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By Monica M. Cole

The Empress nickel/copper deposit west of Gatooma in Rhodesia occurs within gabbro and amphibolite, disposed at the contact of a granodiorite stock (Barebottom Hill) and the surrounding greenstones of the Archaen Bulawayan System. The orebody has a pipelike form and a poor surface expression due to plantation of the area by Miocene (Africa) and later Victoria Falls erosion cycles. Barebottom Hill represents a monadnock remnant in the geomorphological surfaces while traces of the once larger Empress orebody have been removed. Limitations in soil geochemistry necessitated both studies of the vegetation ecology and the biogeochemistry of the area, both of which were anomalous. The use of geobotany was found to be restricted but biogeochemistry offers a most effective prospecting tool and was found to define the sub-outcrop of the ore-body more precisely than soil geochemistry since these methods reflect and differentiate anomalies emanating from bedrock mineralisation and those due to surface phenomena.

By P. Maais

This paper gives an account of the development of a plant for the differential flotation of mixed sulphide ore, special reference being made to the separation of copper and zinc sulphides. The uniqueness of the geology, mineralogy, and metallurgy of each complex ore-body is stressed. Consideration is given to the scale-up of laboratory data, and to some of the factors involved in the design of milling and flotation plants for this type of ore. Process control and development are discussed, as are the human requirements for the optimum operation of a concentrator.

Jan 1, 1980

By W. J. Jordaan

The ability of soils to retain and hold cations is called the cation exchange capacity (CEC). Adsorbed cations, however, can be replaced by other cations through the process of cation exchange. Heavy mineral deposits contain a significant portion of slimes including the very fine clay minerals. In most circuits the slimes fraction hampers efficiency and has to be removed during early stages of the process. Being a nonvaluable process stream, the processing of the slimes is a costly exercise. In thickening applications it might be possible to manipulate the ability of clay minerals to retain and hold positively charged cations in order to optimize flocculation and therefore reduce flocculation costs. The CEC value of the slimes could be a measure of this possibility. To investigate this hypothesis, different slimes samples were characterized for size, chemical composition and clay minerals present. The CEC value of each sample was determined and explained in terms of the mineral phases present. Settling tests were conducted and an attempt was made to explain the CEC characteristics of the clay minerals in terms of settling rate. The scope of this investigation was to test the hypothesis and should not be seen as an in-depth study of the subject matter. A greater number of samples and detailed analyses to identify and quantify minerals and phases present would be required to investigate further the relationships between clay minerals in the deposit, CEC and settling rates. Location and geological setting Exxaro KZN Sands is mining a heavy minerals deposit at Hillendale mine located at Richards Bay, South Africa. The orebody consist of a dune some 8 km inland from the coast to the north of eSikhawini. A geological synopsis undertaken by Botha1 concluded that the Hillendale mining area represents a coastal dune sequence that accumulated north of the Tugela River. The northward movement of sediment by long shore drift currents result in a high sand budget on the beaches north of the river youth and is the dominant contributing factor to the accretion of the coastline and development of parallel dune systems along the coastal zone in this area. Beach swash zone processes and enrichment of the fine sand fraction occurs during wind transport off the beach by ascending parabolic dunes that form the coastal barrier dunes. This process results in heavy mineral concentration on the windward dune face and localized enrichment parallel to the dune forms. The aeolian sedimentary facies processes result in the primary concentration of higher grades in the upper silt-enriched reddish brown horizons of the profile. The synopsis by Botha1 further showed that an additional component of heavy mineral concentration can be ascribed to the post-depositional relative enrichment of heavy minerals due to weathering. Therefore, it is likely that the Hillendale orebody protolith was pedogenically weathered to form the homogeneous, silt-enriched, clayey reddish brown to dark red, palaeosol profile that grades downwards into yellowish brown, less clay-enriched sand. Slimes characterization Samples The Hillendale orebody was divided into geochemically discretized zones based on the concentration of ilmenite and other specific minerals and/or phases. Six composite samples were made up from exploration samples taken from Zone 9, Zone 11 and Zone 12. The red and orange horizons within these composite samples were separated and test samples were prepared to conduct test work and analyses. The test samples were submitted for preparation and analysis to characterize the slimes properties. Each test sample was deslimed at 45 µm representing the slimes fraction (-45 µm) and dried at 40°C. The -45 µm slimes samples were then split to conduct size analysis, chemical analysis, XRD and to determine the CEC. Size analysis The size distribution of the composite samples is shown in Table I. The size analysis shows that there is a difference in size distribution between the orange and red horizons of each zone. The orange horizons contain less 850 µ material as well as less slimes (-45 µm). The red horizons contain yore slimes (-45 µm). The size distribution of the slimes fraction (-45 µm) was determined using Malvern size analysis. The cumulative particle size distribution of the slimes is shown in Figure 1. The red horizons of the different zones show similar size distributions. The orange horizons show some differences. However, there is a difference in size distributions between the red and orange horizons.

