Search Documents

By Raymond B. Ladoo

Garnets are usually found well crystallized in the cubic system , the principal forms being rhombic dodecahedrons , tetragonal trisoctahedrons or combinations of the two , and hexoctahedrons . They also occur as rounded disseminated glassy grains and in compact massive , laminated or gramlar aggregates . They vary greatly in color , but the most common garnets , almandite and andradite , are most often found of a dark red or reddish brown color .

Apr 1, 1922

By ALICE V. Petar

Thallium is one of the rare metals that has come into commercial use within recent years . Its comparative scarcity , combined with a resemblance to the common metal lead , have retarded the development of uses for thallium . Although production is still measured in pounds rather than in tons , it is now finding application in a number of fields . Perhaps the earliest commercial use of thallium was as a constituent of optical glass of higher refractive power than similar glasses containing lead . One of the later applications to attract attention was the use of the oxysulphide in a sensitive electrical device similar to the selenium cell . The " Thalofide " cell , which was patented in 1919 , constituted for a time the most important outlet for thallium. During the next few years the limited use of thallium and its salts in other fields was insufficient to absorb an annual production of a few hundred pounds , and the price dropped from $ 16 or $18 per pound in 1922 to $ 5 per pound in 1924 . Beginning in 1925 several new uses were developed , especially as a poison for rodents and ants , and as a result the demand for thallium increased sufficiently to cause a recovery in price to the present level of from $12 to $15 per pound .

Jun 1, 1931

By K. K. Kelley, W. W. Weller

Heat capacity measurements of lead molybdate and lead tungstate were conducted over the temperature range from 51 ° to 298 ° K. The entropies were found to be S298.15 = 39.7 ± 0.5 cal / deg mole for lead molybdate and S298.15 = 40.2 ± 0.5 cal / deg mole for lead tungstate . The entropy values were combined with other pertinent data to obtain the entropies of formation of the two compounds from their constituent elements and oxides .

Jan 1, 1964

By I. L. Nichols, K. C. Dean, P. H. Johnson

Hydrochloric acid , sulfuric acid , and chloridizing roast- water leaching methods for dissolution of cesium and rubidium from Maine , Canada , and Southern Rhodesia pollucite ores and their flotation products were investigated by small- scale tests . Optimum conditions were determined to be ( 1 ) for hydrochloric acid leaching , use 12.7 equivalents of 8.8 normal acid per equivalent of cesium in the sample and leach for 6 hours at 100 ° C ; ( 2 ) for sulfuric acid leaching , use 12.7 equivalents of 14.4 normal acid and leach for 2 hours at 120° C ; and (3 ) for chloridizing roast - water leaching , roast minus 200 - mesh ore, limestone , and calcium chloride in a ratio of 2 : 4 : 1 , respectively , for 1 hour at 900 ° C , and leach the calcine for 1 hour at 80 ° C with enough water to give 35 pct solids . Extractions of cesium from ores and flotation products containing over 20 pct cesium were in excess of 97 , 93 , and 96 pct for the hydrochloric acid , sulfuric acid , and chloridizing roast - water leach processes , respectively .

Jan 1, 1964

By Robert W. Smith

[In a certain application it was necessary to compute the incomplete beta function, ß(1/2, p, q), for a certain set of values of p and q. Since the set of p and q values was much more finely spaced than those in any published tables, the authors have decided to make their results available in this report. In connection with this application, the function ß(1/2, p, q) was needed at various points in the p, q plane at intervals of 0.05, 0.05 p = 2q < 10.00. Fletcher, Miller, and Rosenhead3/ state that the only tables available in the desired range are those of Pearson.4/ However, the interval used by Pearson was not small enough for the present application. For this reason, it was decided to calculate the function ß(1/2, p, q) for p = q = 0.05 (0.05) 10.00. This table is published because of the fundamental importance in mathematical analysis of the incomplete beta function.]

