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By J. W. Horne

The United States Bureau of Mines in cooperation with the State of Colorado at the University of Colorado has conducted experiments to determine the amount and composition of the non-condensable gases evolved when crude shale oil is distilled under pressure. Hydrogen sulphide is one of the components found in the complex mixture of Gases produced by the distillation of shale oil under pressure. This paper deals with the apparatus and method used in determining the amount of hydrogen sulphide evolved in the laboratory experimental cracking stills. The study required a complete extraction of all the hydrogen sulphide from the gas stream after it left the water-cooled distillate condensers and before the gas stream entered the charcoal absorber for removing the light naphtha. In devising the method it was necessary to take into account a constant variation of velocity, pressure, and percentage of sulphide in the total gas stream coming from the still. Ordinarily, the quantitative determination of hydrogen sulphide in gas is made by analyzing small samples taken at regular intervals. This estimation can be accomplished by use of the Bunts gas burette as modified by Tutriler, or by a similar method. In the industries where the flow of gas is constant and of uniform composition, this practice is sufficiently accurate for plant control. For experimental work where many variables have to be taken into consideration, as in the case at band; these methods are not applicable.

Jan 1, 1931

By J. W. Horne

The United States Bureau of Mines in cooperation with the State of Colorado at the University of Colorado has conducted experiments to determine the amount and composition of the noncondensable cases evolved when crude shale oil is distilled under pressure. Hydrogen sulphide is one of the components found in the complex mixture of uses produced by the distillation of shale oil under pressure. This paper deals with the apparatus and method used in determining the amount of hydrogen sulphide evolved in the laboratory experimental cracking stills.

Jan 1, 1931

By A. R. Taylor

The Bureau of Mines has determined the heat capacity and enthalpy values for beryllium sulfate (BeS04) throughout the temperature ranges of 10° to 300° K in an adiabatic calorimeter, and 350° to 860° K in a Bunsen-type ice calorimter, The heat-capacity data were extrapolated to 0° K, and smooth values of heat capacity, entropy, enthalpy function, and free-energy function were reported at 10-degree intervals between 0° and 300° K. The method of least squares was used to fit the enthalpy data with an algebraic equation. The equation also was used to calculate values of heat capacity, entropy, enthalpy function, and free-energy function at 50-degree intervals between 300° and 900° K.

Jan 1, 1963

By R. V. Ramani, A. S. C. Owili-eger

Mathematical modeling is a scientific exercise with the objective of developing simplified mathematical statements that relate to one another the same way as the processes that are being modeled. The utility value of the model is dependent on the ability of the model to closely approximate prototype behavior. Development of a perfect model, therefore, is an unrealistic objective because of the simpli¬fying assumptions made in building it. However, for a model to be acceptable for application, its operating characteristics or data generated from it should, within reasonable accuracy, duplicate proto¬performance. The validity and accuracy of a model depends on the mathematical constraints presupposed in model formulation. The final model must be tested for mathematical validity and for closeness of representation of the prototype. Mathematical validity, does not, however, imply that the model is accurate and correct but is prerequisite. Model testing and verification for the steady state model are given in Owili-Eger et al (1973). The unsteady state model has been tested for mathematical validity and found to be correct but has not yet been applied to a field condition for lack of data. However, in the application discussed below, the unsteady state model results are compared with pressure curves reported in literature and also with results from the steady state model. Coal seam characteristics and gas reservoir pressure used in this application are extracted from Kissell (1972). These characteristics are for the Pittsburgh seam, Federal No. 2 Mine, Fairview, West Virginia.

Jan 1, 1974

This is an audience, I know, that shares my interest in a subject that is currently getting a lot of attention -the tendency of our Nation to draw increasingly on overseas supplies of certain mineral commodities, and proportionately less on domestic sources for these minerals. That we do obtain substantial quantities of some essential minerals from abroad is easy to demonstrate. That we will continue to do so in the foreseeable future is not in doubt. Uncertainty begins, however, when we try to interpret the significance of these facts. As with many phenomena, their meaning is open to a variety of interpretations.

