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By George A. Desborough

Marine black shales of Paleozoic age in the Western United States that exceed 10 weight percent organic carbon contain as much as 5,000 ppm vanadium, 1,000 ppm molybdenum, 1,300 ppm nickel, 600 ppm cobalt, 16 ppm silver, 7,000 ppm chromium, 18,000 ppm zinc, 280 ppm cadmium, and 350 ppm selenium. Depositional settings include: (1) continental-rise and marginal-ocean basins, (2) continental-shelf and foreland basins, and (3) cratonic-platform embayments. Most of these metalliferous organic-rich shales have not been examined for resources because of rapid weathering and poor exposures which preclude easy sampling of unoxidized rock necessary to determine actual concentration and residence of indigenous metals. Generally, the marine black shales of Paleozoic age in the Western United States are richer in metals than marine Paleozoic black shales in the Eastern United States.

Jan 1, 1982

By G. A. Kordosky

The control of pH in solvent extraction circuits is an old technique (1,2) but one which has a large potential for future use. The equilibrium position of any reaction which has hydrogen or hydroxide ions, either as products or as reactants, can be controlled by pH adjustment. Several examples of reaction types which are important in solvent extraction systems and which also show a pH dependence are shown in Figure 1. The examples were chosen to show the wide variety of reactions which fit the above criteria, but it is not meant to be a complete listing of all the possible reaction types, Some of the reactions are presented in a simplified form. It is the intent of this paper to discuss pH controlled solvent extraction reactions for some relatively simple systems through more complex ones.

Jan 1, 1979

By M. T. Worley

Joint Development Associates International, Inc. (JDA) began humanitarian relief and community development in Central Asia in1992, following the collapse of the former Soviet Union. Appropriate technology has played an important role in their efforts to assist those segments of society that are most vulnerable to poverty and disease. Three case histories are described to illustrate the successful implementation of simple, but effective technology in community development.

Jan 1, 2004

By Harry H. Posey, John Woodling, Miriam L. Renkin

Natural acid drainage is generated from pyritic rock underlying 17 percent of the upper Alamosa River basin. About one-third of these acid producing rocks have nil carbonate buffering capacity; there the streams carry significant acid plus dissolved Al, Cu, Fe, and Zn. In part of the basin, aquatic life is limited by the natural acid drainage. In the four miles where the Alamosa flows through pyritic rock the river grows toxic to trout. Inhospitable conditions continue downstream for at least another four miles. The waters become refreshed, naturally, through metal dilution, metal oxide and hydroxide precipitation, and acid neutralization. Water quality fluctuates in seasonal cycles. Dissolved metals and acid, which are generated year-round by weathering, are stored over winter in the unsaturated zone in the retained water and in soluble metal- sulfate minerals that form by evaporation of acid-metal waters. Seasonal discharge variations cause metal concentrations and pH to shift in the trunk stream; the acid drainage source streams, however, shift only slightly by season. In early spring, metal concentrations and metal loads increase as metals and acid are flushed from the unsaturated zones by melting snow. Peak metal loads occur at this time, and precede peak flow by up to two months. Other metal load peaks occur during peak flow and monsoon flow, even though metal concentrations are diluted at that time by precipitation. In late spring and thereafter, discharge of neutral pH water wanes, so trunk stream pH falls and metal concentrations return to previous high levels. Metal concentrations appear to be low from November through January when dilution from precipitation is lowest, but rise in February to near peak yearly concentrations. In years with high monsoonal flows, metal-laden waters apparently flush from the unsaturated zone and metal concentrations remain low from about October through January. In years with low monsoonal flows, however, metal concentrations in October and November at least are higher.

Jan 1, 2000

By Bruce H. Mason

The exploration for a commercially acceptable deposit of limestone is consid¬ered by many to be a relatively easy task; however, trying to locate a zone of high calcium limestone of economic thickness within a formation, which outcrops only in a narrow band varying in width from a quarter mile to ten miles, adds considerably to the normal problems experienced during an exploration program. The existence of varying glacial and karst features in the outcrop area intensified the problems encountered and complicated the interpretation of the economic value of the deposit. This paper highlights a recently completed five year exploration program during which approximately 3,900 acres of ground in seven civil townships were evaluated as potential sources of high-calcium limestone. Details are given with respect to the final site chosen and the methods used in determining the suitability of the site. This site exhibited many karat features and several methods were utilized to determine the effect of these features on the gross characteristics of the deposit. Aerial photography for both mapping and interpretation were utilized. Black and white panchromatic photography, black and white infrared and color infrared photography were flown. Resistivity, diamond core drilling and close-interval angering were used to supplement the information obtained from the aerial photography.

