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By Richard F. Link

The principal procedures for the statistical analysis of gold assay and other trace-element data depend on applying either the normal frequency distribution or the lognormal frequency distribution. The consequences of applying both methods are examined through reference to example data from United States and South African gold mines. It is concluded that for estimation of average grades, except for certain data with a very high coefficient of variation (ratio of standard deviation to mean), use of the lognormal distribution is ordinarily undesirable because bias may be introduced and little efficiency can be gained. However, if biased average grades can be tolerated, as in the examination of data from surveys in exploration geochemistry, use of the log-normal distribution may be desirable. Various statistical analyses are detailed, and the tables presented to implement the analyses are more complete than those previously published.

Jan 1, 1971

By D. W. Richardson

This Bureau of Mines publication provides the enthalpy of formation of malachite [Cua(COs)(OH)2] as determined by hydrochloric acid solution calorimetry. At 298.15 K the enthalpy of formation from the component oxides is -15.l0±0.30 kcal/mole and from the elements, -251.9±0.5 kcal/mole.

Jan 1, 1974

By Thomas E. Green

A solvent extraction procedure using 8-hydroxyquinoline and chloroform was investigated by the Bureau of Mines as a preconcentration technique for the determination of aluminum, calcium, cobalt, copper, iron, lead, magnesium, manganese, nickel, and zinc in large samples of high purity tungsten. X-ray spectrographic and atomic absorption methods were used to determine the trace metals after preconcentration. The presence of 10 grams of tungsten had a pronounced effect on the distribution of 8-hydroxyquinoline between the aqueous and chloroform phases. This change in the 8-hydroxyquinoline distribution in turn had an adverse effect on the extraction of the trace metals. Extraction efficiencies can also be adversely affected by an increase in the quantity of extractable metals present, as shown by radiotracer tests using 65Zn. Excess 8-hydroxyquinoline in the extracts did not interfere with the determination -of the serious interference in the combined ion exchange paper--X-ray spectrographic method. Although preconcentration by 8-hydroxyquinoline extraction was found to be partially successful, other preconcentrationn methods based on ion exchange and dithizone extraction were found to be superior.

Jan 1, 1968

By McHenry Mosier

Mercury is one of the strategic metals the supply of which has been raised from critical uncertainty to more than enough for essential demands. Work by the Bureau of Mines has contributes substantially to increased production of mercury in the United States and to consequent accumulation of Governments stock. Other contributing factors were higher prices for mercury and Government loans to operators. The Bureau has undertaken 15 exploration projects, 13 of which have been completed. This work comprised 40,307 feet of drilling arid 35,082 linear feet of sure ace trenching and has indicated commercial ore containing 37,400 flasks of mercury and marginal ore contain¬ing 29,200 flasks - a total of 66,600 flask , equivalent, respectively, to domestic production at 50,000 flasks per year for 9 months , 7 months, and 16 months. Early in 1944, as Government stocks had become adequate, domestic production was gradually curtailed cancellation of Government contracts for the purchase of mercury and Government control of labor and operating supplies.

Jan 1, 1944

By D. Eugene Rannels, Yu-Chen Lee, John W. Swisher

"Inhaled dust particles of appropriate size contact cells of the alveolar region.' The acute response to coal dust appears to involve a variety of cell types, including alveolar epithelial cells, interstitial fibroblasts, both resident and recruited macrophages, and cells of the immune system. Direct and indirect effects of dust, which may be mediated by soluble factors,'' can initiate acute and long-term lung injury. While it appears that epithelial cell growth and differentiation, along with integrity of the epithelial basement membrane, may play a role in the long-term response to dust exposure, little is known of the role the alveolar epithelium may play in the progression of injury. The broad hypothesis that underlies these experiments is that short- and long-term consequences of coal dust exposure involve changes in structure and function of the alveolar epithelium and the underlying extracellular matrix. Recent studies show that coal dusts exert direct effects to modify pulmonary epithelial cell-extracellular matrix interactions in vitro.3EXPERIMENTAL PROCEDURESType II cells isolated on day 0 by density centrifugation and differential attachment4 were plated overnight in D MEM containing 10% fetal calf serum before exposure to anthracite dust PSOC 867 sonicated into culture medium (750 ug/mL).3 Synthesis of extracellular matrix proteins was determined on day 3 of primary culture, as detailed elsewhere. 5 Cells were removed from extracellular matrix by extraction with NH4OH and high salt. Extracellular matrix synthesis and fibronectin content were evaluated based on radiolabeling with 3 H-leucine and on Western blot analysis, respectively. Additional analytical methods and calculations are detailed elsewhere.3-5"

Jan 1, 1998

By V. B. Dale

This paper is one of a Federal Bureau of Mines series covering the mineral resources of the Nation. It briefly describes most of the tungsten deposits in Cochise, Pima, and Santa Cruz Counties, Ariz. Most of the descriptions are from field examinations by the two senior writers, prior to July 1957. Wolframite first was identified in Arizona in 1896 by W. P. Blake, Territorial Geologist. Tungsten mining began about 1900 in the Little Dragoon deposits of Cochise County, and about 1901 in Las Guijas district of Pima County. The price history of tungsten is an erratic one; consequently, production has been erratic. Prices rise during wars and periods of national preparedness. Production of tungsten ore was stimulated greatly by a Government purchasing program, announced on May 10, 1951, wherein the Government agreed to purchase standard-grade tungsten concentrates at $63 per short ton unit5/ for 5 years or until 1,468,750 units were purchased. This was later increased to 3,000,000 units, and after this amount had been purchased in June 1956, the purchase of an additional 1,500,000 units was authorized. Government purchase, however, was suspended in December 1956 before completion of this latter program, and the price of tungsten concentrates declined sharply. The price had dropped to $15 per short ton unit, duty extra,6/ by the last part of July 1957.

