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By J. H. Jensen

Bromine is the intermediate member of the halogen family of elements between iodine, a solid: and chlorine, a gas. The name is derived from the Greek "bromos," meaning stench. Bromine is the only nonmetallic element that is liquid at room temperatures with a melting point of -7.2" C and a boiling point of 58.78" C. Reddish brown in color, it dissolves easily in water to yield a red solution. Bromine volatilizes at ordinary temperatures to a red vapor that is very irritating to the eyes, nose, and throat. Density of the liquid is 3.12 and gas weighs 7.59 gpl at standard conditions. As the element is highly active, it exists in nature only as bromide compounds. Bromine was discovered by Antoine Jerome Balard in seawater bitterns in 1826 and first prepared in quantity in 1860. Distribution Bromine is widely distributed in nature and compounds occur in solution in natural brines, in seawater, saline lakes, oil and gas well brines, and in evaporite chloride minerals. The concentration of bromine salts ranges from 60- 65 ppm in seawater to several thousand ppm in oil well brines and saline lakes. The distribution of bromine in marine evaporite minerals and in the solutions from which they crystallized was determined many years ago by H. E. Boeke (1 908). Theoretical aspects regarding the geochemistry of bromine have been published in numerous papers (Raup and Mite, 1969). Bromine occurs in solid solution in carnallite and sylvite associated in potash de- posits; in halite in salt beds; salt in oil shales; and in trona deposits. Its presence is useful as a guide in geochemical exploration. The analysis of small amounts of bromides in the presence of large amounts of chlorides is discussed by W. Schwerdtner (1963). Manganese, iron, and iodine may interfere with the determination. Other analytical methods are discussed at length in the literature (Stenger and Atchison, 1964). Sources and Reserves The sources and reserves of bromine, given in [Table 1], appear ample to meet present and foreseeable requirements in all producing countries. With the occurrence of bromine salts in sea-water and other brines, the potential for bromine production is worldwide. It has been estimated that 99% of all commercially recoverable bromine is in the ocean. However, actual subterranean brines having a higher bromine content than seawater will continue to be the preferred sources of bromine for the foreseeable future. Markets and Prices About 17% (1968) of bromine produced is used in its elemental form, with the balance consumed as bromides and bromates. The largest use for bromine is ethylene dibromide which, together with tetraethyl lead, are used as an antiknock additive in gasoline. Tetra-ethyl lead is the antiknock agent. Ethylene dibromide combines with the lead after combustion in the engine to form a volatile com- pound that escapes from the engine with the exhaust gases.

Jan 1, 1975

By W. H. Bassett

In considering the effects of reducing gases on hot solid copper the following conclusions have been reached. (1) Depth of deoxidation of copper heated in reducing gas is greater the smaller the amount of cuprous oxide originally present in the copper, the range studied being from 0.015 to 0.136 per cent. oxygen. It is suggested that the reason for this difference in depth of deoxidation is that, when the copper is low in cuprous oxide, the reducing gas is diluted less by the gas that is formed in the reaction than when the copper is high in cuprous oxide; and the greater the concentration of the reducing gas the deeper the deoxidation. (2) The rate of deoxidation is much mire rapid at the beginning of exposure than at the end, a condition especially noticeable at temperatures around 900° C.; that is, deoxidation is retarded as the depth penetrated by the reducing gas increases. (3) Within the accuracy of the experiments arsenic in copper up to 0.5 per cent. has no tendency to increase or decrease the action of a reducing gas on the cuprous oxide present in the copper. IN 1912 pieces of 0.365-in. hard copper rod 1/2 in. long were heated in a porcelain tube in an electric furnace, while illuminating gas was passed through. An approximate analysis of this gas is: FIG. 1.-EFFECT OF TIME AND TEMPERATURE ON DEOXIDATION RATE OF 0.365-IN. COPPER BY ILLUMINATING GAS; COPPER PLUS SILVER, 99.983 PER CENT. Hydrogen 38 per cent., carbon monoxide 30 per cent., illuminants 13 per cent., methane 10 per cent., ethane 3 per cent., carbon dioxide 3 per cent., nitrogen 2 per cent., oxygen 0.4 per cent. After heating for various lengths of time at various temperatures, samples were quenched

Jan 1, 1926

By H. M. Thorne

The Petroleum Experiment Station of the Bureau of Mines at Laramie, Wyo., in cooperation with the University of Wyoming, has in progress chemical and refining studies of Wyoming black oils. In general, these crude oils are characterized by their high sulphur, high asphalt, and low gasoline content and are called black oils because of these properties and their color. Characteristics of the various Wyoming black crude oils, as determined by the Bureau of Mines Hempel method of analysis, have been published.4/

