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By R. J. Sweigard

Many states are considering the need to establish or modify policy relating to the disposal of coal ash. One of the primary concerns is the impact of leachate from the ash disposal sites upon groundwater and nearby bodies of surface water. A detailed site investigation was conducted at a coal ash disposal facility associated with a power generation station. The disposal site is situated alongside a major river. Monitoring wells were installed and soil samples were taken for characterization. Groundwater models were used to simulate migration of leachate from the disposal site toward the river. Such models have the potential to be used to verify regulatory compliance. This paper addresses the validation and adaptability of these models to this case and their usefulness as possible tools to be used in future environmental audits.

Jan 1, 1993

By M. J. Laurila

Utilizing data compiled from a drilling program and bulk samples taken from a coal reserve, flowsheet performance for a coal preparation plant can be calculated using a desktop computer. Sets of equations defining material balances involving coal preparation plant unit operations are employed to depict plant performance. Techniques are discussed for interpolating washability data and extrapolating size distributions and other critical data to expand on oftentimes limited sets of quality data to a useable data base from which projections can be made. Simulation of flowsheets can be done for a number of different conditions and configurations while still remaining in a limited working memory capacity of 32,000 bytes. Presented within this paper are several pertinent examples.

Jan 1, 1982

By K. Hanumantha Rao, K. S. E. Forssberg

The separation of feldspars from quartz has been the subject of numerous studies since 1930 and the flotation process so far proved to be the most suitable method. In the conventional process, feldspars are separated from quartz using a cationic collector and hydrofluoric acid as an activator of feldspars. There is no general agreement on the mechanism of fluoride activation of feldspar surfaces and the role of fluoride ions is briefly discussed. The use of HF is no longer acceptable due to environmental and health problems, and a few new reagents schemes have been reported. The available evidence shows that the success of these new reagent schemes is very limited. A new reagent scheme which is environmentally safe and cost effective for the separation of feldspars from quartz is yet to be resolved.

Jan 1, 1994

By Welland L. Ott, Hans J. Rumland

The Falconbridge Dominicana laboratory receives samples from all parts of the operation. Ore, metal and oil samples are taken by operating departments, gas and water samples by the laboratory staff. Physical sample preparation is essentially standard and produces comminuted samples for wet-chemical analysis and X-ray fluorescence analysis (XRF). T he main operating sections of the laboratory are described indicating in each case the type of instrumentation and method used, sample types analysed and comments on problems experienced. Emphasis is given to the sample preparation and X-ray sections especially with regard to the difficulties caused by our heterogenous ore material, calibration of the instrument and operational malfunctions. General problems related to our remote location and the tropical climate are discussed. Limited statistics on instrument availability, and stability, accuracy, precision, etc., are given.

Jan 1, 1979

By Natesa Jayaraman, Jon C. Volkwein, Edward D. Thimons

The Bureau of Mines has studied the impact of shuttle car movement on face ventilation. Real-time measurements of air velocity, methane gas, and respirable dust were recorded and compared with a time study of face shuttle car movement. Work was conducted in a blowing face ventilation section where a scrubber-equipped mining machine operated. Air velocities decreased by an average of 35% as the shuttle car entered the face, restricting air flow, and increased by an average of 35% as the shuttle car pulled away from the face, drawing with it additional air. Return air methane levels follow the face air flow volumes, decreasing as air volume increases. The surge of air created as the shuttle car leaves the face helps to dilute methane. Respirable dust levels, however, were found to increase as the air flow increased and decreased the scrubber capture efficiency.

Jan 1, 1989

Sewage sludge contains heavy metals, pathogens and bears annoying characteristics that limit its land application. For the sewage to be applicable on land, several stabilization methods can be used. Stabilization with lime (CaO) is used to raise pH and temperature and therefore, according to ASTM standards, reduce pathogen levels and achieve compliance with regulatory requirements. Although the process results in the production of a stabilized material, its direct application to soils is rather limited mainly due to the improper product texture. Inert materials can be further added to sewage sludge stabilized with lime to tackle this problem. The objective of this study is to investigate the potential use of dried bauxite residues as an inert material together with lime for the stabilization of sewage sludge from a municipal water treatment plant. It was indicated that the addition of bauxite residues and lime to sewage sludge apart from meeting the requirements of ASTM standards, it further reduces moisture content, improves material texture and eliminates odors. It was also found that although some elements leachability increased due to the treatment with lime, it further decreased when bauxite residues were also added.

