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By E. Forssberg

Studies have been carried out with the High Pressure Roller Mill, HPRM, to produce calcium carbonate minus 10 micron. This paper presents the optimization of the specific grinding force of the HPRM system for a maximum energy utilization when limestone is ground. In addition, experimental tests of producing carbonate minerals using the HPRM as a pre-crusher are described in this paper.

Jan 1, 1996

In 1990, US mine production of barite increased 54.1 %. Barite consumption, sold or used by grinding plants, increased by 27.6%. Imports were about the same as 1989. World mine production in¬creased 12.3%, according to the US Bureau of Mines. The value of domestically produced barite, fob mine, decreased 12.7%, according to the Bureau. The declared value, cif US port, of all imported crude barite during the year 1990 increased from $40.27/t ($36.54 per st) in 1989 to $40.61/t ($36.84 per st). Nevada continued to be the leading producer of barite with 82% of the total, followed by Georgia and Missouri. It is estimated that 750/c, of the domestically mined barite was used as a weighting agent in drilling fluids. The remaining 25% was used in barium chemicals, glass or as a filler. Most of the production from Missouri, Georgia and Tennessee was used in the non-oilfield sector. Of the total barite used by grinding plants and chemical manufacturers, it is estimated that 90% was used in drilling fluids and 10% in the non-oilfield sector. This includes barium chemicals and fillers in paper, plastics, and glass. Tonnage consumed in the drilling fluids market increased due to the higher average rig count during 1990. The average number of rotary rigs operating, (1010), was 16.2% more than the 1989 average of 869 in the US.

Jan 1, 1991

By R. L. Lewis

A simple method for estimating the steady-state water quality of a pit lake is presented. The steady-state concentration of a conservative chemical constituent in a pit lake is shown to be a simple function of inflow rate, evaporation rate, and inflow concentration. An analytical method is presented for estimating the equilibrium ground water inflow rate for use in water quality predictions. The time required to reach chemical steady-state is estimated using an iterative mass balance model. Mine operators should find the methodology useful for planning and screening-level regulatory applications where conservative estimates of pit lake water quality are desirable.

Jan 1, 1998

By R. J. Sweigard

Fine coal refuse is often pumped, as slurry, into surface impoundments as a means of permanent disposal. As the available volume is filled, the height of the embankments are frequently increased. Many times the additional embankment material is placed upon consolidated fine coal refuse. There has been some concern about the long-term effect of consolidation of this material at or above the liquid limit upon its shear strength. A laboratory investigation was performed using three different types of fine coal slurry taken from Central Appalachian coal preparation plants. The refuse was consolidated in 10-foot plexiglass columns under incremental amounts of surcharge loading. The incremental loads were designed to simulate the effect of increasing the height of a refuse embankment on top of the consolidating coal slurry. After the refuse in the columns had consolidated for several months, the columns were cut apart and triaxial tests were performed on both the consolidated material and unconsolidated material for comparison of their shear strength parameters.

Jan 1, 1997

By Peter Zhang

The immediate roof at the test site consisted of laminated clay shale that is likely to be susceptible to weathering. With seasonal dry-wet cycles in the mine ventilation air, the roof in the intake air would deteriorate and lose integrity over time. In many instances, the weathering-prone roof would gradually scale off piece by piece between bolts and over the entry corners. In some long-term entries, roof weathering could develop up to 2-3 ft deep with columns of bolted roof hanging under the upper intact roof. If wire mesh is used, the roof bags down and reduces the entry height, and the weight of the bagged roof tends to pull the bolts out and poses a safety hazard. An effective measure is always sought to support this type of weak roof that is sensitive to moisture degradation. One solution is to seal the roof shortly after entry development to prevent moisture penetration so that roof integrity can be maintained for the long term. In this application, a polymer-based sealing material was tested in the Rockspring mine for weathering protection and reinforcement. The material is a one-component polymer powder for spray application onto the roof and rib. The sealant material is mixed with water in the spraying nozzle to apply to the roof and rib as a paste. The product sets within 5-10 minutes and forms a membrane as thin as about 1/8-in. The membrane will quickly develop tensile and bonding strength within minutes and completely cure within a few days. Through sealing, bonding and lateral reinforcement, the integrity of the weak roof can be maintained. The material has been tried in a long-term evaluation over several months in a set of main entries in the Rockspring mine owned and operated by Rockspring Development, Inc., affiliate of Foundation Coal. Preliminary evaluation has shown that the material is an effective and economical solution to ensuring the long-term stability of weathering-prone roof.