Jan 1, 2007

By A. Sampson-Forsythe, P. Morissette, A. R. Punkkinen, D. R. Chinnasane

"The performance of ground support systems under dynamic loading is typically assessed in a qualitative and subjective manner. As a result, it is difficult to develop an explicit knowledge on the mechanisms of action and interaction of support elements subjected to rockbursts. This paper examines rockbursts that have occurred at Creighton, Copper Cliff, and Coleman mines since 2000, 2004, and 2006, respectively. The mines are located in the Sudbury Basin, in Ontario, Canada. The majority of pertinent information was obtained through on-site field assessments, seismic system records, and numerical elastic stress modelling. Passive monitoring is used to link the evolution of the frequency and severity of rockbursts to the evolution of mining and support practice at the three mine sites. Based on the collected data, ground support elements that enhanced the capacity of support systems to withstand dynamic loads are identified. IntroductionThe selection of appropriate mining methods, extraction sequences, rock mass de-stressing techniques, and ground support systems is of great importance in mitigating the level of rockburst-related risk. In burst-prone conditions, the design of support systems should account for the anticipated dynamic load demand and the capacity of the available support options. Furthermore, an economical design should, implicitly or explicitly, take into consideration the consequences of a rockburst and its impact on worker safety and mine productivity. Stacey (2012) has argued that we have a limited understanding of the mechanisms of rock mass behaviour in seismic conditions. This is compounded by a ‘lack of understanding of the mechanisms of action and interaction of support elements under dynamic loads’ (Stacey, 2012). Consequently, the design of support systems required to manage dynamic loads is usually based on experience. The assessment of the dynamic performance of ground support systems is typically subjected to qualitative (and sometimes subjective) interpretations from ground control personnel."

Jan 1, 2017

By E. Spicer

X-Ray diffraction (XRD) provides useful information about the composition of an ore sample in terms of quantification of crystalline phases and amorphous content. The use of new, fast detection systems in XRD creates the opportunity to use this technique in modern process control. In the analysis of heavy mineral sands, XRD can identify the main mineral phases, such as ilmenite FeTiO3, rutile TiO2, Zircon ZrSiO4and quartz SiO2, and any other minor components present, such as anatase TiO2, magnetite Fe3O4, haematite Fe2O3or monazite (Ce, REE)PO4. Quantitative analysis is possible by various classical methods such as straight line or polynomial calibration with standards, but modern quantification analysis techniques such as Rietveld analysis (Bish and Howard, 1988) are attractive alternatives, as they do not require any standards or monitors. These methods offer impressive accuracy and speed of analysis. The Rietveld method compares calculated versus experimentally derived X-ray powder diffraction patterns for the sum of all crystalline phases. Another analysis technique offering great benefit to mining industries is cluster analysis. Enormous amounts of XRD measurement data are generated during the process control and material evaluation. New ways of handling such vast amounts of data are required to produce meaningful information for the end users. Cluster analysis greatly simplifies the analysis of a large amount of data from different processes or different raw materials, and automatically sorts closely related scans of an experiment into clusters and marks the most representative scan of each cluster as well as outlying patterns. The use of cluster analysis to evaluate the XRD data allows fast and reliable tracking of the process. It is the most economical procedure to have automatic data evaluation without involving any dedicated personnel in the process. Details of the techniques used, sample optimization methodologies, results, data precision and limitations will be discussed. The approach has potential as a relatively inexpensive, reliable tool, useful in the characterization of heavy minerals sand materials.

