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By R. E. Mussier

This investigation was made to study new methods to prepare high-purity yttrium metal, Various methods were used to prepare pure intermediate compounds, primarily chlorides, bromides, and iodides, which were subsequently reduced to metal. The process found most suitable for the preparation of pure anhydrous yttrium chloride involved thermal dehydration of a mixture of hydrated yttrium chloride and ammonium chloride while under vacuum. Yttrium bromide and iodide were prepared most effectively by the direct halogenation of yttrim carbide. Yttrim carbide was obtained by reacting and melting yttrium oxide-carbon mixtures in a carbon-arc furnace. Yttrium halides were purified by vacuum distillation and reduced by alkali or alkaline-earth metals. Lithium and sodium proved to be the best reductants from the standpoint of yield (>95 pct) and purity (>99.8 pct) of the yttrium. The product of the reduction step was sponge metal, which was consolidated readily by conventional cold-mold, arc-melting procedure. The purest yttrium obtained in laboratory scale work was prepared by sodium reduction of yttrium chloride and contained only 125 pp oxygen; other impurities did not exceed 1,000 ppm. In larger scale tests yttrium containing only 800 to 1,000 ppm total impurities was obtained by lithium reduction of yttrium chloride. The tensile properties of high-purity yttrium were determined. Mechanical tests showed that yttrium can be forged, extruded, rolled, spot welded, and deep drawn.

Jan 1, 1963

By W. G. Pariseau

A two-dimensional finite element program has been modified and extended to account for some of the rock mechanics complexities associated with single entry development of longwall coal mine panels. Program capability includes arbitrary assignment of element properties without regard to element ordering, anisotropic elastic, plastic and brittle rock properties that may be time dependent (aging), arbitrary mining sequences and provision for the effects of artificial support on the adjacent strata. Failure is according to an extended von Mises criterion that may be linear or quadratic in form; flow rules are obtained from the yield function taken as the plastic potential, but brittle behavior is treated as a discontinuous process of material properties change with deformation. In either case the extent of failure is calculated from the external boundary conditions. Application of the program to essentially two-dimensional problems resulted in lose agreement between calculated displacements and field measurements in the double entry system. Bleeder entries were stable in one locality and not in another. Artificial support had little influence on stability.

Jan 1, 1978

By Paul Sterling

1. INTRODUCTION. THE general impression regarding the preparation of merchantable anthracite is that it is confined to a colossal, grimy structure, called a "coal-breaker." This name is misnomer; for the desired result is not to break the coal, but to prevent its being broken. Preparation may be said to begin at the face of the chamber, with the mining and loading of the coal. Local conditions vary, not only in the same field or basin, but also in the same mine, so that there is no fixed empirical rule governing the method of blasting or cutting coal. Tests should be made, when possible, to determine the explosive, or the mechanical coal-cutter, which will produce the largest percentage of what are locally known as " lump " and " prepared sizes " of anthracite. The prepared sizes are those mostly consumed for domestic purposes. All other sizes might be called by-products of the anthracite industry; for they are not especially desirable, being the degradation resulting from the mining and handling of a brittle or laminated material. Being low in volatile combustible matter, anthracite burns most successfully when nearly of a uniform size, permitting the easy passage of air through the voids. This accounts for the large number of sizes into which the coal is separated. Table I. gives the various sizes, the diameter of ring over and through which each size is made, and the usual purpose for which it is employed.