Jan 1, 1980

By Philip W. Holland

This U.S. Bureau of Mines (USBM) report describes a chromatographic method that is used for rapid field determinations of carbon dioxide in natural gas streams at a USBM helium production facility. The method employs a commercially available portable gas chromatograph that is equipped with a 10-m fused-silica capillary column coated with a porous polymer. The instrument operating parameters permit determinations to be performed over a concentration range of 10 ppm to 10 pct with a frequency of 20 samples/h. The speed at which determinations can be performed is an important factor when evaluating efficiency or troubleshooting processes at the helium facility.

Jan 1, 1994

By R. R. Schehl

The Bureau of Mines has developed a quantitative Analysis for pyrite in coal by X-ray diffraction that can be accomplished in little more than 1 hour. To minimize the sample analysis time, data processing has been completely computerized with pertinent output information displayed on a VR12 cathode-ray tube display. Use of this computerized system is not only advantageous during the experimental stages of the pyrite analysis project but would also be essential if the X-ray diffraction procedure is accepted as a standard method of analysis.

Jan 1, 1973

By P. C. Good

The work reported here was undertaken by the Federal Bureau of Mines to investigate new methods of preparing high-purity metal. Tungsten hexachloride was prepared by direct chlorination of scrap tungsten metal and by treating tungstic oxide with carbon and chlorine. The resulting tungsten hexachloride was purified by distillation and reduced win: sodium, magnesium, or hydrogen. The metal prepared by these techniques was at very high purity after arc melting but of variable quality prior to arc meIting. Metal recovery ranged from about 40 to 90 percent of theoretical values, It was found possible to deposit a smooth, dense coating of high-purity tungsten on the inside of a heated tube by vapor-phase reduction of tungsten hexachloride at reduced pressure.

Jan 1, 1961

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

By M. G. Zabetakis

At ordinary temperatures and pressures methyl ethyl ketone (MEK)-air mixtures containing between 2.0 and 11 vol.-pct. MEK and methyl isobutyl ketone (MIBK)-air mixtures containing between 1.5 and 7.5 vol.-pct. MIBK are flammable. However, MEK-bromochloromethane (BCM)-air mixtures containing at least 6.2 vol.-pct. BCM and MIBK-BCM-air mixtures containing at least 7.0 vol.-pct. BCM are nonflammable. Also, MEK-BCM-air and MIBK-BCM-air mixtures containing less than 18.7 vol.-pct. oxygen are nonflammable. To assure the formation of nonflammable mixtures when mixed with air, MEK-BCM vapor mixtures must contain at least 1.6 vol. BCM per volume MEK, and MIBK-BCM vapor mixtures must contain at least 2.8 vol. BCM per volume of MIBK; these quantities of BCM would be produced by liquid mixtures containing 55 vol.-pct. BCM in the first case and 60 vol.-pct. in the second. An MIBK-BCM-trimethylene chlorobromide mixture containing equal volumes of each liquid forms nonflammable mixtures with air at ordinary temperatures and pressures. The same is true of a liquid mixture containing 34.6 pct. (liquid volume) BCM, 34.b pct. perchloroethylene, 15.4 pct. MIBK, 7.7 pct. toluene, 3.85 pct. ethyl amyl ketone, and 3.85 pct. trimethylene bromide.

Jan 1, 1960

By W. R. Reed

A computer model named the "Dynamic Component Program" (DCP) was specifically designed for predicting the dispersion off dust from haul trucks at surface mines. Validation of the DCP was completed by comparing its results with the results of the 1SC3 model and with actual dust measurements taken front two operating mine sires. Comparisons of the field measurements, predictions of the ISC3 model and the predictions of the DCP demonstrate that the results from the DCP represent, on average, an 85% improvement truer the ISC3 dust dispersion model results.

