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By V. van der Merwe, C. W. Siyasiya

"A petrochemical company experiences premature thermal fatigue failure of the casting moulds used in catalyst production. The aim of the project was to find an alternative alloy that would outperform the current low-alloy cast steel used for the moulds. Based on their thermo-fatigue properties, 3CR12 ferritic stainless steel and H11 tool steel were chosen for testing and comparison with the currently used BS3100 B7 cast steel. Samples of each material were subjected to temperature cycling in a Gleeble 1500TM thermo-mechanical processing simulator, followed by surface analyses. The main parameters derived from the test work were the total true strain, the hot strength of the materials, and the number of cycles to failure. Additionally, the coefficient of thermal expansion for each material was measured using a Bähr dilatometer. H11 tool steel yielded the best performance by way of having the fewest surface cracks, the lowest total true strain per cycle, the most cycles to failure, the highest hot strength, and the lowest coefficient of thermal expansion.IntroductionThe Catalyst Manufacturing Plant (CMP) is a dusty environment with temperatures higher than ambient. Molten mill scale (magnetite, Fe3O4) is tapped from the electric arc furnace into the casting moulds at temperatures close to 1600°C. After 10 seconds the magnetite is quenched with a water spray for 50 seconds to a minimum temperature of 400°C. Sometimes there is residual water in the pans from the cooling fog process (water sprays) in the empty mould. In a typical plant, the factory produces 40–44 batches a day containing between 150–300 moulds, depending on the time required for the specific batch (Buchholz, 2014). The typical batch in the CMP usually weighs about 6 t. The thickness of the tap, speed of the casting belt, and tilting angle all affect the number of moulds per batch.One of the main problems faced during the molten mill scale casting is the premature failure of the casting moulds. Cracks initiate on the surface of the mould, which is in contact with the hot catalyst, and propagate into the interior of the mould. Cracks are generally concentrated in the middle area of the mould where the catalyst makes first contact with the mould, and which experiences the highest temperature fluctuations. This suggests that the cracks are caused by thermal fatigue during the casting process."

Jan 1, 2016

COUNCIL The following served on Council during the year under review: Office bearers: Prof D. D. Howat (President), Dr J. P. Hugo and P. W. J. van Rensburg (Vice-Presidents), V. C. Robinson (Immediate Past President) and D. G. Maxwell (Honorary Treasurer). Ordinary Members of Council: H. P. Carlisle, R. C. Espley-Jones, G. H. Grange, Dr D. I. Legge, W. W. Malan, Prof R. P. Plewman, Dr R. E. Robinson, Dr M. D. G. Salamon, L. W. P. van den Bosch and P. A. von Wielligh. Branch Chairmen: A. Bain (Witbank-Middelburg Branch), J. M. Meyer (O.F.S. Branch). Past Presidents serving on Council: R. J. Adamson, M. Barcza, H. Britten, H. E. Cross, J. K. E. Douglas, R. C. J. Goode, P. Lambooy, Prof J. de V. Lambrechts, Dr J. T. McIntyre, J. F. Reid and H. Simon (until March 1972). Ten Council meetings were held during the year with an average attendance of nineteen, and the standing committees held 27 meetings. FINANCE The annual accounts which are attached to this report show an excess of income over expenditure of R21 519. It is very gratifying to be able to report that Council's efforts to stop the depletion of our accumulated funds are meeting with success. The most important contributors to our surplus this year are symposia and colloquia, sales of publications, Company Affiliate subscriptions and the profit on the journal. While we do not expect continued profits from all these sources in the future we do feel that we are now in the process of accumulating a substantial financial foundation. This will give the Council the necessary confidence to initiate the new developments in the activities of the Institute which are now under consideration. The decision to create a new grade of membership, Company Affiliate, is dealt with elsewhere in this report. There has been a generous initial response from companies and this is the cornerstone of our improved financial expectations. The MacArthur Forrest Memorial Fund shows an excess of income over expenditure of R91 and the total fund was, therefore, increased by this amount to R4 502. The balance sheet shows that the market value of quoted shares and debentures increased during the year from R9 160 to RH 331, which is R2 134 in excess of the book value. Accumulated funds now amount to RH 529 compared with R23 010 a year ago. MEMBERSHIP Sixteen Fellows, twenty Members, six Graduates, nine Associates, twelve Students and twenty-four Company Affiliates were elected during the year. One Member and two Associates were reinstated. Twelve members were admitted to retired membership. Transfers: Member to Fellow, three. Graduate to Member, seven Associate to Fellow, one. Student to Member, one. Student to Graduate, four. Student to Fellow, one. Your Council records with deep regret the death during the year of the following: Dr A. J. Orenstein (Honorary Life Fellow), R. A. Cooper, R. J. Spargo, H. Simon and F. Meyer (Life Fellows), S. D. Loxton, W. P. Arnold, G. C. Needham, W. G. Pyne-Mercier, J. Innes and O. T. Wright (Fellows), E. P. Mennell and O. B. Prentis (Members), J. Brits (Associate). After careful consideration of all the implications it was decided during the year to create a new grade of membership to be known as Company Affiliate, in order that there might be a formal and permanent channel for companies to contribute to the important work of the Institute. As recorded above, 24 companies had joined by the end of the year and many further applications have been received since. We extend a hearty welcome to all our new members. A comparative statement of membership as at 30th June, 1972, and the end of the previous year is shown in the following tabulation:-