Jan 1, 2009

By John G. Myers, William A. Vogely, Harold J. Barnett

INTRODUCTION, CONCEPTS, AND MEASUREMENT Introduction Periods in the history of man, from his earliest appearance to the present, are often characterized by the principal materials used. In nearly all cases, the material or fuel is of mineral origin-stone, copper, bronze, iron, coal, and so forth-indicating the principal ingredient of the tools or source of power of the period. Each of these periods represented great improvement over the preceding one in terms of human well-being, as measured by population growth and other indicators (Cipolla, 1978). A major reason for the improvements in production and well-being was the nature of the material or fuel, each successively superior to the preceding, which made it possible to produce more food, fuel, shelter, and clothing with a given amount of labor. If we accept this well-documented description of economic progress as accurate, we may then turn to the consideration of two related questions concerning this development. The first, easily answered,-is why man spent long periods of time (millenia, in many cases) making tools from inferior materials, such as copper, instead of passing directly to superior materials, such as iron and steel. The second, closely related question, concerns the relation between the rate of economic growth and the quantity of mineral reserves available at any time. For the first question, the answer is that the technology required to discover, extract, and process each successive material had to be discovered and developed before the material could be used. Once the technology was available, the new material could be and was exploited widely, raising productivity-output per unit of labor- and consequent consumption per person. This familiar idea underlies a fundamental principle of the economics of resources, namely, at any time, available resources depend upon available technology. No mineral or other raw material is a resource unless the technology has been developed to utilize it. But once the technology is at hand, the new resources associated with it provide the means for economic growth and rising levels of living. This principle is subject to certain conditions. For example, governments or other institutions may prevent a mineral from being used, even though the technology is available. And, if a mineral is located in a remote place, transportation charges may make it uneconomic to exploit. Such minor qualifications do not, however, change the thrust of the argument that technology is the overriding determinant. With respect to the second question, it might seem apparent that the greater the quantity of reserves available, up to some point, the more economic growth will be facilitated. This line of reasoning leads to the conclusion that as re- serves are consumed the quantity available will be reduced and economic growth will eventually be restrained. Reasoning of this sort underlies much popular (and scholarly) thought, in which depletion of mineral and other resources is assumed to lead to constraints on economic growth, through higher materials costs and absolute limitations on materials use. Two important qualifications must be made to this explanation, however, which together

Jan 1, 1985

By R. A. Haney

The Mine Safety and Health Administration has developed a model to estimate diesel particulate (dp) exposures in underground mines. The estimate uses either in-mine measured dp concentrations or engine manufacturers' standardized emission data and through a series of calculations estimates full shift dp concentrations by applying standard engineering principles of ventilation, control technology and work cycle. This model, in the form of a computer spreadsheet, provides the mining industry with a method to estimate diesel particulate levels and determine the impact of various diesel particulate controls on occupational exposure to dp in underground mines. A detailed description of the estimator and several examples demonstrating the results are provided.

Jan 1, 1998

By C. R. Stephan

Explosion-resistant seals in underground coal mines isolate the environment within the sealed area from the active workings of the mine. The current United States Title 30 Code of Federal Regulations (CFR) requires these seals to be constructed of solid concrete blocks. The CFR also allows for alternative methods or materials to be used to create a seal if they can withstand a static horizontal pressure of 138 kpa (20 psi), provided the method of installation and the material used is approved in the ventilation plan. The purpose of this report is to identify those explosion-resistant seals that have been tested and meet or exceed all the requirements of the CFR.

