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By Jim Lauder, Russ Calow, Ken Maley, Michael Ounpuu, Stuart T. Caverly

"Stuart T. Caverly, Section Head XRF Laboratory, Jim Lauder, Systems Engineer, Russ Stuart T. Caverly, Section Head XRF Laboratory, Jim Lauder, Systems Engineer, Russ Concession Street, Lakefield, Ontario KOL 2HOAbstractOn-stream X-ray analyzers have become an integral part of modem milling operations. The calibration of these instruments is not difficult but must be performed carefully and with consideration for the principles of X-ray spectrometry. A discussion of successful calibration procedures as well as examples of several common mistakes is presented.IntroductionOn-stream X-ray analyzers (OSA) have become an integral part of modem mineral dressing plants. Advances in instrumentation and computer software make the analysis of process streams fast, accurate and precise. Proper instrument calibration that respects the fundamentals of X-ray spectrometry is essential if the data generated are to be reliable. Often the importance of this task is underestimated and delegated to a person with inadequate XRF training. Successful OSA calibration is the result of careful, systematic procedures.On-stream analysis is perhaps the most important tool that has been provided for the concentrator metallurgist. Combined with powerful, low cost PC's and distributed control systems, real-time elemental analysis affords today's metallurgist many opportunities to troubleshoot and optimize his process.Before OSA, operators had to be very experienced if they were to achieve good results. Even with hourly grab samples, most changes in control approach would still be based on visual cues from the circuit and gut instinct. Real-time analyses have changed that completely.The last two decades have seen a persistent drive to reduce production costs. Operations utilizing OSA have been the most successful in this endeavor. Direct benefits from the application of OSA are fairly obvious. Operators are able to make incremental changes in operational parameters (e.g. reagent addition, pH, cell level), and immediately monitor the effects. Variations in the characteristics of the mill feed can be identified and addressed immediately. More progressive operations have linked analyses to control loops to adjust process setpoints ( e.g. reagent additions), and to change them automatically according to formulas based on previous experience."

Jan 1, 1996

By J. P. Mogan, E. D. Dainty, A. Lawson

"The toxicity reduction of emissions from two diesel engines by the emulsification of water into fuel oil was investigated to determine the applicability of such systems to underground mining machinery. . The engines studied were: 1) the Deut; F6L7J4, four-stroke, air-cooled, 6-cylinder, V-configuration, indirect-injection (IDl) engine, and 2) the Detroit Deisel Allison Division 8V7JN, two-stroke, water-cooled, 8-cylinder, V-configuration, direct-injection (Dl) engine.The application of emulsified fuel treatment to the two-stroke engine did not prove to be practicable. In the case of the Deutz engine, however, substantial benefit resulted. For a modest J5 per cent water content in the fuel and an injection timing of24° BTDC, approximate reductions of40 per cent in the concentrations of both particulate matter and nitric oxide (NO) were produced. These reductions were accompanied by insignificant changes in other toxic constituents. The net result was an approximate 30 per cent reduction in the over-all exhaust toxicity for typical LHD operation as assessed by the Health Effects Index criterion. This toxicity reduction represents a significant advance from the points of view of an improved underground environment and/or reduced ventilation costs."

Jan 1, 1981

By A. Sheikh, S. Hardcastle

"Various methods of leaching are being used by Denison Mines Ltd. Uranium Operations. This study was designed to investigate the flood leaching operation of two parallel inter-connected stopes contained by pressure bulkheads. The teaching muck piles, created from large scale uppers production blasts, are aerated by compressed air lines laid beneath the pile prior to blasting.A SFr, tracer gas, injection technique has been employed to determine the post-blast integrity of the single-ended air distribution system. SF6 was injected into the compressed air line feed to the stopes and collected at borehole exhausts from the stopes in grab-sampling bags. Analyses of the air samples were performed with a gas chromatograph.The system was designed to give a sufficiency of oxygen to sustain bacterial activities used to enhance the leaching recovery in the muck piles. The results obtained indicated that there is a minor anomaly in the distribution system that may not be critical to the operation. Compared to an idealized case, the over-all efficiency of aeration throughout the muck is estimated at over 85%."