Jan 1, 2008

By R. R. Sayars

"Carbon monoxide is a gas slightly lighter than air, with which it diffuses readily to make a homogeneous mixture. It will burn and has a wide explosive range, that is, an explosion is possible when the air contains from 15 to 73 per cent of the gas3. This explosive range is about the same as that for hydrogen and over nine times As Tide as that for marsh gas (methane). Like air, it has neither color nor taste and has no odor in concentrations usually encountered, therefore it cannot be detected by the ordinary senses with which men are endowed. It is produced by burning carbon containing fuels, no coal, wood, gasoline, etc., whenever not enough air or oxygen is supplied to burn and oxidize the fuel completely.The human race has probably been exposed to this gas since men first began using fires in confined or sheltered places. The poisoning as usually encountered is an acute condition resulting from breathing atmospheres con¬taining this gas. A number of eases described in the ancient literature Indicate that carbon monoxide was a frequent cause of death by accident, suicide and is a means of punishment or torture. A quotation by Lewin from Aristotle who lived in 384-322 B.C., states that ""animals collapse from harmful odors as men gets a severe headache and often dies through charcoal vapors"". The Roman knew that smoke was poisonous, and used the greenest most smoke-producing wood to put persons to death. The occurrence of carbon monoxide increased in frequency through the years until at the present time it is found in the home as well as in many industries. The following table gives the approximate percentage of carbon monoxide found in gases from various sources of poisoning.4"

Apr 1, 1924

By F. W. Lee

Operating engineers and mining executives are interested in the science of applied geophysics, but are looking for a simple and understandable exposition of its problems, instead of dissertations which are becoming more and more involved and increasingly difficult to comprehend. It may be well to discuss the goal, the attempted methods of reaching it and the psychological motive, if any, tack of the science. Where does the subject of applied geophysics stand from the viewpoint of (1) the physicist, (2) the mathematician, and (3) the geologist? Fundamentally, the science aims at a differentiation of subterranean geology with the object of finding useful mineral products by the study of gravitational, magnetic, seismic, electric, and other fields which may be associated with the materials naturally or which may be applied to them. The more skillfully these fields are recognized, applied, and analyzed the greater will be the possibility of interpreting results in a way that will be remunerative both economically and scientifically.

Oct 1, 1931

By D. G. Kesterke

Research was conducted to determine the feasibility of extracting elemental oxygen from silicate-bearing melts by high-temperature electrolysis. The method was based on a modification of existing processes for electrowinning metals from their oxides dissolved in molten halide systems. Electrolyses were performed at temperatures ranging from 1,050° to 1,250° C in boron nitride cells that incorporated a silicon carbide cathode and an iridium anode. The electrolytes contained volcanic scoria as the oxygen source, plus mixtures of BaF2 and LiF as fluxing agents. Cell gases containing almost 14 volume-percent oxygen were obtained. The average anode current efficiency for several experiments of extended duration was calculated to be 55 percent. Cell design and operating conditions are described, and some of the problems associated with the process are discussed.

Jan 1, 1971

By Oliver Bowles

"Rhodesian asbestos is of high quality and is much in demand by American consumers. Production in Rhodesia was first reported in 1909. The production for this and each succeeding year is shown in the following table:The serious curtailment in production for the years 1912 and 1913 was occasioned by transportation difficulties. In 1914 a railway was projected to Victoria and thereafter production increased greatly. Up to 1916 asbestos was obtained,from the Victoria district only, but thereafter the Bulwayo district became an important,producer with minor quantities from Gwelo.In the Bulawayo district the productive area is about 2 1/2 miles long, with Shebanie mine at the north-west end, the Nil Desperandum at the south end, and the Birthday claims between them."