Jan 1, 1974

By W. K. Utt, C. C. Woodward, W. L. Howie, G. G. Miller

The process of roof drilling and bolting is one of the most dangerous jobs in underground mining. In the United States, roof drilling and bolting results in about 1,000 accidents with injuries each year. Researchers, from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health are studying the feasibility of using a drill-monitoring system to estimate the strength of successive layers of rock and assess the integrity of a mine roof. Such a system would allow roof drill operators to be warned when a weak layer is being drilled. Using measurements taken during drilling, a neural network can classify mine roof strata in terms of relative strength. The concept has been proven in principle. This research project was undertaken to increase the safety of underground miners, especially those involved in roof bolting. The system should be applicable to the mobile drills now used in underground mines, and the system would likely find wider application as well.

Jan 1, 2003

By Carlos Viramontes Aldana

Mining in Mexico is one of its post traditional activities, whose influence in the development of important cities and communications has been decisive. Precious metals and, to some extent, copper and tin were known and used before the Colonial period, but from the sixteenth century to tie end of the nineteenth century, mining and metallurgical industries were concentrated in the precious metals, mainly silver. This silver was exported to Spain and other countries under the Spanish. Rule, Mexican peso was known world wide since the end of the sixteenth century and Mexico ranked as the first silver producer since the eighteenth century.

Jan 1, 1985

By Tsuneyoshi Funazaki, Takayoshi Nakamura, Keizo Miki, Takashi Imaishi

The underground portion (about 10 km) of Tokyo Wan Aqua-Line consists of eight shield tunnels connected with Kawasaki Man-Made Island in between, at four underground locations. The connection work had to fulfill strict precision and safety requirements in the ground about 60 m below soft seabed, but was completed successfully in May 1997. This report describes the connection work in detail, featuring the method of investigating shield machines’ relative positions, ground freezing method and connection mechanism and procedures. It also mentions the present state of Tokyo Wan Aqua-Line that was put in service on December 18, 1997.

Jan 1, 1999

By B. Hagemeyer

The trend to higher solids paper coating and to neutral/alkaline papermaking is causing an above average growth in the use of calcium carbonate as both a paper coating and a paper filling pigment. These developments are expected to continue well into the 1990s. Thus, calcium carbonate will account for a somewhat larger percentage of total paper pigment volume. Nevertheless, overall growth in paper tonnage coupled with an increase in filler pigment percentages will create a demand for larger quantities of other pigments as well. Kaolin will continue to be the dominant paper pigment by far, with continued growth though at a somewhat slower rate than calcium carbonate.

Jan 1, 1986

By Erkan Bozkurtoglu

The most important difference between weathering and alteration, which are the definition of the change in rocks that occur with the help of physical and chemical effects, is a new product is formed as a result of alteration. Although atmospherical conditions are the most important factor during rock change, geothermal fields play a large role in the developing of alteration phenomenon. Because every geothermal system shows different characteristics including the chemistry of geothermal fluids and their potential applications, alteration on the field is important for the studies to find geothermal energy sources and to obtain the thermal fluids. The development of weathering and alteration which is the mark of interaction , between the physical and chemical properties of geothermal fluids and gases with the reservoir and wall rock, gives out important data about the hydrogeology, hydrology, reservoir conditions and characteristics of reservoir rocks of the geothermal field. Therefore defining the development of weathering and alteration phenomenon in a geothermal field and modeling the change in rocks, is very important for the benefication of the geothermal field economically. In this study 70 km2 that reside between Kösedere plains, Uzunburun, Çamtepe, Centirler villages in Çanakkale - Ayvacik - Tuzla geothermal field were studied and subsurface travel of saline thermal fluids and their interaction with the rocks and development of weathering and alteration phenomenon in the field were investigated. For this purpose geological mapping of the field were done and observations and measurements as well as rock sampling were carried in locations more than 220. As the result of petrographical investigations of rock samples development of weathering and alteration phenomenon were defined and 16 rock samples out of 220 that represent the field in general were chosen to be chemically analized and after that geochemical comments on the Tuzla geothermal field were made. Also hydrothermal alteration zones that are located in Tuzla Tepe, on which weathering and alteration phenomenon is observed as widespread and thermal water discharge locations in the near perimeter of Tuzla Tepe were mapped and from these data rock change in Tuzla geothermal field were modeled.