Jan 1, 1988

By P. K. Frempong, S. D. Butt

"A case study for the application of a novel geostatistical technique for resource estimation of a narrow steeply dipping, gold-silver mineralized quartz vein deposit is presented. The technique is novel in two respects. First, mineral grades are kriged directly rather via the accumulation method more often applied to vein deposits and, second, a modified 2D ordinary kriging algorithm is used that allows the calculation of a single grade and variance for irregular shaped blocks of varying sizes. The objective of this investigation was to evaluate the suitability of this novel geostatistical technique for resource estimation of the Poura mine deposit and, if appropriate, to lay a firm foundation for future geostatistical work at the mine.The reserve estimation concentrated on the remnant ore blocks and pillars in both underground and surface workings. The data, which was collected in 2D coordinates with grade and vein thickness values, was first analyzed statistically and used to compute experimental semi-variograms. Appropriate semivariogram models were fitted and various aspects of the estimation technique were evaluated using cross-validation error analysis, with acceptable results. A block kriging computer program called Krige2D was developed to implement the modified 2D kriging algorithm and calculations. Production data were not available to evaluate the computed block resources, but they were compared with a previous resource data determined using an arithmetic approach. The geostatistical technique estimated slightly higher grades but lower overall tonnages as compared to the earlier arithmetic estimates."

Jan 1, 2004

A case study for the application of a novel geostatistical technique for resource estimation of a narrow steeply dipping, gold-silver mineralized quartz vein deposit is presented. The technique is novel in two respects. First, mineral grades are kriged directly rather via the accumulation method more often applied to vein deposits and, second, a modified 2D ordinary kriging algorithm is used that allows the calculation of a single grade and variance for irregular shaped blocks of varying sizes. The objective of this investigation was to evaluate the suitability of this novel geostatistical technique for resource estimation of the Poura mine deposit and, if appropriate, to lay a firm foundation for future geostatistical work at the mine. The reserve estimation concentrated on the remnant ore blocks and pillars in both underground and surface workings. The data, which was collected in 2D coordinates with grade and vein thickness values, was first analyzed statistically and used to compute experimental semi-variograms. Appropriate semi- variogram models were fitted and various aspects of the estimation technique were evaluated using cross-validation error analysis, with acceptable results. A block kriging computer program called Krige2D was developed to implement the modified 2D kriging algorithm and calculations. Production data were not available to evaluate the computed block resources, but they were compared with a previous resource data determined using an arithmetic approach. The geostatistical technique estimated slightly higher grades but lower overall tonnages as compared to the earlier arithmetic estimates.

Feb 1, 2004

By James L. Oleson, Hunter R. Propsom, Kevan J. R. Ford, Robert D. Henderson, Bob Musgrove

"Kinross’ Fort Knox Gold mine, near Fairbanks, Alaska has successfully implemented two major metallurgical continuous improvement projects resulting in growth of gold production and an extension of mine life. In 2009, Fort Knox produced 263,153 oz of gold at a cash operating cost of $543/oz. In 2010, approximately 63% of the gold will be produced from the CIP circuit, 15% of the gold from the gravity circuit and 22% of the gold from the heap leach.In 2009, a 44,000 ton per day run-of-mine valley fill heap leach facility was constructed and commissioned as a cost effective treatment option for low grade ores to supplement the higher grade mill. The heap leach facility will produce approximately 100,000 ounces of gold per year under severe winter conditions. Heap leach gold recovery, based on test work shows 30% after a 55-day leach cycle, with long term ultimate gold recovery targeted at 65%. The paper presents the heap leach design concepts and production data.Additionally in 2009, installation of a Knelson gravity concentrator unit (XD70) was completed. This together with an Acacia intense leach reactor (AILR) has increased overall mill gold recovery from 79.3% to 80.7%. A manual shaking table gold recovery operation has been replaced by batch intensive cyanidation of the high grade Knelson concentrates. Increased removal of coarse gold and difficult-to-leach gold species from the grinding circuit, via the gravity circuit, has improved gold leach recovery in the conventional whole-ore tank leach CIP circuit. The paper presents plant operating data, showing the improvements over the old flowsheet.Focus on the metallurgical properties of the high grade and low grade end components of the Fort Knox ore has resulted in significant improvement to gold recovery."