Jan 1, 1997

By David A. Lindsey

In this paper, we present a physiographic classification of gravel deposits, identify some field measures of aggregate quality, and describe sampling strategies for mapping aggregate quality in the Front Range Urban Corridor of Colorado. Gravel occurs in four types of deposits along the Front Range of Colorado: (1) piedmont alluvial fans, (2) high dissected terraces, (3) high (continuous) terraces, and (4) floodplains and low terraces. The four deposit types are the basis for definition of gravel-deposit models, which differ in geologic environment, deposit characteristics, deposit size, environmental impacts of mining, and post-mining use. Of the four types, floodplains and low-terrace deposits have been exploited most for gravel. High terraces also have been mined. Deposits of high dissected terraces and dissected alluvial fans have produced minor amounts of gravel, mostly for use as local fill. Studies to identify useful field measures of aggregate quality and to determine the appropriate scale for sampling were conducted on gravel deposits beneath the flood-plain and low terraces of the South Platte River north of Denver and the Cache la Poudre River between Ft. Collins and Greeley. Gravel deposits of the South Platte were selected for study because they represent the last major resource of gravel for aggregate in the Denver metropolitan area. The Cache la Poudre valley is the primary source of gravel aggregate for rapidly urbanizing areas around Ft. Collins and Greeley. Of all the field measures of gravel quality, the most important is particle size. Various parameters that measure particle size were investigated, but the easiest to determine, and the most useful to the aggregate industry, are measures of the proportion of coarse sizes. Particle size varies widely in gravels of the urban corridor. Gravel lithology, particularly the presence of deleterious particles such as reactive volcanic rocks and decomposed rocks, must be determined to assess aggregate quality. Studies of South Platte and Cache la Poudre gravels have not revealed large proportions of deleterious lithologies. Studies of particle shape revealed only small numbers of physically weak shapes in both the South Platte and Cache la Poudre gravels. Particle shape does not appear to vary from place to place in the gravels. Rounding, or the ab¬sence of angular corners, may play a role in the tendency of loose gravel to yield under load. South Platte and Cache la Poudre gravels are rounded, and rounding tends to increase upstream. Before the quality of gravel in a valley can be assessed, the stratigraphy of the gravel must be known because it affects sample design. If only a single gravel layer is to be studied, only the thickness of the gravel must be known before sampling. If, however, more than one layer of gravel-distinguished by particle size, sorting, or lithology-is present, sampling must take into account the thickness and distribution of each layer. For example, three gravel layers of different particle size underlie the floodplain and low terraces of the South Platte. The tributary Cache la Poudre, on the other hand, contains gravel layers that can be distinguished only locally and vary slightly in particle size. Sampling experiments were conducted on gravel bars in the South Platte River and in gravel pits on the floodplain and low terraces of the South Platte and Cache la Poudre Rivers. Experimental results indicate that, even where sample error is large, regional and stratigraphic variation may be measured if it is large relative to sample error. Using vertical trench samples weighing an average of 40-90 pounds, down-stream decrease in coarse particle size was mapped for Cache la Poudre gravel, and differences among superposed gravel beds were measured for South Platte gravel.

Jan 1, 1999

By V. B. Menon, L. D. Michaels, M. E. Mullins

Introduction The cleaning of coal to remove sulfur and inorganic impurities has, in recent years, become an essential operation in any coal utilization process. US coals, on average, contain about 3% total sulfur, of which more than 60% is generally inorganic or pyritic sulfur. Existing technologies such as heavy media cycloning, selective agglomeration, and electrostatic separation have the potential for removing about 80% of the pyrite from coal (Khoury, 1981). In view of the large volumes of coal being used today, there exists a need for the development of new processes to further improve the separation of pyrite from coal. Colloidal particles in suspension possess surface charges that are related to the chemical composition of the particles. In aqueous suspensions, the surface charge is a function of pH. For coal-pyrite mixtures, it is possible, by an adjustment of the pH (also a function of polar molecules), to reach a state where the charge on coal is very close to zero, but the charge on pyrite is still substantial. The introduction of collector particles with a charge opposite that of the pyrite should then result in the selective flocculation of pyrite and collec¬tor. These flocculates should settle out much faster than coal and could be removed from the bottom of the settling column. This note discusses our preliminary observations of the effect of clay-based collector particles, especially bentonite, on the settling behavior of coal and pyrite. These experiments were conducted with a view to developing a new electrokinetic flocculation process for separation of coal-pyrite mixtures. Experimental The objective of the experiments was to determine the effects of clay-based additives on the settling rates of clean coal, pyrite, and coal-pyrite mixtures. Illinois Colchester (No. 2) coal was obtained after processing in an existing coal cleaning facility. This coal was reported to contain less than 0.3% pyritic sulfur, which was in the form of a fine powder with an average particle size of 5µm. Pyrite (of average particle size 5 µm) was also obtained from the same facility and reportedly contained less than 0.1% coal. The zeta potentials of coal and pyrite in water were measured as a function of pH using a zetameter. The pH was adjusted by adding sodium hydroxide or hydrochloric acid to the suspensions. Sedimentation experiments were conducted in 50-mL glass cylinders, and settling rates were measured by noting the height of clear liquid above the settling front as a function of time. Settling behavior was also charted by periodically taking photographs of the system. The following systems were investigated: •a slurry consisting of 2.5 g of clean Illinois Colchester coal in 50 mL of water of pH 6.0, with and without the addition of 0.5 g of bentonite (Fisher, purified grade) ; • a slurry consisting of 2.5 g of pyrite in 50 mL water of pH 6.0, with and without the addition of 0.5 g of bentonite ; and • a slurry consisting of a mixture of 1.25 g clean coal and 1.25 g pyrite in 50 mL water of pH 6.0, with and without the addition of 0.5 g of bentonite. In addition, experiments were conducted with kaolinite (Bath, South Carolina) and alumina (Fisher, purified grade) as collector materials to verify the observed effects. Results and discussion Figure 1 shows the zeta potential values for the Illinois coal and pyrite as a function of pH. The zeta potentials of coal and pyrite decrease with increasing pH, changing from an initially positive value at low pH to a negative value at high pH. The point of zero charge (PZC) for the coal is at a pH of 6.2, while the PZC for pyrite occurs at a pH of 10.3.

