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By Philip W. Holland

The Bureau of Mines has developed a trace helium analyzer for deter-mining helium-4 in the parts-per-billion range. The instrument is used for analyzing pure gases, laboratory-prepared standards, and atmospher-ic samples. Accuracy at the 95-pct confidence level in the 50-to 20,000-ppb range is within ±2 ppb or ±0.4 pct, whichever is greater. The minimum detectable helium-4 concentration is calculated to be 5 ppb. The analyzer consists of a modified helium leak-detector mass spec-trometer, a laboratory-built sample inlet system, and a liquid-nitrogen-cooled charcoal trap. A programmable integrator and event-control module make automatic operation possible. The portability of the analyzer allows it to be used in the field.

Jan 1, 1984

By J. R. Welty

High-temperature thermodynamic data have, in recent years, become increasingly important for the extractive metallurgist. The extraction of metals from their ores previously was based on trial and error methods, involving hours of testing and often costly equipment fabrication. Using thermodynamic data it is frequently possible to predict the feasibility of a proposed metallurgical process as well as the optimum operating conditions for the process with reasonable accuracy. Such predictions can save consider-able tim~ and expense. Widespread use of thermodynamic analyses has been handicapped by lack of dependable experimental data. Investigators, notably K. K. Kelley (4)4. have devoted many years to determining and compiling such data. These investigators, although prolific in their production of thermodynamic values, have been unable to meet all the needs of industry and other branches of science. This becomes obvious when one considers the aeronautical and nuclear fields, in which previously unimportant, therefore uninvestigated, substances have become of prime importance.

Jan 1, 1962

By Clete R. Stephan, Mark J. Schultz, William A. Slivensky, Eric S. Weiss, Kenneth W. Jackson

he Pittsburgh Research Center (PRC)~ and the Mine Safety and Health Administration (MSHA) are participating in a research program to evaluate the strength characteristics and air leakage resistance of seals and water trap designs for use in underground coal mines. This program is being conducted at PRC's Lake Lynn Laboratory near Fairchance, Fayette County, PA. Seals designed with a 40-cm-thick polymer (polyurethane) and aggregate core between two dry-stacked (no mortar) concrete block walls (coated on out by sides) withstood a 138-kPa pressure pulse while maintaining acceptable air leakage rates. Similar seal designs utilizing a 97-cm-thick, 91-kg/m7-density, polymer-only core did not survive; however, a 5 1 -cm-thick, 203-kg/mi-density, polymer-only core seal successfully withstood the explosion pressures. Evaluations of cellular concrete seal designs have shown that a two-pour slurry injection technique did not adversely affect the strength of the 1.2-m-thick seals when subjected to a 138-kPa pressure pulse. Two seal designs utilizing low-density cementitious block have also been evaluated with successful results. In addition to seal strength tests, various 15- and 30-cm-diam U-shaped water trap pipes and a water trough design were evaluated under explosion conditions and were shown to be inadequate when evaluated under worst-case conditions. Simple modifications to the various water trap designs were successfu1 in preventing the passage of explosion flame through the trap.

