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By M. Vulkov

The paper is focused on the optimal selection of grinding medium for a drum mill. The decision-making is based on the fuzzy multiple attribute approach. One way to optimize the grinding process in a tumbling mill is associated with the development and testing a new shape of grinding body. Family of new grinding bodies ? spheroidal tetrahedrons (tetraballpebs) has been manufactured. Two types of spheroidal tetrahedrons and a classical ball (sphere) with one and the same weight are compared. A fuzzy entropy method to calculate the weight of the attributes is suggested. A grinding body which is the best approximation to the fuzzy formulated technological conditions is selected. Keywords: grinding, spheroidal tetrahedrons (tetraballpebs), balls, fuzzy sets

Sep 1, 2012

By S. Safak

Europe retains a modest position in world mining activity in terms of scale of production and mineral reserves but maintains a non-negligible role in the world mining industry. The concept of sustainable development resting on three pillars of economics, environment and social development has become an increasingly important factor in the European mining sector and a major influence on the related policies of the European Commission. Members of European mining industry shall conduct their activities according to the principles which promote sustainable development. A successful minerals planning policy should create the legal administrative environment that is necessary to ensure the sustainable supply of minerals to society within the framework of sustainable development. Members of the European mining industry shall conduct their activities according to principles which promote sustainable development. The challenge for sustainability is to find a balance between securing minerals supply, protecting the environment and achieving social progress. The point of balance depends on the range of policies adopted by governments. In this paper the development of the sustainability of the mining sector in EU and the social component of sustainability in the mineral industry is discussed.

Jan 1, 2014

By S. Banisi, A. Ghasemi, S. Zare, F. Ghorbani, E. Nematollahi

"Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Working at the maximum operating capacity of comminution equipment plays a significant role in the efficiency of the circuit. Appropriate design of cone crusher feed box could result in the choked crushing which is known as a vital factor in achieving target performance. In this research, the non-uniform cone crusher feeding at the Sarcheshmeh copper complex was studied and appropriate measures were taken to solve the problem. The problem resulted in non-uniform and high wear rate of crusher liners and high fluctuations of power draw. In recent decades, the discrete element method (DEM) has been applied successfully to study the effect of different factors on the behavior of particles flow. In this work, various designs for feed box were tested using an in-house developed DEM software called KMPCDEM©. The best feed box design obtained from the simulations was selected, constructed and installed in of the cone crushers. The new feed box design resulted in more uniform feed distribution on the distributor plate of crusher indicated by a reduction of the standard deviation of power draw measurements from 13 to 3 kWh. The better control of the crusher, 49% increase in the crusher throughput and finer and narrower product size distribution were the main outcomes of the installation of the new feed box. Furthermore, the wear rate on mantle and liners of crusher not only decreased but it also became uniform.INTRODUCTION Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Reaching the maximum operating capacity in comminution equipment is a key sign of approaching the nominal productivity of the process. Due to the effect of crusher efficiency on the downstream circuit performance, optimization of the crushing circuits has received considerable attention (Herbst, & Potapov, 2004; Quist, & Evertsson, 2010; Li, Huiqi, McDowell, Glenn R, Lowndes and Ian, 2014; Cleary, Sinnott, Morrison, Cummins, & Delaney, 2017). Improving the performance of crushing circuits not only decreases the capital and operating costs but also increases the efficiency of downstream grinding circuits (Jacobson, Janssen, & Urbinatti, 2010). In cone crushers particles can be subjected to two different modes of compressive breakage; single particle breakage (free feeding) and inter-particle breakage (choked feeding). The maximum efficiency of the cone crusher directly depends on the type of feeding arrangement (Operation Manual, 1977). An appropriate feeding must lead to choked feeding the cone crusher. If the rate and method of feeding the crushers are correctly be executed, the maximum efficiency of the crushers could be available (Jacobson et al., 2010)."