Jan 1, 2007

By M. Berjak, D. M. Hawkins, V. E. Marting, R. B. MacGillivray

Contributions to discussion V. E. Marting (Associate Member): The authors of this paper should be congratulated in having pioneered the application of the Sharapov predictor to local data, and in having made a valuable contribution to South African experience in the quantitative treatment of geological information using a digital computer. Although the existing set of three programmes has been described as a 'suite' it does not represent an integrated system in the accepted sense since the communication between runs is made in the form of punched card files to enable the mining engineer to exercise discretion and control over the data entered at each phase. Although the authors are justifiably proud of the successful results obtained through the application of this method, I feel that it is my duty to comment that the computer aspect of the work has not reached full development and is deserving of the financial support needed to increase its widest usefulness. At the present moment a routine to detect 'missing information' has not been commissioned. Due to the lack of documentation the use of the programmes is restricted since the format for the submission of data is known only to the authors. It is very unlikely that a profitable return on the development costs will be enjoyed before the programme is fully documented and made available to wider use. My criticism of the present incomplete state of the work is being voiced purely with the intent of focussing on the significance of this project and the fact that it is deserving of development on an industry basis. It should be noted that at the economical cost of R4.00 per sq ft of computer print-out, a mining engineer can hardly afford to miss the opportunity of using the programmes on other (e.g. metalliferous) mineral deposits of tabular formation. Since the publication of this paper I have had an opportunity to see the results of the programmes developed by Drs M. D. G. Salamon and F. Deist for designing bord and pillar workings. The basic data for these latter programmes are extracted from iso-line plans drawn conventionally by geologists, a task that could be considerably expedited through the use of Mr Hawkins' programmes. It appears that the efforts of these respective teams are complementary and it is in the interests of the industry that these individual components should eventually form part of an integrated system. E. Margo* (Member): This paper is a good example of how and where the backroom scientist-in this case the mathematical statistician-can aid the mining engineer to develop not only more accurate means for dealing with valuation problems but to develop a tool that can also cope with changed geological specifications.

Jan 1, 1969

By Z. Levinson, R. Dimitrakopoulos

A mining complex is an engineering system where raw materials are extracted from several mines, processed, transported, and sold to the market. The uncertainty and local variability of material grades and their locations within the related mineral deposits are critical for determining the optimal life-of-mine extraction sequence, destination policy, operating modes, and capital investment decisions, which define the production schedule of a mining complex. Infill drilling is used to further characterise a mineral deposit and reveals information that changes the representation of the resource model and potentially the resulting optimal long-term production schedule. A self-learning reinforcement learning approach is proposed to determine the optimal drilling locations that maximise the net-present value of the long-term production schedule and the associated financial forecasts by adapting the schedule to additional information. A case study at a copper mining complex demonstrates a $70 M increase in project value by collecting drilling information with a $1 M budget.

Sep 1, 2021

By P. J. D. Lloyd, Jill Urban, M. R. Urban

The adsorption of gold from cyanide solutions onto constituents of the reef, and its role in reducing the efficiency of the gold-recovery process by M. R. URBAN. M.Sc. (Chem. Eng.) Rand (Visitor). JILL URBAN. B.Sc. (Chem. Eng.) Rand (Visitor) and P. J. D. LLOYD. Ph.D. (Cape Town) (Fellow) Evidence for the adsorption or re-precipitation of gold from cyanide solutions onto gangue minerals of the Witwatersrand reefs has been gathered over a number of years by various investigators. The evidence from tests using radioactive tracers is conclusive and indicates thlt adsorption contributes about 0,1 g/t to the total gold loss from conventional reduction works. The loss is a function of the alkalinity and cyanide concentration of the solution, and it appears to be affected by the extent of time between milling and cyanidation. The heavy minerals appear to be the strongest adsorbers, and the clay minerals somewhat less strong adsorbers. A sensitive qualitative test based on thin-layer chromatography permits the extent of adsorption and desorption to be readily determined.