Jan 1, 2005

By Maria C. Jaime

Optimization of the rock cutting performance plays a major role in the tunneling operation. For a given set of tool and cutting environment, rock fragments may be chipped away in numerous manners and it is crucial to understand and be able to predict the dynamics at the cutter-rock interface. This paper presents rational and realistic 3D finite element modeling of rock cutting where typical computational issues ?such as contact formulation, appropriate rock material response, mesh distortion, and crack propagation? are overcome. Cutting forces and failure mechanisms in this finite element analysis are successfully validated by laboratory single-cutter scratching tests in sandstone.

Jan 1, 2010

By Bruce L. Bryson

In the past decade a principal growth area in refractory technology has been the development and use of extra high alumina refractories. The refractories user is asking for, and is prepared to pay for, higher purity, more dense materials with longer life, less maintenance, and better dimensional tolerance to meet the exacting demand of high output processes. High alumina and bauxite refractories are being used more and more to keep pace with the demand for guaranteed performance. The steel industry, for example, is starting to place great reliance on these products. A unique material now available with all the requirements for extreme purity and density is tabular alumina, already proving itself in many refractory applications.

Jan 1, 1973

By S. Bastola

Over 80% of roof falls in Illinois coal mines occur at intersections. Regular intersection geometries with sharp corners have been typically analyzed in literature. This study has analyzed stress distribution around typical field 4-way intersection geometry and compared it with similar data for regular four-way intersection geometry. These analyses were performed using 3-D numerical analyses for a typical lithology associated with No 6 coal seam in southern Illinois. Linear elastic and non-linear analyses, using Hoek-Brown failure criteria for different lithological units, were performed. The 3-D models incorporated bedding planes and pre-mining horizontal stresses. Effect of diagonal widths of the intersection and pre-mining horizontal stresses were examined due to their influence on stability. In addition to stress distribution, contours of safety factors, and displacement analyses were performed to assess stability of intersections.

Feb 27, 2013

By D. C. Wilder

Deformations during heating and cooling of three drifts in granitic rock were influenced by the presence of faults and shear zones. Thermal deformations were significantly larger in sheared and faulted zones than where the rock was jointed. but neither sheared nor faulted. Furthermore. thermal deformations in faulted or sheared rock were not significantly recovered during subsequent cooling thus a permament deformation remained. This inelastic response is in contrast with elastic behavior identified in unfaulted and unsheared rock segments. A companion paper (Butkovich and Patrick, 1986a) indicates that deformations in un- sheared or unfaulted rock were effectively modeled as an elastic response. We conclude that permanent deformations occurred in fractures with crushed minerals and fracture filling or gouge materials. Potential mechanisms for this permanent deformation are asperity re-adjustments during thermal deformations. micro-shearing, asperity crushing and crushing of the secondary fracture filling minerals. Additionally, modulus differences in sheared or faulted rock as compared to more intact rock would result in greater deformations in response to the same thermal loads.

Jan 1, 1986

By G. Gillet

The conventional magnetic separators used in the mineral industry are equipped with traditional magnetic circuits or with permanent magnets (rare earth). However, when processing minerals with low magnetic susceptibilities or minerals of very small particle size, these separators are inefficient. In addition, a conventional magnetic circuit consumes considerable amounts of electricity to generate a relatively low magnetic field (~2 Tesla). The equipment is also heavy and bulky. Only a separator having a superconducting sole-noid can contribute in solving most of the problems, and only such a separator can produce high magnetic fields with low energy consumption. New developments and the experience acquired in using these superconducting magnets have resulted in new uses for magnetic separation, especially in the environmental area. This paper presents and describes a separation system that uses superconducting magnets that are completely automated and able to treat raw materials (concentration or purification) or liquid industrial effluents containing heavy metals in solution. Several industrial sectors, including the surface treatment, petroleum and chemical industries, are generating effluents containing heavy metal ions. The main metal ions found in such effluents include zinc, copper and vanadium. The purification of such effluents by magnetic separation is performed by adding a certain proportion of iron salts. The treated effluent passes through a superconducting separator where the flocs are retained in a matrix of steel wires. The efficiency of supraconducting high-gradient magnetic separation (HGMS) by this method exceeds 95%. Mineral separation and industrial-waste purification results are presented.

