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By N. F. LeJeune, Earl C. Lane

This is the third of a series of reports on a survey of petroleum prod- ucts manufactured on the Pacific Coast from California crude oils. California crudes differ in many characteristics from the petroleum produced in the other parts of the United States, and the claim has been made that some of the present Federal Specifications for petroleum products tend to discriminate against Cali- fomia products. The purposes of the present survey are to determine what par- ticular specification requirements Califomia petroleum products characteristical ly fail to meet, how widely the products deviate from these requirements, and if possible to show whether the fault lies with the specifications or the products, or along what lines investigation to determine this question should proceed. The first report of the series gave the physical and chemical properties of the samples of gasoline and mineral spirits. A second report**, gave the physical and chemical properties of samples of lubricating oils. The present report deals entirely with burning and fuel oils. The refin ing companies have continued their very cordial and helpful cooperation. Seven samples of kerosene, four samples of Diesel fuel and eight samples of fuel oil were obtained. The methods of analysis used are those adopted by the Interdepartmental Petroleum Specifications Committee, published by the Bureau of Mines in Technical Paper No. 323. The specifications used for corparison are those officially adopted by the Federal Specifications Board for the use of the various Depart- ments and Independent Establishments of the Government, effective February 3, 1923, and published by the Bureau of Mines in Technical Paper No. 323, Part 1. Specific gravity, degrees A.P.I., viscosity and other special tests al- though not required by the specifications have been given for comparison. All temperatures are recorded in degrees Fahrenheit. Tables have been prepared giving data on physical and chemical propertios of the individual samples. Before each table the classification and specifica- tions for the particular class of oil considered in the table are given. Follow- ing each table, brief notes show wherein samples deviate from specification re- quirements.

Aug 1, 1923

By R. V. Thurston, Edmund S. Leaver

"During the development of the sulphur dioxide leaching process for the treatment of ""mixed"" copper ores at the Southwest experiment station of the Bureau of Mines*** the pulp from treatment of roasted cupriferous pyrite with sulphur dioxide gases and water showed an unexpected amount of sulphuric acid. After following out several false premises it was found that this was due to iron in the solution, and also that this iron tended to oxidize to the ferric state if the concentration of sulphur dioxide in the roaster gases used did not rise above a certain figure. While the percentage of iron present was email it was enough to cause an entirely different set of conditions from those of the original sulphur dioxide leaching process and to promise a much wider application of the general idea. Sulphurous acid dissolves only certain copper minerals, sulphuric acid solutions certain additional minerals and ferric sulphate solutions certain further additional copper minerals, so this observation was of importance in connection with possibilities in the hydrometallurgy of the so-called ""mixed"" or partly oxidized copper ores.The work has been carried along by a number of experimenters. L. R. Eckman, junior chemist of the Southwest station, contributed largely to the early developments. L. Roberts, W. D. Bonner and C. G. Maier each in turn physical chemists at the Pacific Experiment station, (Berkeley, Calif.) have studied the reactions involved. A complete report of all the work on this process will be prepared later under the direction of O. C. Rolston. The purpose of the present paper is to place a summary of the more practical phases of this seemingly important piece of work before those interested."

Dec 1, 1923

By L. A. Haas

The feasibility of removing sulfur dioxide by carbon monoxide reduction in a fixed-bed catalytic reactor was investigated by the Bureau of Mines. The reduction rate of sulfur dioxide with carbon monoxide was significantly dependent upon the iron and alumina content of the mixed catalyst. Maximum catalytic activity was obtained with about 40 percent iron-alumina mixture with a nominal gas mixture of 10 percent carbon monoxide, 5 percent sulfur dioxide, and the balance nitrogen. The synergistic effect of this catalyst mixture was explained by a dual reaction site mechanism, with both iron and alumina augmenting their specific sites at their interparticle contacts. The catalytic activity also increased with decreasing catalyst pellet size. With O.7-mm pellets, the entire pellet appeared to be catalytically active in a 2-gram catalyst bed. The apparent activation energy of the reaction was 18.3 kcal per mole in the temperature range of 350° to 600° C. Carbonyl sulfide (COS) was produced by the interaction of carbon monoxide and sulfur. The amount decreased with decreasing CO concentration. The ratio of COS formed per SO2 removed reached a maximum at about 400° C. The reaction rate appeared to be independent of S02 concentration in the range of 0.2 to 16 percent. The rate, however, increased directly with the CO concentration in the range of 5 to 20 percent. The presence of CO2 (<15 percent) had no appreciable effect on the rate. However, not over 0.5 percent oxygen could be tolerated. This method appears feasible for removing S02 from waste gas if the oxygen is removed prior to the catalytic S02 reduction process.