Jan 1, 1988

By Williams R. Reynolds

Studies of the northeastern Mississippi bauxites were initiated primarily for the purpose of ascertaining the quality and quantity of the ore. Subsequently, this ore was found to have a rather dubious economic value as was previously suspected but never established in earlier economic reports (1, 2, 3). However, the quality of ore was found to be higher than previously thought. Even though the ore bodies were determined during the early stages of this study to be too thin, small and widespread for commercial production a continuation of the study was not abandoned. On the contrary, the present investigation was intensified concentrating less on the economic application and more on stratigraphy and genesis. Considering the ever increasing demand for aluminum products the northeastern Mississippi bauxite district which includes portions of Tippah, Benton, Pontotoc, and Union Counties may soon become, in spite of inferior quantities of ore, an attractive area for bauxite production. Presently, however, the meager quantity of ore discourages exploitation. On the other hand, these northeastern district bauxites are facies of more extensive units of lignite bearing high aluminum clays, and considering the advances in aluminum extraction from clay these clays may in the future beckon mining interest. The bauxite of the northeastern Mississippi district, mapped as a part of the Betheden Formation (4). has an outcrop trend along the county lines of Tippah and Benton Counties and the extreme western portion of Union and Pontotoc Counties. Studies of exposures and cores stratigraphically positions the outcrop between the middle Midway Porters Creek Clay and the lower Eocene Wilcox sands and