Jan 1, 1938

By H. M. Thorne

The Petroleum Experiment Station of the Bureau of Mines at Laramie, Wyo., in cooperation with the University of Wyoming, has in progress chemical and refining studies of Wyoming black oils. In general, these crude oils are characterized by their high sulphur, high asphalt, and low gasoline content and are called black oils because of these properties and their color. Characteristics of the various Wyoming black crude oils, as determined by the Bureau of Mines Hempel method of analysis, have been pubished.4/

Jan 1, 1938

The HB 2500 hydraulic breaker attachment from Atlas Copco Construction Tools features Krupp percussion technology and a service weight of 2,500 kg (5,512 lbs). This makes it ideal for demolition, tunneling, trenching, foundation work, rock mining and secondary breaking. Suitable for carriers in the 29-to 43-t (32-to 47-st) weight class, the HB 2500 accepts maximum hydraulic flow of 219 L/min (58 gpm) at 18 MPa (2,610 psi) of pressure, and delivers an impact rate of up to 550 blows per minute. The HB 2500 features PowerAdapt, a new system that automatically shuts down the breaker in the event that it receives excessive oil pressure from the carrier.

Jan 1, 2006

By Charles H. Simmons

Two versions of a VF transceiver to aid in location of trapped miners has been developed and tested. The belt worn model was produced in both transmitter and transceiver configurations. In addition, a quantity of the belt worn models were fabricated using aluminum wire instead of copper in order to reduce unit weight. Ten prototypes of a battery cap model VF transceiver were also fabricated demonstrating further unit size and weight reduction while maintaining electrical performance. Samples of- both versions were tested environmentally and the test data is included in this report. While both versions of the VF transceiver are similar electrically, and are constructed using convential manufacturing techniques, the battery cap model realizes a lower total weight, smaller volume and production cost than the belt worn version. Operationally, the battery cap model assures that the VF transceiver will always be with the miner.

Jan 1, 1981

By Sandin E. Phillipson

The Mine Safety and Health Administration?s Roof Control Division responded to a massive ground failure at an underground marble mine in northern Georgia. The ground failure occurred in a benched area that had been abandoned in the early 1990s. It involved the failure of an estimated 19 pillars, in conjunction with a massive roof fall of an undetermined extent that was at least 60 ft high. Pillars in the benched area had been mined nominally 40 x 40 feet to a height of 50 feet ft, with 40-ft mining widths, although it seems likely from measurements and accounts from mining personnel that pillars were even smaller than intended. Average overburden depth was 500 ft, and the rock mass was characterized by three sets of intersecting geological discontinuities that not only defined very blocky conditions that were conducive to pillar spalling and volume loss, but they were also adversely oriented in such a way as to cut diagonally through pillars at a high angle. The recently released S-Pillar software from NIOSH was used to determine pillar safety factors in the failure area and indicated that pillars were undersized for the conditions. S-Pillar was used to assess pillar stability in active areas to evaluate the likelihood of experiencing similar collapses in the future. S-Pillar correctly identified the pillars in the bench area as having been at risk for instability, in light of their ultimate failure. A two-dimensional finite element model was used to evaluate the possible stages of failure and to assess the likelihood of continued failure in the benched area that might affect more distal mine openings. Although stone mines are generally characterized as having more forgiving conditions than those found in softer sedimentary rocks, the failure shares some characteristics with domino-style massive pillar collapses experienced in coal and trona mines. First, the minimum dimension of the benched area approached 350 ft; second, the pillars defined by benching had small width-to-height ratios (0.8), and; third, the pillar failure area was slightly greater than 4 acres. The massive pillar collapse and associated roof fall illustrate the importance of incorporating pillars that have been properly sized for depth and for the final bench height. Furthermore, the designed dimensions must be adhered to during the actual mining process. Finally, the importance of understanding the geological conditions and their effect on the rock mass is critical.

Jan 1, 2012

By Napisporn Memongkol

Syntheses of Al-TiC-Al2O3 and Al-SiC-Al2O3 composites were obtained in situ by carbothermal reduction of mixtures of Al powder, TiO2 powder and activated carbon powders and Al powder, SiO2 powder and activated carbon powders. The reductions were carried out in a horizontal tube furnace under flow of inert gas. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The synthesized products were mixtures of aluminum reinforce with titanium carbide and alumina and aluminum reinforce with silicon carbide and alumina. The effect of the reaction temperature (1000 o C ? 1200 o C) and condition of precursors on the Al powder, TiO2 powder and activated carbon powders and Al powder, SiO2 powder and activated carbon powders were investigated using XRD and SEM method. The synthesized products showed those composites with aluminum matrix and titanium carbide and alumina as reinforced phases and aluminum matrix and silicon carbide and alumina as a reinforced phase was formed.

