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By M. G. Zabetakis

At ordinary temperatures and pressures methyl ethyl ketone (MEK)-air mixtures containing between 2.0 and 11 vol.-pct. MEK and methyl isobutyl ketone (MIBK)-air mixtures containing between 1.5 and 7.5 vol.-pct. MIBK are flammable. However, MEK-bromochloromethane (BCM)-air mixtures containing at least 6.2 vol.-pct. BCM and MIBK-BCM-air mixtures containing at least 7.0 vol.-pct. BCM are nonflammable. Also, MEK-BCM-air and MIBK-BCM-air mixtures containing less than 18.7 vol.-pct. oxygen are nonflammable. To assure the formation of nonflammable mixtures when mixed with air, MEK-BCM vapor mixtures must contain at least 1.6 vol. BCM per volume MEK, and MIBK-BCM vapor mixtures must contain at least 2.8 vol. BCM per volume of MIBK; these quantities of BCM would be produced by liquid mixtures containing 55 vol.-pct. BCM in the first case and 60 vol.-pct. in the second. An MIBK-BCM-trimethylene chlorobromide mixture containing equal volumes of each liquid forms nonflammable mixtures with air at ordinary temperatures and pressures. The same is true of a liquid mixture containing 34.6 pct. (liquid volume) BCM, 34.b pct. perchloroethylene, 15.4 pct. MIBK, 7.7 pct. toluene, 3.85 pct. ethyl amyl ketone, and 3.85 pct. trimethylene bromide.

Jan 1, 1960

By R. Carson Dalzell

The use of nuclear fission for chemical process heat offers the special advantage of high temperature, limited only by materials of construction. The process heat may be supplied economically at elevated pressures, since no compression of combustion air is required. For the initial effort in developing a high-temperature reactor, the indirect cycle, using helium as the heat-transfer medium, was chosen. The major problems are the design of high-temperature fuel elements, construction of an exchanger to transfer heat to process streams in the range of 2,500° F., and development of compressors capable of recycling helium at 1,000° F. and above. A conceptual design of a nuclear reactor to furnish process heat for coal gasification has been made. Spherical fuel elements utilizing a graphite structure, impregnated with uranium carbide fuel, were chosen, as spheres offer the possibility of easier loading and unloading of the reactor. Calculations of pressure drop and gas-pumping power for the system are included.

Jan 1, 1959

By R. P. Maloney

The Bureau of Mines conducted a reconnaissance of the less accessible parts of the Beluga River coalfield in August 1957 to determine, if possible, which areas were most favorable for developing large reserves of coal suitable for open-pit mining. Several outcrops of subbituminous coal were observed within an area about 30 miles long and 3 miles wide; neither the length nor the width of the coal-bearing area was delineated by the examination. Coal beds 30 feet thick or more outcrop at two places, and beds 5 to 20 feet thick or more outcrop fairly abundantly along the Beluga River and its tributaries The coal measures appear to occur in a series of folds. The overburden comprises glacial gravels and poorly cemented sandstones and ranges from 20 to 400 feet in depth. Few partings were seen in any of the coal beds. Samples ranged in calorific value from 6,240 to 8,246 B. t. u. on an as-received basis. Adequate water is available for stripping by hydraulic methods.

Jan 1, 1958

By W. K. Tolley

This report presents data collected during research by the Bureau of Mines on corrosion of grinding media. Corrosion rates of eight alloys commonly used in grinding media were tested in synthetic mill water using an ultrasonic grinding device especially designed for this work. Electro-chemical measurements showed variations in corrosion rates for these alloys between 9.8 mpy for medium-carbon steels and 0.14 mpy for high chromium white irons. Bureau data are discussed along with data from the literature to indicate that corrosion causes less than 10 pct of the wear of grinding media in commercial grinding mills. A comparison of corrosion rates for various types of grinding media shows that alloying elements and electrochemically active inclusions in steel affect the corrosion behavior of the media.

Jan 1, 1984

By Fred C. Turin, Lisa J. Steiner, Kim M. Cornelius

Like many experienced workers, remote control continuous miner operators perform their everyday jobs making choices and decisions that they may not consciously think about. While performing tasks, they are continuously processing feedback and cues which guide them for the next move. Initial training teaches the operators the tasks necessary to operate the equipment and perform the job. However, with experience they are better able to deal with hazardous conditions and non routine situations. To better understand what potential cues and feedback help to guide the operators, a questionnaire was developed to learn what factors affect decisions. Operator responses address issues related to specific tasks, equipment operation, visibility, lighting, and communication issues. The information collected is useful to understand what cues experienced operators use to make task performance decisions. Results will be used to develop interventions and training for safe and effective operator performance.