Jan 4, 1996

By W. J. Fene, H. B. Humphrey, J. J. Forbes

"INTRODUCTION Loss of life from coal-mine explosions in the United States in 1949 was the lowest in any year since before 1870. Although fatality reports from coal nines before 1910 were incomplete,' the explosion fatalities from single disasters or individual States exceeded the 1949 total in each year as far back as 1870, when the records become fragmentary. Since 1890, the only other year in which fewer than 35 were killed was 1946, with a total of 32. Figure 1 shows the total yearly fatalities from explosions in all coal mines and those in anthracite mines alone since 1870. The fatalities in bituminous coal mines were not completely reported before 1910, but enough reports were issued by major coal-producing States to compile reasonably representative figures back to 1885. Any corrections would be additions to these totals.The reason for the moderate total of 46 explosion fatalities in 1948 and the low total of 8 killed in 1949 is thought to be the serious and careful attention devoted to elimination of coal-mine explosion hazards after the disastrous explosions in 1947. The standards now being observed generally with respect to ventilation, rock-dusting, and inspections for gas are better than those found earlier in even the mines having the best reputations for safety. Exceptions are still numerous, but they are fewer, month by month, because of the pressure of Federal and State inspections and a changing conception of the hazards that should not be permitted underground. The prevailing precautions have not eliminated all ignitions of gas or dust, but they have limited propagation to small explosions and have prevented serious loss of life.The number of ignitions (14) reported for the year was less than the average (24) for the 5 years 1944-48 and only half the average for the fiscal years 1929-44. Another favorable factor is that Bureau of Mines representatives were probably in closer contact with both small and large mines in nearly all coal-mining districts. Inspectors now assigned to individual districts are better able to keep informed on the happenings and the progress of safety in their districts. In 1948, one-fourth of the explosions were in mines that employed fewer than 10 men; this condition was duplicated in 1949."

Jul 1, 1950

By Howard E. Parkinson

The mine pager phone to public telephone interconnect system permits mine paging telephones to be interconnected with the public phone system, thereby providing emergency and off-hours communications. The system, a push-to-talk, push-to-listen system, is compatible with any mine paging system utilizing dc voltage on the line to enable paging. A tone generator of the proper frequency enables an outside caller to page over mine pager system loudspeakers. A caller inside the mine can make an outgoing call to a preselected, preprogramed number with the use of a proper frequency tone generator. The system includes an automatic hangup timer that restricts the time off-line due to a wrong number or incorrect hangup to 20 seconds and 6 minutes, respectively.

Jan 1, 1974

By T. C. Higgins, J. S. Malesky, J. A. O'Connor

"INTRODUCTION This circular contains the story of a stubborn mine fire of electrical origin that started on the main haulage road of No. 59 mine of the Peabody Coal Co. and illustrates that sometimes serious fires can be fought by direct attack. The story also points out that the cost of such procedure can be extremely high, and it is better, therefore, to minimize the possibility of a fire of electrical origin by suitable over-current and line-fault protection. The lives of 163 men were saved by utilizing a recently sunk air shaft near active workings as an escapeway. These men could not have reached the older openings. Also described are the rescue of 75 additional men through another air shaft, sealing of the fire, attempted extin¬guishment with carbon dioxide, and the difficulties of fighting the fire and recovering the mine.A fire occurred shortly before 12 o'clock noon, August 15, 1949, in the No. 59 mine, Peabody Coal Co., Springfield, Ill. All 257 men underground escaped to the surface. One group of 75 men was delayed from escaping for several hours after the alarm was given because smoke and fire gases were circulating in a main return airway, which intervened between their working section and one air shaft, and also in the stairway compartment of the shaft. After being supplied with universal-type gas masks, or self-rescuers, these men were conducted from the mine by members of a State mine-rescue team and other mine employees. Six nine officials were hospitalized because of exposure to carbon monoxide during fire-fighting activities; all were discharged a few days afterward. Later, while doing work incident to fighting the fire, two men were killed, and several were injured by falls of roof and rib.The fire broke out after a collision of a loaded trip with four empty mine cars on the main east haulage entry. The mine cars were jammed against the trolley wire causing a sustained electric arc that ignited the wooden mine cars and the fire spread to the timbers and coal."

Apr 1, 1950

By Pablo Velasco

The Ecuadorean mineral sector and overall economy have retained their traditional dependence upon the production and export of hydrocarbon products. Exports of crude oil and its products accounted for 62% of the country's export earnings in 1985. Ecuador's major mineral commodities produced and exported were cement, gold, limestone, liquefied natural gas, liquefied petroleum gas, natural gas, natural gasoline, crude petroleum and condensate, raw steel, semimanufactured steel products, and sulfur.