Jan 1, 1971

By John Durkin

Owing to the daily exposures of uranium mining personnel to 222Rn daughters, a device is needed that will continually monitor individual exposure. Such a device has been built and tested by the Bureau of Mines and is known as a radon daughter dosimeter. This is an electronic instrument using a solid-state detector and circuitry. The concept of the instrument, which is a personal device worn throughout the working shift, is to evaluate an individual&apos;s cumulative exposure to airborne radon progeny, expressed in units of working level hours. Since the instrument is in close proximity to the miner and measures continual exposure, it avoids the errors caused by the present technique of spot checking of the environment and provides a more accurate account of total cumulative exposure.

Jan 1, 1977

By R. V. Ramani, R. Bhaskar

"The spatial distribution of airborne dusts, deposition of dust in the airway, as well as the effect of airflow velocity and particle density on dust behavior in mine airways were studied in a set of experiments performed in a mine airway under controlled conditions. Considerable deposition of dust near the source was indicated. Pronounced effects due to velocity were observed in ambient dust concentration and deposition along the mine airway, both in the respirable and the total size ranges. Cross-sectional concentration measurements indicate an increase in concentration from the roof to the floor. The average cross-sectional concentration is about 75% of the concentration in the center of the airway.IntroductionA number of studies have been performed since the early 1950s on the behavior of dust in mine air (Bradshaw and Godbert, 1954; Dawes and Slack, 1954; Bradshaw et al., 1954; Hall, 1955-56; Reinhardt, 1971; Ford, 1971; Courtney et al., 1982). While the experimental data available from these studies are indeed useful in understanding dust cloud behavior in a specific situation, no generalized conclusions can be drawn because of the lack of data on parameters such as flow velocity, size distribution of the source dust, and particle density. These change from mine to mine or even within the same mine. The present study is aimed at providing a better understanding of the temporal and spatial behavior of dust particles in underground mine airways (National Academy ofSciences, 1980). The characteristics studied encompassed airborne concentrations and floor depositions over the entire size range as well as the respirable size range. The experimental results in this paper are intended to complement a mathematical model developed to predict ambient concentration and deposition of airborne dust in mine airways (Bhaskar and Ramani, 1986)."

Mar 1, 1989

Determine the minimum waterflow rate needed for effective control of dust produced by cutting machines used to mine water-soluble ores. Approach Conventional wet-bar cutting techniques were studied to evaluate their dust control performance, and the optimum water flow needed for dust suppression was determined. Wet-bar type cutting techniques are used to help control mine dust by keeping the cutting chain wet. As the chain cuts the kerf, it dampens the dust produced by the cutting action at the point of generation. The Bureau, under contract, evaluated three basic wet-bar techniques, as shown in the diagram: water-trickle system A uses a gravity-feed or low-pressure (less than 50 psi) pump to send water through the bar and to discharge it at the bar tip. Water-spray system B uses a low-pressure spray nozzle located at the front of the cutter head. For protection the nozzle can be located within the cutter

Jan 1, 1982

By G. H. Hopkins

Like most industries, the refining industry has in recent years been confronted with the problem of a decreased martin of profit, due both to a general lowering of prices and to rising costs. This has resulted in accelerating a program of increased efficiency an evidenced by improved methods and the installation of equipment designed to affect a number of economies hitherto regarded as unimportant. Perhaps the most important of these has been that of fuel economy for, as is not often realized, a refinery consumes about one-tenth as much fuel as it produces. A recently completed canvas., made by the Bureau of Mines for the purpose of determining the trend of fuel consumption at refineries in the United States, showed the following outstanding points, (1) a decrease in the use of oil for fuel in 1926 of approximately 4,000,000 barrels as compared with 1925; (2) a small decrease in the use of coal; (3) a material increase in the use of gas, both natural gas and refinery gas; and (4) a considerable increase in the use of petroleum coke.