The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal. All papers must meet the standards set by the Council of the Institute, and for this purpose all papers are referred to at least two referees appointed by the Council. Although the worldwide readership of the Journal results in a preference for papers in English, the Council treats papers in Afrikaans on an equal basis, but, to meet the needs of the majority of readers, an English summary of some 5OO to 750 words should be provided.

Jan 1, 1984

By M. Klapwijk

Ancient Metallurgy - In addition to the preceding three papers, the following three contributions were received for publication 1. An analysis of Bantu-made iron implements from the Letaba district M. KLAPWIJK INTRODUCTION It has often been stated that it is hardly possible in South Africa to classify Bantumade iron hoes according to their places of origin and manufacture. It is well known that these hoes were used for barter, and as currency in the purchase of livestock or the payment of lobolo, although reports of the value of the hoes differ widely. The difficulty in their classification has arisen from their distribution over a very wide area.

Jan 1, 1974

The Institute has concluded an agreement with the Chamber of Mines whereby the Chamber Librarian maintains a section in the Library for the Institute. Surface effects of underground mining South Africa is blessed with vast mineral resources. It is essential to exploit those reserves if the country is to remain economically viable. Surface-mining equipment The Goldfields Mining Expo '86 is to be held in Kalgoorlie, Western Australia, from 30th October to 1st November, 1986, in conjunction with the Annual Conference of the Western Australian School of Mines. Mintek reports Report M142D Characteristics of gold and pyrite flotation at the Chemwes plant. (1st issued May 1984.) Report M159D Beneficiation tests on andalusite ore from the Marico district. (1st issued Aug. 1984.) Report M164D The recovery of tungsten from South African low-grade schee/ite concentrates. (1st issued Sep. 1984.)

Jan 1, 1986

By K. B. Owusu, W. Skinner, R. K. Asamoah, J. Karageorgos, M. Zanin, C. Greet

High Pressure Grinding Rolls (HPGR) are mostly used prior to pelletising processes to increase the specific surface area (SSA) of iron ore concentrate. For expressing SSA, the Blaine index is utilised as one of the most important dimensional properties of iron ore pellet feed. ISO 21283 is a standard test method that explains the manual of Blaine air-permeability apparatus for determination of this parameter. In this standard, the disaggregation method is based on passing the minus of 1 mm samples from the 0.150 mm sieve. The disaggregation process has an effective role on the results of Blaine airpermeability test especially for regrinding HPGR products. In this research, firstly the Blaine index of samples was measured without disaggregation. Following this, disaggregation was done by passing the minus of 1 mm samples through three sieves with different dimensions, 0.150, 0.090 and 0.045 mm, separately, and the Blaine index was calculated for each one. Finally, lab-mill with rubber balls, called Jar mill, was investigated as another option. Screen analysis and image analysis with SEM were performed to evaluate the effects of the sample's disaggregation on the size distribution and agglomeration of samples. The results showed that the disaggregation method with sieve size 0.150 mm, according to ISO 21283, was not applicable for HPGR products because the particles were still stuck together. In addition, the disaggregation method with the sieve size 0.045 mm or with Jar mill offered reasonable results. Keywords: Disaggregation, Blaine index, specific surface area, regrinding HPGR, ISO 21283, Jar mill