Jan 1, 1987

By Wilbur I. Duvall

In this report, the Bureau of Mines presents a theoretical solution for the stresses and displacements in an infinite elastic plate containing a circular hole the boundary of which is loaded by applied radial stresses over four separated arcs. The problem solved is a two-dimensional approximation of the stresses and displacements developed by a large tunnel-boring machine anchored in a circular tunnel. Analysis of the solution shows that the tangential tensile stresses induced on the boundary of the circular opening can be minimized in the roof and maximized in the floor of the opening by proper spacing and loading of the four arcs.

Jan 1, 1967

By R. V. Ramani, V. T. Burgos, J. A. McClay

Cost Systems Cost systems are organized methods of collecting, allocating, and accumulating resource utility expressed in terms of money. There are two major spheres of cost accumulation: financial accounting and cost accounting. Financial accounting deals primarily with historical costs and provides a means of measuring and recording cost events which have al¬ready taken place. While there are no legal requirements to control the methods of recording and reporting cost data in the United States, the procedures in use are guided by professional organizations such as the American Institute of Certified Public Accountants. The final pro¬ducts of financial accounting practices are the income statement and balance sheet which describe the financial status of the organization under study. Cost or managerial accounting is an expansion of financial ac¬counting procedures, providing more detailed cost breakdowns on present operations with one objective being the projection of present costs into the future. The projection process tends to limit the accuracy of the information; however, to management and project justification per¬sonnel, data on future operations tends to be of greater value. The basic principle behind cost accounting is the cost cycle. As products are developed from raw materials, the value of the work-in¬process increases due to the cost input of the various fabricating ele¬ments. Thus, from the basic input elements of facilities, labor, and raw materials, costs are added to each unit of production as a function of the work performed on that unit.

Jan 1, 1975

By Joseph V. Mather, E. H. McCleary

"INTRODUCTION Workmen are transported in shafts in various types of cages or skips, most of which were designed primarily for hoisting cars and materials. Therefore, in general the cages or skips are not completely enclosed, adequate and gates are not always provided, and at many mines signaling devices and telephones are re¬stricted to those at the various landings in the shafts.Shaft accidents are usually severe - frequently fatal - and as a rule such an accident is caused by failure to comply with company rules or by ignoring them.Sixty men were killed and 555 men were injured in shafts of the anthracite and bituminous coal mines of the United States during the 5-year period 1938-42. 4/ Many of these accidents could have been prevented by having properly enclosed cages and adequate locking devices on doors to prevent workmen from falling into the shafts.The officials of the Heidelberg Coal Co. contemplated utilizing an old coal-hoisting shaft as a man-hoisting shaft; however, it was their desire to avoid the use of the conventional cage and to try to provide a safer means of transporting men in the shaft. Investigations and studies made by the officials revealed that an elevator similar to those used in large buildings would be more economical in first cost, maintenance, and operating costs would be less, and it would be safer and more convenient for the workmen. Effective safety devices for such elevators have been developed to such a high degree that those properly installed seldom fail. The elevator or man cage finally chosen cannot be pulled above the top landing through mechanical or man failure; it stops automatically at each landing and cannot be moved while a door is open; when the cage leaves the landing the doors opening to the shaft are automatically locked by mechanical and electrically operated locks; electric lights, telephone communication, and push-bottom controls are available on the cage, and adequate safety switches and overspeed controls are provided."

Jun 1, 1947

By Joseph B. Huvos

Said to be one of the world's most under-developed countries, Benin had a gross national product (GNP) estimated at $1 billion in 1980.2 Contribution of the mineral industry such as cement and limestone to the GNP was negligible, but exploration of mineral potential continued Minerals.-The United Nations Development Program (UNDP) conducted an investigation of three deposits from 1977 to 1980: Phosphates (Mekrou), gold (Perma), and chromite (Buem). A phosphate rock deposit containing about 4.5 million tons recover- able by opencast techniques was discovered. It was not known if the gold and chromite deposits were recoverable economically. Iron ore deposits of some 230 million tons near Loumbo-Loumbo are at present not exploitable because of lack of infrastructure in the northern part of the country. Geologic mapping with British and French assistance was also pursued in 1980.