Jan 1, 1927

By J. S. Malesky

"INTRODUCTION The Airdox method of breaking coal utilizes compressed air under high pressure and was developed to replace explosives. It is used in Illinois and Indiana mines to a large extent and also has been introduced in mines in a few other States.ACKNOWLEDGMENTThe author gratefully acknowledges the information and photographs furnished by the Cardox Corp.HISTORYIn the early 1920's, with the adoption of mechanical mining in States where on-shift shooting was prohibited, it became desirable to develop some means of breaking coal from the face without the use of explosives. At that time it was thought that a pressure of 20,000 pounds per square inch would be necessary to break the seal. It was impossible to obtain a compressor that would develop this pressure therefore, the 'patentees developed and applied the Cardox method, which utilizes liquid carbon dioxide as the blasting medium."

Aug 1, 1948

By A. A. Berk

In the course of a study of the formation of external deposits on tubes in water-tube boilers it became desirable to determine the sulfur dioxide (SO2) and sulfur trioxide (SO3) in the Due gases. Determinations made by the A.S.M.E. method for SO2 and SO3 in gaseous products of combustion did not give accurate results. It was found that minute quantities of copper, present in the flue gases from the coal in use, caused oxidation of sulfite in the absorption bottle and that the carbon dioxide (CO2) in the flue gases caused high values for SO2. The A.S.M.E. test procedure was revised to prevent oxidation of sulfite in the absorption bottle and to allow for the effect of CO2; subsequent analyses of flue gases produced reliable results. The revised procedure is described.

Jan 1, 1950

By Wm. W. Odell

In distributing natural and mixed gas, the industry is each year confronted with the problem of manufacturing gas in increasing amounts as the supply of natural gas becomes more nearly exhausted. The manufactured gas is now used in mixtures with the still available natural product, and will subsequently be used straight as a substitute gas. The gases that might be considered, and are producible by tried and developed processes, include water gas, carbureted water gas, and coal gas. Singularly, these gases can be used in this manner in ordinary appliances only when proportional amounts of them in the mixtures do not vary beyond rather definite limits, unless burner adjustments are made. The limits are defined by the specific gravity, content of inerts, and burning properties of the respective gases. Anticipating a future standard for city gas lower than that of natural gas during the period when considerable natural gas is available, there is justification for considering the possibility of re-forming natural gas and making a product that has substantially the same properties as other gases which can readily be generated. This report gives the results obtained during a series of tests made under a cooperative agreement by the U. S. Bureau of Mines with the Ohio Fuel Gas Co., re-forming natural gas at Toledo, Ohio, in full-scale operation in a water-gas generator having a grate area of 25.1 square feet. ACKNOWLEDGMENTS The Ohio Fuel Gas Co. constructed a special water-gas generator for the tests and provided men and the necessary funds for its operation. Appreciation is expressed for the general spirit of helpful cooperation which was evidenced in the activities of all those who took part in the work. Particular acknowledgment is made of the assistance rendered by C. W. Wallace, manager, and by C. F. Cramer, superintendent, and A. Upp, foreman of the plant.

Jan 1, 1929

By J. N. Tomlinson

Trailing-cable splices are evaluated for moisture exclusion abilities after repeated travel over shuttle-car sheave wheels. Tests are conducted on cables with jackets made of neoprene, cholrosulphonated polyethylene (CSPE), and nitrile butadiene-polyvinyl chloride (NBR-PVC) to 50° C. The results show that some splice kits are effective as received, others are improved with minor but significant changes, and still others must be redesigned to be effective in underground applications. Laboratory results are compared with actual underground splice results. Recommendations for cable preparation prior to splicing are presented.

Jan 1, 1979

By Robert P. Vinson, Kissell. Fred N., Edward D. Thimons

"The Bureau of Mines investigated the presence and extent of methane accumulations in mine roof cavities using a full-scale mine model. Methane was released at a constant rate into the roof of a cavity built onto a 700-ft wind tunnel. Two box-shaped roof cavities were used in the study: one had a volume of 114.7 cu ft; and the other had a volume of 57.3 cu ft. Methane concentration was measured at 28 sampling points in the cavities using 21 different combinations of gas emission rates and air velocities. Brattice hung in the cavity helped reduce methane concentrations without auxiliary ventilation. It was also found that the effective ventilation rate increased by a factor of 40 in the large cavity and by a factor of 20 in the small cavity when air velocity was increased from 100 to 600 fpm.INTRODUCTIONAny location in a coal mine where 5 pct or more of methane is present constitutes a potential site for an explosion and roof cavities are likely locations. Unfortunately, little is known about the buildup of methane in roof cavities. Some research has been done using scale models where no air flows past the cavity so that methane disperses only by diffusion (5) 4 a rare situation in mines.No known cavity-model investigations have been made that simulate air and methane flow conditions normally encountered underground. These Bureau of Mines studies were undertaken to determine the extent and manner of methane buildups in coal mine roof cavities with air velocities in the range normally found in coal mines and with various methane emission rates."