Oct 1, 1911

By J. S. Coffman

Wyoming is estimated to have more than 700 million tons and Utah more than 2.5 billion tons of +10 percent P2O6 phosphate rock considered to have some future economic potential. In Wyoming, the +24 and +18 percent P205 rock potential resources total nearly 250 and 450 million tons, respectively. In Utah, the +31, +24, and +18 percent rock total approximately 33 million, 222 million, and 2.2 billion tons, respectively. These resources are all located above the local drainage levels and do not include latent resources. All of the mining and beneficiation of phosphate rock in the two States is done by San Francisco Chemical Co. The facilities include open pit mines at Vernal, Utah, and Leefe, Wyo.; an underground mine in the Crawford Mountains, Utah, and beneficiation plants at Leefe and Vernal. One of the principal markets for the phosphate rock is Western Phosphates, Inc., fertilizer plant at Garfield, Utah. Recent exploration and development has been under-taken by different companies in the Southeastern Wind River Range, Sublette Range, and Crawford Mountains. The facilities at Leefe and Vernal are in the process of expansion. Some of the areas of western Wyoming contain vast quantities of phosphate rock in minable units, but, because of their remote location, are classed as latent areas. In these areas, there are estimated to be about 700 million, 2 billion, and 3 billion tons of phosphate rock in the +24, +18, and +10 percent P205 grade classes, respectively. The Snake River Range of Idaho and Wyoming is also estimated to contain roughly 21, 106, 177, and 214 million tons of potential resources in the +31, +24, +18, and +10 grade categories, respectively. This area also contains a large amount of latent rock in the more remote areas.

Jan 1, 1967

By S. R. Crane

One Bureau of Mines goal is to minimize the undesirable environmental impacts associated with industrial plants emitting waste gases containing S02. To help meet this goal, a regenerable flue gas desulfurization process was developed. This process, known as the citrate process, uses a buffered weak acid solution to absorb S02 from the waste gas. The absorbed S02 is reacted with H2S to precipitate elemental sulfur and regenerate the solution for recycle. The H2S feedstock for the process, if not otherwise available, may be produced by reacting two-thirds of the recovered elemental sulfur with natural gas and steam. Laboratory investigations and pilot plant operations were conducted by the Bureau to determine if H2S from the natural gas, sulfur, and steam reaction was suitable for the citrate process. The laboratory investigations, in which an H2S generator was integrated with other citrate process operations, provided a basis for design and operation of the pilot plant. The objective of the pilot plant was primarily to provide H2S for the citrate pro-cess pilot plant at the Bunker Hill Co. lead smelter in Kellogg, Idaho. The design capacity of the pilot plant was 0.4 to 1.25 tons of H2S per day. The operation demonstrated that (1) a 77-to 79-dry-volume-percent H2S product could be produced from pilot-plant product sulfur, natural gas, and steam; (2) the product R2S regenerated the SO2-loaded citrate solution; and (3) under certain conditions over 95 percent of the natural gas could be converted to H2S.

Jan 1, 1981

By B. Radwanek-Bak

The assurance of future raw materials supply to the EU mineral industry has become, in recent years, one of the most important tasks of the EU Commission. It is focused on creation a new mineral policy within the EU zone. One of the starting points for this activity was identification of the mineral commodities that are critical for the sustainable development and technological progress. The paper presents the glance to this problem from the National Member level. Domestic mineral reserve base as a possible source of critical raw materials for the EU was shown. Poland cannot be considered as its resource base. The source of these raw materials are not only scarce in Poland, but also they are not produced, and their demand is now - and according to forecasts is going to be in the future - met by imports. The raw materials in question are not considered exactly critical for Polish economy, but they are of limited economic importance. On the other hand, their growth is a best opportunity and at once the need to the future sustainable development.

Jan 1, 2011

By D. N. Nilsen

A mathematical modeling method was developed by the Bureau of Mines for the prediction of the principal equilibrium species in the solvent extraction of copper. The use of models for predicting the amount of metal extracted can reduce the amount of experimental work required to characterize a system for purposes such as optimization studies. Models were developed for the extraction of copper from ammoniacal sulfate and carbonate solutions with commercially available extract ants commonly used by industry. Results from laboratory shakeout tests compared well with predictions of the equilibrium concentrations of copper and pH values. For example, the loading of copper onto the solvent was predicted for most cases within ±S pct of the measured values, and the pH to with-in ±O.l pH unit in sulfate systems and ±O.2 pH unit in carbonate systems. Both mechanistic and empirical extraction equations were developed from laboratory data for copper and ammonia. The empirical-based models were slightly more accurate than were the mechanistic-based mod-els. Industrial level concentrations of the aqueous and organic constituents were used in this work. Independent variables included copper concentration, ionic strength, and initial pH of the aqueous phase; extractants, diluents, and their concentration in the organic phase; and temperature.