Jan 1, 2018

By Susanna A. C. Stadler, Chris Aldrich, Jacques J. Eksteen

Slag foaming occurs in several pyrometallurgical processes. These processes include steelmaking in basic oxygen steelmaking furnaces and electric arc furnaces as well as various non-ferrous operations like sulphide smelting/converting and base metal slag cleaning. Although slag foaming in steelmaking processes has been extensively researched, little attention has been given to slag foaming in non-ferrous operations. Slag foaming phenomena are complex because often the system consists of three or more phases. With this in mind, factors previously identified as influencing slag foaming were investigated. These include the slag basicity, physical properties of the slag, namely viscosity, surface tension and density, the formation of particles due to undercooling of the slag and the FexO concentration in the slag. The effect of increasing FexO concentration was found to decrease the foam index due to lower viscosities, but higher surface tension depression appears to have led to increased foam index values at high FexO concentrations. The foaming index decreases with increasing basicity, until precipitation of solids occurs. After this point, the foaming index was found to increase with increasing basicity due to increased solids precipitation. In general, increasing amounts of slag-wettable solids led to higher foam indices, but the precise nature of the effect on slag foaming was dependant on the nature of the solid precipitate.

Jan 1, 2003

By J. Kolacz

A new optical sorting system based on a complex image analysis and high definition imaging has been developed by Comex. The image analysis is based on high definition cameras of different types and advanced filtration tools for verification of waste particles. Different mineral properties are used to identify the processed material. The system is further combined with a high speed rejection mechanism based on FPGA technology and operating in real time conditions. This provides a minimal error when removing waste particles from the sorted material.

Jan 1, 2014

By Carlos Collado, Oscar Jimenez, Francisco Diaz, Rodrigo Bernal, Carmen Salinas

Water is a strategic resource for the mining industry. The rising cost has forced the industry to become more efficient in their use, reduce and recycle waste as much as possible. The importance of having a reliable water balance is increasingly urgent, because the resource is scarce and vital to the sustainability of human life, animal and ecosystem. Conventional flowmeters can suffer disruptions or failures by corrosion, fouling, presence of elements in the water as acids, salts and suspended solids. Use of radiotracers is advantageous to determine fluid velocities that are transported through pipes, as they are detectable by means of the radiation emitted, the same way for surface flows, such as natural watercourses and drainage from tailings dams, fluorescent tracers are those with the best advantages. For velocity measurements in pipelines a Iodine-131 tracer solution, around 5 mCi was injected into the suction of the pumps. The technique used is the transit time between detectors at known distances and determining the time of passage of the radiotracer. For measurements of surface fluxes using the fluorescent tracer Rhodamine WT by tracer dilution technique, injecting the tracer at a constant rate and measuring it known concentration diluted downstream. This work has been performed in Minera Los Pelambres, located in the IV Region of Chile, measuring the flow rate pumped from 12 pools with 1-7 pumps operating, obtaining speeds of 0.56 to 2.62 m/s. In pumping wells three facilities have been measured at speeds of 0.111-0.223 m/s, plus six surface flows with flow rates of 8.45 to 357.2 L/s.

Jan 1, 2014

By W. G. Liu

Phenyl malonic acid (PMA), a new chelating collector, which contains a phenyl structure and a malonic acid chelating group, has been synthesized and its collecting capabilities to calamine, hematite, quartz and hemimorphite are also studied in laboratory. From the experimental results, it can be seen that the PMA has somewhat flotation ability to calamine, hematite and quartz, while it nearly has no collecting ability to hemimorphite. With the increase of PMA concentration, the flotation recovery of calamine increases. When the dosage of PMA was 560g/t and at pH=7~9, the flotation recovery of calamine gets its maximum of 45.94%. The test results about the influence of pH on the flotation recovery of quartz show that the flotation recovery increases with the increase of pH, and the maximal flotation recovery can be gained in alkaline media. On the other hand, PMA has stronger flotation capability to hematite than to other minerals. The flotation recovery of minerals increases with increase of PMA concentration. When the dosage of PMA is 560g/t and at pH=5~7, the flotation recovery of hematite is 82.96%. Mean-while, the influence of pH on the flotation recovery of hematite was studied and test results showed that, as pH increases, the flotation recovery sharply rises until pH=4, then the increasing rate de-creases outstandingly, at pH=6 the flotation recovery reaches its maximum of 82.96% and it de-creases speedily in alkaline media. Finally, through the measurement of infrared spectroscopy and in terms of solution chemistry of collector, the flotation mechanism has been discussed. It was concluded that the adsorption of PMA on minerals surface is chemical adsorption in nature through two oxygen atoms in the polar group of phenyl malonic acid chelating with the metal ions of minerals surface to form a hexagon-cycle chelate complex: C(=O)-O-M-O-(O=)C.