Jan 1, 1982

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies were determined calorimetrically for Na2Cr04, A reversible transition was found at 700° K with an isothermal heat of transition of 2,263 cal/mole. High-temperature X-ray diffraction analysis showed that the transition was a crystal change from the low-temperature orthorhombic form to the high-temperature hexagonal form. At 795° K the hexagonal form had the parameters a, = 5.691 and co = 7.478 A. Powder diffraction data for the high-temperature form are given and possible structures discussed. The melting point was determined to be 1,065° K with a heat of fusion of 5,810 cal/mole. Enthalpy and entropy increments from this investigation were combined with other data from the literature to calculate enthalpies of formation, free energies of formation, and equilibrium constants of formation from 298° to 1,400° K. Equations that represent enthalpies above 298° K are given.

Jan 1, 1972

By B. T. Brady

Results of a study are presented of the effect of low radial reinforcement pressure on the postfailure characteristics of two types of granite, a sandstone, and marble. The low radial reinforcement pressure is applied to the rock surface by a gooch rubber sleeve. The gooch rubber sleeve provides a radial pressure of less than 1 psi pressure to the rock surface. This method of support gives an average strength increase of approximately 8 percent to the fractured rock sample.

Jan 1, 1973

By A. N. Styler

As part of its water-jet assisted rock cutting research, the Bureau of Mines has initiated a study into the mechanism of rock fragmentation by water-jet-assisted mechanical tools. The objective of this research is to increase coal extraction efficiency by seeking an improved understanding of the synergistic relationship between mechanical cutters and water jets, enabling the design of more effective cutterheads. Rock chips collected during laboratory traverse speed jet-assisted cutting tests were analyzed with respect to the size distribution of the chips and the forces measured during cutting. As the water-jet pressure was increased, the size distribution of the product became coarser with V-face type cutting tools producing less fine material than conical cutting tools. Fracture mechanics theory accounted for less than 10 pet of the energy consumed during fragmentation of the rock. The energy consumed by processes other than rock breakage decreased with the use of water jets and increasing advance rate.

Jan 1, 1987

By John R. M. Hill

The Bureau of Mines performed elastic-plastic, finite-element analyses to investigate the support performance of hydraulic backfill. A mathematical model was developed for two vertically adjacent stopes separated by a sill pillar. An exact duplicate of a working stope was not intended; however, the model did simulate a working stope to the extent that field measurements from an active stope could be used for comparative purposes. Using a predetermined mining sequence, the computer analysis simulated the mining operation as a series of incremental cut-and-fill steps. Computer results included a complete history of stope closure and pillar stresses throughout the mining sequence. With the mining sequence and rock properties held constant, three separate analyses were made using varying backfill properties. These cases included no fill,-low-to-medium-quality fill, and medium-to-high-quality fill. Results of these analyses show decreases in stope closure and pillar stresses as the backfill quality increases, thus reducing the possible occurrence of rock bursts. Predicted stresses within the backfill compare favorably with field measurements. A relationship between maximum stress normal to the stope wall and the ratio of relative fill stiffness to relative rock stiffness was also indicated.

Jan 1, 1974

By C. H. Elder, Maurice Deul

Coal degasification boreholes drilled from the surface have been success - fully hydraulically stimulated to increase the flow of gas from the coal. This Bureau of Mines report describes the hydraulic stimulation procedure for a coalbed, the equipment required, and design criteria for the treatment. Three examples of stimulation treatment show from fivefold to twentyfold increases in gas production. The tests were conducted in the Pocahontas No. 3coalbed, Buchanan County, Va., the Pittsburgh coalbed, Washington County, Pa., and the Mary Lee coalbed, Jefferson County, Ala. Two sites where the coal was hydraulically stimulated and exposed by subsequent mining show no adverse effect on mining operations through the treated zones. The induced vertical partings were confined to the coalbed and did not in any way affect either roof or floor rock.