Jan 1, 1988

By G. G. Goble

Dynamic pile testing is now over 20 years old as a routinely applied tool for evaluating driven pile installation. The first test on a cast-in-place pile was performed more that 15 years ago. The research that produced the method began almost 30 years ago. But, questions still arise regarding the appropriate use of this technique so some review is useful. Today a number of methods including dynamic testing all depending in some way on the application of dynamics are in routine use. First, Wave Equation analysis can be used to predict pile driveability before going to the field. The same approach can be used during driving to estimate the bearing capacity based on the blow count observed in the field. Dynamic measurements, on the other hand, can only be used after pile driving has begun. They offer predictions of pile capacity as well as measurements of hammer, driving system, and pile driving performance characteristics. The first part of this paper will be devoted to discussing how the foundation engineer can use these tools. First, a brief review of what dynamic methods actually do. In Wave Equation analysis a numerical model of the hammer, driving system, pile, and the soil is created by the engineer. The hammer is dropped on the pile and using a discrete, dynamic analysis the motion of the individual pile elements is calculated as a function of time. Of course, input information must be supplied by the program user to describe the hammer, driving system, pile, and soil. In the current state of development, the primary problem in input data is with the hammer performance (efficiency) and the soil description. Research may be able to do a better job with the soil data, but hammer performance will always vary from hammer to hammer and is dependent on the affectiveness of the inspection process. Prior to beginning pile driving the Wave Equation analysis supplies the best available estimate of what will happen when driving begins. It gives an estimate of blow count during driving, driving stresses, both tension and compression in the pile, and for diesel hammers, stroke. The selection of the driving system can be checked with the results of Wave Equation analysis and modifications can be made if required. For example, if the blow count at the required capacity was deemed excessive by the contractor a larger hammer could be tried or if driving stresses were too high changes could be made in the cushion or the hammer selection could be modified. All of these modifications are possible with only the cost of a computer run. The primary questions regarding the accuracy and reliability of Wave Equation analysis at this time is with regard to the assumptions made to represent the soil characteristics and the difficulty in predicting hammer performance.

Jan 1, 1993

By Denis Tepavac, Mark Trim

Structural performance of fiber reinforced concrete (FRC) depends on its ability to carry tensile forces after cracking. Australian Standards AS5100-2017 and AS3600-2018 are the only available design standards that establish a test procedure to determine strength and toughness of an FRC in direct tension. Direct tensile testing of fiber reinforced shotcrete samples was performed to determine if the model and guidelines in AS5100/3600 were applicable to shotcrete; all previous testing was from cast samples. In addition to direct testing, micro CT-scanning was also performed. The paper presents tests performed, results, and how the tests could be used on future projects. In addition, a brief summary is provided of the guiding structural mechanics used for estimating residual tensile strength and test methods utilized to verify those estimates.

Jun 13, 2023

By Richard J. Finno

Detailed measurements made at a test section adjacent to a deep braced cut and other published data are combined to illustrate the limitations of the common methods of predicting movements associated with excavations in soft to medium clay. While past performance data can be used to estimate expected responses before construction in many cases, actual wall and soil deformations throughout construction can only be estimated using finite element procedures. Success of such analyses depends equally upon considering all aspects of construction that induce strains in adjacent soil, such as wall installation, excavation and bracing sequence, and time, and adequately modeling soil stress-strain behavior. Even when these two criteria are met, soil deformations can not be predicted adequately when strain levels exceed those that produce peak shear stress.