Jan 1, 2014

By S. Castro, L. Uribe

Seawater can be considered as a particular process water with a high concentration of NaCl (about 0.5- 0.6 mole/L) and high concentration of hydrolyzing metal cations (mainly, Mg2+ and Ca2+ ions). Micro-flotation tests, induction time measurements, and zeta potential measurements have been used to investigate the effect of these ions on the natural floatability of molybdenite. The results demonstrate that molybdenite is strongly depressed in the alkaline pH range over which hydrolysis products of Mg2+ and Ca2+ ions are formed. At pH 10, colloidal magnesium hydroxide seems to be responsible for molybdenite depression in seawater and in Mg2+ solutions. This is also supported by the measurements of the effect of Mg2+ ions on the zeta potential of molybdenite. The mechanism of depression of molybdenite with Ca2+ ions is different, and depression takes place in the pH range were Ca(OH)+ complexes are formed, below the pH of precipitation of calcium hydroxide. Adsorption of the cationic hydroxy species and/or hetero-coagulation of the positive charged colloidal hydroxide on the negative charged molybdenite particles seem to be the main mechanisms involved.

Jan 1, 2014

By F. v. d. Meer, G. Kretschmar, T. Mütze, T. Leißner

"Dynamic air classifiers separate particles in a gas flow due to different particle trajectories utilizing differences in the settling velocity of particles as characteristic property for separation. The present contribution takes a close look at the separation of heterogeneous mixtures, in which valuables and gangue minerals show significant differences in density. The focus was on a moist iron ore sample, which was characterized in terms of mineralogy, grain size distribution, and particle size distribution. The material was classified at a cut size of 45 µm and at feed moistures between 0 and 6 wt.-%. Additionally to standard characterization techniques, the moisture of both products was measured as well as the yield of fines as product fraction in a corresponding processing plant. In addition, an automated mineral liberation analysis (MLA) provided information of the enrichment and segregation of individual mineral phases in the products. The MLA of the classification products reveals a selective comminution of the mineral phases and especially on overmilling of the valuables. For the first time, the separation of individual mineral phases has been assessed and compared to the classic assessment of classification processes by means of particle size analyses. KEYWORDS Dynamic classifier, segregation, MLA, selective comminution INTRODUCTION Dynamic air classifiers separate particles in a gas flow due to the different trajectories of the particles. The result of such a separation process depends on the gas throughput of the classifier, the dimensions, design and rotational speed of the deflector wheel, as well as the state of dispersion and thus the geometry of as well as the turbulence and interparticle interactions in the separation zone. Air classification of moist feed materials can be divided into several sub-process (Leschonski, 1977; Mütze et al., 2016): - dosage of the feed material, - dispersing the solid feed material into a gas stream, - feeding the dispersed material into the classification zone by pneumatic conveying, - drying of moist particles during pneumatic conveying, - separation of coarse and fine particles, and - separation of fine particles from gas."

Jan 1, 2018

By Lorenzo Reyes-Bozo, Ronaldo Herrera-Urbina, Pablo Higueras, Alex Godoy-Faúndez

"The copper mining industry in Chile and perhaps in other countries as well is faced with the challenge to implement the best practices in order to achieve a sustainable and more environment-friendly growth. Relationships between mining industry and society have been historically complex due to its environmental impacts. Whereas the ore grade has declined continuously, this has involved an intensive energy and water consumption thus increasing operational costs at different stages of the concentration process. In the case of copper sulphide ore concentration, froth flotation is the main technology used worldwide. The amount of the different chemical reagents used in flotation plants (i.e., collectors, depressants, frothers and modifiers) affects significantly production costs and has a negative effect on the environment as well. The objective of this research work was to evaluate the use of biosolids and their main components (i.e., glucose, proteins and humic substances) as more environment-friendly flotation collectors for chalcopyrite and molybdenite. For this purpose, microflotation tests were conducted in a modified Hallimond tube. In addition, FTIR and zeta potential experiments were performed to investigate the interaction of biosolids with these sulphide minerals. Biosolids and their main components may interact through physical and chemical ways due to different affinities with such sulphide minerals as chalcopyrite, pyrite and molybdenite, which are present in copper sulphide ores. In alkaline pHs, biosolids and their main components make the zeta potential of the sulphide minerals investigated more negative. These results may provide important information concerning the behavior of the main sulphide minerals in the concentration of copper sulphide ores at industrial scale, wherein mill processes could affect their surfaces properties. Therefore, biosolids and their main components may open an opportunity to be used in copper sulphide flotation plants to partially replace conventional reagents, which are more hazardous and less environment-friendly."