By S. H. Ash

The United States Bureau of Mines has published relatively little on the flooding and unwatering of coal and metal mines. Bulletin 229, Fifty-Nine Coal-Mine Fires, published in 1927, contains several instances of the flooding of mines or sections thereof to extinguish fires but does not describe their unwatering. Report of Investigations 2649, Explosion Hazards Incidental to Unwatering Coal Mines, published in 1924, warned against the possibility of gas accumulations in flooded mines and indicated the precautions to be taken. Report of Investigations 2255, An Unusual Hazard in Reopening Long-Flooded Timbered Metal Mines, published in 1921, told of methane being pocketed and the danger thereof. The flooding of mines originates in many ways. At some mines flooding followed reopening after what was thought to be permanent abandonment; also, explosions have caused some mines to be flooded. Extinguishing fires, accidental encountering of underground streams or flooded old workings, and caves of strata admitting water from underground workings, water-bearing strata, or surface accumulations have also flooded all or parts of mines. Unfortunately, un watering often necessitates much study and causes apprehension largely because experiences in similar situations are not generally known, as few descriptions of successful or unsuccessful methods are available. The job has sometimes been contracted for outside the local management involved and has become a matter of record for the contractor only. As the cost-plus contract system often employed in the past is now known to be expensive, careful managements elect to handle the problem themselves, in line with the general policy of cutting expense where possible. This report describes specific in-stances of successful unwatering by operators.

Jan 1, 1933

By C. J. Walker

The Bureau of Mines undertook a theoretical and laboratory study to determine the feasibility of using ethylene as a tracer for natural gas in underground gas-storage reservoirs. The study indicated that ethylene was a useful gas tracer in underground gas storages. Tracer losses were not excessive. Laboratory tests were conducted at pressures as high as 500 psia in both wet and dry consolidated-sandstone cores, evaluating tracer loss with gas blends containing natural gas with different concentrations of ethylene tracer. Under certain conditions losses were less than 17 percent.

Jan 1, 1966

By G. J. Slavens

The Bureau of Mines has devised technology to recover cobalt, nickel, and byproduct copper from domestic lateritic material using an oxidative, ammoniacal ammonium sulfate leach. Nickel, cobalt, and copper were recovered by solvent extraction and electrowinning. To reduce the cost and complexity of cobalt recovery, an alternate method using lig-nite to extract Co3+ was investigated as reported herein. In the first 25 BV (bed volumes) of solution contacted with lignite, 97 wt pct of the Co3+ was extracted in & downflow column at pH 9.3. After 85 BV, the lignite was loaded to 1.5 wt pct Co3+ and further ex-traction was minimal. The lignite extracted cobaltic ammine complexes rather than cobalt ions and was nonselective as to other -metal cations and ammonium ions. Deleterious cations and 80 wt pct of the nonammine ammonium ions were removed prior to acid elution of the lignite. The removal of the ammines prior to elution to produce an ammonium-ion-freeCo3+ eluate was only partially successful. Thus Co3+ removal from ammoniacal solutions by lignite is technically difficult and economically unfeasible. It was also determined that reduction of Co3+ to Co2+ occurred during the extraction-elution process.

Jan 1, 1984

By Alla D. Mah

Combustion energies of barium and strontium were measured by means of the combustion bomb calorimeter. The heats of formation obtained for the oxides were ?H298.15 = -139,060 ± 700 cal/mole of barium oxide (BaO) and ?H298.15 = -144,440 ± 400 cal/mole of strontium oxide (SrO). Tables containing heats and free energies of formation from 298.15° to 2,000° K were prepared.

Jan 1, 1963

By John C. Gagliardi

The size and complexity of modern surface haulage trucks has resulted in an increased reliance upon sensors and electronic-based instrumentation for safe and efficient operation. Design engineers need accurate information about the equipment vibration environment to efficiently and effectively build components for installation on mobile mining equipment capable of withstanding the mine environment. Examples of such components include backup alarms, communication equipment, microprocessor-based controllers, and a wide variety of sensors. Unfortunately, this information is not available to the majority of both original equipment and aftermarket equipment manufacturers. To address this problem, the U.S. Bureau of Mines performed field vibration measurements on a variety of surface mining haulage trucks. The vibration measurements were then analyzed and test specifications were developed in the form of envelopes. In conjunction with test specifications, recommendations to aid manufacturers in implementing a vibration environment test program have been included with an illustrative example.