Jan 1, 1978

By John M. Dower, Ralph W. Plummer, Terrence J. Stobbe, Hyunwook Kim

"The relationship between exposure to coal mine dust and the development of various respiratory diseases is well recognized. The cause of these diseases however. Is still uncertain. To study this cause-effect relationship, It Is necessary to characterize the coal mine dust In terms of the quantity of dust present and mineral content of the dust. Dust samples were collected using a Portable Continuous Aerosol Monitor (PCAM) and 4-stage cassette Impactors at various locations in an upper Freeport seam coal mine In West Virginia. The samples were analyzed using an X-ray microdiffraction film technique and energy dispersive scanning electron microscopy. This paper presents the results of the first phase of this characterization work which Includes determining the size distribution of the dust and the mineral content of the size intervals.IntroductionDiseases associated with dusts in coal mine environments continue to afflict miners in today's modem mines. These diseases still persist because, as Olishifski points out an employee rarely experiences exposures to a single environmental stress but rather to an Intricate Interplay of multiple stresses.(1) In the case of coal mining the multiple stresses are varying sizes of dust particles originating from coal imbedded minerals. Immediate roof strata bottom strata. Incombustible rock and the coal itself. The site of this Intricate Interplay Is the miner's lungs and the resulting diseases are a function of the composite dust exposures.The proper study of coal mine dust toxicity requires that the dusts used replicate existing coal and mineral dust compositions in their relevant size fractions. The purpose of this project is to develop the size and mineral content data necessary to support this ongoing toxicological effort.Existing coal mining standards and regulations also address total and respirable dust exposures. These dust terms refer to both the quality and quantity of the dust segment in the mine atmosphere. Dust quality addresses its coal and mineral content. whereas dust quantity Is described by mass per unit volume (mg/m3) The comprehensive characterization of coal mine dust exposures will enable revision of these standards and regulations to address the specific minerals and size fractions found to be toxic to human lung tissue."

Mar 1, 1989

By T. M. Ruff

The U.S. Bureau of Mines has developed a portable, inexpensive teleoperation system for mobile hard-rock mining equipment. The system was tested on a compact loader-trammer in a simulated stope. The teleoperation system includes radio remote control and computer-assisted navigation. A recent enhancement includes video cameras mounted on the machine to provide visual information to the operator. This system allows the operator to remain in a safe location while operating the machine from a distance, thus increasing both operator safety and mining productivity.

Jan 1, 2010

By Wilson Blake

The Bureau of Mines used a mathematical model based on the finite element method of stress analysis to calculate stresses and displacements surrounding an open pit mine in a gravity-loaded rock mass. Comparison of the finite element solution for a semicircular notch in a gravity-loaded plate with the theoretical solution for a semicircular notch in a plate under uniform compression parallel to the free boundary demonstrates the inapplicability of the latter method to openings at the free surface of a gravity-loaded medium. High stress concentrations are formed at irregularities along the boundary of an open pit in a gravity-loaded continuous competent rock; however, for this type of rock the magnitudes of the stresses are too low to be considered a major factor in open pit slope stability. High stress magnitudes will occur if, in addition to the gravity stress field, a large horizontal stress field exists.

Jan 1, 1967

"Introduction.The Bureau of Mines has taken up the problem of determining a method or methods whereby underground compensation insurance rates for metal-mining companies can be equalized in proportion to the underground hazards involved. This study has been started by the writer with the assistance of Mr. I. M. Wolfin* as consultant.The present paper briefly reviews the origin of accident compensation, gives a digest of State compensation laws, and describes types of insurance carriers. This will be followed by study of the basis of premium rate, risk differentials, and cost of compensation insurance to mine operators. These data will be supplemented by an analysis of the accident hazards in different mining methods and practices, and the severity and frequency of accidents classified by time lost and period of exposure to hazard, for different States, mining methods, occupations and nationalities. Attention will be given to standardized preventives for underground accidents in metal mines, and, finally, the classification of underground metal-mining hazard for workmen's compensation insurance premium rating."