Jan 1, 2020

By D. D. Howat

In the field of high temperature smelting processes there have been two dramatic changes in the past twenty years. These are, first, the application of tonnage oxygen for direct injection for the refining of molten iron and other metals and to provide the means of enriching air used for the combustion of fuel. Second, the application of electric power for the generation of high temperatures in place of the combustion of fossil fuels. Of these two developments the application of tonnage oxygen for the refining of molten iron has virtually revolutionised the steel industry throughout the world. The magnitude of this development is exemplified by the fact that less than 5 per cent of the world's steel production in 1960 was made by this process or 16 million tons out of a total of 350 million tons of steel produced, while in 1970 over 40 per cent of the world steel production was made by this process, ie, 251 million tons out of 628 million tons total. In the same period the proportion of steel produced by the old-established open-hearth process has shrunk from 75 per cent to 38 per cent. In the whole history of the development of high temperature metallurgical smelting processes there has never been anything remotely approaching this. The other development, the application of electric power for the generation of high temperatures has not had the impact of the oxygen injection process but I believe that what we should call the electric smelting revolution in metallurgical processes has very far-reaching ramifications for steel production and other pyrometallurgical processes. This may seem a bold and brash statement but it must be remembered that the oxygen injection process constitutes a link in the chain critically dependent upon the production of vast tonnages of molten iron from very large modern blast furnaces. The Achilles heel of this chain of processes, upon which such a large percentage of the world's supply of steel depends, is the availability of metallurgical coke in turn dependent on natural resources of coking coal. Without any exception each industrial country in the world faces a shortage of resources of coking coal and in some cases a critical shortage. Certainly within the present century the major iron and steel producing countries of the world will face this critical shortage of coking coal and major modifications to steel making processes will become inevitable. W. F. Cartwright (Deputy Chairman of B.S.C) said recently that there are considerable doubts as to whether the world will be able to provide enough coking coal to meet world steel demands from the late 1970's onwards if the B.F.remains the main means for making iron from ore. This is one of the supreme ironies of the world metallurgical situation to-day when the technology of iron and steel production has reached an extremely high peak of technical efficiency. The newest modern iron blast furnace capable of producing 6 000 to 8 000 tons per day of molten iron represents probably the most efficient piece of high temperature metallurgical plant and operation known to man. The conversion of this molten iron into steel by the oxygen injection process has made available to the engineering industry steel of a quality and at a price which is quite remarkable. Yet this vast metallurgical pyramid rests on the completely insecure and uncertain foundation of inadequate world resources of coking coal. The shortage of reserves of coking coal in this country is acute and it is possible that these resources will be exhausted within the next twenty years. Yet unless some completely unexpected catastrophe occurs the demand for steel in this country will probably rise at a faster rate than in the Western world due to the expansion of the Bantu population and the increased standard of living. To offset the inevitable shortage of coking coal are our much greater resources of bituminous coal which although of low grade provide a suitable fuel for electric power generation. The geographical disposition of the coal fields in relation to the great industrial areas of the Transvaal makes it inevitable that the development of the pyrometallurgical industries must depend heavily on electric power. The position in this country with regard to electrical power generation and consumption is rather anomalous. Per capita consumption of electric power is high - in 1964 almost twice the world average of 870 KWH and twenty-five times the average of 34 KWH for the Continent of Africa. In 1964 fifty-four per cent of the total world electric power was used in industry - the ratio being approximately 1/9 mining to manufacturing uses. As shown in Table I in 1969 67.2 per cent of the total output of electric power from ESCOM was used for mining and other industrial uses but almost in the ratio 6/4 mining to industrial uses. These figures emphasise the enormous importance of the mining industry to the economy of this country and underline the major contribution made by the gold mining industry. What is of very significant importance is that although the mining industry remains by far the largest single consumer of electrical power the consumption of power for industrial uses is rising rapidly as shown in Table II.