Jan 1, 1991

By J. W. Mills

This paper's aim is to demonstrate, by reviewing findings and conclusions of earlier authors and through recording and interpreting the outcome of recent laboratory study of the ores, that the ores around the Gem stocks are metamorphosed equivalents of common siderite-sulfide ores far from the stocks, as was first proposed by Hershey (1912, 1913). That is, all the ores probably have the Precambrian age of 1250 million years reported by Long et al. (1960). Those near the Gem stocks, however, were extensively metamorphosed in Cretaceous time during the emplacement of stocks so their resemblance and relation to other veins in the district are camouflaged.

Jan 1, 1985

By G. S. Harper

Noise in general and drilling noise in particular have received increasing attention within the South African mining industry during the last 10?15 years. The Mine Health and Safety Committee1, during their 2003 annual summit, established two significant milestones to be met by December 2008 and December 2013. The 2008 milestone target is that of no more than ten per cent deterioration in hearing among occupationally exposed individuals, whereas the 2013 milestone target is that of less than 110 dB sound pressure levels at any place in the workplace. While these targets relate to general noise within the mining industry, it is widely believed that the most significant source of noise contributing to noise induced hearing loss (NIHL) among the underground workforce, is that of pneumatic rock drills. Data pertaining to the noise emission level of any machine is generally reported as either a sound pressure level or a sound power level of a single machine measured under free field conditions as defined in Appendix 3 of SABS-ISO 37442. However, rock drills are seldom used in isolation and underground conditions cannot be considered as free field. A methodology for the selection of rock drills on the basis of total operating cost has been developed. However, this paper focuses on the noise elements of the generic methodology and provides a model for the prediction of the composite sound pressure level and the equivalent noise exposure levels of groups of individuals from machines, used singly and in combination in an underground environment based on the sound pressure level determined according to SABS-ISO 3744 under free field conditions. The methodology includes provision for the consideration of the effect of hearing protection devices and the use of multiple machines in combination and provides an indication of the potential costs of hearing compensation.

Jan 1, 2006

By S Brochot

During the development of a mining project, samples are taken for metallurgical tests. The sample can be a composite sample made of material coming from a selection of various drilling products or a sample coming from a mining test. This sample can represent several tonnes of material which are analysed and split to be used in various tests.In the current case, a composite sample is dedicated to semi-autogenous grinding (SAG) pilot plant tests. The property of interest is then the size distribution of the material. The sample is mixed and a subsample is taken to measure the size distribution which is considered as the feed size distribution. Then the remaining material of the sample is divided in several subsamples for batch grinding tests at different operating conditions. The product of each grinding test is then analysed to measure its size distribution.The grinding performances are analysed at the light of the measured size distributions for feed and product. But what is the accuracy of the measurement of these size distributions? What is the variability of the feed knowing each feed is just a subsample of the initial sample?The Pierre Gy theory of sampling answers these questions.The current paper presents, through a real example, the calculation of the measurement error of the size distributions and the variability of the feed between the different tests. The uncertainties of the grinding performances are then calculated and their impact on the results interpretation is then analysed.CITATION:Brochot, S, 2012. Sampling for grinding pilot plant test - the effect of size distribution variability, in Proceedings Sampling 2012 , pp 127-134 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

By P Mulvey

"Currently mine process studies and geochemical waste characterisation are considered as two interdependent studies, necessary for the development of the mine and inclusion in the environmental impact statement (EIS). Geochemical waste characterisation will utilise the simulated tailings produced by the mine process studies team to understand the behaviour of the tailings, but the two teams rarely integrate these to develop a coherent and agreed final design.Thorough mine waste geochemical assessments can develop processes to minimise environmental harm, resulting in substantial savings in the decommissioning, closure and rehabilitation phases, and may also be able to address changes in mineral processing methods that can result in substantial savings in process inputs, or even recovery of metal concentrates.Based on geochemical waste characterisation, the full cost of waste management can be calculated and incorporated into the costing of milling.  This allows for a more effective evaluation of the metallurgy.  A number of examples are presented in which substantial improvements have been made from the collaboration of both the metallurgical and geochemical teams during planning and the metallurgical team and environmental team during operations.*This paper is only available for individual download. It is not included in the conference proceedings*CITATION:Mulvey, P, 2013. Optimising metallurgy at the planning stage to minimise environmental impact - a feedback loop from geochemical waste characterisation, presented to MetPlant 2013 Conference (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 15, 2013