Jan 1, 1977

By Haydn H. Murray, Fred G. Heivilin

The "Hormite Group" was proposed for palygorskite (attapulgite) and sepiolite for their complex magnesium silicate composition and elongate crystals (Martin-Vivaldi and Robertson, 1971). These minerals occur in close association with each other and more complex structural variations may exist (Bailey, 1972). In 1862 Savchenkov used the name palygorskite to describe a mineral from the Palygorsk locality (Hay, 1975), near the Ural Mountains. Ovecharenko and Kukovsky (1984) mention that when mountain leather deposits were prospected in the Palygorsk Division mine it was assumed this unusual mineral was a variety of asbestos. Early mineralogists used the terms "mountain cork" or "mountain leather" when referring to palygorskite. Robertson (1986) mentions that it appears palygorskite was known since Theophrastus&apos; time, ca. 314 BC. J. de Lapparent used "attapulgite" for clays from Attapulgus, GA, and Mormoiron, France, because he thought them different from palygorskite, but the two types were proved to be the same (Bailey et al., 1971). The name attapulgite is still used for the Florida and Georgia deposits when the crystal length to diameter ratio does not exceed 10:1(Merkl, 1989). Georgia palygorskite clays are of much shorter length compared to classic palygorskite. In 1847 Glocker first used the name sepiolite which was called "Meerschaum" by Werner (1788) and Hauy (1801) namedit "Ecume de Mer." Brochant (1802) described low density and white magnesium silicates adding the name Talcum Plasticum and Ecume de Mer. In the Meigs-Attapulgus-Quincy district palygorskite (attapulgite) commonly occurs in two distinct forms referred to as short length palygorskite (Meigs Member) and long length palygorskite (Dogtown Member) (Merkl, 1989). Long length palygorskite crystals (> 10 pm) are rarely observed in the Meigs and Dogtown Members, but when present are in association with dolomite crystals. The short length form is usually less than 2 pm in length and has a low magnesium content whereas the long length form has a high magnesium content and a length greater than 2 pm. The distinctions in morphology are not only important because of the relationship to the origin of the deposits, but also in relation to activity in causing membranolytic activity related to data on palygorskite samples from 9 locations ranging from relatively inert to active in work reported by Nolan et al. (1989). The > 10 pm lengths amounted to only 51 of 17,401 fibers sized. The shortest lengths (< 0.5 pm) were relatively inert. This study pointed out that surface activity, morphology, and chemical differences may be distinctly different within the definition of palygorskite, or for that matter for any individual mineral so that health and other properties must be measured because the name alone does not necessarily indicate uniformity. Palygorskite (attapulgite) fuller&apos;s earth was first sold for drilling mud in 1941. The market for this use expanded slowly and has maintained a level of 7 to 10% of the total US production during the last few years. Most of the fuller&apos;s earth sold for drilling mud comes from the southern part of the Meigs-Attapulgus-Quincy district of Georgia and Florida. Palygorskite clays produced in this area are superior to most other fuller&apos;s earth for mud used in drilling salt formations, but because of high water loss, they are inferior to bentonite where the rocks drilled contain no saltwater. According to Oulton (1965), more than 90 different grades of fuller&apos;s earth are produced. Some of these grades are used for pharmaceuticals designed to absorb toxins, bacteria, and alkaloids; for treatment of dysentery; for purifying water and dry cleaning fluids, dry cleaning powders and granules; for the manufacture of NCR (no carbon required) multiple copy paper; for the manufacture of wallpaper; and as extenders or fillers for plastic, paint, and putty. Fuller&apos;s earth mined near Ellenton, FL, was used for making lightweight aggregates for the construction of concrete barges during World War I1 (Calver, 1957). Still other uses of fuller&apos;s earth and its suitability for uses in new products are outlined by Haden, Jr., and Schwint (1967), Haden, Jr., (1972), and Haas (1970). One special use of fuller&apos;s earth is as a carrier of platinum catalysts that are made in the United Kingdom from sepiolite clays mined in Spain. Other uses of sepiolite fuller&apos;s earth (Chambers, 1959) are similar to those of the palygorskite (attapulgite) type mined in the United States.

Jan 1, 1994

By B. R. Green, Ms. M. H. Kotze

Ion-exchange fibres (IEF) were prepared by the ir­radiation grafting of styrene onto polypropylene, which was then subsequently functionalized. Strong- and weak-base exchangers were prepared and evaluated Tor their ability to extract gold cyanide selectively. The IEF prepared had loading capacities similar to those of the corresponding resins and they had good selectivities for gold cyanide when contacted with a mixed metal-cyanide solution. The expected advantage of IEF over granular exchangers, that of faster kinetics, was illustrated. The strong-base Iibre in particular seemed to be very effective for the extraction of gold cyanide from dilute solutions such as return-dam waters.