Jan 1, 1975

By T. Whitrnoyer, J. Sneckenberger

"The acOustic impedances of seven rat lungs were measured at frequencies between 100 and 6400 Hz. Rats were divided into two groups: a silica exposed group (N=3) and a control group (N=4). The silica exposed group was injected intratracheally with silica solution. Three of the control group were intratracheallyinjected with saline. Between four and six weeks after theinjections, all lungs were excised and degassed. Lungs were,suspended in a pressure Chamber, with the trachea canula attached to the end Of a tapered impedance tube. The lungs were subjected to transpulmonary pressures between -30 cm H2O and 6 cm H2O to simulate deflation and inflation. With transpulmonary pressure being held constant, the impedance tube was excited with random noise. A dual channel analyzer calculated H12(f), the transfer function between the two microphones. This function was used to calculate the lung's impedance at that pressure. The impedance magnitude spectra of both groups typically had peaks at 2000,3500, and 5500 Hz. Statistically significant differences. (90%confidence level or greater) between the two groups occur at the 3500 Hz peak at transpulmonary pressures of 20, 8, 6, 4, and 2 cm of H2O. This fact seems to confirm that this method can detect. lung disease. Further research will indicate whether this method will be able to detect the onset Of coal worker's pneumoconiosis.INTRODUCTIONOne of the first studies of impedance Of the human lung were conducted by DuBois et al.[2] using the forced OscillatiOn technique. This technique, however, was limited to frequencies below 30 Hz. Further studies by Van Den Berg [6] revealed thatthe lung reflected higher frequency sounds (100-10,000 Hz), instead Of behaving as an anechoic termination. This discovery has lead to several studies of the acoustical properties of both human and animal lungs at high frequencies [3,4,5]."

Jan 1, 1988

By C. E. Jordan

The Bureau of Mines conducted tests on seven samples of Florida phosphate operations.slimes to develop a method to recover phosphate presently being discarded because of its small grain size. A system of hydrocyclones and hydroseparators was used to recover up to 96 pct of the plus 400-mesh material from the slimes. This plus 400-mesh material was subjected to fatty acid flotation, and concentrates containing up to 33.4 pct P205 were produced. As much as 88 pct of the phosphate (P205) was recovered from the plus 400-mesh material, and up to 29.6 pct was recovered from the total slimes.

Jan 1, 1982

By Kathleen Madland Kowalski

In recent years the issue of human stress response in emergency workers has begun to receive attention. This paper presents a rationale for considering human stress as a significant factor in the management of emergencies It discusses the concept of stress, Critical Incident Stress in emergency responders, and intro¬duces the Critical Incident Stress Debriefing (CISD) process. It is suggested that in a disaster, the CISD process can improve the effectiveness of response teams on site, their turnaround time on site, and post disaster time off the job. This paper, prepared by a US Bureau of Mines research psychologist, offers some ideas to the mining industry in general, mine rescue trainers and more universally, to those responsible for developing emergency management plans.

Aug 1, 1998

By A. R. Rule

Research was conducted by the Bureau of Mines to develop a process for utilization of Idaho kyanite. A continuous gravity-flotation separation process was applied successfully to recover kyanite-group minerals from an Idaho ore containing about 21 percent combined kyanite, andalusite, and sillimanite. Dry magnetic separation of the concentrate resulted in a product containing about 90 percent kyanite at a recovery of 63 percent of the kyanite-group minerals in the ore, Alumina and silica analyses were within the range generally accepted for conversion to mullite, and the finished products had a pyrometric cone equivalent of more than 38. A recovered garnet coproduct may be of commercial value.

Jan 1, 1973