Jan 1, 2011

"INTRODUCTIONThe Kidd Creek Concentrator is located 28 kilometers east of the city of Timmins, Ontario. Two types of ore are treated; 'A' type, a copper-zinc-low silver ore producing copper and zinc concentrates, and 'C' type, a copper-lead-zinc-high silver ore producing copper, lead and zinc concentrates.The ore is processed at a combined rate of 12,400 metric tonnes per day through four parallel grinding and flotation divisions. Three divisions treat the 'A' type ore and the fourth treats the 'C' ore. Each division is fed from its own fine ore bin.This paper reviews the grinding section with specific emphasis on grinding media consumption and the factors affecting it as related to 'A' type ore. At Kidd Creek there was an awareness that grinding media consumption varied on a weekly and monthly basis. The reasons for this variation was usually attributed to ore hardness as evidenced by short term variations in the circuit feedrate and head assays. However, there has been a diversity of opinion published in recent years regarding the factors contributing to steel consumption. This initiated a study of historical Kidd Creek operating data, from the period 1970 to 1986 inclusive, to determine the effect of various operating parameters on media consumption. The results of the study could then be used as a baseline for future media consumption testwork."

Jan 1, 1988

By David E. Pearson

"There are many tests that can be used to characterize and classify coals, and describe their quality. One of the easier tests, and most versatile in its application, is petrography. Rank and coal type are precisely defined by petrographic evaluation, and in this paper they are compared with other definitions of rank and coal type. Brief descriptions are given of the various rank tests, and of rheological and coking tests used to describe coking-coal quality in Canada. Similarly, tests used to evaluate thermal coal quality are discussed. Finally, the use of these tests as parameters to classify Canadian coals is examined with reference to four coal classifications.Introduction Among all coals there are two independent variables that are required to evaluate coal quality. These are, coal rank and coal type (or composition), and although coal petrography can be used to precisely define them, other methods are often used to provide values that are, in fact, functions of rank and coal type. For example, volatile matter yield is used as a proxy for rank, and free swelling index is used as a proxy for coal type in the International Classification of Hard Coals by type. Currently, there are a number of methods in use in Canada to define rank. The approach taken here, (obviously the author's bias), is that Romax, the mean maximum reflectance of vitrinite, is both a quick and an accurate measure of rank. It is logical to compare the other techniques employed in the measurement of rank to this favoured method. Coal type is, in theory at least, simply a quantitative measure of the various varieties of coal. In practice, the microscopic entities are assigned to a Reactive or Inert category, and at that point objectivity fades from petrography. Despite this somewhat subjective approach, petrographic composition of coals remains an independent variable of such.importance that its place in the evaluation of coal is essential. In this paper, a variety of me.thods that are used to assess rank and coal type are reviewed and compared; the influence of these variables over other parameters that are used to determine the quality of metallurgical and thermal coals is examined, and their usefulness in coal classifications is discussed."