Jan 1, 2014

By R. Paturi

Mill liners play an important role in the operation of a mineral concentrator influencing the throughput, availability, power drawn and the efficiency of the mill in the plant. Liners protect the shell and transfer energy to the grinding charge. Metso Technology Development has conceptualized, developed and successfully implemented physics based 3D DEM simulation techniques to predict charge motion, power drawn, energy spectra and wear over the life of the liner. This paper will present a case study of shell liner optimization for a 34? SAG mill including the input data requirements, and shell liner optimization methodology using the 3D simulations that eliminates the need for the traditional expensive and lengthy proto-type testing. These simulations will cover ball and particle movement, liner wear and mill power draw, and do not cover particle breakage and slurry flow. Even the liner manufacturers lack the ability to provide this type of qualitative and quantitative information on their products. The data from these simulations provides the plant engineers a scientific basis for their decision making and thus eliminates guess work. Keywords: liner, optimization, multi-physics, 3D-DEM

Sep 1, 2012

By Yuemin Zhao

Pre-combustion cleaning of coal plays a key role in the process of efficient and clean utilization of coal resources. Recently, wet beneficiation of coal is predominant around the world. Nevertheless, wet beneficiation processes are limited by the increasingly serious problem of worldwide shortage of water, especially in China. Thus, it is imperative to develop efficient dry coal beneficiation techniques. Currently, several technologies such as air dense medium fluidized bed, compound dry cleaning and air jigging have successfully achieved high-efficiency separation of 50~6 mm coal. However, in recent years, a large amount of fine coal is generated as the mechanized mining technology has been progressively deployed in coal sector. Thus, it is necessary to develop efficient dry beneficiation techniques for fine coal. In recent years, many countries including China, India, Canada, Germen, and Australia have carried out many research works on fine coal dry beneficiation techniques. China University of Mining and Technology has carried out systematic researches on the introduction the vibrated energy to traditional air dense medium fluidized bed for fine coal beneficiation. This paper studied air dense medium vibrated fluidized beds (ADMVFB) for fine coal dry beneficiation. The experimental results show that the coal of <6 mm size can be beneficiated in an ADMVFB efficiently with the E value of 0.065~0.085, the separating density can be adjusted in the range of 1.45~2.2 g/cm3, and the lower limit of beneficiation can reach to 0.5 mm. Keywords: fine coal, air dense medium vibrated fluidized bed, coal separation, dry separation

Sep 1, 2012

By S. V. Volkova, S. V. Mamonov, T. P. Dresvyakyna

"The purpose of the work is complex processing of sulphide-magnetite ores with the separation of iron into iron concentrate, copper and noble metals into copper concentrate.The work shows the research results of the material composition of the sulfide-magnetite ore in the South part of the Peschanskoye deposit. According to the research results it is found that ore contains 0.59% of copper, 66% of which is related to chalcopyrite; 39.9% of iron, 81% of which is magnetite and 3.87% is sulfur, 42% of which is associated with pyrrhotite, 65% of which is a monoclinic modification. According to the results of the mineralogical analysis, it is found that the main iron-containing mineral in the ore under study is magnetite, the content of which is 45%. In addition to magnetite, iron is found in carbonates, pyroxenes, amphiboles, chalcopyrite, pyrrhotite and pyrite. The main copper mineral in the sample is chalcopyrite; covellite, chalcosine, bornite have a subordinate value. The total content of copper minerals in the sample is about 1%. The processing technology provides the three-stage grinding of the ore to a size of 65% of the class-71 µm; a cycle of copper flotation; a cycle of pyrrhotite flotation; wet magnetic separation of flotation hosts. The following optimal parameters are established for the ore under study: the alkalinity of the slurry is 250-280 g/m3 of free calcium oxide in the liquid phase of the slurry; the duration of the main copper flotation is 20 min; the consumption of butyl potassium xanthate is 20 g/t; the consumption of the foam generator T-92 is 15 g/t; the consumption of copper sulfate for the activation of pyrrhotite is 300 g/t; the magnetic field strength is 1500 Oersteds.A complex flotation-magnetic technology for the enrichment of sulfide-magnetite ore has been developed in the laboratory in order to produce a copper concentrate containing 21.6% of copper with 91.7% extraction and an iron concentrate with 66.5% of iron mass fraction and 1.2% of sulfur with an extraction of iron into the concentrate of 87.9%."