Jan 1, 2000

By Zeynep Aktuna

In this study, the formation of zeolites around Kizkapan and Karlikoy villages (Sothwest Kesan) were investigated. In this region, stratigrafically, Upper Eocene Kesan Formation, i.e. sandstone and rarely shale are observed at the bottom. Early Middle-Oligocene Yenimuhacir Formation is composed of sandstone, marl and tuffs. The zeolitisation is determined in the dasitic tuffs of the Yenimuhacir Formation. In this tuffs' zone, alteration had primarily resulted in zeolites, mainly mordenite, heulandite-clinoptiIolite. Silicification and alteration to clay minerals are also common. The Miocene-Pliocene Ergene Formation and alluvium deposits are the top units in the area. In the studied area, zeolite occurences have economic importance. The results show that successively rapid and short term periods are responsible for the clinoptilolite-heuylandite formations. The homogene chemistry of the solutions may be evaluated for a possible successive zeolitisation period. Multi-periodic vocanic activity and also circulation of thermal water had resulted in a continous dissolution of volcanic glass; moreover, resulted in the formation of suitable conditions of zeolite formation. The mineral crystallization sequences and alteration products as zeolites within the wall-rock, circulated solution reaction depends on a serie of parameters such as chemical composition of both initial materials and volcanic solutions during rock¬solution interaction period. The previous researches and the chemical studies support our results and observations in the studied area. The aim of this study is to investigate the presence of zeolitisation and to explain the formation steps of zeolitisation in Kesan Area by considering the content and distribution of major and minor elements determined in zeolite bearing tuffs. The chemical structures of both zeolite bearing volcanics and zeolite minerals are compared to the results of previous studies. Two dimentional behaviours of major and minor elements were discussed in order to caracterize zeolitisation development and to postulate a probable formation type of zeolitic alteration.

Jan 1, 2005

By D. W. Fuerstenau

One of the more energy-efficient methods for size reduction, namely particle-bed comminution under high compressive loads, was employed to grind eight minerals and ores, using up to 250 MPa pressure. A new approach based on the self-preserving character of the ground product size distributions and a linear energy-reduction ratio relationship is proposed for analyzing this mode of size reduction. The grind ability of the material when comminuted in a particle bed is about one-half that of the single-particle crushing mode, which is in agreement with previous estimates of the relative efficiencies of energy utilization based on direct measurements of surface area produced. The loss of efficiency may be attributed to energy dissipation by particle interaction phenomena in compressed beds.

Jan 1, 1993

By Mahmood B. Mirza

The geology of the Gulf Coast Salt domes has been extensively studied by Kupfer (1,2,3,4,5), Atwater (6,7), Balk (81, Hawkins (9), and Wharton (10). dominant geological feature of Southern Louisiana is the Gulf Coast Geosyncline. The axis of this geosyncline corresponds with the present day coastline of Texas, Louisiana, Mississippi, Alabama and Florida. This geosyncline has been continually subsiding since Cretaceous times and receiving large deltaic accumulations of sediments from Central North America. These accumulations progressively thicken toward the South. In the vicinity of the Coast, these sediments are reported to be about 40,000 feet thick. Another dominant feature of the region is the large number of salt domes scattered along the Gulf Coast (fig. 1). Typically, these domes are roughly cylindrical in shape, 1 to 5 miles in diameter, and extend to more than 20,000 feet in depth. It is hypothesized that these domes are derived from the thick Louann salt formation lying below the deltaic sediments. Due to its low specific gravity and buoyancy, the salt layer protruded upwards plastically and pierced the overlying strata. As a result of this upward flow, the adjacent strata are locally lifted upwards, creating excellent traps for petroleum accumulation.