By D. E. Etter, J. E. Selle

The Pu-Ce phase diagram was determined by differential thermal analysis, metallography, and elechm-nricroprobe analysis. The dingram is chararterized by a eutectic with extensive solid solubility in the cubic Phases of both cerium and plutonium. No intermediate phases were found. Cerium is soluble in e plutonium to 16.0 at. pet Ce at 626OC nnd in d plcltoniurn to 23.0 at. pet at 613 "C, decreasing to 17.5 at. pet at room temperature. No solubility in the a, ß, or ? phases was jound, and the mininum cerium required to stabilize 5 plutonium to room temperature is 3.2 at. pet. The maximum solubility of plutonium in 6 cerium is 19.5 at. pet at 721OC, and the maximum soluhility of plutonium in ? cerium is 34.5 at. pet. Invariant points in the system are: a) eutectic at 626oC, L16.5 = E Pu16.0 + y Ce65.5; b) peritectoid at613oC, e Pu13.5 -y Ce65.5- d Pu23.0. AS part of a program aimed at the determination of the phase equilibria in the Pu-Ce-Cu ternary system, preliminary investigations were made of the three binary systems. A survey of the Pu-Ce binary system by differential therma1 analysis indi- cated several areas of disagreement with the published diagram,' primarily in the shape of the liquidus surface. Consequently, a thorough investigation of the system was undertaken, and this report presents the results of the study. EXPERIMENTAL PROCEDURE Three methods of investigation were used: differential thermal analysis (DTA), metallography, and analysis with electron-microprobe X-ray analyzer (EMX). The EMX analysis was particularly useful for the determination of solvus lines. The DTA method was most useful for the determination of the liquidus curves. Metallography complemented both of these techniques. Materials. The cerium metal used for most of this work had a freezing point of 805°C. This material showed 15°C premelting, and was found metallographically to contain some unidentified in~lusions.2 The temperature of premelting is defined as the point at which the DTA curve breaks away from the base line, analogous to a curve obtained from a solid-solution alloy. Several compositions were prepared near the cerium end of the diagram with higher-purity material which had a freezing point of 800°C. etallographic analysis showed this material to be relatively free of inclusions and only 8°C premelting was observed. Major impurities were found by spectrographic

Jan 1, 1964

By Gao Dazhao

This paper presents some research results of pile foundation performance. Measurements on the bearing behaviour and driving effects of piles have been carried out during pile testing and pile driving. It has been found that the ratio of end resistance to the ultimate load depends on the pile length, and the ratio in general is less than 40% for single piles. However for pile group, the end resistance seems to be greater than skin friction. The characteristic curves of skin friction and end re­sistance appear as interaction between soils and pile. The contribution of skin friction to the pile bearing capacity not only depends on soil properties but also on the relative position of the soil layer. The pore pressure and the lateral pressure in ground have been observed during the stage of driving piles. Based on the available data, the radius of plastic region and the coefficient of pore pressure A can be found analytically. The pore pressure time process curves which may be used for practice have been predicted by means of numerical method.