Jan 1, 2018

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By Yang Xiao, Zhang Yimin, Bao Shenxu, Liu Chun

Stone coal is a unique vanadium-bearing resource in China. Many techniques, such as salt roasting-water leaching, blank roasting-acid leaching, direct acid leaching etc. have been developed for vanadium extraction from stone coal. The vanadium leaching rate can reach 74.9% for stone coal from Jiangxi, but only about 27% of vanadium is leached for Hubei ore by applying salt roasting-water leaching technique. This paper investigats the vanadium occurrence in stone coal by microscope observation and electron probe, and compares the minerals components of stone coal from Jiangxi and Hubei. Although most vanadium exist as an isomorphism by replacing Al(III) from dioctahedral structure in mica group minerals in stone coal from two regions, the free vanadium is remarkably abundant in Jiangxi stone coal than in Hubei stone coal, which results the fact that vandium is relatively readily extracted from former. Moreover, the content of calcite in Hubei stone coal is much higher than that in Jiangxi stone coal. Calcium can react with V2O5 to form water insoluble calcium vanadates during roasting and this may be the reasone why the water leaching rate of vanadium is low for Hubei ore. Acid leaching is more beneficial to the vanadium leaching but other extra methods, such as adding aid-leaching agent and/or increasing acid concentration is need for the ore where vanadium is embeded firmly. This study can effectively guide the selection of vanadium extraction techniques for stone coal from different regions.

Jan 1, 2014

By N. D. Ilankoon

"The use of thiosulfate as an alternative lixiviant for cyanide to treat complex refractory ores followed by the use of ion exchange resins (IX resins) for gold recovery has become an industrial reality. In this study, polyethylenimine (PEI) coated iron oxide magnetic nanoparticles (MNPs) were used to recover gold from the leaching solutions that consist of calcium thiosulfate, copper and gold. The gold loaded MNPs were easily separated from the solution using an external magnetic field. Proposing a novel adsorbent with characteristically easy solid-liquid separation, to recover gold from synthetic thiosulfate leaching solutions and gold elution and reuse of MNPs were the main objectives of this study. Adsorption isotherm studies revealed that the data fitted both Langmuir and Freundlich isotherm models equally well. The maximum adsorption capacity was 18.5 mg/g at pH 8 and 50?C. According to thermodynamic studies the physisorption process was exothermic and spontaneous. Gold and copper elution, and the regeneration and reuse of the nanoparticles were investigated and promising results were obtained. Different elution systems comprising sulfites, chlorides, glycine, EDTA (ethylenediaminetetraacetic acid) and sodium hydroxide were considered. Among them, EDTA for copper elution and NaOH for gold elution were the most efficient eluants. Regeneration and reuse studies revealed that the MNPs can be used for several cycles without significant performance loss. INTRODUCTION Although cyanidation has been used for gold leaching for more than 100 years, some major drawbacks associated with cyanidation have led to a quest for alternative lixiviants for gold leaching. Cyanide is ineffective in treating carbonaceous refractory ores as gold cyanide complex is adsorbed onto the native carbon in the ore itself known as preg-robbing. On the other hand environmental concerns associated with cyanidation drives the need for environmental friendly alternatives for cyanide. As of today, thiosulfate is known to be the most extensively studied and most promising alternative lixiviant for cyanide in both technical and environmental perspectives (Aylmore and Muir 2001, Oraby 2009)."

Jan 1, 2018

By Fengming Li, Baocheng Song, Yuemin Zhao, Hailin Dong, Liping Peng, Chusheng Liu, Chenlong Duan

The large-scale vibrating screens with high processing capacity and efficiency are now in great demand in the mineral processing industry of China. However, as the equipment is always suffering from the strong external harmonic exciting force, the inertial force and the impact from the minerals, the fracture of the beam and the crack of the lateral plate are easy to occur, which has a negative effect on the reliability of the equipment itself and the industrial production. Considering the essential high reliability of the equipment, a new large-scale vibrating screen with duplex statically indeterminate mesh beam structure (VSDSIMBS) was developed. The natural characteristics, namely, the natural frequency (or the modal frequencies) and the natural mode, and the dynamic characteristics of the VSDSIMBS were obtained by the modal analysis and the harmonic response analysis. In addition, the dimensions and the constructions of the statically indeterminate plate and the mesh beam were chosen as the design parameters, to which the sensitivity of the whole mass, the maximum deformation and the maximum stress of the duplex statically indeterminate mesh beam structure (DSIMBS) were summarized for the optimization of the DSIMBS. Now the large-scale VSDSIMBS is being well used in China.