By E. Öğretici, S. Kahraman

The indirect estimation of intact rock properties is particularly useful for preliminary investigations in engineering projects. In this paper we examine the usability of electrical resistivity, a nondestructive measurement, for the prediction of physical and mechanical rock characteristics. Physico-mechanical tests (uniaxial compression, Brazilian tensile, density, and porosity tests) and electrical resistivity measurements were performed on specimens of 36 rock types. Before the resistivity tests, the specimens were completely saturated with saline solution. Evaluation of the test results showed that there are medium or strong correlations between resistivity and rock properties. There are also strong or stronger correlations between the two parameters for the rock classes. The regression equations developed were statistically tested, and their validity was confirmed. The results were also compared with previous studies. The conclusion is that electrical resistivity measurement can be used for reliably estimating physical and mechanical rock characteristics.

Aug 8, 2024

COUNCIL AND STANDING COMMITTEES - 1973-1974 Office Bearers: P. W. J. van Rensburg (President), Professor R. P. Plewman and Dr R. E. Robinson (Vice Presidents), J. K. E. Douglas (Honorary Treasurer), and Dr J. P. Hugo (Immediate Past President). Elected Members of Council: Dr M. G. Atmore, G. H. Grange, Dr P. R. Jochens, J. G. Kirchner, Dr D. I. Legge, W. W. Malan, Dr M. D. G. Salamon, L. W. P. van den Bosch, D. A. Viljoen, P. A. von Wielligh. Branch Chairmen: B. T. Hosking (Witbank-Middelburg Branch), E. T. Wilson (Orange Free State Branch). Past Presidents Serving on Council: R. J. Adamson, M. Barcza, H. Britten, H. E. Cross, Professor J. de V. Lambrechts, R. C. J. Goode, Professor D. D. Howat, D. M. Jamieson, D. G. Maxwell, Dr J. T. McIntyre, V. C. Robinson. Ten Council meetings were held during the year, with an average attendance of 19, and the standing committees held 30 meetings. COMMITTEE CHAIRMEN Membership, Dr R. E. Robinson ; Metallurgical Colloquia, Dr R. E. Robinson ; Mining Colloquia, L. W. P. van den Bosch; Awards, P. W. J. van Rensburg; Excursions, P. A. von Wielligh; Dinner, G. H. Grange ; Constitution, Rules and Policy, Dr J. P. Hugo; Adjudicating, P. W. J. van Rensburg; Mines and Works, W. W. Malan; Education, Dr J. P. Hugo. REPRESENTATIVES ON OTHER BODIES Associated Scientific and Technical Societies: Members : V. C. Robinson and D. G. Maxwell Alternates : P. W. J. van Rensburg and Dr J. P. Hugo. Federation of Societies of Professional Engineers Members : J. K. E. Douglas and P. W. J. van Rensburg Alternates : Dr J. P. Hugo and G. H. Grange. South African Council for Professional Engineers Members : R. C. J. Goode and J. K. E. Douglas Alternates: G. H. Grange and Dr R. E. Robinson. Engineers' Liaison Committee (Pretoria): Member: Professor J. de V. Lambrechts Alternate : Dr J. P. Hugo. MEMBERSHIP Seventeen Fellows and Members, twenty-three Graduates, ten Associate Members, twenty-two Associates, thirty-four Students, and seven Company Affiliates were elected during the year. Eleven Fellows and four Members were admitted to retired membership. Five Fellows were elected to Honorary Life Membership. Four Members, two Graduates, and one Student were transferred to Fellows ; eleven Graduates and Students were transferred to Members ; eight Students to Graduates; and four Students to Associates. A statement of membership as at June 30th 1974 and the end of the previous year is given in the following tabulation 30th - 30th June, - June, 1973 - 1974 Honorary Life Fellows 4 - 9 Honorary Fellows 9 - 8 Life Fellows 177 - 170 Fellows 536 - 544 Members 487 - 512 Associate Members - - 10 Graduates 128 - 130 Associates 186 - 194 Students 183 - 173 Company Affiliates 64 - 70 1 774 - 1 820 OBITUARIES Your Council records with deep regret the death during the year of the following members : Dr P. N. Lategan and Dr O. A. Jackson, Honorary Life Fellows and Past Presidents; C. Airth, T. L. Blunt, J. B. Dennison, A. E. Frazer, C. L. Lamb, V. O. Reid, K. Richardson and