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By Anna Paula Littig Berger

O objetivo deste artigo é analisar a influência das fases presentes nas misturas iniciais e finais na eficiência de desfosforação do ferro-gusa. Foram realizados 8 experimentos no forno de resistência, na temperatura de 1400°C, e além disso foram feitas simulações no software FactSage 6.4. Como resultado, obteu-se que as misturas DP3 e DP4 são as mais eficientes, possuindo tanto na mistura inicial quanto na final saturação em CaO, ou seja, atividade do CaO igual a 1; atividade de FeO maior possível e maior quantidade de fase líquida possível. As misturas com fases sólidas DP5 a DP8 apresentaram menor eficiência de desfosforação, pode-se concluir então que as fases sólidas diminuem a eficiência de desfosforação em processos reais, apesar de reterem mais fósforo no equilíbrio.

Aug 17, 2017

By Steven R. Ruggieri

This report documents the work performed and the results obtained during the field demonstration of the Remote Sealing System at the USBM's Jenny Mine near Inez, KY in the Fall of 1978. Although various portions of the Remote Sealing System had been used on a number of prior occasions, the field demonstration at Jenny Mine marked the first use of the complete upgraded system including the use of the inert gas generating system for seal placement and the first application of the new froth foam system. The objective of the field demonstration at Jenny Mine was to demonstrate the complete system by emplacing and evaluating several complete underground seals under conditions representing those of a mine fire situation. Several critical sealing conditions were identified including: ? High entry airflow ? Standing water (1 to 2 ft) in the entry ? Flowing water (150 gal/min) ? Irregular roof ? Sealing a 4-way intersection. Four seals were successfully placed under the conditions mentioned above. The demonstration served to verify proposed techniques to handle these conditions as well as to dispel any doubts about the system's capabilities. As a result of the successful field demonstration, the Remote Sealing Equipment is now under the jurisdiction of MSHA's Mine Emergency Operation ready for a mine fire emergency.

Jan 1, 1980

By Paulo Augusto Cota Leite

Os aços inoxidáveis martensíticos, em geral, aliam boas propriedades mecânicas e satisfatória resistência à corrosão, características associadas à possibilidade de realização de tratamentos térmicos de têmpera e revenimento. Nesse contexto, no presente trabalho foram avaliados os efeitos das condições desses tratamentos na microestrutura e nas propriedades mecânicas de um aço inoxidável martensítico de médio teor de carbono. Foram consideradas três temperaturas de aquecimento na têmpera e seis temperaturas de revenimento. A avaliação microestrutural foi realizada por meio de microscopia óptica e microscopia eletrônica de varredura. As propriedades mecânicas foram avaliadas por meio de ensaios de dureza. Foi observada a elevação na dureza do aço com o aumento da temperatura de aquecimento na têmpera, assim como a dissolução dos carbonetos presentes no material. No revenimento subsequente observou-se o aparecimento do pico de dureza referente ao endurecimento secundário a uma temperatura de 500°C.

Aug 17, 2017

By Gerald H. Luttrell, Mohammad Rezaee, Roe-Hoan Yoon, Rick Q. Honaker, Aaron Noble, Abhijit Bhagavatula, Michael J. Kiser

A field study was undertaken to experimentally measure the concentrations of rare earth elements (REEs) contained in the process streams generated by a group of 20 coal preparation plants located in the eastern USA. For each site, representative samples of clean coal product, coarse refuse, and fine refuse were collected. Each sample was then partitioned into preselected size and density classes by wet screening/sieving and float-sink testing. The resultant products were dried and subjected to laboratory analyses to determine ash contents and rare earth element concentrations including Yttrium and Scandium. A detailed analysis of the database generated by this exercise showed that coal-based products from these preparation plants contained significant quantities of rare earth elements. In particular, the coarse refuse streams currently discarded by the 20 plants examined were found to contain a sufficient tonnage of REEs to satisfy the current domestic demand for these important elements. The data also showed a strong positive correlation between ash content and REE concentration, which suggested that the primary association of REEs in eastern USA bituminous coal sources is likely within fractions containing inorganic impurities. This association was well described using a simple power equation relating ash content and REE concentration. The ratio of heavy-to-light rare earth elements was discovered to be significantly higher in organically rich fractions of clean coal, suggesting that mineral impurities intimately associated with carbonaceous matter have elevated concentrations of heavy rare earth elements. A similar trend was observed for a grouping of rare earth elements (Y, Nd, Eu, Tb, and Dy) that are likely subject to near-term supply shortages. Finally, the database showed that a linear correlation existed between La for many REEs of interest, although there were several notable exceptions for some high-value REEs (Lu, Pr, and Tb).