Jan 1, 2014

By Robert Snow, Shibo Zheng, Wenyi Song, Xiaoqing Ma, Patrick Zhang

Numerous phosphate mineral depressants have been reported in the literature for use during anionic flotation of dolomite from carbonate fluorapatite in slightly acid circuits. In one part of this research, laboratory flotation experiments were conducted to compare the effectiveness of phosphate depressants to process ground, deslimed high-MgO Florida phosphate pebbles. Ten potential phosphate depressants were evaluated during laboratory anionic flotation of dolomite from phosphate in a slightly acid circuit using a sulfonated oleic acid soap plus oil as the dolomite collector. Eight of the depressants have been used by various investigators with foreign and domestic carbonate-phosphate ores. Four of the depressants were found to be reasonably effective during the current flotation study, namely: sodium tripolyphosphate (STPP), sodium hexametaphosphate (SHMP), tetrasodium pyrophosphate (TSPP) and diphosphonic acid (DPA). Without depressants, the sulfonate collector required to produce cell underflow phosphate products containing <0.80% MgO and MgO/ P2O5 ratio <.033 was 1.13 kg/ton of flotation feed at a flotation pH range = 5.5-6.0. Using this collector level with 0.91 - 1.36 kg/ton of feed of STPP, SHMP or TSPP yielded phosphate products analyzing 0.73-0.92% MgO and MgO/ P2O5 ratios = .027-.034 at 90.0-96.8% P2O5 recovery. Similar grade phosphate products were obtained using DPA as the phosphate depressant at 84.1-87.5% P2O5 recovery. When no depressant was used, a similar grade phosphate product was obtained at only 65.9% P2O5 recovery. Another part of the research aimed at reducing MgO content in the final concentrate from Florida phosphate plants by conducting dolomite flotation on the final concentrate. Numerous phosphate depressants were tested for this purpose, including acidic, neutral and alkaline reagents. The most effective phosphate depressant was found to be phosphoric acid, giving both high grade and recovery.

Jan 1, 2014

By D. J. Zhao

The reduction of ilmenite pellets was investigated at 950°C and 1000°C under a CO-N2 gas mixture with 10 L/min gas flow rate. All the reducing reactions were conducted in a furnace with a thermogravimetric analysis system. The reduction rate is higher at 1000°C than that at 950°C. At the early stage of the reactions, with the CO concentration increasing in the gas mixture, the reduction rate increased at 1000°C. In addition, at the early stage of the reactions, a rapid temperature increment and a rapid conversion of oxygen were observed on the curves of temperature versus time and conversion of oxygen versus time under different experimental conditions. The solid reaction products obtained in these experiments were analyzed by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometers (EDS). Metallic Fe with small amount of Ti dissolved in it and oxides of Ti were found in the solid reaction products, but the formation of any nitride phases was not found under the prevailing conditions.

Jan 1, 2014

By Y. D. Gao

A new technique has been developed for comprehensively recovering tantalum niobium tungsten ore by adoption of stage grinding, stage separation, combination of flotation and gravity separation, gravity separation for coarse particles, flotation for fine ones, combination of ore-dressing and hydrometallurgy. The new type and high efficiency combinative collector mainly composed of benzyl hydroxamic acid is firstly used to treat tantalum niobium and tungsten slime, besides the new type equipment for gravitational separation ?YTF-C shaking table for fine particles is adopted to treat flotation rough concentrate, hence having notably enhanced both recovery and concentrate grade of fine tantalum niobium and tungsten minerals. The commercial test obtains the tantalum concentrate assaying Ta2O5 31.98% with recovery 43.44% and tungsten product assaying WO3 89.40% with recovery 76.02%. The developed technique provides a reliable approach and an effective way for comprehensive utilization of lean fine complex refractory tantalum niobium tungsten ore resource.

Jan 1, 2014