Jan 1, 1990

By Christopher M. St. John, Michael P. Hardy

INTRODUCTION Geotechnical models, particularly those based on the finite element method, have been available to aid in en¬gineering design of underground mining excavations for over ten years. Despite this fact there are remarkably few cases of their use in mine design documented in the literature. It is therefore to be anticipated that many potential users of these models are relatively unaware of their capabilities and limitations and also of the form and detail of geotechnical data needed for their success¬ful application. This subsection attempts to address this problem by discussing the different types of numerical models now available and by noting how some of them have been used to study a variety of problems associated with underground mining. The subsection concludes by discussing the applica¬tion of the displacement discontinuity method to the de¬sign of possible mining systems for the copper-nickel deposits of northeastern Minnesota. The object of the analyses, which were nonsite specific, was to determine the significance of geotechnical parameters, such as ini¬tial stress and rock structure, on the stability of under¬ground excavations and hence to provide guidance for future geotechnical investigation. NUMERICAL MODELS In the geomechanical design of underground mining openings, use is made of numerical models that repre¬sent or simulate the large-scale mechanical behavior of rock. There has been less interest in analysis involving fluid flow and heat transfer, but with increasing interest in such areas as in-situ retorting and solution mining it is likely that there will be a growing need for numerical models embracing and coupling all three physical proc¬esses. However, the emphasis in this subsection will be on mechanical behavior. Models which simulate such behavior will be divided into two groups: continuum models and discontinuum models. These will be dis¬cussed in turn in order that some insight into alternative solution strategies and their merits may be gained. Continuum Models Almost all geomechanical numerical models must be classed as continuum models even though particular computer codes incorporate special provisions for rep¬resenting discontinuities such as faults, bedding planes, or joints. They are continuum models because they pro¬vide solutions for cases where material behavior is governed by the differential equations of continuum mechanics. Two basic solution strategies for such equa¬tions may be identified immediately: the differential ap¬proach and the integral approach. In the differential approach a means of approximating the differential equations over the entire region of interest is sought. In the integral approach use is made of fundamental solutions from continuum mechanics, and these are used to construct a solution to the whole problem, making approximations only on the boundaries of the region of interest. The several differential and integral methods are identified in Table 1. Differential Methods: Problems in continuum me¬chanics involve the solution of three types of partial differential equations. Two of these govern the behavior in so-called initial value problems, in which variables change both in time and in space. Examples of such problems include nonsteady heat transfer and fluid flow, and stress wave propagation. The last type of partial differential equation governs the behavior in boundary value problems. In these, variation is in space but not in time. Solution of initial value problems may be achieved in two significantly different methods: implicit and ex¬plicit. The differences between these two methods will be illustrated by considering a very simple initial value problem, that of one-dimensional heat diffusion. The equation governing this process may be written as: [ ] where T is temperature, K is thermal conductivity, p is density, c is specific heat, t is time, and x is the spacial coordinate. In finite difference form this equation might be written as: [ ] where the superscripts refer to the time and the sub¬scripts to the spacial location. Several solution strategies for this equation have been used. Two important ones may be illustrated very simply by discussing the signifi¬cance of the superscript * on the right-hand side of the equation. If i + 1 is substituted for * then the second derivative of the temperature with respect to distance is evaluated at the end of the next time step (using tem¬peratures not already known). Such an approach leads to a set of equations involving unknown temperatures and a solution procedure which is referred to as being implicit. The important characteristic of the implicit procedure is that it leads to a set of equations that must be solved for each time at which the temperature dis¬tribution is required. If instead of substituting (i + 1) for the superscript *, i is substituted, the following equation is obtained: [ ] {In this case the new temperature is defined in terms of an already known temperature distribution. The solution procedure is now known as explicit and has the impor¬tant characteristic that there are no equations that have to be stored or solved. A practical advantage of this

Jan 1, 1982

In 1989, United States mine production of barite decreased 13% while world mine production decreased by 8.6%, according to the US Bureau of Mines. Consumption, sold or used by grinding plants, decreased by 21.2%. And imports decreased by 12.8%. The value of domestically produced barite, fob mine, increased 17.4%, according to the Bureau. The declared value cif US port of all imported crude barite during 1989 increased from $38.10/t ($34.56 per st) in 1988 to $40.27/t($36.54 per st). Nevada continued to be the leading producer of barite with 77% of the total, followed by Georgia and Missouri. The Bureau of Mines estimates 75% of the domestic mine production was used as a weighting agent in drilling fluids. The remaining 25% was used in barium chemicals, glass, or as a filler. Most of the production from Missouri, Georgia, and Tennessee was used in the nonoilfield sector. Of the total consumption used by grinding plants and chemical manufacturers, it is estimated that 80% was used in drilling fluids. The other 20% was used in the non-oilfield sector, including barium chemicals and fillers in paper, plastics, and glass. The tonnage consumed in the drilling fluids market decreased due to the lower average rig count during 1989. The average number of rotary rigs operating was 869, 7.2% less than the average of 936 in 1988. Crude barite imports were down 12.8% from 1988. Imports accounted for 73.8% of the barite consumed (apparent) in the US. China continued to be the leading exporter of crude barite ore to the United States with 63% of total crude ore imports. India followed with 27.4%, Peru 4.3%, Chile 2.9%, and Canada and Mexico, each with 1.1 %. About 97% of the imported barite ore was used in the oilfield sector.