D. G. Roberts, Life Fellows ; H. F. Allan, J. T. Beaumont, M. Eisenstein, J. C. Hall, C. F. Louw, H. H. McGregor, R. Murchison, and J. E. Williamson, Fellows; and R. B. Miles, Associate. FINANCE The annual accounts, which follow this report, reflect a healthy position and show that measures taken by Council over the last few years to boost income have been successful. A higher income was needed not only to meet rising costs but also so that the services provided by the Institute for its members could be expanded. This year's income of R55 025 showed a further increase compared with last year's figure of R48 307. Income from subscriptions was higher mainly owing to an increased number of Company Affiliates, and this is indicative of the support given by mining and metallurgical companies to the good work being done by the Institute. Further sales of publications of the symposia held over the last few years again made a useful contribution to income of R4560. The first Winter School held in 1973 yielded a surplus of R7495 after the expenses had been deducted from the income received from registration fees. The cost of administering the Institute increased by R2212 compared with the previous year. Included in this was a donation of R1000 to the A.S. & T.S. Trust Fund. The cost of publishing and printing the Journal increased by R2034, but advertising and extraneous sales of the Journal were higher, with the result that the net cost of the

Jan 10, 1974

By S. Kauvosaari, M. Olofsson, O. Haavisto, M. Kosonen, J. Martikainen

The target in grinding circuit operation is usually to maximise the throughput and energy efficiency while keeping the product particle size on an optimal level for downstream operations. Furthermore, feed ore variations in size and hardness need to be compensated in order to stabilise the process. This is a challenging task for any circuit and requires good instrumentation, combined with careful control design. This study investigates the control of a two-stage iron ore grinding circuit with an AG and pebble mill at LKAB Kiruna KA3 concentrator in northern Sweden. A new control approach based on multivariable model predictive control (MPC) is designed, implemented and evaluated for the circuit. Additionally, advanced instrumentation including a volumetric charge measurement for grinding mills is utilised. The MPC control approach starts with step tests that are used to model the effect of manipulated variables (MVs) like feed rate, water addition and primary mill speed on controlled variables (CVs) such as final product particle size, power consumption and volumetric charge of the mills. In the control implementation phase, the models are then utilissed together with current process measurements and known operating limits to predict optimal future changes for the manipulated variables in order to reach the desired process output values. It is shown that the new control approach improves the stability of the circuit and reduces energy consumption. Keywords: Model predictive control, grinding, optimisation

Jan 1, 2020

By F. Rosenblum, K. E. Water, J. A. Finch, S. Moon, Y. H. Tan

Previous work has shown that sulphide self-heating occurs in three distinct stages referred to as Stage A, Stage B and Stage C. In this paper the focus is on the transition from Stage A to Stage B, which occurs at ca. 100OC. Background literature hints that the transition corresponds to the transformation of the rhombic form of elemental sulphur to the more reactive monoclinic form that occurs at 96OC. A test apparatus is modified for adiabatic heating to track the transition. The results support this transformation of sulphur as being key to the transition, and the transition temperature is thus modified to 96OC. Variations in a sample’s response under adiabatic conditions are observed and possible reasons are discussed. Testing in adiabatic mode provides new insights into the sulphide self-heating process that complement the test designed to identify propensity to self-heat. Keywords: Self-heating; Stage A/Stage B; transition; rhombic/monoclinic elemental sulphur; adiabatic heating

