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By Kira Mizell, James R. Hein

Ferromanganese (FeMn) crusts form by precipitation of iron and manganese oxides from seawater onto a rock substrate and are therefore considered hydrogenetic in origin. Diagenesis does occur however, through the process of phosphatization. During phosphatization, abundant dissolved phosphate in seawater replaces carbonate in the detrital fraction as well as directly precipitates within the FeMn matrix as carbonate fluorapatite (CFA). This process is likely accompanied by the partial dissolution or replacement of the oxide phases [1]. As a result of these diagenetic processes, trace elements adsorbed on the oxides are released and can either be depleted or enriched in the phosphatized FeMn crust layers. Pb, for example, has been shown in sequential leaching experiments to associate with the iron oxyhydroxide (FeOOH) phase in purely hydrogenetic layers, while >95% of Pb in phosphatized crust layers is found in the CFA fraction [2, 3]. However, previous sequential leaching studies analyzed bulk layers of phosphatized crusts and only a few crusts, from the Pacific Ocean. Here we present concentration data for Pb and other trace elements in the CFA fraction leached from thin stratigraphic intervals of the phosphatized portion of FeMn crusts from the Pacific and Atlantic oceans to confirm consistency of trace metal association with CFA both throughout the phosphatized section and in two ocean basins. The Pb and trace element concentration data from this study will also be compared with data from non-phosphatized crusts from the global ocean. We can then determine the effect of phosphatization on the concentration of Pb and other elements of greater economic interest in FeMn crusts, specifically whether there is overall enrichment, depletion, or possibly even phase transfer of each metal in the phosphatized layers.

Jan 1, 2018

By J. W. Jamieson

"The future of the marine mining industry is tied to the resource potential of the seafloor. Everything from economic feasibility, policy decisions and environmental impact assessments to extraction techniques and mining tool design rely on an understanding of the size, composition, and distribution of the deposits. Development and regulatory decisions must ultimately be tied to not only the grade and tonnage estimates of individual deposits or groups of deposits, but also an understanding of the uncertainty of these estimates. Here, we will discuss how seafloor massive sulfide (SMS) deposit grades and tonnages are evaluated, and the sources of the uncertainties associated with these values.TONNAGE UNCERTAINTYFirst-order tonnage (size) estimates for SMS deposits are primarily determined from calculating the volumes of material that occurs as positive bathymetric features on the seafloor. The extent of sulfide mineralization on the seafloor can be determined either from visual surveys (camera-tow, remotely-operated vehicle (ROV), or human-occupied submersible surveys) or from volume calculations of bathymetric features identified from digital elevation models of the seafloor, or a combination of both methods. For bathymetric models to be used to identify deposits in the absence of visual groundtruthing, data resolution of 1 m or less is generally required to confidently identify a feature as being hydrothermal in origin (as opposed to a volcanic or tectonic feature), and therefore near-bottom multibeam data acquisition (e.g., using autonomous underwater vehicle (AUVs) or remotely operated vehicles (ROVs) is required (Fig. 1). Specific characteristics of bathymetric features, such as shape, slope angles and surface roughness can be used to identify features of hydrothermal origin (Fig. 1). However, so far, bathymetric features mapped at a resolution of ~1 m cannot be relied upon to unambiguously distinguish a sulfide mound, and the additional use of multiple AUVmounted sensors, such as magnetometers, which can be used to detect hydrothermal upflow zones, or self-potential sensors, which detect electrical fields related to the oxidation of sulfide minerals, can increase the confidence that a bathymetric feature is indeed a sulfide body, without the need for expensive and time-consuming visual surveys (c.f. Petersen et al., this volume)."

Jan 1, 2017

By Marco Figoni

The increased interest on deep water minerals resources is a challenge for both mining and oil industry. The exploration and production of oceans minerals require a synergy between of different technologies. While mining industry is leading the dredging and processing part of the system, oil industry is contributing through development of ore lifting technology based on existing subsea knowledge. The paper presents an overview, based on published projects around the world, of different approaches to marine mining. Several exploration techniques and offshore production systems were already designed and assessed, all of them with apparently positive results. Exploration phase is well advanced and in continuous expansion allowing the discovery of increasing resources around the world of different nature but production can be considered to be in an early stage. Different from onshore mining, subsea operations require a closer cooperation with international and local authorities to preserve as much as possible the environment. There are still many uncertainties at respect and all the exploration process must be carefully evaluated to allow subsea mining to develop in a sustainable manner. Technically, mining at seabed was already demonstrated and the process is based on three main components, namely seafloor mining tools, riser and lifting system and production vessel support. This layout is based on the concept that ore must be disaggregated at seafloor first, transported to surface in form of slurry that must be dewatered before loading to be transported to processing plants onshore. The challenges are rising because the environment and safety must be taken into consideration as a priority when evaluating the efficiency of the system. The most critical challenges regarding the production operations, especially in deep water are the deep-sea excavation process, the transport of large slurry volumes, the slurry abrasivity, the power supply management and the subsea