Jan 1, 1985

By F. Hassani, K. Moozar, J. Ouellet, P. Gauthier

"This paper describes a sudden spill of waste rock used for backfilling from a waste pass at an underground mine in Canada, thus causing a major failure/accident. The mine operator immediately launched a detailed investigation to understand the causes of this accident and develop procedures to prevent any recurrence of such events in the future. The authors from McGill University were invited to collaborate with the engineers at the mine to examine this accident. The events leading to the accident were studied, appropriate measurements were taken and samples of the waste material were collected for further testing and analysis.The field visit and the interview of the witnesses allowed the detailed documentation of the events. The sequence of events related to the incident, along with the experimental results obtained in the course of the investigation, are presented. The waste material was characterized in the laboratory with regard to its behaviour in the presence of water. This information is discussed and the failure mechanism involved in the accident is identified. Finally, the full recommendations as well as the immediate operational measures implemented by the mine to prevent the future occurrence of such events are presented and discussed."

Jan 1, 2004

By Francis Chachula, Niel Erasmus

"In 2002, Titanium Corporation Inc. focused its attention on the development of a process for the recovery of valuable heavy minerals, including zircon and titanium bearing minerals from oil sands froth treatment tailings. The development of a process flowsheet to recover the titanium and zircon minerals from the Athabasca oil sand tailings has evolved through many laboratory, bench and pilot scale iterations.Initial development work focused on so-called ‘beach sand’ material, which is tailings material deposited over a period of time close to the tailings pipe discharge. The derived process flowsheet primarily consisted of gravity concentration stages, which is typical of all mineral sands operations. Titanium Corporation’s business plan calls for the utilization of tailings directly from the tailings pipeline – the process developed around the beach material is therefore risky as it differs from the live tailings in a number of aspects, with the effects on the process unknown. Titanium Corporation successfully obtained an intermediate product through a ‘bulk sampling plant’ coupled directly to an Oil Sands operator’s froth treatment tailings pipeline, during the summer of 2005. Subsequent further processing of this material resulted in poor separation or concentration of the heavy minerals due to a number of reasons. A more effective process flowsheet had to be developed.The newly derived process is basically a marriage between mineral sands technology and oil sands technology that can economically concentrate and recover the heavy minerals and entails the incorporation of a flotation process that takes advantage of the entrained bitumen in the feed to separate the heavy mineral fraction from the quartz gangue This paper will describe the newly derived process as well as the successful results of a subsequent on-site concentrator pilot campaign completed during the 3rd Quarter of 2006."

Jan 1, 2008

By Paulo F. T. Sachs

ERP systems have been widely implemented nowadays in several industries. However, ERP was originally designed to fit former MRP and MRP II users, and most of the ERP research has been focused on discrete manufacturing . On the other hand, process industries ? and mining in particular ? present many peculiar characteristics, which are difficult to comply with ERP systems standard functionalities. Again, very limited research has been developed covering enterprise management systems in mining. The objective of this paper is to identify, through an explanatory study that includes a case study methodology, how ERP systems manage the functional areas of the mining industry, and how they fit into the mineral value chain IT requirements. A secondary objective is to identify the gaps between ERP?s functional capabilities and the mining industry business requirements, and to point out the perceived benefits they generate to the companies.

May 1, 2004

By Jacques Ouellet, Ferri Hassani

"Within the mining industry paste backfill technology has evolved over the last two decades. This technology aims at producing safe and cost effective backfill of high strength. When used as cemented backfill underground the usual practice in the mining operations was to consider the backfill as a component under the production engineer responsibility. With its growing use in various site conditions some problems were encountered. Over time the mechanical characteristics of paste backfill could deteriorate. Investigations on these problems brought an increased understanding of paste backfill chemistry. Effectively, paste backfill is produced with tailings slurry having sometimes very complex chemistry and mineralogy. The bonding agents can be sensitive to the chemistry of these slurries. Today, a new understanding of the complex chemical reactions involved in cementing paste backfill is derived from concrete research literature. Cemented paste backfill is a manufactured product and as thus all steps involved in its making must be looked at. Both the processing engineers and mining engineers need to be involved. The proposed paper will go over the various developments and new understanding gained over the years on paste backfill chemistry. The authors had the opportunity to work with various Canadian mines that implemented paste backfill in their operations. Chemical alterations case study will serve to illustrate the importance of a good understanding of cement and paste chemistry. The authors will then conclude on research orientations needed to bring a more efficient use of paste backfill technology. The crucial role of the processing engineers in the paste backfill manufacturing will be discussed.INTRODUCTIONPaste backfill is usually prepared from a mixture of solids and water containing at least 15% particles smaller than 20 microns with the addition of binders for mechanical strength. Historically, tailings had been classified to extract the fines and only the coarse part was placed underground as sand slurry. Paste fill was researched in the last three decades to enable mining operations to use all the tailings, including fines, in backfill. The outcome of the early studies showed that paste fill provides high strength but due to preparation complexities and transportation problems is expensive. A greater understanding of the transportation mechanisms and advances in dewatering technology in recent years has resulted in more practical use of paste backfill."