Jan 1, 2020

By H. P. Kritzinger, T. C. Kingsley

Rotary kilns are used for a variety of mineral processing operations. Hatch makes use of a kiln model developed from first principles to evaluate designs for its clients. This tool has been applied to a variety of pyrometallurgical applications. This paper illustrates the application of numerical optimization techniques in combination with the kiln model in the interrogation of a generic iron-ore reduction process. The fundamental modelling concepts are explained, followed by a description of the optimization approach. The results show how the combination of the two methods, with modern computing power, can generate a large number of viable design and operating candidates.

Jan 1, 2014

By L. Naude, J. Cloete, S. Engelbrecht

The results of an investigation evaluating whether an industrial plant, currently operating using sodium isobutyl xanthate (SIBX) as primary collector for sulphide minerals (mainly chalocopyrite), could adapt to operate using an alternate primary thiol collector without compromising plant and metallurgical performance. Initial laboratory scale flotation tests identified commercial dithiophosphate (DTP)-based and thionocarbamate (TC)-based collectors, that when blended, showed potential to replace the incumbent SIBX primary PGM collector. Industrial plant trail results show that there was no deterioration in recovery of 4E PGMs, even at a lower concentrate grade when operating the plant on the identified (DTP + TC)-based collector blend compared to SIBX. The effect on Cr2O3 content in the final concentrate was also found to be negligible. The (DTP + DTC)-based collector blend also showed promise in terms of plant adaptability in accommodating a new primary specialty collector blend. These observations highlighted the potential of replacing xanthate primary collectors with alternate thiol collector blends for PGM flotation. Keywords: PGM, xanthate replacement, specialty collector, sodium iso-butyl xanthate (SIBX), dithiophosphates (DTP), dithiocarbamates (DTC)