Sep 14, 2011

By David S. Cronan

Submarine hydrothermal mineralization occurs in at least three locations along the Hellenic Volcanic Arc in the Eastern Mediterranean Sea. Weak hydrothermal discharges occur off Kos and Nisseros at the eastern end of the arc and off Milos at the western end. In both cases the hydrothermal solutions are rich in iron and manganese and are precipitating iron oxides variably enriched in minor elements. This points to the likely presence of sulphide minerals at shallow depth below the sea floor at these locations. By contrast, at Santorini, in the centre of the arc, the hydrothermal discharges are much stronger and rate of deposition of the hydrothermal minerals much greater. Indeed, in one of the two hydrothermally active embayments off Santorini (Nea Kameni) hydrothermal deposits are accumulating up to five times as fast as in the Atlantis II Deep of the Red Sea. Radiocarbon dating indicates that these deposits have been accumulating for about 100 years. In the other embayment off Santorini (Palaea Kameni), hydrothermal deposition has taken place over a longer period (more than 1,000 years) but the deposits are not so hydrothermally enriched due to the simultaneous deposition of biogenic silica and detrital mineral with the hydrothermal deposits. The observed pattern of increasing intensity of submarine hydrother¬mal activity from the extremities of the arc towards its centre argues for additional hydrothermal mineralization on poorly explored areas of the sea floor between Milos and Santorini and between Kos and Santorini.

Jan 1, 1994

By James R. Herring

An unusual combination of ten new, deep (-100 m) coreholes and an extensive high-resolution seismic reflection network enables us to produce a detailed study of the phosphorite resources in the Tertiary strata of the Georgia continental shelf. These strata are mixtures of a terrigenous facies, notably quartz and clay along with minor amounts of other aluminosilicate minerals, and of a marine facies, notably phosphorite and carbonate. Phosphatic sediments occur throughout the cores, however the richest phosphorite beds are in the middle Miocene (Serravallian) sediment, where they constitute up to 70 percent of the sediment mass. Major zones of phosphate enrichment occur chiefly at major unconformity boundaries (tops of Oligocene, lower and middle Miocene, upper Miocene, and lower and upper Pliocene) and at prominent intrastratal reflectors representing minor unconformities within units. Phosphorite co-occurs with the clay minerals, especially palygorskite, but correlates inversely with carbonate and detrital quartz, indicating a low-energy depositional environment. The clay minerals present in these strata, which have an environmental consequence on recovery of the phosphorite, are varying concentrations of smectite, kaolinite, mica, palygorskite, and sepiolite. Phosphatic resources have been determined within only the Miocene strata. Sediment volume for this unit to the 100 m isobath on the continental shelf has been established using the high-resolution seismic reflection network that has been calibrated using the deep coreholes. Phosphorite grains larger than 0.1 mm average about 40% of the sediment. In turn, most of the remainder of the sediment in this size range is quartz, which is separable from phosphate grains using conventional flotation techniques. Our estimate is that 300 Gt of phosphorite lie within the Miocene strata of the Georgia continental shelf.

Jan 1, 1994

By C. R. Pearce, B. Murton, S. Howarth, P. Lusty

"With the expansion of “green” energy technologies, the demand for the critical raw materials required to sustain this growth is increasing. Many E-tech elements, including tellurium (Te) and rare earth elements (REEs), suffer from high supply shortage risk and the need for more diversified metal supply routes is driving research into alternative resources. Hydrogenetic ferromanganese crusts, seafloor deposits of Fe- and Mnoxyhydroxides that form from the direct precipitation from seawater, present a potentially important future source of E-tech elements. With growing interest in the potential wealth of these deposits and the issuing of permits for deep-sea mining and exploration, more work is underway to understand the nature of ferromanganese crust deposits, their elemental concentrations and distributions, and the potential impacts of mining activities.This research focusses on the formation of ferromanganese crust deposits and processes that control the extreme enrichment of elements such as Te, Co and REEs. The crusts were systematically sampled and mapped between ~ 1000 – 4000 m depths using ROV ISIS, from a range of environments, substrates and morphologies from Tropic Seamount (NE Atlantic) in order to determine the seamount-scale factors that control major and trace elemental concentration variations. These factors include depth, surface roughness and micro-bathymetry, location relative to long-term mean current direction and energy, influence of tidal energy dispersion across the seamount, sediment supply, substrate lithology, biological productivity and phosphatisation. The study analyses trace-element characteristics of 100 ferromanganese crust samples alongside standard reference materials NOD-A-1 and NOD-P-1 (US Geological Survey manganese nodules). At this initial stage, we report results from whole rock acid digestion and ICP-MS analyses."