By S. Gallagher, A. Mayton

Introduction The mining industry has long been associated with a high incidence of low back disorders and pain (Klein et al. 1984, Leigh and Sheetz 1989, Brinckmann et al. 1998). It is believed that the higher incidence of these injuries among miners is the result of high exposures to postural demands, heavy manual work, and exposure to whole-body vibration (WBV). Recent work has indicated that miners involved with heavy lifting (especially in restricted spaces or on uneven ground) or who have been exposed to whole-body vibration in undamped seats experience noticeable changes in their spines that are consistent with degeneration of the intervetebral discs of the spine (Brinckmann et al. 1998). As will be described shortly, there is mounting evidence that disc degeneration plays a large role in the development of low back pain, particularly chronic back pain. Until fairly recently, medical doctors generally assumed that back pain was the result of muscle strain, ligament pain, or so-called “trigger points” (Bogduk, 1997). However, research supporting these mechanisms of pain has been very scant. When subjected to scientific scrutiny, none of these mechanisms has been shown to relate to back pain in a convincing manner. On the other hand, there are three mechanisms that have been shown to be highly associated with back pain in controlled scientific studies: sacroiliac pain (present in 13% of back pain sufferers) (Maigne et al. 1996), facet joint pain (present in 15 % of back pain sufferers) (Schwarzer et al 1994), and disc disruption and degeneration (present in 39% of chronic back pain sufferers) (Moneta et al. 1994). The latter mechanism, which bears the highest relationship to back pain that has been objectively demonstrated, will be the focus of this section. Scientists now believe they have a good idea how back pain may develop in cases involving disc disruption and degeneration (Bogduk 1997). As the spine experiences loading during lifting tasks or whole body vibration, the first structure to fail is called the vertebral endplate, which is a structure that attaches the disc of the spine to the vertebral body (Figure 1). The endplate typically experiences a fracture, which the body will attempt to heal by means of scar tissue. Unfortunately, this scar tissue impedes the flow of nutrition to the disc itself (discs are dependent on nutrition from the vertebral bones), and if the supply is reduced sufficiently, the disc will start to degenerate. As this degeneration process proceeds, fissures or tears in the fibers of the disc start to develop. If any of these tears is a grade 3 fissure (Figure 2), an inflammatory response occurs in the disc, which will lead to the well-known sensation of low back pain (Peng 2006).

Jan 1, 2007

By A. W. BELDEN

Among the investigations that the Bureau of Mines is conducting witha view to increasing efficiency in the utilization of fuels belonging to or for the use of the Government is an investigation of the processesthat take place in a foundry cupola during a melt. Some observations on the results of cupola tests of cokes at the Government fuel-testing plant in St. Louis, Mo., the coke being fromcoal from many coal fields of the United States, have been stated in a previous bulletin.s Especial attention was given to the meltinglosses that resulted from the use of different grades of coke, light and porous or heavy and dense. These losses amounted in one instance to 52.5 per cent of the iron charged and showed, in convincing manner, the need of exact information in regard to conditions in the fuelbed of the cupola.b Melting losses of iron have been fully appreciated but little under-- stood. The fact that these losses were possible with either light or heavy coke led to the belief that by using small charges 80 placed that. melting would take place in that zone of the cupola where the highest heat and the smallest percentage of oxygen prevailed and by confiningall melting to this zone these losses would be eliminated and the economical use of practically any coke produced for metallurgical purposes would become possible. This widening of the field from whichcoke might be drawn for foundry purposes would serve to place the foundryman in an independent position as regards his source of supply, and would tend to conserve the better grades of coking coals, which are being rapidly exhausted, by making the poorer grades available for mixing with them. In order to investigate conditions within a cupola, the Bureau of Mines as a first step decided to install a commercial cupola, to sample the gases during their travel from the tuy~res upward, and to determine the temperature of the fuel bed.

Jan 1, 1913

By Dale Matthews

The Getchell Mine, near Winnemucca, NR, was discovered in the 1930s and was initially mined to recover gold from oxide ores. During the 1940s and 1950s, gold was recovered from the highly refractory arsenic sulfide ores using horizontal kilns to roast the ores. During the 1960s, fluid bed roasters were used to oxidize the ore and recover the gold. The mine was shut down from 1968 through 1985. In 1985, heap leaching was started on the low-grade oxide ores that were available. In 1989, a pressure oxidation circuit was started to recover gold from the higher grade sulfide ores. Flowsheet The basic plant flowsheet of the Getchell Mine are shown in Figs. 1 and 2. The plant was designed to process a nominal 2.7 kt/d (3000 stpd) of ore with about an 85% onstream availability and a gold production of 15.5 kg/d (500 oz/ day). Run-of-mine (ROM) ore is fed directly to a wet semiautogenuous grinding (SAG) mill after the +457-µm (+18in.) rock is removed on a stationary grizzly. From the SAG mill, the ore goes to a ball mill where it is ground to 80% -75 µm (-200 mesh) and is then sent to a thickener. The SAG and ball mill operate in closed circuit using cyclones.