Jan 1, 2010

By Thomas H. Dubaniewicz

The National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, conducted a study of past mine explosions to identify the ignition locations and ignition sources responsible for the most severe explosion events resulting in death. Since the Scotia disaster of 1976, many fatalities from underground coal mine explosions have been linked to nonpermissible electrical equipment ignition sources located in intake air courses. With few exceptions, explosion protected equipment is generally not required in intake air courses of gassy underground coal mines in the US. Cigarette lighters were another prevalent ignition source for fatal explosions ignited in intake air courses. Several mine rescue/ recovery teams have encountered electrical ignition hazards. The study provides evidence that intake air courses of gassy underground coal mines fit the description of certain Hazardous (classified) locations described in the US National Electrical Code®. Class I Division 2 or Zone 2 explosion protection tech¬niques may be used to design intake air equipment so that it does not present an ignition source under normal operation, before mine power is shut down in emergency situations. Nonpermissible circuits in intake air courses that are likely to remain energized during emergencies, e.g. battery powered equipment, should be protected by more stringent Class I Division 1, Zone 1, or Zone 0 techniques, to protect rescue/recovery personnel.

Jan 1, 2009

This report presents a Bureau of Mines study comparing the construction costs, leakage measurements, and predicted performance of different types of large stoppings built and tested in a room-and-pillar oil-shale mine. The six full-sized structures (30 ft high by 55 ft wide) included both permanent and temporary stoppings and were fabricated using materials ranging from structural steel to coated brattice cloth. Leakage across each stopping was measured at differential pressures ranging up to 1.0 in w.g., using both the brattice window method and sulfur hexa-fluoride (SF6) tracer gas. Blast air pressures resulting from a full-scale face blast of approximately 1,800 lb of ammonium nitrate-fuel oil (ANFO) explosives were measured across two of the stoppings and the pre-and post-leakage rates were compared for all the stoppings. Overall performance of the stoppings for production applications was evaluated using an operational model of a two-panel oil-shale mine. Different combinations of temporary and permanent stoppings were evaluated based upon ventilation performance and construction and operating costs.

Jan 1, 1988

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

BIBLIOGRAPHY 1. Dougherty, John J. , "Control of Mine Fires", Publication of the Mining Extension Service, School of Mines, Appalachian Center, West Virginia University (1969). 2. Coal Age, "Fire, Explosions and Recovery, Federal No. 1 Mine", November, 1963. 3. Nagy, et al., "Sealing a Coal Mine Passage through a -Nor-ii-hole: A Progress Report", U.S. B. M. Publication No. 6453, (1964). 4. Murphy, et al., "Use of Fly Ash for Remote Filling of Underground Cavities and Passageways", U.S. B. M. Publication No. 7214, (1968). 5. Pennsylvania Drilling Company, Pittsburgh, Pennsylvania. Personal Review of Equipment. 6. Industrial Hazards and Communication, Division of U. S. B. M. Personal Communication with John Murphy and Merle Bowser. 7. Instrument Technology, Inc., Borescopes and CCTV Systems for Inspections of Nuclear Reactors; Personal Communication. 8. "Public Works", July, 1972. 9. The Industrial Hazards and Communications Division of the U.S. B. M. , Personal Communication regarding Cohu Model No. 2006. 10. "Bibliography on Underwater Photography and Photogrammetry", Eastman Kodak Pamphlet No. P-124. 11. Optical Properties and Visual Effects of Smoke-Stack Plumes, U.S. Department of HEW, 1967. 12. Middleton, W. E. K. , "Vision Thru the Atmosphere", Univ. of Toronto Press, 1952. 13. Kodak "High Speed Infra Red" film and Singer Corporation Model TI Silicon Vidicon TV Camera. 14. Night Vision Laboratory, Fort Belvoir, Maryland; Barnes Engineering Company, Stamford, Connecticut, Model, T-101; AGA Inc. , Secaucus, New Jersey, Model, "Thermovision" 680.

Jan 1, 1973

By Albert E. Long

To date the commercial diamond bit setters have been principally interested in the speed with which they could produce a sharp, fast-cutting bit. Thus, a premium has been placed on setters who combine a high degree of manual dexterity with the ability quickly to select the Sharp points and edges of the diamonds and set them in the mold without lost motion. The premium on speed does not allow the setters the time, nor are they trained, to consider also the crystallographic structures of the diamonds which are the clues indicating the harder and more suitable working surfaces. Since early fall of 1949, the Bureau of Mines has been conducting a long-range series of experiments in which drill bort have been oriented in diamond bits in an effort to determine the effects and economic practicability of utilizing the hardest surfaces of the diamond crystal structure. The preliminary experiments completed to date indicate that a substantial saving in diamonds may be affected by using the harder areas of the diamonds as working surfaces in the crown of diamond bits. The experimental work is being conducted by the Bureau of Mines in the laboratories and full-scale mine of the Mining Research Branch, Minerals Technology Division, Region VIII, of the U. S. Bureau of Mines at the Mount Weather Station, Bluemont, Va.

