, A. J. Dentsoras

The objective of this paper is the development of a reliable simulation model for the operation and production capacity of an aggregates quarry. Based on this model, a computer program is introduced that provides the final production outputs according to the defined material gradation and machinery characteristics. The program takes into consideration all operational parameters that may be introduced by the user through the whole machinery network. As a result, all production parameters are properly updated. The structured simulation program can help detect production inefficiencies that result from design ineffectiveness. Additionally, the program can be used for the generation of alternative scenarios for future modifications of a plant's configuration. Finally, a designer can use it as a tool for obtaining optimum solutions concerning newly designed quarries. As a case study, a quarry operating at Heraklion, Crete, was examined. The application of the program to the plant produced a complete image of the quarry's input/output characteristics, along with some suggestions for improvements on certain production processes.

Jan 1, 1998

By B. Bringhurst, J. J. McClelland

A filter consisting of a synthetic fibrous material has been determined to be a viable alternative to the wire mesh panels currently used in irrigated filter dust collection systems. An extensive laboratory investigation of the material showed that it removed a higher percentage of both respirable coal and quartz dust from the air entering a collector than did the flat and pleated wire mesh panel designs. This improvement in dust collection efficiency reduced the amount of coal and quartz dust discharged from the collector exhaust by approximately 44%. Since continued exposure to excessive levels (>5%) of respirable quartz dust presents a severe health hazard, this alternative filter medium could be of use to those mines required to comply with more stringent dust standards due to quartz.

Jan 1, 1992

By Eleanora I. Robbins, Motoaki Sato

Many problems associated with acid mine drainage (AMD) are caused by the complex way molecular oxygen (O2) oxidizes reduced matter at surface temperatures. In aqueous solution, O2 kinetically "prefers" to go through the formation of hydrogen peroxide (H2O2) as an intermediate. Being innately unstable, H2O2 is quickly decomposed back to water and oxygen in the presence of dissolved Fe and Mn, both catalysts for the decomposition. Direct addition of H2O2 to AMD produced similar results. Ozone (O3) is a much faster and stronger oxidizer than either O2 or H2O2. In the laboratory, O3 rapidly precipitated Mn, Fe, Ni, Co, Pb, and Ag even in acidic solutions. The experiments indicate that AMD can probably be processed with ozone and metal oxides/hydroxide recovered in flow systems using only septic-tank-size reactors and small sedimentation ponds.

Jan 1, 2000

By Jiqing Zhang, Jon C. Yingling, Andrzej M. Wala, Richard Ray

The purpose of this paper is to present how Computational Fluid Dynamics (CFD) simulations can be used to study the flow across the main airways of a mine ventilation system. in particular, the flow through the transition zone between the upcast shaft and main fan ductwork was investigated. These studies consider potential design modifications of this transition zone to reduce the energy cost. Although CFD has many advantages, it does not completely eliminate the need for experiments, which are still needed to validate numerical solutions. For this reason, data collected during actual mine tests and CFD simulations are compared in this pa- per. This comparison allows a better understanding of the flow phenomena. Moreover, once the numerical solutions have been validated, CFD can be used with better confidence to predict the effect of changes in ductwork configurations on energy losses. CFD reduces the number and cost of tedious experiments, while enabling a broader scope of design comparisons.

Jan 1, 1997

By M. Karmis

The algorithms for the mathematical modeling to predict productivity of underground room-and-pillar mining systems are well known and documented. These algorithms consider the time-varying relationships between mining equipment for a given geometty of operations as well as other constraints. This paper presents WebConSim, a newly developed, Web-based, user-friendly computer simulation tool for the Windows environment. The simulator is easily customized for use by field engineers, planning engineers and management and will help mine operators plan the optimum mining sequence for different mine geometrie and equipment layouts. Program output includes production data and equipment utilization indices, as well as time driven event chains that can be used for virtual reality presentations.

Jan 1, 2002

By Robert W. Bartlett

Pretreatment of sulfidic refractory gold ore by biooxidation in coarse-crushed ore heaps is a promising new technology, especially for low-grade ores that cannot afford pressure leaching or roasting. An algebraic equation for determining the economically optimum biooxidation of the sulfide minerals in the ore is provided that is based on the empirical biooxidation rate constant for the ore, the project's financial discount rate, the ore grades of both refractory and non-refractory gold, and the gold price. Then, the economically optimum duration of bioheap pretreatment, t$, is determined from its logarithmic relation to the optimum fractional extent of ore biooxidation, F$, through the ore's biooxidation rate constant. In doing so, it is assumed that the ore is adequately crushed and amenable to bioheap pretreatment and that the cumulative oxidation of the ore with time is known from ore testing so that the rate constant can be determined.