Jan 1, 2006

By James M. Prudden, E. P. Jucevic

The Divide mining district occupies the center of a Tertiary caldera hosting the famous Divide silver lode and the crosscutting Gold Mountain mines. The northwest-southeast trending silver lode hosted ore with typically a 100:1 silver:gold ratio, high molybdenum content and argillic alteration dated at 16.5 m.y. within the Fraction Tuff. The east-west trending Oddie Rhyolite flow dome at Gold Mountain experienced possibly several periods of resurgence with repetitive silicification, brecciation and attendant precious metal deposition forming stockwork type mineralization. Silver-gold ratios average 10:1 for the mineralization phase of this 16.4 m.y. intrusive event. Similar chalcedonic mineralization registering a 3:1 silver:gold ratio cements conformable breccias within the Oddie Rhyolite basal flows unconformably overlying the Siebert Tuff on the northern flanks of Gold Mountain. Gray and red chalcedonic breccia matrix in the King Tonopah member of the Fraction Tuff contains a 50:1 silver :gold ratio.

Jan 1, 1990

By David R. Baughman, John C. Gathje, K. C. Oberg, Gary L. Simmons

Santa Fe Pacific Gold Corp. conducted pressure-oxidation pilot plant studies on refractory carbonaceous gold ores from the Twin Creeks Mine in Nevada. The tests were conducted at Hazen Research Inc., Golden, CO, during 1993 and 1994. Laboratory investigations using CIL cyanidation after batch pressure oxidation demonstrated gold recoveries of 90% to 95%. However, pilot plant testing showed that several of the same ore types responded very poorly, with gold extractions of only 45% to 75%. Plant testing was suspended for approximately four months while extensive research was conducted to determine why these ores responded poorly and to identify potential solutions. This paper describes the batch and pilot plant test results, the extensive research activities that eventually identified the cause of the gold recovery problem and the final semicontinuous and continuous pilot plant operations that confirmed possible solutions. Final pilot plant results showed gold recoveries that were consistently greater than 90%.

Jan 1, 1999

By B. Whitmoyer, J. Tian, J. E. Sneckenberger, M. A. Jerabek, C. A. Chandler

A computational procedure has been developed to determine the lung volume function for the upper airways of the human respiratory system. This analytical procedure computes a person's partial lung volume from an experimental two-microphone acoustic measurement of the upper airway passages obtained through a molded tubular mouthpiece. The theoretical transfer function for the two microphone signals as well as the related acoustic impedance and reflection coefficient for the upper airways are calculated using two-channel spectrum analysis techniques. An inverse spectrum analysis scheme then converts the reflection coefficient to an impulse response from which the airway area function is extracted using an area recovery algorithm. Numerical integration of the upper airway area function yields the lung volume function for the upper airways of the human respiratory sysytem. A software program to accomplish this computation of human upper airway volumes will be described in this paper. Application of this computational procedure to the measured tracheal acoustic impedances of 15 human subjects will illustrate the program's capability toward early detection of lung dysfunction using a prototype clinical facility.

Jan 1, 1991

By D. D. Banerjee, S. K. Kawatra, T. C. Eisele

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. The majority of the sludge is simply landfilled, but with increasing landfillimg costs this can cost the plant millions of dollars per year. As a result, this option is rapidly becoming less attractive. Producing marketable materials from the sludge is a far more promising avenue, provided that the products can meet the necessary specifications at a reasonable cost. In this paper, a method is described for using froth flotation and water-only cyclones to remove unreacted limestone from scrubber sludge. The water-only cyclone was found to be very effective for removing the coarser unreacted limestone, grinding ball chips, gravel, and similar coarse impurities. Froth flotation was found to remove fine unreacted limestone, with a minimum of reagent addition.