Jan 1, 1951

By Andrew B. Cecala

The U.S. Bureau of Mines has designed and tested a system called the Bag and Belt Cleaner Device (B&BCD) to reduce dust levels in and around the bag conveying and stacking process. The device physically cleans either 22.7 kg (50 lb) or 45.4 kg (100 lb) paper bags by using a combination of brushes and air jets. It is completely self-contained and is kept under negative pressure by a baghouse to ensure that dust and product removed from the bags during cleaning does not flow into the work environment and contaminate workers. The bags travel through the device on a chain conveyor, which permits any product or dust cleaned from the bags to fall into a hopper at the bottom of the device and be recycled back into the process via a screw conveyor. Once exiting the B&BCD, the outside of the bags and the conveyor are essentially product and dust free. The B&BCD was evaluated at two mineral processing plants to determine reductions with the device in use. The results of both field evaluations showed that the amount of product removed from the outside of the bags varied from 77 to 93 pet.

Jan 1, 2010

By W. P. Diamond, B. M. Bench, C. M. McCulloch

Coalbeds exhibit a directional permeability, with the maximum permeability oriented parallel to the face cleat. Thus, the most efficient pattern of vertical degasification holes for a coalbed is dependent upon cleat orientation. Surface joints, infrared photolinears, and Ronchi grating photolinears were investigated as potential estimators of subsurface cleat orientation. Cleat orientations were masured in 18 mines, in the Pittsburgh coalbed in southwestern Pennsylvania and northern West Virginia to be used as a standard against which prediction techniques would be evaluated. Two cleat systems with a strong geographic segregation were measured in the study area: N 67° W - N 28° E (95° separation) for the north, and N 76° W - N 17° E (93° separation) for the south. Directional data obtained from the three techniques investigated yielded satisfactory regional predictions of cleat orientation. Analysis of surface joints was the only technique considered sufficiently reliable on a local basis. Prediction of cleat orientation is based on the pairing of the principal directional sets into all reasonable combinations of fundamental systems. The system or systems composed of the most dominant sets nearest to 90° separation are likely to be a reliable prediction of cleat orientation. The most dominant set of the system selected is likely to be the face cleat.

Jan 1, 1976

Mine closing methods should be carefully considered. If not properly sealed, an abandoned mine may continue to produce acid water. Since 60 to 90 percent of the total acid discharged from all coal mines is from abandoned mines,(58) some states require that provisions for sealing be contained in the mining permit application. Closing an operation to prevent harmful mine drainage into nearby runs and streams is a subject of much concern to states as a result of continuing problems from long abandoned mines which were improperly closed.

Jan 1, 1970

By A. D. Mah

Thermodynamic data on compounds of arsenic and sulfur were critically evaluated by the Bureau of Mines. Changes of standard enthalpy and Gibbs energy, and logarithms of the equilibrium constants were tabulated as a function of temperature for reactions involving these compounds.

Jan 1, 1982

By Allen D. Look, Norman King

For many years, much thought and effort have been devoted to the achievement of safety in the use of explosives by those interested in the preservation of human life and the protection of property. As a result, we now have adequate rules pertaining to the safe use of explosives , which, if observed, would prevent many, perhaps ail , of the explosives accidents that yet occur . Although the rules respecting the use of explosives are believed to be well - known, many accidents occur because they are disregarded . The mental awareness aroused by a tragic accident usually will cause safety precautions to be taken for a while ; however , this awareness gradually disappears unless a sincere effort is made permanently to prevent similar accidents . Frequently, because safe methods are more irksome than unsafe methods , the lessons taught by accident experience are forgotten in a short time , vigilance is relaxed , and there is a gradual return to unsafe , easy methods of performing work. If the preservation of human life is important , the unfortunate experiences of others and the lessons taught by them should be applied to reduce unnecessary loss of life . The value of a life lost as the resuit of accident should be calculated not only from the monetary and humanitarian standpoint but also according to what the accident could contribute in the way of saving other lives and suffering . This saving of other lives can and will , if the lessons from unfortunate accidents are applied , convert a loss to a gain a gain of such magnitude that the accident victim could be considered

May 1, 1944

By John D. Corrick

The environmental and nutritional characteristics necessary for maximum copper extraction from a low-grade ore by Ferrobacillus ferrooxidans have been explored as have many of the limiting parameters. Criteria considered were oxygen consumption, copper extracted, soluble copper concentration, temperature, pH, particle size, nutrients, and other inorganic salt concentrations. A set of environmental and nutritional conditions were developed for E. ferrooxidans Which supported cell reproduction and maximum microbial oxidation of a low-grade copper sulfide ore. Percolator tests conducted under these optimum conditions resulted in an 18 percent increase in the quantity of copper microbially extracted over that extracted under conditions considered to be standard. Manometric tests determined those extremes of environmental conditions and nutritional factors Which were detrimental to the extraction of copper by E. ferrooxidans.

Jan 1, 1965