Jan 1, 1995

By L. E. Baker, M. J. Leck

OSIRIS is a continuous monitoring system for respirable dust which has been specifically designed for mining and related industries. By using the latest microprocessor technology, OSIRIS provides a sophisticated dust measuring system which is a cost effective alternative to regular gravimetric sampling. The system is certified intrinsically safe for use underground. Up to eight underground OSIRIS sensors can be controlled and monitored by a single IBM PC computer located at the mine surface. This computer provides continuous and instantaneous information about the dust concentrations at the sites being monitored. Information is available in tabular and graphical form. The paper gives details of proving trials of the OSIRIS system in some UK coal mines. During these trials, adjacent OSIRIS sensors placed on the same underground roadway cross-section gave virtually identical results. Throughout a good correlation was obtained with conventional gravimetric dust samples. The OSIRIS equipment proved both reliable and easy to operate. OSIRIS was designed and developed by the Safety Engineering Laboratory of the UK Health and Safety Executive. It is now available commercially and is being

Jan 1, 1987

By R. L. Bleifuss, S. Zhong, H. E. Geotzman

Microwave heating of iron ore was investigated as an alternative to conventional reduction processes to solve the problem of slow heat transfer. Microwave heating and reduction tests were run on composite green balls made from coal and magnetite concentrate. Benchscale tests were run on both powdered and pelletized feeds using a 15 kW microwave generator. A significant increase in the reduction rate was obtained. With 20% excess stoichiometric carbon in the mix, more than 90% reduction of the iron ore can be achieved in about 10 min at temperatures of around 1,000°C. The reduction of iron ore with coal by microwave heating produces a pure, dust free, high-Btu flue gas that can be used in related thermal operations. Depending on the purity, the reduced iron product could be fed directly to an electric arc furnace for melting. In some cases, the removal of a slag phase may be required to eliminate excess silica and alumina.

Jan 1, 1997

By Leo Wagner

In relation with the construction of the Sölk power station in Steiermark, Austria, tenders were called in October, 1976, for the construction of the 12-km "Donnersbach collector tunnel" by "Steirische Wasserkraftund Elektrizitäts AG". The specified showed both conventional blast tunneling as well as mechanical excavation with a tunneling machine, diameter 3.55 m. Total construction time from the date of the invitation to tender was given as 4 years. Part of the project was the construction of a concrete circular tunnel lining 20 cm thick. In 1977 the contract was awarded to "Arbeitsgemeinschaft Donnersbach", a joint venture formed by two companies, G. Hinteregger & Söhne, Salzburg, and G. Hinteregger, Bregenz. It provided for the project to be carried out with a tunnel boring machine. GEOLOGICAL DATA The entire tunnel was to be bored through a complex of the garnet mica schist group of the Wölz schists formations. These range from highly quartz-bearing to quartzitic mica schists, with thick, discordantly interstratified beds of marble and dolomite. In the western sector the axis of the collector tunnel intersects the bedding at an angle of 30° to 40°, in the eastern sector the bedding is about

Jan 1, 1979

By A. D. Trujillo, R. D. Wunder

The Chino Mines Co., a Kennecott- Mitsubishi partnership, located in Hurley, NM, recently completed a $405 million modernization of its mine, concentrator, and smelter facilities. The mine/concentrator modernization commenced in 1980, and the smelter modernization began during 1982. Modernization of the mine and concentrator facilities involved increasing the mining rate from 98 kt/d (108,000 stpd) to 152.2 kt/d (167,800 stpd). Ore mining was designed to increase production from 20.2 kt/d (22,300 stpd) to 34 kt/d (37,500 stpd). A new concentrator was con- structed near the mine using semiautogenous grinding. The new smelter uses the INCO flash smelting process, increasing capacity by 40.8 kt/a (45,000 stpy) to 99.8 kt/a (110,000 stpy) of saleable copper.

Jan 1, 1988

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, the pH decreased and metals increased. Output pH increased from 4 to more than 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long-term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2002

By W. K. Tolley, D. G. Kotlyar

Oxidized sulfide minerals, commonly formed by weathering, are becoming increasingly important resources as primary sulfide deposits are depleted. Oxidation, in general, reduces selectivity and recovery in flotation. The objective of this research was to determine the mechanisms of oxidation and collector adsorption in sulfide systems as a step towards developing improved technologies for beneficiation of oxidized sulfides. Data from microcell flotation tests are combined with electrochemical and spectrophotometric measurements. The adsorption of ethyl xanthate (EX) on oxidized sulfides was characterized using AC impedance and voltammetry techniques, and correlated to flotation response. Oxidation resulted in an electrically resistive, nonporous surface layer. The floatability of chalcocite, chalcopyrite and pyrite was dependent on the extent of oxidation. Oxidation for one day or more at 65ºC suppressed chalcocite flotation. Oxidized chalcocite also inhibited flotation of chalcopyrite and pyrite. Oxidation caused decreased chalcopyrite flotation. Pyrite flotation, however, increased after oxidation.