Jan 1, 1960

By A. B. Whitehead

A spectrographic method for the determination of 18 impurities in cerium is presented. The carrier distillation technique is utilized to separate the spectra of impurities from the complex spectrum of cerium. Metal samples are ignited to the oxide, mixed with silver chloride carrier containing an internal standard, and excited with a 20-ampere direct-current arc. An additional exposure, made after carrier depletion, provides for the determination of refractory elements. Experiments to determine the best carrier, sample-carrier ratio, electrodes, arc current, exposure conditions, internal standards, and any matrix effect are described. The relative standard deviation of the method at the 20- and 200-part-per-million levels is about 25 and 15 percent, respectively. The average relative error is about 20 percent in the 10- to 1,000-part-per-million concentration range.

Jan 1, 1962

By H. B. Brunot

A complete list of permissible mine equipment, tested and approved by the Bureau of Mines previous to January 1, 1947, was published as Information Circular 7432.2/ A list of permissible mine equipment tested and approved by the Bureau of Mines during the calendar years 1947, 1948, and 1949 was published as Information Circular 7569. The present list supplements Information Circulars 7432 and 7569 and includes all of 'the equipment approved during the calendar year 1950. Information Circular 7465, which included a list of permissible mine equipment tested and approved by the Bureau of Mines during the calendar year 1947 therefore is superseded.

Jan 1, 1951

By A. R. Taylor

Low-temperature heat capacities of cesium chloride (7° - 300° K) and cesium iodide (13° - 300°K) were measured with an adiabatic calorimeter. The heat-capacity measurements were analyzed graphically to determine smooth values of heat capacity, entropy, enthalpy function, and free-energy function at 10° K intervals and at 273.15° and 298.15° K.

Jan 1, 1963

By Charlie Wyche

The principal minerals produced in the Dominion of Fiji in 1982 were unrefined gold, silver, and tellurium. The combined value of these commodities was about $16 million,2 representing over 85% of the total value of mineral output. Cement, sand and gravel, and quarry products were the other minerals produced in Fiji. Despite the small part played by minerals in Fiji's economy, exploration on land and in the coastal areas was carried out by several international mining companies representing Australian, British, Canadian, West German, and U.S. interests. At the end of 1982, 30 prospecting licenses covering 2,300 square kilometers were issued. Most licenses were for copper, zinc, gold, and silver. Total expenditure on mineral exploration was $3.5 million.

Jan 1, 1984

By R. R. Hornor

BIBLIOGRAPHY OF ARTICLES RELATING TO THE PRESERVATION

Apr 1, 1922

By O. C. Blade

This report on the properties of motor fuels sold through service stations In the United States was made In accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the items Is confidential. 1t presents analytical data for 4, 802 samples, representing the products of 117 companies. The samples were collected during December 1954 and January and February 1955. As in previous surveys, the gasolines covered 6y this survey Include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation, A list of the National Motor-Gasoline Survey reports published during the past 10 years is given on page 5.

Jan 1, 1955

By Steve Bessinger, Steve Signer, James Pile

The San Juan Mine and the National Institute for Occupational Safety and Health conducted a study to measure how development mining affected bolt loads. Twelve fully grouted, instrumented roof bolts were installed at two three-way intersections as part of the standard bolting pattern. Newly developed miniature data acquisition systems (MIDAS) were used to measure bolt load changes during initial face advance and cross-cut breakthrough. The effects of cut placement and depth on roof bolt loads were studied. This test showed how bolt loads increased at five positions along the bolt length during initial mining. Both entry advance and cross-cut breakthrough produced a similar percentage of increase in bolt loads. Geologic differences between the test sites were probably responsible for the differences in amounts of bolt loading. The test site with more top coal and a higher rock quality designation (RQD) had lower bolt loads.

By Bradley V. Johnson

The Bureau of Mines constructed a microminer--a scaled-down (5-by 5- by 11-foot) continuous-mining machine of the drum type with a unique triaxially controlled head--for use in a research program to study the effects of continuous-mining-machine parameters on the generation of respirable dust. This report describes field research with the microminer at the Bureau's Experimental Mine at Bruceton, Pa. Experiments were conducted to determine the effects of depth of cut, rotational speed, and sump and shear rates on the generation of respirable dust. The cutting forces were also monitored and compared with depth of cut. There appears to be a reduction in the amount of respirable dust generated when the depth of cut is increased or rotational is speed lowered, Variation of other machine parameters seems to have little effect on dust generation.