Jan 1, 2017

By Will Roberts, M. E. Williamson

After verification of methodology and testing of prototype systems during 2005/06, Nautilus Minerals expanded their Papua New Guinea (PNG) operations to a full commercial exploration program in 2007. Included was the deployment of sensors and survey systems to locate, characterize and verify massive sulfide deposits with potential as mine sites within the tenements held by Nautilus in PNG. This presentation discusses some of the gear developed and operated during the 2007 PNG investigation.

By Tetsuo Yamazaki

Deep-sea rare-earth element-rich mud (REE Mud) distributes in pelagic clayey sediment column on ocean seafloor at 4,000-6,000 m deep. The thickness ranges 5-80 m and the burial depth 0-100 m. The REE content ranges 600-2,250 ppm in Pacific and one of the richest, maximum 6,500ppm, has been found in Marcus Is. exclusive economic zone. By applying a conventional hydraulic excavation and lifting methods, the economy of REE Mud mining around Marcus Is. is preliminary examined. Because the waste content in REE Mud is high and the disposal cost in Japan is very expensive, the mining is recognized far away from economy.

Sep 14, 2011

By Hjalmar Thiel

Issues of deep-seabed mining are discussed since four decades and extensive efforts have been invested in oceanographic studies related to environmentally sound harvesting of polymetallic nodules. Because mining on the deep seafloor seems to range from large-scale, two-dimensional dredging or scooping up of the ore from the uppermost surface sediment layer to more localized drilling or deeper digging into a three-dimensional ore body, it appears to be justified to reconsider some concepts for environmental impact evaluation. Based on the experience gained during preceding years in environmental studies related to polymetallic nodule mining, some interrelated hypotheses and proposals will be presented. It is suggested that these proposals be considered in future plans for environmental impact evaluation and that observations on community re-establishment be conducted before massive sulphide mining or other ore extractions enter the commercial mining phase.

Aug 24, 2006

By Nobuyuki Okamoto

Ferromanganese crusts on the seamounts in the Pacific Ocean are potential resources of cobalt, nickel, platinum and REEs. Particularly, those of the Republic of Marshall Islands and the Federated States of Micronesia (FSM) waters are believed to be of the highest resources potential area in the Pacific Ocean. The total six cruises using the Japanese Research Vessel Hakurei Maru No. 2 were carried out in the seamounts of the Marshall Islands in 1996, 1998 and 2002, and of the FSM in the 1997, 1998 and 2005 for evaluation of economic potential for cobalt-rich ferromanganese crusts as part of the Japan-SOPAC joint project. During these cruises numerous data such as bathymetric, geological, geophysical and environmental data were obtained. Geophysical exploration with backscatter mapping and side scan sonar, visual imaging using towed TV camera and geological sampling using dredge bucket and/or benthic multi-coring system (BMS) were conducted on these seamounts. In this presentation, we will report the mode of distribution of the crusts and calculated resource estimation based on the results of these geological and geophysical shipboard survey and land-based analyses. Keywords: ferromanganese crusts, Marshall Islands, Micronesia, resource potential

Jan 1, 2011

By Cheng Xiangzhou

The China's Pioneer area includes two parts. The topography in the western part is very different from that in the eastern one. The distribution of the manganese nodules in these two regions differs correspondingly China Ocean Mineral Resources Research and Development Association (COMRA) will take appropriate measures so that the next development will be adapted to the features of its potential minable area.

Jan 1, 1996

By Robert R. Tarver

A long history of gold production at Nome, Alaska has resulted in long term interest in the nearshore environment as a production target. Mining by Western Gold Exploration and Mining Company offshore of Nome yielded approximately 100,000 troy ounces of gold in the period 1986 through 1990. This study was designed to determine the relationship between heavy minerals, sediments, and gold concentrations which occur in the upper meter of sediment offshore of Nome. Standard procedures were implemented for grain size analysis, heavy mineral separations, and heavy mineral frequency determination.