Jan 1, 1995

By O. Olajide, E. H. Cho

A laboratory study of the jigging process with Pittsburgh seam coal has been conducted. The laboratory-scale Baum jig used in this study was a McNally-Norton LO30X Right Hand Model Baum jig with an effective screen area of 0.186 m2 Feed material was prepared by selecting a size range from 6 mesh to 1.91 cm. Solid feed rates were 27.2 kg/min and 32.7 kg/min. Water flow rates were varied from 37.9 to 94.6 L/min. It has been found that smaller particles give higher values of density of separation and lower efficiency of separation. Increasing water flow rate increases the discharge rate of clean coal at a constant solid feed rate. It appears that the efficiency of separation increases by increasing water flow rate up to a certain value, and then levels off upon increasing the flow rate further.

Jan 1, 1988

By Ronald E. Heuer

It is not possible to accurately predict water flow into rock tunnels during construction, because all of the relevant factors cannot be accurately determined ahead of time. But an estimate is needed, because water inflow can be a major problem during construction, hence also a major concern for project design. There currently is no simple, generally accepted method of estimating inflow. This paper describes a semi-empirical method for estimating possible water inflow based on borehole water pressure test results, using correlations from previous tunnel experience. The method provides an estimate of percentages of tunnel length which will experience different intensities of long term steady state inflow, and provides an estimate of possible initial heading inflow. The method is applicable for distributed sources of water inflow due to rock mass features such as systems of joints and bedding planes, and accounts for different boundary conditions of water head and recharge. The metric system flow units used in this paper are liters per minute (L/min) and liters/minute/meter of tunnel (L/min/m), to be compatible with rock mass classification systems commonly used today.

Jan 1, 1995

By G. D. Criswell, F. Palkovits, J. M. Johnson

A paste technology investigation was completed for non-pozzolanic fly ash from Units 3 & 4 of PPL Montana’s Colstrip Steam Electric Station. The purpose was to assess the feasibility of converting from dilute slurry deposition of ash products to a system using thickened or paste ash to reduce excess water storage in the impoundment, reduce seepage losses, and increase storage efficiency. The investigation included laboratory and field testing to characterize the rheological, geotechnical and dewatering properties of the ash products, an assessment of potential seepage reductions and an evaluation of potential for increased ash storage capacity by modifying impoundment operating procedures. The studies concluded that the conversion project was feasible, cost effective, and permittable. Critical facilities for the conversion project are currently under construction.

Jan 1, 2004

By J. Hong, K. Han, C. Park, C. Yoon, H. Yoon, N. Kim

The contents of three platinum group metals (PGM-platinum, palladium and rhodium), from the spent automotive catalyst, and two NIST SRM (National Institute of Standard and Technology Standard Reference Material, Used Auto Catalysts) were determined by the X-ray fluorescence (XRF) spectrometry. The XRF technique has been proven to be a fast, effective and accurate method in determining not only PGM but also other solid materials of less soluble for wet digestion analysis. The detection limit of the XRF analysis is better than that of the inductively coupled plasma mass spectrometry which usually requires significant dilution to avoid high dissolved solid concentration. However, the XRF technique suffers from a strong matrix dependent problem. The objective of this study was to examine the applicability of the XRF analysis where the sample matrix was not exactly the same as the standard materials with particular reference to PGM analysis. This study enabled to compare the effect of various matrices including alumina, iron, copper and nickel on determination of the contents of PGM.

Jan 1, 2004

By B. J. Arnold

A coal's size distribution clay content and moisture content can affect its handling behavior. But the combined effects of these properties and the effects of other properties are not known. Research underway at CQ Inc.'s (formerly EPRI's) Coal Quality Development Center (CQDC) and at Iowa State University (ISU) will answer these questions as part of a four year project to develop a coal handleability index for utilities to use when specifying coals. This paper will present preliminary data from the first year of the project, which focused on obtaining data on the chemical and physical properties of carious coals and their measured handling properties. Additionally, size, ash and moisture analyses and shear test data for several coals used at one power plant will be presented along with correlations between these physical and chemical properties and the measured handling properties. These data lead to the conclusion that while moisture content is the most important variable, the amount of -44 µm (-325 mesh) coal fines is a significant factor in determining coal handling behavior.