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 30th August, 1972. Professor D. D. Howat (President) was in the chair. There were also present sixty-two Fellows, twenty-four Members, two Associates, three Students and eighteen Visitors, making a total of one hundred and nine. The President declared the meeting open at 4.05 p.m. OBITUARIES The President: It is my sad duty to announce the death of six members of this Institute. The first of these is Dr A. J. Orenstein, Honorary Life Fellow, who joined the Institute in 1916 and died on Seventh July. Dr Orenstein became almost a legendary figure in Medicine as a result of his work in the control and elimination of malaria during the digging of the Panama Canal and I believe he was actually engaged working until four days before his death. The other members who have died are: F. Meyer, died on 8th June; S. D. Loxton, Fellow, died on 13th May; J. Innes, Fellow, died on l0th January, 1970; O. B. Prentis, a Member, died on 4th June, and J. Brits, Associate, died on 27th June. As a mark of respect to the memory of the deceased and in sympathy with the bereaved may I ask you to rise and observe a few moments silence. MINUTES The President: 'The second item on the Agenda, the minutes of the meetings held on March 22nd and May 10th, 1972, as tabled. May I confirm these minutes'? Agreed. WELCOME TO VISITORS 'On behalf of the Council, may I say how delighted we are to have such a splendid gathering with us on this our Annual General Meeting. Dames en here vir die omvang van my Afrikaanse woordeskat verdien ek weinig lof, boonop is dit nog Afrikaans met 'n Skotse aksent, wat u asseblief moet verskoon. Tog wil ek se hoe dankbaar ons is dat sy Edele, die Minister van Mynwese, dr Koornhof en mev Koornhof vandag hier teenwoordig kan wees. In addition to our own newly appointed Minister of Mines, we are also honoured by the presence of the Minister of Mines of Rhodesia, Mr I. B. Dillon. I think not even our oldest members can recall an occasion on which two Ministers of Mines were present at a meeting of the Institute. It is a particular pleasure to welcome them this afternoon. I am happy to say that Minister Koornhof is an Honorary-Vice President of the Institute, and Minister Dillon is an Honorary Member. The presence of your goodselves, gentlemen, with us this afternoon, I am sure underlines the great significance which we believe both countries attach to the economic exploitation of the vast mineral resources of Southern Africa. For over 70 years, this Institute and its members have been making their contribution to this great task of mineral exploitation, and we feel that your presence with us today, is a token of the confidence of your governments in what this Institute and its members have been endeavouring to do. Also present with us today, is Mr R. C. J. Goode, President of the Chamber of Mines, and Honorary President of this Institute. I was going to say I welcome Mr Goode, but it is rather difficult to welcome a man to his own home, and this is the case with Mr Goode. He is a very distinguished and a very recent past president of this Institute and he remains now, as he has been for as long as I can remember, one of our most active and valuable members. This I think, ladies and gentlemen, is the second rather unique feature of this occasion this afternoon, because no one else can recollect an occasion on which the President of the Chamber of Mines was also a past president and an active member of our Institute. A special word of welcome, Mr Goode. Mr Tommy Gibbs, our Government Mining Engineer, is in a somewhat similar position as he is also a member and an old and valued friend of our Institute, - welcome to you, Mr Gibbs. Mention I think, must be made of the fact that we are very glad to have with us Dr A. J. A. Roux, President of the Atomic Energy Board, and Mr Stanley Craib, President of the Associated Scientific and Technical Societies. Then, within the great family of the A.S. and T.S., we have the presidents, or the vice-presidents of I believe 13 of the constituent societies. These gentlemen, like all the rest of us, have the rather tiring task of supporting and upholding their fellow presidents on occasions such as this. We particularly appreciate their presence this afternoon and the effort they have made to be with us. We are happy to have with us: Dr R. E. Robinson, Director-General, National Institute of Metallurgy, Mr E. Boden, Manager, Associated Scientific and Technical Societies, Dr H. G. Denkhaus, President, The S.A. Institute of Mechanical Engineers, Mr G. Goedhals, Vice-President, S.A. Institute of Electrical Engineers, Mr E. Dalton, President" S.A. Institute of Certificated

By P. G. H. Pistorius, D. S. Konadu, G. Lubbe

The aim of this investigation was to determine whether the composition of a shielded-metal arc-welding electrode coating affected the low-temperature impact toughness of austenitic stainless-steel weld metal. It is generally accepted that increases in the δ-ferrite and nitrogen contents result in a decrease in toughness at low temperatures. Weld metal from electrodes with a basic coating also generally exhibit better toughness than those from rutile (acidic) electrodes. An increase in basicity was expected to decrease the number and size of inclusions, which in turn provides a tougher weld metal. Three commonly available potassium–rutile E308L electrodes were used, complying with the E308L-16 and E308L-17 specifications. Analysis of the electrode coatings showed very similar chemistry and basicity. Significant differences in the inclusion contents of the weld metals were observed: the E308L-17 weld metal had a lower inclusion content (1.4% by volume) than the E308L-16 weld metal (3.7%). The former had higher impact toughness at all temperatures, despite a slightly higher nitrogen content. Regression analysis confirmed that the inclusion content had a significant effect on the impact toughness at all temperatures.