Jan 1, 1991

By Janine Lahr, Peter E. Halbach

The Manus Spreading Ridge is located within the EEZ of Papua New Guinea and lies in the Manus Basin ENE of the PNG Island and N of the Island New Britain. The divergent backarc spreading system is caused by the subduction of the Solomon plate in the South under the Bismarck plate in the North along the lineament of the New Britain trench. The rate of divergence is relatively high compared to other back arc spreading systems and amounts up to 12 cm/year [3]. Since submarine volcanism and associated hydrothermal circulation as important parts of the oceanic heat transfer system are also dependent on the rate of spreading, hydrothermal fluid venting and respective deposition of polymetallic sulfides can be expected there. In late 1985 first indications for hydrothermal activity were observed on a swell within the central rift valley of the Manus Spreading Centre during a photographic survey of the seafloor by an expedition of the Hawaii Institute of Geophysics with the American RV Moana Wave [1]. Detailed geological investigations including successful sampling were first carried out in June 1990 within the scope of the OLGA II research project (conducted by Prof. Tufar, Marburg) using the German RV Sonne equipped with a deep-sea television sledge and Tvcontrolled grab systems. Simultaneously a research cruise with the Russian RV Akademic Mstivlav Keldysh took place using the manned submersible Mir; the findings of the OLGA II cruise were immediately used for planning and organization of the Mir dives [3]. The massive sulphide samples which we used for our geochemical and mineralogical studies originate from the hydrothermal fields 1 and 2 and are from grab stations of the OLGA II expedition [4].

Sep 24, 2006

By Kyung-Ho Park

The smelting leaching process is known as one of the most favorite methods for the processing of deep-sea manganese nodules because of its smaller environmental impact and easiness of manganese recovery. The sulphuric acid pressure leaching of the matte prepared from deep-sea manganese nodules was studied to dissolve the valuable metals. Almost complete dissolution of Cu, Ni, and Co from matte was achieved under the following conditions: leaching temperature 180°C, time 4 hours, PO2 10 kgs/cm2, acid concentration 2.5% (vol/vol), pulp density 5%, ammonium sulphate 40 g/l. Under these conditions the iron concentration of leach liquor was 0.95 g/l. Optimization of leaching parameters was carried out by statistical design of experiments using 23 full factorial matrix. The linear and interaction co-efficients were evaluated for dissolution of metal values and also for iron concentration in leach liquors.

Jan 1, 2003

By Chul H. Jo

The functions of miner mainly include the pick-up manganese nodules laying on the surface of the seafloor, the separation them from sediments, the crushing the nodules and the covey to the inlet of the flexible hose. The miner is connected with umbilical cable that can supply power, instrument signal, communication data, etc. The major concerns of the system is to monitor and control the launching and retrieval operation, the landing, maneuvering and track keeping, to monitor the pick-up operation and to monitor the hydraulic system. Also as per the seafloor profile the track and pick-up processes need to be controlled. The recent research and development of deep sea miner is mainly focused on the efficient performance and workability in deep water. To communicate and control the miner, navigation and positioning system have been applied. As the miner is being deployed or retrieved, it is very critical to avoid any damage to the device that would be caused by the dynamic behavior of surface vessel or the minor itself with wave and current motion. The fast deployment and retrieve should be considered very important to minimize the possible damage. The paper introduces the various type of deployment devices and recommend the possible system to the miner developed by KRISO.

Jan 1, 2003

By Alexander Malahoff

A shipboard research system capable of operating in waters of up to 2,000 m has been designed and implemented by the Hawaii Undersea Research Laboratory (HURL), University of Hawaii. It uses a remotely-operated ocean bottom survey camera system, ROV, bottom TV grab, the PISCES V submersible, and a submersible emergency recovery system aboard the 225-foot RN KA'IMIKAI-O- KANALOA. All systems are operated from the stern of the KA'IMIKAI with a mounted Caley telearm and articulated A-frame system. The system was designed for multi-purpose use of the telearm for launch and recovery of the PISCES V submersible on a lift recovery line (with or without diver assistance), or night-time operations with an electro-optical cable using either the HURL ocean floor sidescan, or photo and video system operated at 10 m above the ocean floor. The 1.14-inch diameter cable is also used to operate the RCV-150 garage/ROV system. The garage/ROV system has also been designed to act as a submersible rescue system with a submersible lift capability.