Jan 1, 2020

Your Council has pleasure in submitting its report for the year ended 30th June, 1969. COUNCIL The following served as Office Bearers during the year under review: Messrs. R. C. J. Goode (President), J. K. E. Douglas and V. C. Robinson (Vice-Presidents), P. Lambooy (Immediate Past President) and D. G. Maxwell (Honorary Treasurer). Members of Council: Messrs R. J. Adamson, M. Barcza, F. P. Bath, Or J. M. Bereza, Or W. Bleloch, Messrs H. Britten, H. E. Cross, A. R. C. Fowler, A. E. Gilfillan, G. W. Holl, Prof D. D. Howat, Or J. P. Hugo, Messrs C. J. Irving, D. M. Jamieson, J. G. Kirchner, Prof J. de V. Lambrechts, Mr C. E. Mavrocordatos, Or J. T. McIntyre, Mr J. A. Nixon, Prof R. P. Plewman, Messrs J. F. Reid, H. Simon, C. G. Sowry, W. T. Stobart and P. W. J. van Rensburg. Ten Council meetings were held during the year with an average attendance of eighteen. FINANCE The annual accounts, which are attached to this report, show an excess of expenditure over income of R2,124, compared with an excess of income over expenditure of R4,218 last year. There are a number of reasons for this substantial change. There was a loss on realization of investments compared with a substantial surplus in recent years. The publication of the Journal once again resulted in a large loss in spite of a generous subvention of R2,000 from the Department of Cultural Affairs and other assistance amounting to R750. The revenue from sales of publications was down considerably. This is a figure which fluctuates considerably from year to year. The secretarial fee was considerably higher than previously. Due to pressure of work it was necessary for the Secretary to relinquish his duties with the Institute of Land Surveyors and, therefore, for this Institute to assume the additional staff costs involved. Finally there was unusual expenditure on the 75th Anniversary celebrations. There was a pleasing increase in revenue from subscriptions, due to the steadily increasing membership, but this was quite inadequate to cover the substantial increases in expenditure and losses in revenue mentioned above. The changes that have been effected in the arrangements for the publication of the Journal have been mentioned elsewhere in this report. It is expected that these will bring about substantial financial benefits in the long term. The MacArthur Forrest Memorial Fund shows an excess of income over expenditure of Rl00 and the total fund was therefore increased by this amount to R4,206. The balance sheet indicates that the market value of quoted shares and debentures increased during the year from R8,755 to R13,059, while the Accumulated Funds now amount to R22,567 as against R24,691 last year. MEMBERSHIP Fifty-six Members, fifty-five Associate Members, thirteen Graduates, twenty-two Affiliates and twenty- nine Students were elected during the year. Twelve Members were admitted to Life Membership; seven Associate Members were transferred to the grade of Member; four Graduates and two Students were transferred to the grade of Associate Member; five Students were transferred to the grade of Graduate; three Affiliates were transferred to the grade of Member; five Affiliates were transferred to the grade of Associate Member. Three Members, seven Associate Members, two Graduates, two Affiliates and six Students were removed from the Membership Roll in terms of By-Law 7.7.1. Your Council records with deep regret the death during the year of the following members: E. F. J. Bulman (Member), E. F. Chapin (Member), R. A. H. Flugge-de-Smidt (Hon. Life Member), T. S. Haldane (Member), J. M. Massie (Associate Member), S. W. Page (Student), S. R. Rabson (Member), M. Ramsay (Member), F. Wartenweiler (Hon. Life Member). A comparative statement of the membership as at 30th June, 1969, and the end of the previous year is shown in the following tabulation: 30th June 30th June 1968 1968 Honorary Life Members 12 10 Honorary Members 6 6 Life Members 176 189 Members 488 514 Associate Members 409 448 Graduates 60 68 Affiliates153 155 Students152 162 1,456 1,552 PAPERS AND JOURNAL The Institute is changing the format of the Journal from the present size to the standard international A4 size with effect from August, 1969. In making this change it will conform to more general practice today in regard to publications and this should effect certain economies and facilitate selling of advertising space. It has been arranged that in future the publication of the Journal, including advertisement sales, will be handled by Kelvin Publications (Pty.) Ltd. who are already doing this work satisfactorily for the Mechanical and Electrical Engineering Institutes. In making these changes the opportunity was taken of redesigning the outer cover of the Journal to incorporate the new coat of arms. The Presidential Address by Mr R. C. J. Goode and twelve papers which were published in the Journal during the year are listed below: August, 1968: Presidential Address: "The Institute-In retrospect and prospect." September, 1968: "Rotary mill liner practice in the South African gold mining industry," by J. H. French and O. E. Lissner.

By W. Guiye, L. Chongjun, L. Huinan, Z. Yangge, H. Long

The current application of copper-molybdenum (Cu-Mo) separation inhibitors is often associated with large dosage, high toxicity, environmental pollution problems. In order to solve these problems, a light sensitive Cu-Mo separation inhibitor LS（light sensitive inhibitor，abbreviated to LS） was developed. In this paper, inhibitory performance, photodegradation rule, and acting mechanism of LS were studied. The subsequent test results showed that, compared with traditional inhibitors, LS has shown comparative advantages, with lower dosage and good inhibiting effect. A series of flotation tests with LS as inhibitor were conducted on a Cu-Mo concentrate. A locked-cycle test showed that a molybdenum concentrate containing Mo 49.88% and Cu 0.6%, with 93.23% molybdenum recovery and a copper concentrate containing Cu 29.92%, with 99.99% copper recovery can be obtained. The photodegradation performance of the reagent was investigated under 365 nm, 254 nm and sunlight irradiation. The degradation of the reagents could be completely achieved by irradiation of three wavelengths of light. However, with the different wavelength of irradiation light, the degradation rate is different, the time required to reach 50% degradation rate being 3 h (254nm), 4 h (solar light) and 6 h (365nm) respectively. The inhibition mechanism on chalcopyrite was studied. FTIR study showed that LS could be adsorbed on the surface of chalcopyrite by chemical adsorption, which could enhance the hydrophilicity of chalcopyrite. Ultraviolet adsorption tests indicated that the adsorption capacity of LS on chalcopyrite surface was greatly affected by pulp pH value, and the proper pH value was 5-9. Keywords: Copper-molybdenum separation, Inhibitor, Light-sensitive, Photodegradation, Mechanism.