Jul 2, 2022

By G. D. Rosales, P. F. A. Braga, S. C. A. França, C. P. Pinto

The growing market demand for lithium is mainly due to its use in the manufacture of batteries for electric or hybrid vehicles and portable equipment (smartphones, tablets, power tools, notebooks, etc.). Currently there is great interest in finding new sources of lithium and technologies for its utilisation. Li-S batteries have received attention due to their theoretically high specific energy density, which is 3 to 5 times greater than that of Li-ion batteries. Unlike Li-ion batteries, of which the main raw materials are lithium carbonate and lithium hydroxide, the main raw material for Li-S batteries is lithium chloride. The anode used in Li-S batteries is metallic lithium, produced by a molten lithium chloride electrolysis process. The extraction of lithium from pegmatites such as spodumene, previously abandoned in the 1990s for being uneconomical, has become attractive due to the increase in prices as well as the need for greater lithium purity of products made from lithium-bearing minerals. The main methods used for lithium recovery from spodumene ore include the sulfuric acid process, the alkaline process (lime or limestone as raw material) and the chlorination roasting process. Thermodynamic modelling using HSC software 5.1 was conducted to predict different reactions that could occur during chlorination roasting of the spodumene/MgCl2+CaCl2 system. Lithium extraction from the solid obtained after the chlorination roasting was also investigated. The results of thermodynamic analysis provided a better understanding of the chlorination roasting process for lithium extraction. Metallurgical tests with a mass ratio of 1:6 (spodumene:chlorides) and molar ratio of 2:1 (MgCl2:CaCl2) allowed over 95% recovery of the lithium contained in the spodumene concentrate. Keywords: Spodumene, lithium chloride, chlorination roasting

Jan 1, 2020

By A. Schippers, S. Hedrich

Chalcopyrite represents the most important copper resource and is currently mainly exploited using pyrometallurgy. Bioleaching is an environmental-friendly and economic alternative to conventional mineral processing technologies. The technical feasibility of stirred tank reactor bioleaching of copper ore concentrates using acidophilic iron-/sulfur-oxidising bacteria is proven, however, often incomplete due to inefficient chalcopyrite dissolution. A decoupling of bacterial growth from bioleaching activity in one bioreactor by adjusting appropriate temperatures for both process steps allows for almost complete chalcopyrite dissolution. Separation of copper and recovery of other metals from the PLS was possible by implementation of different biological and chemical techniques. The Ferredox process has been proposed to treat limonitic laterite ores for cobalt and nickel recovery by means of anaerobic reductive dissolution with autotrophic, acidophilic bacteria. As a modification, aerobic reductive dissolution of laterites with acidophilic bacteria has shown economic and environmental advantages over anaerobic reductive dissolution. The reductive bioleaching technology has the potential to increase metal recovery in existing mines, and transform unexploited ores and limonite stockpiles into valuable resources. Keywords: Biomining, bioleaching, chalcopyrite, laterite, Ferredox process

Jan 1, 2020

By A. Kapito

The ferrite-pearlite microstructure is the most popular microstructure for alloys used in structural applications, including railway wagon wheels. These alloys have been designed through alloying and thermo-mechanical processing to have a refined microstructure. Ferrite-pearlite alloys are low cost, weldable, have good fabricability, and are reliable under extreme conditions. Given these performance attributes, it seems unlikely then that their dominant position as structural steels would ever be challenged by alternative microstructures. One major achievement in the development of ferrite-pearlite steels has been in the refinement of their interlamellar spacing to very fine distances of the order of < 0.3 µm. A refined microstructure increases the hardness of the alloy, thus increasing its life under wear conditions. The interlamellar spacing in pearlitic steels has, however, been refined almost to its theoretical limit. The increasing demand for speed and increased axle loading on railway wagons requires the use of stronger, tougher, and more durable materials. This has opened the window for the development of novel bainitic steels. Bainitic alloys have a higher level of microstructural refinement than pearlitic ones. They have shown to have good wear resistance and rolling-contact fatigue resistance, and high toughness. This paper will discuss the progress to date on the development of bainitic railway wheel alloys. Four alloy chemistries have been chosen for possible further development.