Jan 1, 1994

By Ramana G. Reddy, Yuxiang Peng

The long-term corrosion behavior of Haynes 230 (H230) alloy in MgCl2–KCl eutectic salt was evaluated at 1273 K for 500 h in Ni crucible in argon gas. The results showed H230 alloy has good corrosion resistance. In addition, corrosion was noted to occur by depletion of Cr, which was deposited on the Ni crucible. Based on the calculation of Gibbs energy of Ni-Cr alloy and exchange current density of Cr in MgCl2–KCl, the Tafel model was constructed to investigate the corrosion potential and rate. The galvanic corrosion can be explained as the predicted results were in agreement with the experimental data.

Mar 1, 2017

By C. Musingwini, A. S. Nhleko

"Since the Global Financial Crisis (GFC) in mid-2008, capital has been more difficult to access. Mining projects must contend with projects from other industries for scarce capital. A decision to invest available capital in mineral projects requires that valuation be conducted to assess the expected return on the projects. The discounted cash flow (DCF) analysis is generally applied for the valuation of mining projects, whereby future cash flows are discounted to present value using an appropriate discount rate. The discount rate significantly affects the outcome of a valuation. Economic and finance theory provides tools to calculate discount rates. The discount rate must account for factors such as the risk and stage of development of the mineral project; hence the appropriate discount rate to utilize in a project is often a subject of debate.The discount rate is the weighted sum of the cost of debt and equity. There are several methods for determining the cost of equity. This study considers the commonly applied Capital Asset Pricing Model (CAPM) and Gordon’s Wealth Growth Model because of their simplicity and availability of parameters required to estimate the cost of equity. This study explores how differences in the cost of equity obtained by these two methods can be explained for a mining environment. Data for empirical analysis were collected from the I-Net Bridge, McGregor BFA, and Bloomberg databases. It was found that Gordon’s Wealth Growth Model provides better estimates of the cost of equity compared to the CAPM under depressed market conditions. Therefore, this research recommends that Gordon’s Wealth Growth Model be used to estimate the discount rates for mining projects during periods of depressed market conditions."

Jan 1, 2016

By C. J. Wilhelm, John M. Devine

"Hydrogen aulphide associated with natural as was noted as early as at Point Albino, Canada. 4 The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence ma by no means common. However, in recent years, with the development of the producing zones of west Texas and the Texas Panhandle the production of ""sour"" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor-frequently a major problem—in the drilling and operation of any wells in those areas.The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen sulphide. From the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. 5 Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.6"

Sep 1, 1931

By M. Dayne Aldridge

A discussion of the definition of automation in mine ventilation applications is presented. The results of theoretical studies, experiments and practical experience from work in the United Kingdom, Belgium, Poland, the Soviet Union and the United States are summarized. Conclusions are drawn from these efforts and the prospects for the future development of automatic mine ventilation systems are explored.

Jan 1, 1978

By LUIS EAIYLNN SALAS

IF the ordinary wet method be attempted for silver-bullion containing tin, much trouble is experienced, varying with the amount of tin present. Even with a percentage as low as 0.05, the end-point is masked by a persistent turbidity, while with amounts ranging from 0.5 per cent. upward, the determination of the exact end-point is impossible, owing to the finely divided or colloidal metastannic acid resisting all efforts to cause it to settle, or to give a clear supernatant liquid. The object of the following experiments was to seek a remedy for these difficulties, and to find the conditions whereby the Gay Lussac method might be applied directly to these bullions. Material containing tin is met with frequently in bullion from Mexico or Bolivia; and tin is carried (sometimes in large quantities) in jewelers' sweeps. 1. A bullion was prepared containing Ag, 74; Cu, 25; and Sn, 1 per cent. A weighed amount was treated by the humid assay-method as if it were an ordinary bullion free from tin. Ten cc. of HNO3 (1.21) was added, and the bottle was heated until all traces of red fumes had been expelled. Before heating, the solutions were moderately turbid; and after heating, the turbidity greatly increased. One hundred cc. of normal NaCl solution was added and the bottle was shaken vigorously at intervals during 30 min. The turbidity persisted. The bottle was allowed to stand over