Jan 1, 1979

By S. Zendejas-Mendivil, E. Pérez-Segura

The Cananea porphyry copper-deposit is the site of the second largest mining operation in Mexico. Mineralization is related to quartz-monzonite Laramide stocks that intrude volcanic and volcaniclastic Mesozoic rocks. The ore deposit is a stockwork and breccia-pipes system with Cu-Mo sulfides and pervasive quartz-sericite hydrothermal alteration. A study was made of the arsenic distribution in the mine and the ore-dressing plants. The arsenic (As) in the mine is related to a feldspathic quartz-porphyry type rock associated mainly with the breccia pipe structures (100-700 ppm As in the Veta 7 Breccia). There is vertical zoning, with As decreasing in the deepest part of the breccias. This As mineralization corresponds to a later sulfide hydrothermal stage. The concentrates are made of Cu, Fe and Mo sulfides and some minor quantities of As minerals. The most important copper minerals are chalcocite-covellite, bornite and chalcopyrite. Some of these minerals have 390-880 ppm As. The main As mineral is enargite[ [Cu2.97Fe0.06(As0.90 Sb0.01Pb0 01 )0.92 S4 051 and there are traces of stibioluzonite-luzonite I Cu, .95(Aso.4vSbu.49)0.9rfS4.07-Cu2 93(Aso.H4Sba.10)0.94S4.13] and of another stibioluzonite mineral type with substitution of As by Bi[Cu,96(Ascr,,'Sb0ccrB'OJ3jI~6S] These minerals contribute 80% of the As in the concentrates.

Jan 1, 1992

By Paul L. Russell

Introduction As the US and world population increases, so does the problem of supplying expanding energy needs. Early requirements worldwide were mostly met by abundant forest vegetation. Man's large scale use of minerals-energy resources is a fairly recent development. It occurred only during the past 200 years. Coal was the first mineral fuel to be used extensively. It was not a large factor in US energy production until the beginning of the 19th century. Petroleum and natural gas use is about 125-years-old. Electricity generation by falling water is about a century old. Atomic energy is only about 30-years-old. Extensive use of it is still in the future. Solar energy is in its infancy. Other energy sources such as wind, peat, and geothermal energy are minor and primarily of local importance. There were three main features of the fuel supply picture during the past 125 years. By 1900 coal replaced wood as the principal energy source. Since 1900, oil and gas have captured many coal markets. And after the mid-1970s, there was a resurgence of coal usage. (Figs. 1 and 2). Wood Until the advent of mineral fuels for energy, the major global energy source was wood. But populations increased and became centered in towns and cities. The problem of a sufficient energy supply first developed as nearby, easily obtained wood was exhausted. This problem became more acute as industries such as shipbuilding, smelting, and pottery making, became more widespread. Results of wood use as an energy source and building material are starkly evident in areas of the world where civilization is oldest. Entire forests were consumed and have never been replaced. In the US, wood supplied 90% of all fuel requirements until about 1850; and more than 50% until after 1880. By 1900, wood still supplied 20% of all energy uses. In the mid-1970s, energy costs increased, due largely to the oil embargo. This increase resulted in an increased wood demand for domestic heating. While large quantities of wood were being used, its share of the total energy market was still less than 3%. By 1983, wood was becoming increasingly scarce and more costly near most large US cities. Wind Wind powered ocean vessels for many centuries. Sailing ships were still common in 1900. Windmills provided an early, cheap energy source and continue to be used today on farms. Design and development of windmills for electricity generation is being conducted. Interest in wind power is growing worldwide where availability of wind currents warrants the investment. Also, US regulation requires power companies to "buy back" electricity generated by windpower in excess of that used by the windmill owner. Coal By the 1600s, England was producing, 900 kt/a (1 million stpy) of coal for heating and other uses. The first coal-fired blast furnace for iron smelting was developed in 1621. Coke-making was developed in 1755, and Watt invented the steam engine in 1769. Illuminating gas made from coal was introduced in London in 1800. During this same 200-year period, France and Germany developed coal production, but on a smaller scale than England. US, bituminous coal was mined near Richmond, VA, as early as 1748. Major bituminous coal-producing states in the early period were Pennsylvania, Virginia, Ohio, Kentucky, Illinois, and Maryland. West Virginia replaced Virginia as a major producer, when that state was formed in 1863. As the US expanded west, new coal deposits were found and exploited. Indiana, Alabama, Tennessee, Iowa, Kansas, Missouri, Washington, Colorado, Wyoming, Arkansas, Oklahoma (Indian Territory), Montana, New Mexico, and Texas had significant coal mining operations by 1900. Today the eight major coal producing states are Kentucky, West Virginia, Pennsylvania, Illinois, Ohio, Virginia, Wyoming, and Montana. These states accounted for about 80% of all coal (lignite, bituminous, and anthracite) produced in the US during the past several years.

Jan 8, 1984