Jan 1, 1953

By N. H. Darton

In mining coal in the anthracite region of Pennsylvania the general custom has been to leave a large percentage of the coal in place as pillars to support the roof. Evidently any practice that involves partial waste of an important mineral resource is bound to be discarded. It is well recognized that one method of obviating probable waste is to fill the workings with cheap or worthless materials, a process extensively employed in the anthracite and some European mines. At present many of the collieries in the anthracite region of Pennsylvania are utilizing refuse from the old culm banks, which formerly were prominent features in the landscape, and are flushing the fine waste underground so that pillars may be reduced in size or removed. As a result the banks are now disappearing and soon will be gone. The fine culm from the breakers and rock from the mines will continue to be available, but the volume of these materials is insufficient to replace any considerable proportion of the coal removed. The next stage of progress suggested is the use of sand. Fortunately there are available large deposits of this material, much of which can be handled by dredges and pumps. This report is issued by the Bureau of Mines in the interest of safer and more efficient mining methods. I ts purpose is to describe the sand deposits in the northern anthracite coal field in Luzerne and Lackawanna Counties, Pa, Much of the information available is presented in the map, Plate I. Field studies, mostly preliminary, were made in the summer of 1911 to determine the distribution, amount, and character of the larger deposits. It was not thought desirable to make a detailed examination of the region because when the coal companies decide to utilize the sand their engineers will make precise surveys and drill test holes. In preparing the map the various coal companies were consulted; they contributed a large number of facts, especially as to the deposits in the buried valley of the Susquehanna between Pittston and Nan- ticoke, where nearly 1,000 test holes have been bored. The results of these borings were placed at the author's disposal, and have been utilized in drawing the boundaries given in the wide valley area and its extensions up Lackawanna River and NewportCreek. Wyoming Valley contains deposits of sand that are 100 feet thick over a wide area, 200 feet thick in places, and over 300 feet thick in the deep old channel south of Plymouth.

Jan 1, 1913

By Ben E. Argyle

"The tungsten area in southern Mecklenburg County, Virginia, was studied by the Bureau of Mines during the period August 1944 to March 1945. The explorations were an expansion of the work done by the Bureau in 1943 in the tungsten area of Vance County, North Carolina, which joins Mecklenburg County on the south.3/Outcrops of quartz veins in the area were searched for and examined, and the only Promising showing found (a vein on the Gladys N. Taylor tract) was explored by trenching, test pitting, and diamond drilling (fig. 1).Mecklenburg County, Virginia, is in the southeastern part of the State, bordering on North Carolina,U. S. Highways 1, 15, and 58 traverse the County, and State and County roads provide ready access to most parts of the area.In 1942, Joseph and Richard Hamme discovered tungsten-bearing quartz veins in Vance County, Forth Carolina, and started mining and milling the ore. The first concentrates were shipped in July 1943. In August 1943, the Hamme holdings were acquired by Haile Mines, Inc., who continued the mining operations.The Bureau of Mines began exploratory work in North Carolina in June 1943. Reconnaissance work showed that the mineralized belt extends north-ward into Virginia. The Kimball tract, which joins the Taylor property on the north, was explored in 1943 by trenching and drilling by the R. G. Lassiter interests of Raleigh, Y. C., with disappointing results.The topography of the district is mature and characterized by wide, shallow valleys and low, rounded ridges. The main ridges trend northeast. Most of the area ranges from 300 feet to 400 feet above sea level.The relief apparently is controlled by resistant quartz lenses and the associated hard, silicified zones. The enclosing schists and granites are usually deeply weathered. Consequently, most of the quartz veins are found on the ridges."

Apr 1, 1946

By Harry W. Campbell

In 1984 and 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied part of the Meadow Valley Range Wilderness Study Area (NV-050-156) in order to evaluate its identified mineral resources. The study area is located in Clark and Lincoln Counties, NV, about 50 miles northeast of Las Vegas, NV. The Johnston and Fitchett prospect, in the northern part of the study area, has more than 3 million tons of marginal perlite reserves suitable for many commercial uses. A preliminary mining feasibility estimate suggests perlite could be profitably mined from the study area; however, it is unlikely these perlite deposits will be developed in the foreseeable future because of unfavorable market conditions. Zeolite minerals occur in alteration zones adjacent to perlite deposits at the Johnston and Fitchett prospect, but high quality material is closer to potential markets. A metalliferous black shale unit containing 800,000 tons of subeconomic resources may extend into the study area at the Bradshaw vanadium prospect on the northwest boundary. Limestone, stone, sand, and gravel occurrences are wide-spread, but other suitable deposits in the region are more accessible to potential markets. Seven prospects in and near the study area were examined. The entire study area is leased for oil and gas exploration. A group of perlite placer claims covering more than 480 acres was located in the 1940&apos;s in the northern part of the study area. A small group of lode claims was located in the mid 1950&apos;s in the southwest part of the study area. No mining claims are currently (1985) held inside the study area. No mineral production is known from within the study area.