Jan 1, 2012

By Karl-H. Daum

Over many decades, numerous feasibility studies have demonstrated, that the production of sulphuric acid remains the most viable option of sulphur recovery from smelter off gas and abatement of SO2 emissions to the atmosphere. This is particularly more pronounced as smaller but more concentrated off-gas flows are to be treated from smelters, and enhanced sulphuric acid processes be-come available. Off-gas handling systems represent a significant capital and operating cost burden to the metallurgical operation. Modern pyrometallurgical smelter processes for sulphide ores based on the use of oxygen-enriched air, produce relatively small off-gas flows with high SO2 concentrations in the smelter gas of 30?60 %-vol. of SO2. This is a prerequisite for substantial cost reductions in the smelter off-gas handling and treatment system. As an alternative to sulphuric acid production, numerous scrubbing concepts with alkali or dual-alkali combinations as well as organic absorbents have been proposed. Also the reduction of the SO2 to elemental sulphur has frequently been studied. Very few of those alternative processes have been built in industrial scale, but all were generally characterized by none sustainable operation due to cost reasons, problems with issues related to chemicals used and by-products or poor availability. Thus the traditional concept of converting the SO2 to sulphuric acid is most common, although regarded as un-economic, but is at least a proven, environmentally sustainable and reliable way of sulphur gas processing. With the high acid price levels these days, operating companies are even able to generate significant revenue with their otherwise ?fatal? acid. Even though smelter gas is available at high SO2 concentrations, in a conventional acid plant one would add large amounts of air to dilute the gas down to a suitable concentration of 12?13 (14) %-vol. SO2. Dealing with higher SO2 concentrations in smelter acid plants is not feasible, as the gas exit temperature of the catalytic oxidation step would exceed the allowable limit for the catalyst. Hence those conventional acid plants are characterised by the use of large equipment, i.e. high capital cost, high energy consumption and limited flexibility. The newly developed LUREC® process can handle off-gas with significantly higher gas concentrations, even in excess of 25 %-vol. SO2. It is entirely based on well-proven equipment and unit operations. The first industrial application, operating with 16?18 %-vol. SO2 will be presented in this paper, along with the fundamentals of the process. It will be demonstrated that the process requires inherently lower capital cost, fewer operating cost, offers better energy recovery and lower emissions as compared to conventional design. While most existing smelter acid plants would have some built-in spare capacity, any significant increase of smelter capacity, say of 30%, can basically not be accommodated without installing an additional parallel new acid plant unit. An add-on LUREC® module can remove any such restriction, while simultaneously de-bottlenecking the existing acid plant. The paper also discusses the present status of the add-on technology for smelter acid plant expansions with respect to technical boundary conditions of different process alternatives as well as economic and environmental aspects. Application of the LUREC® process to modern smelter acid plants operating with high SO2 gas concentration, will lead to a substantial reduction of the specific size of the gas processing equipment and equivalent savings in capital and operating cost. The LUREC® process is patented worldwide by OUTOTEC.

Jan 1, 2009

By K. Cole, D. Mesa, P. Brito-Parada, M. R. van Heerden

Turbulence in mechanical flotation cells, achieved via an impeller, plays a key role in keeping particles in suspension, dispersing air bubbles, and promoting particle-bubble collision. However, studying the hydrodynamics of a flotation cell is not a simple task, due to the complex nature of flotation systems which are opaque, turbulent, multiphase and polydisperse in terms of particle and bubble sizes. In this paper we study the impact of impeller design modifications on the hydrodynamics of a continuously overflowing bench-scale flotation tank. To this end, two different impeller designs, with and without a stator, were assessed using Positron Emission Particle Tracking (PEPT). This allowed the authors to determine, for the first time, the effect of an impeller design on the behaviour of both hydrophobic and hydrophilic particle tracers. It was experimentally observed that the use of a stator modifies the hydrodynamics within the flotation cell, distorting the lower mixing loop that is characteristic of axial impellers. The role of the stator in dissipating turbulence results in reduced particle velocities outside of the impeller-stator region. These results have important implications for flotation cell design and are discussed in the context of the impact that different designs have on particle movement, flotation hydrodynamics and, ultimately, flotation performance. The data set generated is also extremely valuable for modelling and validation purposes. Keywords: Flotation, flotation tank, impeller design, rotor, stator, PEPT, hydrodynamics

Jan 1, 2020