Jan 1, 2002

By A. Dogan Paktunc

Abstract - The Mechanic Settlement pluton is a small body of mafic and ultramafic rocks of tholeiitic affinity, occurring in the Late Neoproterozoic volcanosedimentary rocks of the Avalon terrane of the Appalachian Orogen. The lenticular-shaped intrusion is layered and consists of ultramafic and mafic lithologies in at least six cyclic units that are relatively thin or short-lived. The lowermost exposed portion of the intrusion is characterized by the cumulate sequences of olivine and olivineclinopyroxene and display relatively flat rare earth element profiles. In the overlying lithologies, plagioclase is the dominant cumulus phase following olivine in the crystallization sequence. Olivine ranges in composition from Fo73 to Fo85 and plagioclase from An62 to An89. Variations in the compositions of orthopyroxene and clinopyroxene are within Wo0-4En52-87Fs11-45 and Wo39-50En23-50Fs3-19. These mineral compositional variations in part reflect cryptic patterns and correspond to normal fractionation trends in cyclic units. Elevated Pt and Pd concentrations of up to 2.6 ppm occur in ten zones within the central cyclic series in association with both the peridotitic and gabbronoritic rock types. The mineralized zones are about several meters thick and appear to have lateral continuities over several hundred meters, suggesting that they are stratiform. Platinum-group elements (PGE) occur as discrete platinum-group minerals (PGM) including vysotskite, merenskyite, michenerite, sperrylite, stillwaterite, and hollingworthite that are associated with magmatic sulfides composed of pentlandite, pyrrhotite, and chalcopyrite. PGM grains range in size from a few micrometers to well above 20 µm. Sulfur isotope ratios and the Se/S ratios of the mineralized rocks are typically higher than the mantle values. Sulfide saturation probably occurred as a result of assimilation of crustal rocks and magma mixing during emplacement of subsequent pulses of magma. Repetition of the PGE mineralization in rather thin cyclic units suggests that the replenishing magma probably had high PGE levels and was saturated with respect to sulfide during emplacement. Ingression of the replenishing magma into the chamber in a turbulent plume and its mixing with the resident magma was probably responsible for the formation of the PGE mineralizations in the Mechanic Settlement pluton.

Jan 1, 2000

By N. Kuyucak

"Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. It occurs as a result of natural oxidation of sulphide minerals contained in mining wastes at operating and closed/decommissioned mine sites. AMD may adversely impact the surface water and groundwater quality and land use due to its typical low pH, high acidity and elevated concentrations of metals and sulphate content. Once it develops at a mine, its control can be difficult and expensive. If generation of AMD cannot be prevented, it must be collected and treated. Treatment of AMD usually costs more than control of AMD and may be required for many years after mining activities have ceased. Therefore, application of appropriate control methods to the site at the early stage of the mining would be beneficial.Although prevention of AMD is the most desirable option, a cost-effective prevention method is not yet available. The most effective method of control is to minimize penetration of air and water through the waste pile using a cover, either wet (water) or dry (soil), which is placed over the waste pile. Despite their high cost, these covers cannot always completely stop the oxidation process and generation of AMD. Application of more than one option might be required.Early diagnosis of the problem, identification of appropriate prevention/control measures and implementation of these methods to the site would reduce the potential risk of AMD generation. AMD prevention/control measures broadly include use of covers, control of the source, migration of AMD, and treatment. This paper provides an overview of AMD prevention and control options applicable for developing, operating and decommissioned mines."