Jan 1, 1987

By D. S. Colby

Statistics on the volume of natural gas produced in the United States were first collected for 1906. A summary of those statistics covering 1906-35 was incorporated in the 1937 Minerals Yearbook. This summary, covering 1936-50 presents, by States, a number of the more important statistics that have appeared in the natural-gas chapter of the Minerals Yearbooks. The period covered has been one of rapid expansion, especially of long-distance transmission lines. Natural gas was made available to some States for the first time; in other States the degree of dependence upon supplies transported from outside their boundaries changed rapidly. Thus, an isolated series of statistics cannot be studied without considering other regional influences that reflect in the overall operations of the industry. These tables accordingly have been designed to show for each State the simultaneous changes taking place in the various sectors surveyed. The tables show production data in the upper portion and consumption data in the lower portion. They are arranged alphabetically, by States. A copy of the 1906-35 production summary from the 1937 Minerals Yearbook has been included.

Jan 1, 1952

By Floyd G. Anderson

The increasing trend toward use of continuous-type mining machines created a significant dust problem in coal mining, which resolved itself into three categories: Visibility at face, deposition on return airways, and the potential health hazard. The control measures applicable to these conditions and studied or developed from 1955 through 1957 are summarized and reviewed in this report. Other important problems brought into focus during the same period were radiation exposure in uranium mining and high temperature and humidity. Although temperature and atmospheric pressure alone may not be contributing factors in the incidence of silicosis, the few mining companies who operate under the extremes of these conditions are dust conscious and keep dust-control engineers on their operating staffs.

Jan 1, 1961

By Tobias W. Goodman, George N. Aul, Joseph Cervik

The Bureau of Mines conducted research to degasify a virgin block of coal in the Beckley Coalbed using long horizontal holes drilled in an array from the bottom of a ventilation air shaft. Eight horizontal holes and an in situ pressure hole were drilled in a radial pattern to depths ranging from 418 to 910 ft (127 to 277 m) and 205 ft (62 m), respectively. The investigation showed the shaft was in a basin saturated with water, which resulted in low gas flows from holes. The in situ pressure at 200 ft (61 m) into the coalbed was 79 psig (544.6 KN/m2). The aver- age gas and water flows for the eight holes were 94,100 ft3/day (2,665 m3/day) and 13 gal/min (49.3 l/min) . After 514 days of degasification, 18.7 million ft3 (0.53 million m3) of gas had been drained. Methane face emissions, which were measured as a section advanced toward the shaft, were reduced about 77 pct, emphasizing the value of drainage by this technique. All holes were grouted before the area around the shaft was mined.

Jan 1, 1982

By H. C. Hamontre

[The Bureau of Mines well-bore caliper was designed to provide an instrument that could be operated through 2-inch tubing, which &apos;a used particularly in many input wells on water-flooding projects of eastern, Kansas and northeastern Oklahoma. It should find wide application elsewhere under many other conditions where it has not been possible previously to make caliper logs with the larger probes used on other instruments. The caliper has three additional advantages over other instruments of this type: (1) It measures 4 radii (up to 18 inches) 90° apart with an accuracy of ± 1/4 inch; (2) the measuring arms can be opened and closed at will by remote control; and (3) it is run and operated on a single-conductor, armored electric cable (Amergraph, type 1-H-0). The caliper probe is 1-3/4 inches in diameter and approximately 6 feet in length. The electrical control and measuring circuits are encased in a stainless-steel tubular case. Measuring arms, made of 5/16-inch aluminum tubing, are attached near the lower end of the instrument. Distances the arms are extended are indicated t the surface by a meter calibrated to read directly in inches. Depths at which the radii measurements are taken are indicated by a wireline depth indicator on the cable-reeling. The instrument is not affected by pressure or temperature, it can be run open hole or under pressure through a lubricator. This paper describes and illustrates the instrument and outlines the operating procedures. A bibliography at the end of the report gives references to articles and patents on the development and use of other well-bore calipers.]