Jan 1, 1992

By Stanley R. Riggs

Onslow Bay is a broad, shallow, high-energy shelf system bounded by the Cape Lookout and Frying Pan shoals. It is generally a sediment-starved shelf system dominated by hardbottoms with a scattered and discontinuous veneer of mobile Holocene sediments. Phosphate-rich beds of the Miocene Pungo River Formation crop out in a belt 150 km long and up to 50 km wide across the continental shelf in Onslow Bay, North Carolina. Previous research has demonstrated that a few of these beds contain vast quantities of potentially economic phosphate resources that occur in the surface and shallow subsurface sediments. Onslow Bay contains five phosphate-bearing beds predicted to include up to 20.7 billion tons of in-place phosphate concentrate with total sediment grades ranging up to 22.9% P2O5 and adjusted average concentrate grades of 29.8% P2O5. These phosphates are lithologically and chemically similar to phosphates currently being mined in the nearby Aurora phosphate district in North Carolina. Various lithologies of the Pungo River Formation and associated rock units of Oligocene and Quaternary age crop out on the sea floor to form extensive hardbottom habitats that dominate almost 100% of Onslow Bay. A large proportion of these hardbottoms appear to be sea floor deserts, whereas others are virtual oases with rich associations of benthic organisms. These important differences in benthic community structure appear to be greatly influenced by one or more of the following variables: 1) geologic framework (geologic formation, hardbottom composition, morphology, and spatial orientation relative to dominant currents and waves), 2) texture, movement, and accumulation of surface sediments, and 3) flow rates and chemical composition of discharged submarine groundwater.

Jan 1, 1992

Massive sulfides discovered in 1991 and further explored in 1993 in the eastern Manus back-arc basin, north of Papua New Guinea, represent one of the few modem seafloor occurrences known to he associated solely with highly siliceous volcanic rocks. As such they are very close analogs of ancient volcanogenic massive sulfide (VMS) ore deposits, and hence an excellent natural laboratory for developing new approaches for land-based VMS exploration. The Manus Basin lies between the active New Britain subduction zone and volcanic arc to its south and the opposed inactive Manus subduction trench to its north. It is being extended in a complex pattern of short neovolcanic zones and oblique transform faults. In its western sector, relatively mature back-arc spreading has created predominantly basaltic segments with characteristics and mineralization generally similar to those of mid- ocean ridges. At its far east, however, the basin is distinctly immature. The East Manus Volcanic Zone lies between two members of the Manus transform set, and is an en-echelon series of neovolcanic edifices constructed on extensionally thinned island arc crust formed during the earlier manus subduction episode. Individual edifices range from predominantly basaltic to predominantly dacitic in composition. Two of the edifices are known to be hydrothermally active, and a particulate plume with unknown source occurs in the seawater column above a third.

Jan 1, 1993

By Akira Usui, Sayuri Kubo, Satoshi Tokeshi, Shingo Kato, Katsuhiko Suzuki, Teruhiko Kashiwabara

"INTRODUCTIONFerromanganese (Fe-Mn) crusts are a kind of marine chemical sediment composed of Fe and Mn oxy-hydroxides as well as small amounts of clastic sediments, which are ubiquitously found on the surface of slopes of seamounts and oceanic plateaus at depths from 900 to 5500 meters below sea level (mbsl). Fe-Mn crusts contain extremely high concentrations of useful minor metals such as Co, Ni, Te, REEs, and thus are expected as submarine mineral resources. Also, Fe-Mn crusts record the change of chemical compositions of seawater during last several tens million years, which allow us to obtain clues to clarify the paleoenvironmental conditions at the time of its deposition. However, occurrence, chemical compositions, microbial community and growth patterns of ferromanganese crusts are yet fully understood. Hence, a comprehensive study on the genesis of ferromanganese crusts, such as growth rates and enrichment processes of elements, is required to better understand their resource potential as well as their applications to paleoceanographic study.Based on the resource potential of ferro-manganese crust, the project entitled “Next- Generation Technology for Ocean Resources Exploration” was launched as one of the governmental projects to develop the exploration technology based on the scientific research on the submarine resources such as hydrothermal deposits (e.g., a poster by Kawada et al.), ferro-manganese crusts. We have made several research cruise to seamounts in the north-western Pacific such as Takuyo-Daigo and Takuyo-Daisan seamounts (Fig. 1) ."

Jan 1, 2017

In the western Woodlark Basin, propagation of seafloor spreading is occurring directly into the continental crust of Papua new Guinea. The spreading is not strictly in a back-arc tectonic setting, rather it appears associated with microplate rotations related to the complex convergence of the Indo-Australian and Pacific plates in the southeastern Pacific region. Volcanic rocks along the western Woodlark spreading axis range from normal mid- ocean ridge basalts to basaltic andesites with back-arc geochemical affinities. Rare peralkaline rhyolites also occur. Hydrothermal deposits occur at a basaltic andesite volcano located on the neovolcanic zone near its westernmost propagating tip. Franklin Seamount is a 250m-high cone constructed largely of pillow lavas and talus which sits astride a 450m-high ridge of similar lavas oriented subnormal to the spreading direction. At its crest, 2150m below sea level, there is a 100m-deep caldera.

Jan 1, 1993