Mar 1, 1912

By I. A. Mwamba

Plain and alloyed titanium aluminides of composition Ti-47.5 at.% Al were prepared by melting commercial-purity titanium and aluminium with additions of 1 at.% precious metal. The as-cast alloys were subjected to potentiodynamic scans in 5, 15, and 25 wt% HCl aqueous solutions at room temperature and compared for their abilities to spontaneously passivate. Addition of precious metals resulted in a general improvement of corrosion resistance by increasing the open circuit potential to more noble values. Addition of 1 at.% gold or silver to titanium aluminide did not significantly increase the corrosion potential (Ecorr) above that of the plain titanium aluminide alloy, indicating that gold and silver are not sufficient cathodic modifiers to improve the corrosion resistance of titanium aluminide in all the solutions tested. However, platinum, palladium, and iridium additions shifted the corrosion potentials to the position of the passive region of plain TiAl for all solution concentrations. This indicated that TiAl alloyed with these platinum group metals would passivate spontaneously by cathodic modification. TiAl alloyed with palladium performed the best in 5 wt% HCl solution with the most positive corrosion potential. In 15 wt% HCl solution, alloys with platinum exhibited the most positive corrosion potentials, while alloying with iridium or palladium revealed more negative corrosion potentials. Thus, palladium alloying led to the best cathodic modification of titanium aluminide in low-concentration HCl solution, whereas platinum and iridium alloying additions resulted in the best cathodic modification of titanium aluminide in high-concentration HCl solutions.

Jan 1, 2013

By Júlia Beltrami

O trabalho estudou a formação, a interação com a escória e a solidificação de inclusões geradas durante o processamento de aços dual-phase com alto teor de silício (>1%). A composição destes aços, se não bem controlada, pode gerar inclusões sólidas de sílica pura durante o lingotamento contínuo. Para o estudo, foram feitas simulações termodinâmicas com o software computacional FactSage 6.4. As simulações mostraram que os fatores mais importantes para a composição inicial das inclusões é a relação %Mn/%Si e o teor de alumínio dissolvido no aço. Ao interagir com a escória, a tendência é que as inclusões se aproximem da sua composição ao longo do tempo. Durante a solidificação, a maioria das inclusões apresentou fases deformáveis e de baixo ponto de fusão, com exceção das inclusões sem CaO e da inclusão com 25% de Al2O3 e teor intermediário de CaO, que apresentaram as fases tridimita, coríndon e gehlenita de alto ponto de fusão e não-deformáveis.

Aug 16, 2017

The Cutoff grade optimization is very critical to the open pit production scheduling. In case of single mineral deposits, algorithms have been developed for determining cutoff grade policy that maximizes the net present value (NPV) of yearly cash flows. For deter-mining the cutoff grade policy for projects with two minerals including stockpiles the problem becomes much more complex. The purpose of this paper is to present fundamentals of a generalized cutoff grade optimization algorithm that will maximize the NPV of a project subject to mining, milling, and marketing constraints. Benefits of the methodology developed are demonstrated on three different case studies.

Jan 1, 1997

The above referenced contract between Badger Manufacturing Corporation and the U. S Bureau of Mines was executed June 30, 1975, as a result of the request for proposals for innovative machine concepts. We selected the cutting machine category because of the obvious lack of technical progress in this field for many years: Phase I of the contract required blasting fragmentation tests to determine proper blasting patterns for use with the auger-type kerf cutting machine. Phase II required design concept development for a machine capable of cutting a circular void as an aid to blasting.

Jan 1, 1975

By M. J. Adam

The Bureau of Mines is investigating the feasibility of partitioning complex sulfide minerals to simpler sulfide phases by sulfidation reactions. Such partitioning can afford opportunity to improve selective extraction of mineral constituents of value. This report describes research involving sulfidation partitioning of byproduct chalcopyrite concentrates from Missouri lead ore processing, and a Utah chalcopyrite concentrate from Cu ore processing. Small chalcopyrite samples were sulfidized with elemental S in glass capsules sealed after evacuating and backfilling with He, by heating for 1 to 24 h at specific temperatures in the range of 250? to 500? C, extending from below to above the boiling point of S (-4450 C).