Jan 1, 2006

By Rob Farnfield, William Birch, Douglas A. Anderson

In the blasting industry, even to the most safety conscious shotfirer, misfires are a constant source of concern. In the United Kingdom, there are two types of misfire, as classified by the Health & Safety Executive. Type A occurs when testing a shot before firing reveals broken continuity that cannot be rectified. However, due to the fact that a majority of quarries use non-electric initiation [i.e. shock tube] that cannot be tested, this type of misfire is very unusual.

Jan 1, 2016

By Iain Finnie

This report is in three parts. The first part presents a review of theoretical models which have been developed to study removal operations for various types of materials. In the second part, a brief summary is given of coal cutting research. The majority of this work has been carried out in Britain using chisel type bits rather than the conical picks which are in general use in this country. However, a comparison of specific energies measured for conical picks in the laboratory and in the mine shows very encouraging correspondence. In the third part of the report, analytical models for coal cutting by picks are suggested. An extension of the British "tensile breakage" theory, developed for chisels, is given for picks. The role of crushing and cutting in coal removal is discussed as a theory which combines the two processes is shown to give reasonable predictions for specific energy requirements. Finally, directions in which the existing theory could be improved are presented and the need for further research is emphasized.

Jan 1, 1977

By J Seppelt, B Akerstrom, A Rice, J Bubnich, T Waters

The Concentrator 1 plant at Cadia transitioned from Cadia Hill open pit to the Cadia East block cave ore body in 2013. As a result of this change, major plant upgrades were required to achieve the desired throughput while treating more competent ore. The 40-foot (40’) SAG mill now receives a feed of predominantly high pressure grinding rolls (HPGR) product with a minor component of secondary crushed ore at a combined F80 of 17 mm. The significant reduction in feed size to the SAG mill has markedly changed the operating characteristics of the mill, which has been extensively studied since commissioning in 1998.This paper examines the operation of the 40’ SAG mill in its new configuration in the Concentrator 1 circuit. Operational stability is highlighted as a significant factor in delivering mill performance, which has been achieved through several key improvement projects utilising a theory of constraints framework. Five years of successful project implementation has progressively lifted the maximum processing rate of Concentrator 1 from the design estimate of 2455 t/h to above 3000 t/h. CITATION:Waters, T, Rice, A, Seppelt, J, Bubnich, J and Akerstrom, B, 2018. The evolution of the Cadia 40-foot SAG mill to treat the Cadia East orebody: a case study of incremental change leading to operational stability, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 217–232 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Charlie Wyche

The British Solomon Islands Protectorate continued developmental work on bauxite deposits on the Islands of Rennell and Vaghena. A feasibility study was completed by Mitsui Mining & Smelting Co., Ltd., and Pacific Aluminum Ltd. (a subsidiary of Conzinc Riotinto of Australia Ltd,), and negotiations with the Government were in progress. The Government will receive a 25% share if the project is realized. It was estimated that the Islands contain 60 million tons of bauxite with an alumina content of 45% to 50%.

Jan 1, 1980

The lignite deposits of the United States represent a huge potential source of fuel for power generation. It has been estimated that lignite constitutes about 24 percent of the remaining National reserves of solid fuel on a tonnage basis and about 15 percent of the reserves on a B.t.u. basis. (See sec. 3, part 1.) The major portion of these reserves is in North Dakota. Lignite has been used locally for domestic heating since the first settlers burned it at forts and fur-trading posts as early as 1855. Some of the first studies of the use of lignite in steam boilers were conducted by the Federal Bureau of Mines from 1910 to 1920 (15, 19) 1/ However, the commercial utilization of lignite as fuel for producing power developed slowly. Not until about 1925 was any really successful lignite industrial fuel-blaming equipment developed. Since then the commercial use of lignite as a fuel for producing power has been increasing steadily.

Jan 1, 1954

By Dave Deglon, Andrévan der Westhuizen

Objectives ?Survey typical Met Accounting streams at the Zincor refinery ?Determine Precision in Metal Conc?s Measurements for Monthly Met Balance ?Determine the Components of Variance in these Met Acc Values (Sampling, Preparation, Analyses) ??Common plant practice? should be mirrored even though not always in perfect agreement with ?laid down procedures? or ?good practice? ?Mass Measurement and Inventory Measurement was considered in less detail ?not reported here