Jan 1, 1954

By Van E. Shaw, D. J. Bauer

Conversion of euxenite concentrate to sulfates with sulfuric acid and solvent extraction of the yttrium- rare - earth mixture with EHPA were studied to determine extraction and separation characteristics . Digestion with 3.5 pounds of 96 percent sulfuric acid per pound of concentrate at 336 ° C for 4 hours resulted in an easily handled product with a yield in excess of 98 per- A thorium- free product was obtained by calcining the sulfated material for 3.5 hours at 650 ° C prior to leaching with water . Di ( 2 - ethylhexyl ) phosphoric acid solvent is an effective extractant with preference for cerium ( IV ) and heavy - group rare - earth elements including yttrium . Separation of complex rare - earth mixtures into light- and heavy - group fractions is feasible , and these fractions can be further processed to isolate ytterbium , neodymium , and dysprosium by changing processing conditions to obtain separation factors greater than two between these and adjacent elements .

Jan 1, 1965

By C. Fang, D. B. Kittleson, K. L. Rubow

"Under contract to the U.S. Bureau of Mines, a study was conducted to investigate the feasibility of using the microorifice. uniform deposit impactor (MOUOI) to measure the size distribution of aerosols containing various mixtures of coal dust and diesel exhaust particles. The project objective was to determine if the mass concentration of diesel exhaust particles, in an airborne mixture of coal dust and diesel exhaust particles, could be determined on the basis of the size distribution of the two aerosols. In general, the mass of diesel exhaust particles is in the submicrometer size range while that of the coal particles lie in the larger size ranges.The MOUDI is a cascade impactor with small diameter nozzles to obtain small cut sizes and rotating impaction plates to avoid particle overloading of the deposit. For this study, a 7 stage version was used. At the sample flow rate of 30 L/min, the cut sizes were 0.10, 0.23, 0.70, 1.0, 2.6, 4.9 and 10 pm.Size distributions of aerosols generated in the laboratory and in several underground coal mines were measured. The primary emphasize of the laboratory tests was to ascertain if the diesel exhaust particles could be separated from the coal dust, regardless of mass fraction of the diesel exhaust particles in the total aerosol mixture. Diesel exhaust, from a Caterpillar Type 3304 NA diesel engine, was mixed with coal dust generated with a· TSI Model 3400 fluidized bed dust generator. Experiments showed the size distributions of the mixed aerosols exhibited two definite modes with the minimum between the two modes in the 0.7 to 1.0 um size range. Distinct modal separation was obtained as the mixture fraction of the diesel exhaust aerosols was varied from 3% to 98%.The field study was conducted in three underground coal mines, two utilizing diesel-powered equipment and the third exclusively using electric equipment. Sampling sites were selected to obtain a wide variety in the diesel exhaust and dust aerosol concentrations. Size distribution data showed these aerosols are bimodal. The mass median aerodynamic diameters of the diesel particulate mode and the coal dust mode were approximately 0.15 µm and 3 to 10 un, respectively. The results, in all cases, clearly show a separation between the two modes in the 0.7 to 1.0 µm size range with the minimum in the vicinity of 0.8 pm. The separation was found to be independent of mass fraction of the diesel exhaust particles, total particle concentration and sampling site."

Jan 1, 1989

By Jr. Smith

The equilibrium compositions of product gases for mixtures of air with methane, propane, or ethylene at and around flame temperatures are reported. For each hydrocarbon, compositions are given for five fuel-to-air ratios--two lean, two rich, and one stoichiometric--at five pressures, from 1 to 20 atmospheres, and at an ambient temperature of 25° C.