Jan 1, 1990

By James Watson Baxter

Fluxes are used to promote pyrometallurgical processes that rely on adhesion (soldering or brazing) or fusion (gas and arc welding) to join metallic surfaces. In the adhesive processes, the metal surfaces to be joined are not melted; the join is formed using a filler metal with lower melting point than the base metal. Fusion welding involves use of heat in excess of the melting point of the base metal. The fused joint may be achieved either by simply fusing together metal surfaces brought in contact with each other or by introducing additional molten metal of similar composition to form a fused joint. ADHESIVE PROCESSES--SOLDERING AND BRAZING In order for molten filler metal, solder or braze, to spread in a manner that creates a successful join; the work surfaces on the base metal must be thoroughly cleansed. Fluxes remove stubborn oxide films and other surface contaminants, promote wetting of the work surfaces, add fluidity to the solder or braze, and enhance workability and ease of spreading. Brazing processes involve higher temperatures than those reached in soldering. Brazing fluxes, which must remain active and effective at the higher temperatures, differ from those employed in soldering. Some common fluxes used in adhesive processes are rosin for soldering tin and electrical connections, hydrochloric acid for use in soldering galvanized iron and other zinc surfaces, and borax for brazing. Soldering and brazing are similar processes, the primary difference being the temperature at which the joining operation is carried out. Soldered joints, produced with low-melting-point fillers (solders) that melt and flow at temperature less that 450°C (Althouse et al., 1988) can sustain loads of 1 to 1.7 MPa for extended periods of time (Anon., 1966). Brazing involves the use of filler materials with melting points commonly above 500°C and generally provides stronger joints than those obtained with solder. Both processes require local application of heat to melt and spread the filler so that the molten filler can wet (adhere to) the base metals by alloying and diffusion. Soldering Soldering is a means of joining metals by adhesion using a metallic bonding alloy as the filler, commonly a mixture of lead and tin. However, the adhesion of solder depends more on its ability to be keyed into minute surface irregularities than on alloying. The most familiar application is to provide and secure electrical connections. Soft solders can range from 1 to 70% tin with the remainder mostly lead. However, for general-purpose, soft-solder work, the alloy is commonly 50% lead-50% tin. Higher lead contents provide a wider range in the melting temperature and, for this reason, a 60% lead-40% tin alloy, which yields a mushy mixture, is used for wiped joints in lead sheet and pipe work. Conversely, 40% lead-60% tin alloys are used in soldering tin and other low- melting-point materials for which a narrower range of melting temperature is required. There are numerous other solder compositions such as tin-silver, 95% tin-5% silver and antimony-tin, 95% tin and 5% antimony (Carlin, Jr., 1992). Heat needed to melt and spread the solders is commonly provided by electrically heated, copper-tipped soldering irons or by means of torches; the solder is applied by hand, usually face-fed by means of wire. For wiped joints in plumbing and lead-cable splicing, the solder is manipulated with cloth pads. The molten solder wets the joint surfaces and is drawn, by surface tension, into minute fissures and capillary openings. Other applications involve use of induction heaters and furnaces with pre-shaped solder appropriately placed prior to fluxing and heating. In some processes, the joints are immersed in molten solder. Constituents and Role of Soldering Fluxes: Soldering fluxes generally fall into one of three categories: highly corrosive fluxes, intermediate fluxes, and noncorrosive fluxes. These same categories are sometimes designated inorganic, organic and rosin-based respectively (Althouse et al., 1988). Common constituents of each group are discussed briefly below. Corrosive Fluxes (Inorganic). Work with aluminum, magnesium, stainless steel, high alloy steel, aluminum bronzes, and silicon bronzes is carried out at temperatures in the upper portion of the range for solder operations. Soldering these materials requires use of highly active, corrosive fluxes to remove and prevent the formation of the especially stubborn, hard, oxide films that form on these materials upon exposure to the atmosphere. The corrosive fluxes consist of inorganic acids and salts that are applied either as pastes or dry. They are active at elevated temperatures and, since they remain active after the soldering is completed, must be completely removed. The main constituent of most corrosive fluxes is zinc chloride with a melting temperature well above the solidus temperature of most commercial tin-lead solders. It is made by the action of hydrochloric acid on zinc. When zinc chloride is used alone, un- melted particles of this corrosive salt get caught up in the joint and weaken it. For this reason, other inorganic salts such as ammonium chloride (NH4Cl) or sodium chloride (NaCl) may be added to lower the melting temperature. A mixture of zinc chloride and ammonium chloride is very effective because the excellent oxide reducing properties of ammonium chloride and the protective action of the molten zinc chloride combine to produce a fluxing action superior to that achieved when either is used alone. In addition to zinc chloride, ammonium chloride, and sodium chloride; common con-