Jan 1, 1995

By M. H. H. Mahmoud, T. A. El-Barbary, E. A. Abdel Aal, I. A. Ibrahim, A. K. Ismail

Fertilizer-grade phosphoric acid with a P2O5 concentration of 50% should contain less than 1.5% Fe2O3, otherwise, the P2O5 water solubility of the fertilizers prepared from high-iron acids will be low. High-iron Egyptian phosphate concentrates fromAbu-Tartur and Sebaiya- West were leached with sulfuric acid and recycled phosphoric acid to produce 50%-P2O5 phosphoric acids containing 4.0% and 2.7% Fe2O3, respectively. The high iron contents were reduced to the industrially accepted limit of 1.5% Fe2O3 by precipitation with potassium sulfate. The factors affecting the effi¬ciency of the precipitation process, e.g., temperature, time and K2O/Fe2O3 ratio, were systematically studied, and the optimum conditions were achieved. The clarification of the prepared phosphoric acid from iron-containing sludges was also investigated by varying the time and temperature. The utilization of the separated sludges as fertilizer and recovery of P205 by pulping in water were also evaluated.

Jan 1, 2000

By Joyce A. Ober

Strontium occurs commonly in nature, averaging 0.034% of all igneous rock; however, only two minerals, celestite and strontianite, contain strontium in sufficient quantities to make its recovery practical, and these minerals are found in sedimentary rocks. Of the two, only celestite has been found to occur in deposits of sufficient size to make development of mining facilities currently attractive. Celestite, the most common strontium mineral, consists primarily of strontium sulfate (SrSO,). Strontianite, the second most common mineral, consists primarily of strontium carbonate (Sr CO3). Strontianite would be the more useful of the two common minerals because strontium is used most commonly in the carbonate form, but few deposits have been discovered that are suitable for development. The physical properties of strontium ores are listed in [Table 1].

Jan 1, 1994

By J. A. Brierley, C. L. Brierley

The history, current applications and future of biotechnical developments in the metals' extraction industry are reviewed. Bioleaching of copper minerals continues to be the most significant application. Uranium bioleaching was successfully demonstrated at industrial scale. Developments are now being made in biooxidative pretreatment of refractory gold concentrates, ores and low-grade materials. Advancements are forthcoming in water and solid mine waste bioreclamation, including metals' biosorption, wetland treatment of acid mine drainage, and biodegradation of cyanide in spent, heap-leach operations. Better understanding of the types and functions of microorganisms involved in metal interactions could advance genetic engineering applications in bioleaching and bioreclamation.

Jan 1, 1993

By Monica Pavlik, Thomas Wildeman

Water from the Forest Queen mine adit near Silverton, Colorado drains into a natural wetland. Because the pH of the water averages 5 and the iron concentration averages 18 mg/L, it was thought that the wetland might naturally treat the water. Of most concern with respect to the aquatic environment is zinc whose concentration averages 0.60 mg/L. Starting in October 1997, the surface waters, ground waters in the peat substrate, and the sediments in the wetland were sampled and analyzed four times over the course of four months. The adit water primarily remains as surface water where Fe, minor amounts of Al, and no Zn are removed. After the adit water enters the peat, then it is found that the pH rises to 5.8-6.5 and sulfate is reduced. The removal of Zn and A1 is caused by these two changes. However, Fe in its reduced state is quite soluble and may be remobilized in the reduced environment of the peat.

Jan 1, 2000

By L. G. Sobral, J. E. Hoffman, T. J. Keefe, A. J. Monhemius, O&apos

The kinetics of electrodeposition of gold from dilute solutions of alkaline KAu(CN)2 at different gold and free cyanide concentrations on a gold rotating disk electrode were investigated by use of a steady-state linear potential scan technique. The design and performance of a laboratory electrowinning cell with a reticulated nickel cathode, operating in the flow-through mode, for the removal of low levels of gold ions from aqueous cyanide media is described. During the batch recirculation of oxygen-free gold cyanide solutions, the gold concentration was reduced from 10 ppm to <0.5 ppm with current efficiencies of up to 80%. The influence of solution flow rate through the cathode and of the pore size of the reticulated nickel foam is discussed. The removal of gold ions from solutions of low ionic strength was also investigated.

Jan 1, 1993

By P. D. Rao, D. E. Walsh, W. W. McClintock

A column flotation system was designed to conduct release analyses on a very finely disseminated, stratiform copper ore from the Denali Copper Prospect in Alaska. Chalcopyrite is finely disseminated in a carbonate matrix, and pyrite is disseminated in both the chalcopyrite and the gangue. Grinding to -20 µm is required for adequate liberation. A 25-mm x 2.4-m glass flotation column was designed. The ore and its flotation tailings were repeatedly floated to obtain a rougher concentrate. The rougher concentrate was then repeatedly floated to produce release fractions. These fractions were analyzed for copper, iron, calcium and magnesium, and release curves were plotted. The procedure was replicated at each of two grinds, i.e., 99% and 88% passing 37 µm (400 mesh). The procedure should find application for flotation characterization and process selection. Bond grindability testing was also conducted.

Jan 1, 1996