Jan 1, 2005

By J. C. Borland, J. H. Rogerson

Jan 1, 1963

By Philip J. Daynes

As part of the regeneration of the centre of Dublin, a multi-functional development is being constructed on the site of the historic Smithfield Fruit Market. The site is being developed in three phases, and includes one of the deepest basements (10m) constructed in Ireland to date. Until the recent improved economic climate, there has been little requirement for deep basements in Dublin, and this is the first to be constructed entirely within fluvio-glacial gravels and boulders. The difficult ground conditions led to the adoption of a diaphragm wall solution to ensure a watertight construction. Tie-back anchorages are utilised in the temporary case, and the wall is propped by floor slabs in the permanent case. Where required by high bedrock levels, the diaphragm wall is dowelled into limestone bedrock to ensure toe stability. The recorded lateral movement of the wall is significantly below that calculated by numerical analysis. Temporary bentonite cut-off walls were installed to divide the site into discrete sections. The basement was constructed as a tanked structure, and is subject to uplift water pressure. Passive tension minipiles provides an innovative alternative to the standard stressed anchorage solution. This paper describes:- design and construction aspects of the diaphragm wall, tie-back anchorages, and anti-flotation minipiles, together with recorded lateral wall movements,

Jan 1, 2003

By B. P. Watson

Several large falls of ground occur annually in the narrow, tabular stopes mined in the Bushveld Complex. These falls comprise safety risks and cause substantial production losses and compromise efforts to increase productivity. Underground observations in conjunction with instrumentation sites were used to establish the strategic parameters required to describe the rock mass behaviour of shallow-dipping stopes on the Bushveld platinum mines. Existing rock mass rating systems were evaluated using the observations and instrumentation results. None of the current systems adequately described all the relevant geotechnical conditions. Thus a hybrid of several current systems was developed, and the proposed system is discussed in the paper. The new rock mass rating system is termed the ?New Modified Stability Graph? system and follows the method originally described by Mathews et al.1and revised by Hutchinson and Diederichs2.Changes have been made to some of the tables provided by Barton3and to the stress analysis suggested by Hutchinson and Diederichs2. In addition, the logistical regression analysis has been applied to databases, formed using the suggested analyses, for three support resistances and risk levels established.

Jan 1, 2004

By M. G. Corson

THE iron-silicon alloy series has always been one of the most puzzling among the binary alloys. Examining the well known mechanical properties of the iron-rich alloys only we meet the following situation: The ultimate strength and yield point of alloys worked and annealed under the usual conditions represent nearly a straight line function of the silicon content up to 4.5 per cent. silicon (Fig. 1). Starting at the ultimate strength of 35,000 lb. and at a yield-point of 16,000 lb. for pure electrolytic iron, one reaches a -maximum strength of 93,000 lb. and a maximum yield point of 74,000 lb. at 4.5 per cent. silicon. This corresponds to an increase in ultimate strength by 13,000 lb. per each per cent. of silicon added and nearly the same rate applies to the yield point. The data mentioned are taken from the investigation by T. D. Yensen,1 and while they do not exactly corroborate the results obtained by earlier investigators, they seem to be the most correct. Plastic properties of the alloys are controlled by a much more complicated relationship. Up to 2.5 per cent. Si, the elongation stays close to 50 per cent. (in 2 in.) and the area reduction amounts to 85 per cent., a situation that forms the usual feature of all alloys representing strictly solid solutions. The plasticity of the latter is always nearly equal to that of their base metal. Beyond 2.5 per cent. silicon, the situation becomes much more complicated Yensen observed an enormous drop in elongation and area reduction at about 2.65 per. cent. silicon, where the first hardly reaches 10 per cent. and the second is still lower; he found, however, a considerable recovery in plasticity at about 2.8 per cent. Si and up to. 4.5 per cent. Si it is represented by 20 per cent. for the elongation and 30 per cent. for area reduction.

Jan 1, 1928

By Haukka M. T

A new low-dilution fusion method which has been successfully used for accurate determination of the major oxide components of silicate rocks, is applicable to rapid, accurate determination of trace or minor eiements in mineral exploration samples. Limit of detection is in many cases less than 5 ppm. Either rapid, approximate measurement and calculation methods (suitable for geochemical exploration), or more accurate methods (applicable to orebody evaluation studies) may be used.Rapid methods are described for nickel in rocks and sulphides containing 10 ppm to >2 per cent Ni, and for gallium. The rarely-determined element gallium is an example of a constituent which may be easily investigatedby XRF using the LiB02 fusion disc, which is a permanent, easily-stored analytical sample available for later rapid or accurate analyses. The method is applicable to over 30 elements at levels encountered in mineral exploration.

Jan 1, 1978

Reports by researchers in government, industry, and universities of the United States are given for various projects on basic coal research concerning, the metamorphism, physical and chemical properties, and reactions of coal, and how many of these studies can lead to better utilization of coal.

Jan 1, 1968