Jan 1, 2020

By A. Lebedev

Application of dynamic simulation for a base metal processing plant is discussed. The plant receives ore of variable quality from two pits and blending had to be applied to maximise recovery. The plant employs multiple stage crushing, screening, dense media separation, two-stage milling, flotation and further filtration. Stockpiles and bunkers are used in the plant to cater for breakdowns and operating delays, the latter being appropriately incorporated in the model. A detail dynamic simulation model was constructed from the rock face to the filtration plant to assist the plant design, notably with definition of the ore blending method, sizing storage capacity and in-plant conveyors. The plant model was broken down to capital equipment items and various feed types and mass balances were tested to ensure that the production target is met. The dynamic simulation tested the proposed blending method, identified bottlenecks, produced risk profiles for all strategic storage facilities and overall helped minimise the project risks and improve confidence in the plant design. Keywords: Dynamic simulation, ore grade, blending, capacity, risk profile, throughput, utilisation

Jan 1, 2020

By D. Kumar, B. Rai, S. G. Srinivasan, V. Jain

Chalcopyrite and pyrite are among the major gold bearing minerals in the world. The gold content in chalcopyrite and pyrite varies from 0.02 to 200 ppm and 0.01 to 20 ppm, respectively. Apart from gold, chalcopyrite is also the primary source of copper. Thus, the recovery of gold and copper are often associated with the recovery of chalcopyrite and pyrite. Flotation is one of the most successful methods applied to beneficiate chalcopyrite and pyrite. The success of a flotation process depends on an appropriate choice of the flotation collector used to achieve the desired selectivity. A thorough understanding of the atomic structure of the predominantly exposed mineral surfaces can immensely aid in developing highly selective collectors that can exploit both the physical and chemical characteristics of these surfaces. In the present study, density functional theory calculations within the plane wave framework are used to understand the surface structure and reconstruction of the most stable chalcopyrite (001), (100), (110) and (112) and most stable pyrite (100) surfaces. The chalcopyrite (001) and (100) metal-terminated surfaces undergo significant reconstruction and result in metal-metal bond formation in the sub-surface layer while the surface layer is replaced by S-atoms. On the other hand, the (001) and (100) S-terminated surfaces show S—S disulfide bond formation upon relaxation, which are consistent with literature reports. The chalcopyrite (110), (112) surfaces and pyrite (100) surface undergo rearrangement, but no reconstructions in terms of metal-metal or disulfide bond formation are observed on these surfaces. Keywords: DFT, surface reconstruction, pyrite, chalcopyrite, adsorption

Jan 1, 2020

By J. L. Broadhurst, S. Rumjeet, S. T. L Harrison, T. Chimbganda

Post-mining land use for the production of industrial crops has the potential to mitigate environmental and socio-economic impacts of mine closure and stimulate post-mining economic growth. Fibre-rich plants are of particular interest due to their multi-product potential. In the South African context, where there are many abandoned and end-of-life mines near human settlements, an opportunity presents to assess the feasibility of transforming post-mining land into productive land and building resilient communities through the development of multi-product value chains from fibre-rich plants such as kenaf, hemp or bamboo. This paper provides an overview of the plant selection criteria, phytoremediation potential and the downstream options for the recovery of products and value from bast fibre plants (hemp and kenaf) and bamboo. Based on findings from a comprehensive review of the published literature, as well as interviews with relevant experts within South Africa, it appears that bast fibre plants are the best downstream option for producing ‘green’ textiles and high-end niche products, whereas bamboo is more suitable as a replacement for conventional timber. Although fibre plants have the potential to extract metals from soils, high concentrations may inhibit plant growth and affect the quality of the final fibre product. Further site-specific studies would thus be required to select the best route for both land remediation and optimal product recovery. Keywords: Bioremediation, bamboo, kenaf, hemp, multi-product value chains, sustainable postmining land use