Jan 1, 1992

By D. K. Sengupta, T. K. Rout, A. R. Prasad, B. P. Singh

The filter cake from the vacuum drum filters of a uranium ore processing plant still contains some leach solution. If the filter cake is not efficiently washed the associated leach solution is lost. Therefore, it is necessary to produce a filter cake that is permeable enough to allow efficient washing. The dewatering characteristics of the solid-liquid system must be improved to obtain flocs with sufficient strength to withstand the suction pressure of the filtration system. To facilitate efficient filtration with minimum cake moisture, studies were undertaken to improve the dewatering characteristics of the cake using different types of flocculants and surfactants. In these studies, flocs were formed with anionic, cationic or nonionic flocculants. The best performance was obtained with a low cationic high molecular weight flocculant. The filtration parameters, namely, capillary suction time, cake resistance, cake permeability and final moisture content of the filter cake, are improved by using a combination of flocculant and nonionic surfactant.

Jan 1, 2002

By Graeme Lyall, Oy Leuangthong, Clayton V. Deutsch

There are many variables to consider in the evaluation of nickel laterite deposits including the concentrations of nickel, iron, silica, and magnesia. These variables show complex relationships with each other such as mineralogical constraints, non-linear correlation, and heteroscedasticity. The complex multivariate relationship between the variables cannot be reproduced by conventional Gaussian or indicator geostatistical techniques. We introduce the stepwise conditional transformation method as a pre- and post-processing multivariate transform for the stochastic simulation of a nickel laterite deposit. Transformed data are multiGaussian and independent at h = 0; thus, cosimulation can be avoided after verification that variables are independent at all lag distances. Back transformation restores the features of the input multivariate distribution to the simulated realizations. The complex multivariate correlations are reproduced and sensitivity issues are addressed.

Jan 1, 2002

By M. H. H. Mahmoud, T. A. El-Barbary, E. A. Abdel Aal, I. A. Ibrahim, A. K. Ismail

Fertilizer-grade phosphoric acid with a P2O5 concentration of 50% should contain less than 1.5% Fe2O3, otherwise, the P2O5 water solubility of the fertilizers prepared from high-iron acids will be low. High-iron Egyptian phosphate concentrates fromAbu-Tartur and Sebaiya- West were leached with sulfuric acid and recycled phosphoric acid to produce 50%-P2O5 phosphoric acids containing 4.0% and 2.7% Fe2O3, respectively. The high iron contents were reduced to the industrially accepted limit of 1.5% Fe2O3 by precipitation with potassium sulfate. The factors affecting the effi¬ciency of the precipitation process, e.g., temperature, time and K2O/Fe2O3 ratio, were systematically studied, and the optimum conditions were achieved. The clarification of the prepared phosphoric acid from iron-containing sludges was also investigated by varying the time and temperature. The utilization of the separated sludges as fertilizer and recovery of P205 by pulping in water were also evaluated.

Jan 1, 2000

Mine managers need useful data to support production and maintenance decisions; for example, to evaluate the performance of replacement components. Today, managers rely solely on past experience, supervisors, opinions, and time studies. Our paper describes the concepts and algorithms we are developing for an automatic, intelligent decision support system (IDSS) that will aid managers by reducing and analyzing large amounts of, monitoring system sensor data and report only key production and maintenance information.. IDSS contains a pattern recognition, subsystem (IDSS/PRS) prototype to report graphical trends in traditional time study elements. We are designing. and prototyping a knowledge representation subsystem, using Knowledge Craft Tools, that will learn and adapt to the dynamic mine environment and reason about the recognized patterns using representations of manager's knowledge, equipment, capabilities, and mine layout and operating procedures. This subsystem will reduce, large quantities of time study type information to key issues that interest different managers.

Jan 1, 1989

By Fathi Habashi

WHILE HYDROGEN SULFIDE precipitates metal sulfides from aqueous solutions, other gases such as sulfur dioxide, carbon monoxide, and hydrogen, under certain conditions, precipitate the metals directly. This can be achieved at high temperature and pressure. Such processes are of great technical importance, since metals of high purity are precipitated economically in a powder form. As a result of the availability of such powders on a large scale. processes for compacting metal sheet and other mill forms directly from the

Jan 1, 1970