Jan 1, 1987

By Peter Price

Introduction The Horne mine, the property of Noranda Mines, Limited, has in the last six years become one of Canada's leading gold and copper producers. Since the smelter was blown-in during December, 1927, up to the end of 1933, it has produced approximately 1,200,000 oz. of gold and 35O,OOO,OOO lb. of copper. The property is situated within an area occupied entirely by pre-Cambrian rocks and characterized by the complexity of rock types and structures common in such terrain. But apart from this the mine also presents other features of unusual interest in the size, number, and variety of the ore-bodies, the mineralogical associations, and the rather exceptional values both in gold and copper. It is not surprising, therefore, that a study of the geology of the mine should bring to light many interesting problems. The present paper summarizes, as concisely as possible, the results of such a study. Actually, it is a much abridged version of a more comprehensive and detailed paper completed by the writer a year ago (1), but embodying certain corrections and additional data made possible as a result of further development at the mine and of field work carried out during the summer of 1933. Owing to limitations of space, the paper is, in the main, a presentation of conclusions arrived at in the course of the study. Much of the supporting evidence cited in the thesis referred to has, of necessity, been omitted here.

Jan 1, 1934

By J. B. Gayle

The Bureau of Mines studied the effects of air oxidation on the recovery of float coal. Both batch-and continuous-type tests were made on six bituminous coals, representing the range in rank of coals now commercially used for carbonization, and on one anthracite coal. The effects on flotation recovery of oxidation at 1000 C for periods up to 50 days were investigated using an alcohol-type frother and a kerosine-pine oil reagent. Two series of release analysis tests were made, using one medium-volatile bituminous coal. Float coal recovery was adversely affected by oxidation in all tests where the alcohol-type frother was used. Conversely, a small degree of oxidation improved recovery with kerosine-pine oil frother for some of the coals in continuous tests. Prolonged oxidation (beyond about 14 days) adversely affected float coal recovery for all coals, the effect being more pronounced for batch-type tests and for tests using alcohol-type frother. Reagent selectivity for the rejection of both ash forming and sulfur bearing minerals was reduced by oxidation. Severe reduction of reagent selectivity required only about 3 days' oxidation for alcohol-type frother but more than 10 days' oxidation when the kerosene-pine oil reagent was used.

Jan 1, 1965

By I. Moreno-Ventas, G. Ríos, J. C. Fernández-Caliani, M. Bacedoni

"This paper delves into the constraints on the nature, origin and thermal evolution of the accretions formed in the uptake shaft of the flash smelting furnace operated by Atlantic Copper in Huelva, Spain, outlining recommended practices for preventing accretion buildup. The accretions were investigated using quantitative electron probe microanalysis, X-ray diffraction and digital imaging techniques, and the experimental data on mineral composition, crystal chemistry and textural relationships were interpreted in terms of thermodynamic phase equilibrium in the SiO2-Fe-O-S system. The results suggest that two distinct types of accretions were formed by the fractional crystallization of two coexisting immiscible melts, under changing conditions of oxygen partial pressure (pO2). The type I accretion of magnetite + delafossite ± cuprite ± tridymite ± metallic copper crystallized from a fractionating copper-rich melt at pO2 above about 10-5 atm, while the type II accretion of magnetite + fayalite + metallic copper + chalcocite derived from a melt with lower copper concentration when pO2 levels dropped below that critical level. Phase compositions and textures were consistent with a cooling history of both compositionally contrasting liquids from about 1,250 °C, the liquidus temperature of magnetite, to eutectic or near-eutectic temperatures of around 1,100 °C. The maintenance of appropriate temperatures — above the liquidus temperature of magnetite — and oxygen partial pressure levels may be critical for the prevention of accretion buildup. IntroductionCopper flash smelting with oxygen-enriched air, an autothermal process developed half a century ago by Outotec (Espoo, Finland), formerly Outokumpu, currently accounts for about 50 percent of the world’s primary sulfide-based copper (Schlesinger et al., 2011). The partial reaction of copper sulfide concentrates produces two separate molten streams, copper-iron-sulfide matte and iron oxide-rich slag, and releases sulfur dioxide (SO2) gas. The matte is sent to converters to remove the remaining iron and sulfur, leaving blister copper with grade of about 99.5 percent copper (Cu), which is cast into anodes for electrolytic refining.The SO2-rich gas generated by the oxidation of sulfide feed particles contains a significant proportion of dust that is entrained in the process off-gas. The gas from smelting is transferred into a waste heat recovery boiler, where it is cleared of dust and cooled before it is converted into sulfuric acid. If the process is not operated properly, the dust-bearing gas may form accretions between the uptake shaft of the flash smelting furnace and the waste heat recovery boiler, causing severe problems in the gas handling system (Swinbourne, Simak and Yazawa, 2002; Miettinen, 2008; Stefanova et al., 2012). Removing the dust accretions usually requires a greal deal of time, effort and resources. Understanding the buildup of accretion may help in reducing the problems and optimizing the process"

Jan 1, 2017