Jan 1, 1975

By V. F. Parry

 The amount of energy required to support a unit volume of industrial production appears to depend on the volume of industrial production, effi- ciency of utilization of fuel, the form of energy used, climate, and popula- tion served. Previous to the first World War, industries of the United States were learning how to use the vast resources of energy that were available. From 1895 to 1900 the total amount of energy produced was equivalent to 3.7 tons of 13,100 B.t.u. coal per capita, but from that period until 1920 the energy used increased steadily until it reached an average of 7.7 tons per capita. Since that time the amount used has fluctuated with business con- ditions and has averaged 6.9 tons per capita.

Jan 1, 1943

By John B. Umhau

In 1930 , 65,448 long tons of virgin or primary tin were consumed by 1,292 establishments in the United States , representing about 91 per cent of the total consumption as computed from imports , exports , and stocks at the beginning and the end of the year . The reported consumption was equivalent to 38 per cent of the world's tin production in 1930 , estimated at 171,000 tons , and was 12 per cent less than the 74,369 tons consumed by 1,307 establishments in 1928 . Decreased consumption of new tin in 1930 ás compared to 1928 was a reflection of the general industrial depression . All of the tin- consuming industries showed substantial decreases except tin plate and terneplate , white metal , and tinning , which showed small tonnage increases aggregating only 1,200 tons . The largest tonnage decrease was in the use of new tin in babbitt which declined 33 per cent in 1930 as compared to 1928. This was largely attributable to the decreased production of automobiles and trucks , which was 24 per cent lower in 1930 than in 1928. Percentage decreases in other important tin- consuming industries were as follows : Solder 18 per cent , bronze 19 per cent , tin foil 40 per cent , chemicals 23 per cent , tin oxide 44 per cent , and type metal 46 per cent . The distribution of the amount consumed by various uses during 1927 , 1928 , and 1930 is shown in table 1 . Consumption studies indicate the fact that variation in tin consumption from year to year parallels the fluctuations in demand for the already wellestablished tin products . For example , the manufacture of motor cars and trucks3 required only 11,000 tons of tin in 1930 compared to 19,000 tons in 1928 ; the canning industry continues to require the greater portion of the tin plate and much of the solder . Recently developed industries , while affecting total consumption of bearing metals , solders , etc. , to some extent , have made little change in the relative importance of these commodities as consumers of tin .

Jan 1, 1932

By F. N. Kissell

The applicability of the "direct method" for determining the methane content of virgin coalbeds was tested. Preliminary results indicate that the direct method, when applied to exploration cores, can be successfully used to estimate coalbed gas content and also approximately predict the total gas emission from a prospective mine located in the coalbed at the exploration site.

Jan 1, 1973

By H. M. Smith

In studying the chemistry of lubricating-oil fractions from so-called ?paraffin-base? crudes, one of the first requisites is a method for the separation and removal of waxy material. A method utilizing solvents for this purpose is described in this report, together with preliminary experiments with solvents that led to its development. The solvents actually used are secondary butyl alcohol, acetone, and mixtures of these.. Isopropyl alcohol was also studied. Preliminary Experiments In previous work on "intermediate-base" crude oil, following the work of Wyant and Marsh acetone had been used for laboratory separations of oil and wax. Then acetone was tried for the separation of the waxes and oils of "paraffin-base" crude, the volume of acetone required (80 parts to 1 part of oil) was found to be too great for large-scale work. For this reason the effectiveness of other solvents was studied; the separation by acetone, however, was used as a standard.

Jan 1, 1927

One of the major unknowns in the use of iron and copper is the quantity of various low level impurities, particularly hydrogen, that may be introduced during the deoxidizing process prior to casting. Introduction of hydrogen results in the embrittlement of components made from these metals. In addition, hydrogen bubbles in castings of copper result in the formation of blisters and swelling of the casting. During the last year, a significant effort has been made at the University of Missouri-Rolla to understand the permeation of hydrogen in galvanized automotive steel components and the hydrogen absorption during the electrodeposition of copper. The galvanized steel components consisted of automotive upholstery clips, seat belt holders and brake clips. Although the process of galvanization protects the steel from corrosion the process invariably causes the steel to pick up enough hydrogen to make it susceptible to brittle fracture.

Jan 1, 1992

Control the release of ground-water into active underground coal workings by short-term pumping from dewatering wells sited on fractures. Approach The sudden release of fracture-stored groundwater into underground coal workings often occurs when mine workings are developed beneath fracture valleys, Pumping from fracture trace-sited dewatering wells, prior to development of the underlying workings, can be an efficient means of intercepting fracture-stored groundwater before it is released into the mine. Dewatering operations are discontinued once the underlying mine workings have been fully developed, and the maximum possible reduction in fracture storage has been achieved through pumping. How It Works An aerial photographic technique known as fracture trace analysis is used to site dewatering wells on rock fractures in a valley bottom. Downhole caliper and temperature logs are used to assess the fracture flow potential of each dewatering well drilled.

Jan 1, 1987