Jan 1, 2002

By André van Wageningen

Long term mine scheduling is one of the most difficult optimization problems. The problem is said to be NP-complete in that the best possible solution cannot be found any quicker than checking all possible permutations and combinations. In current mining operations, it is important to report changes in long term plans as soon and as accurately as possible. Where geological data can change rapidly, such as in narrow vein deposits, the need to quickly identify and optimize different long term alternatives becomes a difficult task and can lead to many permutations of the long term mine plan. The question arises, is the new plan optimal or not? Can the company objectives be met while adhering to operational constraints? Although a number of optimization techniques have been used in the past, many include significant simplifications or fail to produce acceptable results within the required timeframe. Genetic Algorithms (GAs) are among the most promising optimization techniques within operations research. They are based on natural selection and evolution of solutions to complex problems. They have been known to quickly converge within a few percent of the optimal solution by examining only a fraction of the possible permutations. The GA itself contains very little problem specific information and, as such, in this study, has been linked to a discrete-event simulation (DES). The DES is able to evaluate each sequence proposed by the GA and determine the effectiveness and value of each schedule. The DES feeds information regarding the feasibility and quality of the solutions back to the GA during the optimization process. In this paper, GAs and DES are described and the coupling of the two methods is outlined. The GADES module is then used to ?optimize? a narrow vein theoretical case study and the results discussed in a broader mining context.

Oct 1, 2004

By L. Connolly, F. R. De Luca

"Rubber liners at Denison Mines Limited are used in 10 1/2x 24' low discharg0 pebble mills. These were originally 10 1/2 x 13 Dominion overflow type ball mills. Experience here shows that the wear of rubber and ni-hard lifters is approximately the same in the feed end half of the mill, while the wear of rubber lifters is much greater in the discharge half. The wear of rubber plates is considerably less than white iron in the feed end half of the Mill and slightly more in the discharge end half of the Mill. Rubber components are lighter to handle but their installation is time consuming. This leads to the conclusion that a combination of ni-hard lifters a~~ rubber plates is the most economical compromise in Denison's case, for the Mill. Rubber discharge grates are superior to steel grates, while steel feed end liners are superior to rubber.The Use of Rubber Mill Liners at Denison Mines LimitedGrinding is done in two identic0al circuits each consist-ing of one 10 1/2 x 14' Dominion overflow rod mill, two Dorr Oliver quadraplex rake type classifiers, two 10 1/2 x 24' Dominion low discharge grate pebble mills and ancillary pumps and conveyors for pebbles. There is one centrally located distributor box that receives the discharge of the 4 pebble mills and splits it out to the classifiers."

Jan 1, 1974

Stress induced, gravity-assisted failure processes typically dominate long before stress levels approach the strength of the intact rock (at approximately smax > 0.4UCS where smax = 3s1 ? s3 and UCS is the Unconfined Compressive Strength of the intact rock (Martin et al. 1999)). Under these conditions, discontinuities typically become clamped and the failure process becomes brittle. This brittle failure process is dominated by new stress induced fractures growing subparallel to the excavation boundary. While it is possible to identify areas with the potential for brittle failure, for example, using the general assumption that brittle failure will occur in areas at right angles to the major principal stress (Hoek et al., 1995), when the threshold smax > 0.4UCS is reached in areas around the tunnel boundary, or elastic modelling and the Hoek-Brown brittle parameters proposed by Martin et al., (1999) (i.e. m? 0 and s ? 0.11), amongst others, recent observations discussed by Everitt & Lajtai (2004), and Kaiser (2005; 2006) suggest that brittle failure processes are enhanced when structural features such as joints, weakness zones, bedding planes or foliations are preferentially orientated around the excavation boundary creating stress raisers which in turn facilitate the stress-driven rock mass disintegration process (e.g., as illustrated by Everitt & Lajtai (2004) on Figure 1b). Such weaknesses induce stress heterogeneities that thus promote tensile-spalling failure processes (Diederichs 2000). The observations suggest that stress induced damage can occur ?prematurely? depending on the orientation of micro and macro structures in situations where the known stress conditions should not yet initiate brittle failure processes. In general, when structural features (micro and/or macro), especially foliations, are present in a rock mass, the strength is effectively reduced, largely due to tensile strength heterogeneity in areas depending on the orientation of the structural features with respect to the excavation boundary. As a result, stress induced damage could occur in areas not normally considered due to the influence of anisotropy (Figure 1).