Jan 1, 1994

By B. I. Pålsson, H-Å. Häggblad, J. F. Stener, P. Jonsén

"Understanding mill charge motion is important. In the charge, the center of gravity is shifted from the rotational center of the mill system, and its motion is induced by rotation of the mill. At the same time, the charge creates a torque in the mill system. Breakage of ore particles and wear of liners/ball media are closely linked to this motion. To study these phenomena in a physically correct manner, numerical models for different parts of the mill system are needed. Validations of such models are scarce, because of the difficulty of measuring inside a tumbling mill. Experimental measurements in a lab mill were done for a number of load cases: varying feed material, mill filling, mill speed and pulp liquid. The mill is set up to measure the charge-induced torque. The accuracy is good, with relative uncertainty less than ± 2% for relevant load cases. A full three-dimensional numerical model of the whole mill is used to predict induced torque. Agreement between predicted and measured torque at steady-state is good. In addition, the model can accurately predict the mill startup behavior for torque and mill power. This proves that the model is physically correct, and can be used for modeling large-scale mills.IntroductionUnderstanding of the charge motion within the mill is of importance in mill optimization. The breakage of ore particles and the wear of liners/ball media are closely linked to the charge motion. To study these phenomena in a physically correct manner, appropriate numerical models for different parts of the mill system must be used. Validation of these models is of major importance. This has led to an increased interest in obtaining an accurate and direct measurement of mill load and the behavior of the mill charge.For structural analysis, the finite element method (FEM) is the most developed and most frequently used numerical method. FEM is a numerical solution method based on continuum mechanics modeling. A constitutive relation for the actual material is described, and the governing equations are solved in Zienkiewicz and Taylor (2000). Varieties of different constitutive models for a large number of materials are implemented in modern FEM code. The computability of nonlinear problems in solid mechanics is investigated in Belytschko and Mish (2001), among others."

Jan 1, 2015

By H. J. Bogert

Shallow, gently dipping quartz veins at the Mineral Hill Mine are mined in room and pillar stopes. Ore zones are severely folded and fractured, thus actual pillar strength and physical properties of the rock mass deviate significantly from conventional laboratory tests and pillar theory. Laboratory specimens large enough to include pre-existing fractures proved to be representative of actual pillar strength. Further adjustment for specific pillars was based on RQD. Deformation and stress were measured in several pillars during pillar recovery. Stress data and finite element modeling were used to estimate absolute pillar stress at failure. The stress/strain relation provided an excellent indicator of pillar behavior. Good agreement between lab data and underground data was found.

Jan 1, 1995

By S. D. Thompson

Conveyor belt haulage has become the preferred mainline transport method in under-ground coal mining, especially for multi-unit mines. Optimum designs for belts (width and speed) and surge bins (placement, capacity, and discharge rate) are necessary for minimizing haulage cost. Two computer simulation models, CMaCS and BELTSIM, available for optimizing these designs are compared. These comparison include: modeling, input data requirements, statistical flexibility, accuracy of simulated loading, and execution time.

Jan 1, 1989

By J. P. Hedlund

Molycorp&apos;s gravity type panel-caving operation employs a system of short raises to transfer ore from the Grizzly Level to the Haulage Level. The raises have normally been developed using a conventional drill-and-blast method or a combination conventional/raiseboring method. A new method was needed that would be less labor intensive, provide a safer work environment for personnel, provide a stable raise that could be self-supporting and a method that would be cost competitive with the conventional system.

Jan 1, 1991