Jan 1, 1991

By J. H. Nixon

A three phase program evaluated commercial proximity warning devices, developed and designed a microprocessor-based electrostatic field measurement instrument, and utilized this instrument to investigate the electro-static fields about power lines. The Phase I program consisted of test and evaluation of these commercially available proximity devices. The evaluation results were reported in the Phase I report entitlted "Evaluation of Proximity Warning Devices II dated 22 February 1980. The Phase II program resulted in the design and development of a microprocessor-based Distributed Sensor A.C. Electrometer which measures the electrostatic field present at 17 discrete locations along a crane boom. Operator control of the measurement system allows simultaneous electric field measurements from 17 probes, print out of the electric fields measured, and data archiving on magnetic tape for post measurement analysis. Under the Phase III program, electro-static fields around a crane boom were measured by the instrument at 17 high voltage power lines of various voltages and geometries. The electric field data was processed and plotted versus boom distance from the power line. Analysis of the electric field data indicate that the distances at which a single sensor alarm will activate, vary by a factory of 3 to 1. This is due primarily to variations in boom orientation. The results also indicate that in the case of multiple power lines, a single electrostatic field sensor cannot reliably be used to determine the distance from a power line.

Jan 1, 1982

By A. D. Prokop, J. P. Rider

Along with increased production from longwall units has come the likelihood of increased worker noise exposures. In recent years, equipment has become larger, more powerful, and noisier than its predecessors. For these reasons, the Mining Division of the National Institute for Occupational Safety and Health (NIOSH) is investigating worker noise exposure on longwall faces and researching possible solutions to reduce this exposure. Part of this research effort involves studying the effect of covering the underside of longwall shields with acoustical material to reduce reverberating noise along the face. Experiments using acoustical absorptive insulation to cover the undersides of the shields, shearer body, and the shield supports were conducted at the full scale simulated long-wall test facility located at the Pittsburgh Research Center. Sound levels were recorded every 1.5 m [5 fl] along a 15.2 m [50 ft] section of the simulated face for all of the conditions tested. The analysis of the data indicated that a 2.0-3.0 dBA noise reduction was achieved between the shearer drums and a 4.0-5.5 MA attenuation was attained upwind of the headgate drum.

Feb 24, 1997

A short account is given of the theory and practice of determining the true U3O8 content of ore samples by the determination of the beta and gamma activities separately, using the method of Eichholz and his associates.It is shown that, despite the variation of sample activity without change in U3O8 content, the true U3O8 value can still be found.Thorium can be determined simultaneously if this element is also present.

Jan 1, 1957

By H. W. Clair, E. V. Potter, M. J. Speedlove

"INTRODUCTION The behavior of particles in a sound field has long been of scientific interest since Kundt (1) 5/ made his classic experiments on some of the interesting effects of standing waves in cylindrical tubes. With the development of the electronic tube and its application to continuous generation of sound, experimental investigation of the Kundt tube was renewed (2). The more intense vibrations set up by a continuously vibrating diaphragm or rod produce even more striking effects than those observed by Kundt. Instead of the striations at the antinode produced by the stroked rod, then, wafer like barriers are formed at the antinodes, sometimes extending over the entire cross-section of the tube. Furthermore, it was observed independently by Andrade (3), Brandt, Freund and Hiedemann (4); and by investigators in the Bureau of Mines laboratories (5) that aerosols, such as ammonium chloride or tobacco smoke, could be flocculated quickly if passed through an intense sound field, particularly when a standing wave field was set up by a resonant enclosure. Because of its possibilities as a new means for removing suspended particles from dust-laden gaseous furance or smoke, the phenomena attending the behavior of suspended particles in a und field have been studied intermittently by the Bureau of Mines over the past decade.The first experimental work was done with a magnetostriction vibrator and a Hartmann air-jet generator as sound sources. It soon became evident that neither type was entirely satisfactory. Low mechanical efficiency is an inherent characteristic of magnetostriction generators, and the air-jet generator is difficult to control and does not permit accurate measurement of the acoustic output. The search for a suitable sound source led to the development of an electromagnetic generator, which is by far the most suitable for study of the effects of intensive high-frequency sound fields in gases (6)."

Mar 1, 1948