Jan 1, 1965

By James S. Browning

For the past several years, the Bureau of Mines has conducted laboratory and continuous process development work on weathered mica pegmatites and micaceous schist ores to determine the feasibility of recovering commercial-grade mica concentrates by flotation. The research has resulted in the development of two processes for flotadon of mica: an acid cationic method for recovery of coarse mica, and an alkaline anionic-cationic method for recovery of fine mica. The research indicated that the two processes may be effectively utilized separately or in combination for flotation of mica from weathered pegmatites and micaceous schists. Concentrates containing over 98 percent mica, with recoveries ranging from 77 to 92 percent, were obtained from the pegmatite ores. The micaceous schist ores yielded concentrates containing 95 to 98 percent mica, with recoveries ranging from 70 to 83 percent. Part 1 of this report summarizes the process development work and demonstrates the feasibility of producing commercial- grade mica concentrates. The report also includes details of commercial beneficiation and grinding of .mica.

Jan 1, 1973

By Deborah A. Spotts

Researchers at the Bureau of Mines have developed a technique for re- generating chromic acid-sulfuric acid etching solutions used in metal surface treatment operations. The technique utilizes a diaphragm cell equipped with a cation-selective membrane to oxidize cr3+ to cr6+ at the anode and to remove copper, the major metallic contaminant, at the cathode. Normally, spent etchant is discarded after approximately 3 days of use. Using the electrolytic cell, the etchant can be used for a year without replacement, From data obtained from industrial-scale cells, the installation of a regeneration cell with a 1,000-gal catholyte- holding tank has been estimated to save at least $240 per day, The payback period for the investment is estimated to be about 10 mo or less. Because the magnitude of these cost savings will vary at different locations, several graphs are presented to aid in calculating payback for a specific site. Using these graphs and the capital costs presented in this study, the payback period can be determined for installing a regeneration cell with a 500- or a 1,000-gal catholyte-holding tank in an existing surface treatment plant.

Jan 1, 1983

By W. J. Fene, G. W. Grove

An important activity of the Safety Division of the Bureau of Mines , in its efforts to reduce accidents , is the safety inspection of mines . Inspections are made at the request of the operators and are not connected with the inspections by the various State departments of mines . The operating management is furnished with a confidential report of the results of the Bureau's inspections , with recommendations for elimination of the hazards found . These mine - safety inspections include a study of mining practices , conditions , and equipment and in some cases the sampling and analysis of mine air and coal dust . The Bureau of Mines has no regulatory powers , therefore the recommendations made in these reports are merely suggestions , and operators are not required to adopt them . Mine inspections are a check on safety standards , methods , and practices and are essential to any accident -prevention program . A foreman or superintendent may be sincere in his efforts to operate a mine safely and believe that he has done everything possible to attain this end . However , experience has shown that because of his familiarity with the mine and the consequent " nearness " of its various features many unsafe conditions may be , and in most cases are , overlooked ; an inspector , particularly an outsider who is trained to look for hazards , can point out the unsafe conditions overlooked by the foreman or superintendent . Some companies employ safety engineers who make regular inspections of their mines , report substandard conditions and hazards found , and make recommendations for correcting them . Unless these recommendations are carried out the inspections have little value . In making recommendations , due consideration should be given to the feasibility of carrying them out ; the management may and very often does consider a recommendation impracticable because of the

Mar 1, 1935

By B. J. Dalton

The Bureau of Mines Helium Research Center has developed a computer program for solving two-phase equilibria data for binary mixtures and for evaluating thermodynamic functions of interest, including all critical points. This computer program was used to calculate equilibrium points on the PVTu surface for the helium-nitrogen system as predicted by the Van der Waals equation of state. Numerical values are tabulated and illustrations are presented for 1,279 equilibrium points and for quantities needed to construct Ponchon diagrams. Equilibrium ratios as a function of pressure at constant temperature and of temperature at constant pressure-are also shown graphically. In addition, saturated partial molal volume and partial molal enthalpy data are given. It is shown that the Van der Waals helium-nitrogen system exhibits retro-grade condensation of the second type for liquid helium concentrations of about 0.07 mole fraction or less and pressures below about 45 atm. It is also shown that the critical point is at a -maximum value of pressure (at constant temperature) and of temperature (at constant pressure).

Jan 1, 1971

By Raymond B. Ladoo

In order to obtain comprehensive and authentic information on fluorspar mining in the western States , the writer, together with and at the request of representatives of some of the largest fluorspar producers of the Illinois - Kentucky district , spent the month of April , 1922 , in examining all we stem fluorspar deposits ( of which record was available ) believed to be of possible commercial importance .

May 1, 1923