May 1, 2009

By M. H. Moys, J. A. Finch, A. R. Laplante

"A detailed review of ball milling circuit control practices in industry has been carried out. Based on fundamental process performance objectives, a standard system for base-level control of most ball mill installations is presented. This system is simple, inexpensive, and provides the major economic benefits available from contemporary automatic control technology.Value Analysis of Grinding OperationsValue analysis (or engineering, or management), originally developed by Lawrence D. Miles of the General Electric Company (1), focuses on the identification of value (product or process worth versus cost) and provides a systematic procedure for its improvement. A recent research and development project involving the application of the principles of value engineering to grinding operations has provided a basic technoeconomic model of grinding processes (2). The functional objectives of the ball milling process and the means to achieve value based grinding circuit control originate from this study.The Need for Grinding Circuit ControlThe economic effectiveness of a process is determined by the quality or value of the product and the related processing costs. If the inputs (both the raw feed and the applied processing work) are absolutely constant, the product characteristics and the process efficiency will be determined only by the engineering design. The need for and degree of process control is therefore determined by the nature of variations or upsets in the process inputs, and the extent to which these effect product value and operating costs."

Jan 1, 1988

By Michael B. Cortie

The young field of nanotechnology has as its objective the design and construction of useful devices made of nanoscale materials. Objects or structures which have at least one important dimension in the range 0.5 to perhaps 50 nm may be considered to be in the nanoscale domain. These sizes lie far below the 200 nm or so that can be resolved with an optical microscope, and are closer in size to the 0.3 nm diameter of individual atoms. Nanotechnology, which is the study and exploitation of these tiny structures, is attracting keen interest at present. The excitement is motivated by the observation that control of matter at the nanoscale holds the promise of faster computing, better medicines, and smarter materials. In this paper, the physical phenomena on which this optimism is based are broadly discussed and explained. Where appropriate, examples of the rather different and curious properties of gold at the nanoscale are used to illustrate the points covered.

Oct 1, 2003

By M. -C. Noël, G. P. Demopoulos

In this work the formation and environmental stabilization potential of arsenate-containing fluoroapatites is considered. In particular in this research various compounds were precipitated from synthetic solutions containing fluoride, arsenate/phosphate and calcium by varying different parameters-temperature, Ca:As ratio, pH, and P:As ratio, and aging time. The results obtained helped determine the operating window that should be used for the formation of highly crystalline fluoroapatites, in particular svabite (Ca5(AsO4)3F). It was found that svabite has a specific pH range of precipitation, with lower pH yielding CaF2 and calcium arsenate compounds such as CaHAsO4•H2O. At higher pH, a mixture of svabite and johnbaumite (Ca5(AsO4)3OH) precipitated, yielding a less stable material. This range of precipitation varied with the concentration of arsenic in the starting solution, and widened with higher initial concentrations of Ca2+, AsO4 3- and F-. Furthermore, svabite/fluoroapatite solid solutions were formed by using the same procedure as svabite but replacing some of the arsenate in solution by phosphate. The increase in phosphate content yielded a gradual change in morphology and crystallinity. Work on stability evaluation is currently under way.

Jan 1, 2014