Jan 1, 2020

By I. A. Mwamba

Titanium aluminide of composition Ti-47.5 at.% Al was prepared by melting titanium and aluminium of commercial purity with additions of precious metals of 0, 0.2, 1, 1.5 and 2 at.% content. The microstructure, hardness and oxidation properties were assessed. It was found that at 47.5 at.% Al, the microstructure of plain TiAl alloys was duplex, consisting of duplex lamellar grains and ? grains. The lamellar grains consisted of alternating lamellae of ? (TiAl) and a2 (Ti3Al), with overall aluminium content in the range of 43?47 at.%. The ? grains had a aluminium content above 50 at.%. The addition of precious metals to the TiAl alloy resulted in the formation of a new phase, with a high precious metal content, occurring mostly in the ? phase, without any major change to the microstructure. Increasing the amount of precious metals resulted in an increase of the new phase amount, at the expense of the ? phase. The hardness of the different alloys was around 300HV10. Overall, the research has shown that addition of precious metals to TiAl resulted in a slight increase in hardness and a significant improvement of the oxidation resistance. This shows that alloying TiAl with precious metals, at the addition levels investigated, does not alter the mechanical properties very much, but improves oxidation resistance.

Jan 1, 2012

1. Recent books D. K. Hsiao, D. S. Kerr, and S. E. Madnick. Computer security. New York, Academic Press, 1979.276 pp. $18. W. C. J. van Rensburg and S. Bambrick. Economics of the world's mineral industries. Isando, McGrawHill, 1979. R18,95. Soviet metallurgical research 1973-1977. Vo!. 1. Subject index and author index (1963-1972). Vo!. 2. Chronological listing of titles with full bibliographical information (1960-1972). London, Scientific Information Consultants Limited (661 Finchley Road, London NW2 2HN). £24 per set. W. Hoosen. Miners' dictionary. London, Institution of Mining and Metallurgy, 1979. (Reprint.) £11 (£9 for members). G. J. Pitt and G. R. Millward. Coal and modern coalprocessing: an introduction. New York, Academic Press, 1979. 224 pp. $18. D. Stephenson. Rockfill in hydraulic engineering. Amsterdam, Elsevier, 1979. 228 pp. U.S. $45, D.fl.90. 2. NIM reports Report no. 2015 The preparation of synthetic standards for use in instrumental neutron-activation analysis. Report no. 2029 The commissioning of a 5 kW inductively coupled plasma unit for use with a 3,4-metre Ebert spectrograph. Report no. 2032 The Cancer Project: a summary of the computer-aided operation of a 48 MV.A ferrochromium furnace. Report no. 2036 The determination of thallium in ores, concentrates, and metals. Report no. 2040 A solid-state constant-current power unit for the magnetic analyser of the MS702R mass spectrometer. Report no. 2044 The separation and determination of anions by ion chromatography. Computer congress In October 1980, Japan and Australia are hosting the 8th World Computer Congress. This Congress is a triennial event conducted under the sponsorship of the International Federation for Information Processing. INFACON 80 The Second International Ferro-Alloys Congress, organized by IPFEO (Institute of Western European Ferro-alloy Producers), is to be held in Lausanne, Switzerland, on 13th to 16th October, 1980.

Jan 1, 1980

By R. C. Urquhart, D. D. Howat, R. I. L. Guthrie

Heat losses from ladles during teeming by R. C. URQUHART, M.Eng. (McGiII), Ph.D. (Visitor). R. I. L. GUTHRIE, B.Sc. (Eng.) (London), A.R.S.M., Ph.D., D.I.C. (Visitor), and D. D. HOWAT, B.Sc. (Glas.), Ph.D. (Fellow) In an investigation of the loss of temperature by liquid steel during a teeming operation, a numerical technique was used to calculate the heat flows and the rate of temperature drop over the entire teeming operation. The calculations show that, before teeming, approximately 50 per cent of the heat loss is into the ladle wall at the level of the metal. As teeming progresses, the amount of heat lost by radiation to the wall above the metalline increases. The effect of variables, such as initial metal temperature, the preheat of the ladle and ladle cover, and delays, on the rate of temperature loss by the metal were determined.

Jan 11, 1973

1. Book reviews Stainless Steels '84. London, Institute of Metals, 1985. £39 (U.K.), US$62 (elsewhere) Reviewer: J.B. Oalton Process engineering of size reduction: bal miling, by LG. Austin, R.R. Klimpel, andP.T. Luckie. New York, AIME, 1984. 561 pp. Reviewer: M.J. Lazer 2. Recent publications Hard and superhard materials. New York, Worltech Report Inc. (44 Woodbine Avenue, P.O. Box 212, Northport, 11768 U.S.A.), 1985. 270 pp. $1500.International comparison of standard materials-steel and cast iron, compiled by W. Oto and K. Schaning, and edited by DIN German Standards Institute e.V. Berlin, Beuth Verlag GmbH, 1985. 3rd edition, 416 pp. DM 158. Tin and its uses no. 146. Greenford (England), International Tin Research Institute, 1985. Write your own CV, by Max Kowen. Johannesburg, Legal Personnel Selections (404 Medical Centre, Cor Jeppe and Delvers Sts, Johannesburg 2001), Nov. 1985. 40 pp. R12,50 + GST.