Mar 1, 1924

By G. S. McCaa

Rock-dusting is an. effective means of preventing coal-dust from propagating an explosion in a coal mine, but it will not prevent gas from igniting-explosively and with much attendant damage locally. Ventilation must therefore be effective at all times, regardless of the employment of other explosion-prevention methods, if gas explosions are to be avoided. This paper describes a gas explosion which occurred in as bituminous mine that was well rock-dusted at the point of ignition and which exemplifies the value of rock-dusting, the necessity of maintaining effective ventilation, and the need of permissible rock-dusting machines receiving power from a permissible locomotive. Description of Explosion The mine in which this explosion occurred is developed on a panel system in a practically level seam; the panel entries are driven in pairs, and the air current intakes on the right entry and returns on the left entry. Near the mouth of the intake a door is placed to control the ventilation; board stoppings are placed in crosscuts, except the second from the face, in which a brattice cloth curtain is hung, the last crosscut is left open and line brattices conduct the air current from the last crosscut to the faces. In No. 7 entry the last cross-cut was 152 feet from the face, the line brattice being within 38 feet of this face, and the second crosscut was 250 feet outby the face of the back entry or return. Seven days prior to the explosion the intake and return entries were rock-dusted to within 38 feet of the face, and as the entry had advanced during the week, the rock-dusting was to be extended.

Jan 1, 1929

By J. A. Herdlick

"INTRODUCTION The Bureau of Mines began a broad program of exploration of various proportion in the Pine Creek area of the Coeur d'Alene mining region in the fall of 1943. As a part of this project, exploring was done at theLittle Pittsburg property in 1945. The work included driving a 500-foot crosscut from the No, 6 level and drilling four diamond core drill holes to test the behavior of the Little Pittsburg vein at depth. This report presents the data obtained by the Bureau.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources, to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyses samples and performs beneficiation tests.The Bureau's exploration of the Little Pittsburg vein was one of the activities of the Albany Division of the Mining Branch, S. H. Lorain, chief. The project was started by R. M. Gammell, mining engineer, and was continued by the author and J. R. Reynolds, assistant mining engineer.The chemical analyses included in this report were made at Reno, Nov., under the direction of A.C, Rice, acting engineer in charge, Rare and Precious Metals Experiment Station, Bureau of Mines.The cooperation and assistance of the management of the Denver Development Co. is gratefully acknowledged, in particular that of C. E. Nugent, who made available much of the operational data included in this report."

Jan 1, 1947

Reduce the dust exposure to the operator of a longwall shearer with a novel foam spray system. Approach Discharge foam through the nozzles of a shearer drum so that foam and coal are better mixed. How It Works Bureau of Mines research showed that two very important principles for successful application of foam are: (1) moisture distribution and (2) degree of mixing. Foam can distribute a given quantity of moisture much more evenly over a large surface area. Successful Bureau tests of foam for dust control always involve a high degree of mixing between the foam and the material, Mixing, permits a greater distribution of foam throughout the mined product. The most suitable location of foam application would be at the point where the dust is generated, before the dust becomes airborne. Foam nozzles located in the cutter drum (pick face foaming or ejecting foam through scroll sprays) will suppress dust close to its source.

Jan 1, 1989

By Oliver Bowles, J. E. Crawshow

A line of cordeau detonating fuse was placed in hole No. 2, no electric detonators being used in the hole. After 12 or 13 cases of 40 per cent nitro starch powder had been poured into the hole in loose form, it was found that a space of only 17 ft. remained for stemming. It was decided that space for an additional case of powder might be obtained by tamping the charge. The tamping was done with a heavy plunger, about 3 or 3 inches in diameter and 10 inches long, made of lead with an iron core with an iron eye in the top to which a 3/4 inch rope was attached, and weighing between 30 and 40 pounds. This weight was intended for use in sinking explosive in wet holes, and not for tamping. It is estimated that the tamping had continued at least 10 The quarry superintendent had gone a considerable distance for a box of powder, returned, and reached a point about 10 feet from the hole, minutes.

May 1, 1920