Oct 1, 1920

By Arthur L. Murray

"Putting safety over , " using the accepted meaning of the word " Safety " as the elimination of personal injury , resolves itself into the prevention or disassociation of a combination of two distinct circumstances . Opportunity for accidents is afforded by conditions that are likely to cause injuries , but such injuries are effected only when the human body is placed in a position to be injured . As will be discussed later , in mining , as in most other industries , the degree of safety experienced depends upon the disassociation of these two circumstances , first , by making working conditions as free from hazards as possible , thus affording the minimum opportunity for accidents to occur , and secondly , the training of employees to recognize dangerous conditions and adopt measures to protect themselves and their fellow employees against injury . The responsibility for preventing accidents rests upon every person employed in an industry from the directing head down through the individual workers , and the safety of that industry will be proportionate to the extent that each member appreciates and accepts his individual responsibility . Hence , safety becomes decidedly a personal equation . Whether the personal equation will be so applied as to result in the greatest freedom from accidents , however , depends largely upon the initiative of those directing the industry . Putting safety over in a small mine presents the personal equation in a more intensified manner than the same endeavor in a large mine . Large mines , owing to their size and financial standing, can usually main ta in and support an effective safety organization with one or more directors who devote all their time to the supervision of safety work . Most small mines with a limited number of employees and limited capital can not afford and are not justified in supporting a paid safety organization , and must depend upon the close cooperation of their working force in maintaining safe working conditions . On the other hand , if proper supervision is exercised the small mine has in some respects advantages not afforded by the large mine . The limited workings in a small mine should afford less opportunities for dangerous conditions to arise and permits more frequent inspection of the entire mine . The small working force permits more latitude in the selection of employees known or believed to be either safe workers or amenable to safety educational work. Likewise , a small working force facilitates the carrying on of safety educational work and allows a closer personal contact between the superintendent and his employees .

Mar 1, 1923

By Steven E. Mischler

The exposure of mine workers to diesel particulate matter (DPM) and gases is an issue of great concern to the underground mining community in the United States. Approximately 30,000 underground miners are potentially exposed to high concentrations of DPM. In January of 2001, the U.S. Mine Safety and Health Administration (MSHA) promulgated rules setting compliance standards for both underground coal and metal / nonmetal mine workers. As industry works to achieve compliance with these standards, mine operators are looking for feasible methods for reducing DPM concentrations in their mines. In addition, the industry needs methods to accurately measure DPM to ensure that the control strategies they adopt are working successfully. The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) conducts research to evaluate control technologies and monitoring instrumentation that can be used to reduce the diesel particulate matter (DPM) exposure of mine workers. An overview of the strategies being utilized in underground US mines to reduce DPM concentrations will be presented. Also, updates on the development of diesel monitoring instruments such as the continuous elemental carbon monitor or the Personal Dust Monitor for DPM measurement will be provided.

Jan 1, 2010

By R. W. Freedman

The gas chromatographic method, devised by the Bureau of Mines for analyzing routine mine air samples, was compared with the infrared method used for confirmatory determination of methane in mine air. While maintaining the specificity of the infrared method for methane determination, the gas chromatographic method is more precise, much more rapidly performed, and more convenient.

Jan 1, 1968

By Phillip W. Holland

The U.S. Bureau of Mines has developed a mass spectrometer method for determining helium in the parts-per-million to 10% range to an accuracy of ± 1%. The method employs a mass spectrometer, an inlet system utilizing a chromatographic gas-sampling valve, and an activated coconut charcoal trap cooled with liquid nitrogen. Gravimetrically prepared standards of helium in nitrogen were used to demonstrate the linearity of the method over the concentration range of 10 ppm to 10.66% helium.

Jan 1, 2010

By J. D. McLenegan

The purpose of this investigation was to prepare a market survey of the refractories industry in California and Nevada (referred to in subsequent paragraphs as the region), and to determine the degree of self-sufficiency and the potential capacity for anticipated growth. The report includes estimates of the total annual refractories consumption, the quantity of refractories imported into the region, the tonnage of raw materials required for their manufacture, and the resources of fire clay and high-alumina minerals in the region.

Jan 1, 1956