Jan 1, 1986

Council and Standing Committees - 1982/83 President: Prof. A. N. Brown Vice Presidents: Prof. R. P. King and J. D. Austin Honorary Treasurer: Prof. D. G. Krige Immediate Past President: G. Y. Nisbet Members of Council: B. C. Alberts, R. H. English, P. T. Fewell, C. E. Fivaz, J. S. Freer, Prof. G. G. Garrett, J. J. Geldenhuys, Dr A. K. Haines, P. N. Harris, H. E. James, Dr B. K. Loveday, Dr J. Lurie, D. G. Malan, G. Pienaar, B. E. Protheroe, Dr 0. K. H. Steffen, G. C. Thompson, Dr H. Wagner, Dr P. T. Wedepohl. Chairman, Witbank/Middelburg Branch: H. C. van Zyl.

Jan 1, 1983

By C. Dorfling, M. Tadie, S. Grobbelaar

The physicochemical properties of the complex electrolytes used in direct copper electrowinning are an important consideration for the development of a high-fidelity model of the process. Direct electrowinning electrolytes typically contain a high background of metallic impurities. The effect of metallic ions on the properties and accompanying change in the limiting-current density for copper reduction have been the subject of several studies. Although various empirical correlations have been published for describing the physicochemical properties of electrowinning electrolytes, the correlations are only applicable to a limited range of conditions and cannot be extrapolated without further validation. Consequently, in this paper we validated existing physicochemical property correlations for the full range of operating conditions applicable to direct copper electrowinning and developed a new correlation for predicting the associated limitingcurrent density for copper deposition. Following, we evaluated the benefit of using the validated correlations as a component of a dynamic electrowinning model.

Jan 1, 2023

By J. J. Taute, S. J. Archer

"BASF Mining Solutions has developed a new-generation copper solvent extraction reagent that offers significant benefits over standard extractants currently available to the industry. As the name suggests, the new hightemperature (HT) extractant can be used at a higher operating temperature, but also exhibits significantly lower degradation rates, greater copper-toiron selectivity, and is totally nitration-proof compared with the standard extractants. Pilot-plant trials have also shown that lower aqueous-inorganic entrainment can be achieved. This paper investigates the technoeconomic benefit of using the HT extractant as an alternative to the standard extractant in a high-temperature application. The results of the technical evaluation showed that the use of the HT extractant reduces the extractant addition requirements and bleed volume from copper electrowinning; this smaller bleed requirement further reduces acid and limestone consumption, leading to a reduction in valuable metal losses. The results of the economic evaluation showed that the use of the HT extractant represents significant cost savings over that of the standard extractant. IntroductionCurrent solvent extraction (SX) reagents employed for the extraction of copper from typical pregnant leach solutions (PLS) at ambient conditions function well with minimal long-term effects on the extractant’s performance (Taute et al., 2015). This performance, however, deteriorates at elevated temperatures due to the degradation of the reagent’s hydroxyoximes. The degradation mechanism, acid-catalysed hydrolysis of the oxime, is accelerated by high temperature. This has a knock-on effect where the increase in degradation products increases the organic viscosity, leading to increased entrainment, crud formation, and ultimately to an increase in SX reagent consumption (Bender, Emmerich, and Nisbett, 2013).SX reagents also show an increase in the co-extraction of iron as the ferric concentration in the PLS increases. Co-extracted iron is transferred to electrowinning (EW) during stripping of the loaded organic and can adversely affect EW current efficiency. Iron in the EW circuit is typically managed by bleeding the electrolyte; however, this can lead to excessive consumption of EW reagents such as acid, cobalt, and mist-eliminating surfactants. The electrolyte bleed can also affect upstream consumption of reagents, such as lime, due to the high acid concentration recycled to leach."

Nov 1, 2018