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By Çisem Tuba, Ismail Girgin

"Comparative atmospheric H2SO4 and H2SO4 + H2O2 leaching experiments were performed using a Turkish lateritic nickel ore containing 1.52% Ni. In the leaching tests; acid concentration, temperature and leaching time were considered as main variables and the dissolution behaviour of the ore were studied by Ni, Fe, Co and Mg analyses. The dissolution values in the H2SO4 leaching experiments were observed to increase up to 60% (w/w) acid concentration and a temperature of 95°C. Increase of H2SO4 concentration above 60% at 95°C caused decreases in all the dissolution values and this was attributed to the formation of Fe2(SO4)3 and Fe2(SO4)3•HSO4•H2O type compounds. At the considered optimum H2SO4 leaching conditions ([H2SO4]= 45%, T=95°C, t=45 min); dissolution values reached for Mg, Ni, Fe and Co were determined as 99.12%, 95.58%, 92.63% and 78.37%, respectively. An activation energy of 30.57 kJ/mole was determined for nickel dissolution from the evaluation of the kinetic data obtained for H2SO4 leaching showing that the dissolution was controlled by external diffusion and chemical reactions. Caro’s acid solutions were prepared at H2SO4/H2O2 mole ratio of 3 for varying initial H2SO4 concentrations and leaching tests were performed at 25°C. Co behaved very differently and a dissolution value of 83.94% was obtained even at 5% acid concentration in 60 minutes reaction time. Complete dissolution of Co was obtained after 30 minutes of reaction time at 60% initial H2SO4 concentration and the corresponding dissolution values for Mg, Ni, and Fe were reached to 96.16%, 94.27% and 89.46%, respectively. Although the H2SO4 + H2O2 leaching experiments were conducted at 25°C, it was realized that the temperature of the leaching medium was increased to 122°C after four minutes of reaction time due to probable exothermic reaction(s) at 60% initial acid concentration."

Jan 1, 2014

By C. Dorfling, S. Bradshaw, J. Eksteen, M. Khesa, C. A. Snyders

Titaniferous ores serve as a major feedstock for the production of a white titanium dioxide pigment, a titanium metal and several other titanium-based products. Such ores exist mainly as heavy mineral sands. Ilmenite is upgraded to intermediate products namely synthetic rutile and titania slag through the synthetic rutile route and the reductive smelting route respectively. Tronox KwaZulu Natal Sands (Pty) Ltd recovers high titania slag via the reductive smelting process while slag is used as a feedstock to the pigment industry and furnace dust from the gas cleaning plant is disposed as waste. Previous investigations have shown that such furnace dust can contain significant amount of titanium-bearing minerals. This study looks at the characteristics of the furnace dust obtained from Tronox KwaZulu Natal Sands and investigates a possible high temperature recovery route in detail. The furnace dust was examined by using x-ray fluorescence, x-ray diffraction, microscopy and laser-diffraction size analyses. The characterization work showed that the furnace dust was rich in titanium and iron, containing 49.4 wt% ??????2 and 29.5 wt% ????2??3. These oxides were associated with Si, Mn, K, and Al oxides as impurities. A Carbolite® vertical tube furnace was used to investigate the extent of formation of titania slag and metallic iron on a laboratory scale at 1500°C, 1600°C and 1650°C. The laboratory reduction tests revealed that the slag samples with an equivalent titanium dioxide content ranging from 70.9 -76.9 wt% at 1600°C and 1650°C could be obtained. The Fe content of the metallic iron samples produced ranged between 93.0 and 97.1 wt%. The experimental results were found to be in relatively good agreement with the FactSage simulations, both of which demonstrated the potential of producing a titania slag and a metallic iron from the furnace dust.

Jan 1, 2018

By V. F. Petrov, O. D. Khmelnitskaya, V. M. Lodeischikov

"The processing of copper gold ores is one of the major issues of gold-mining industry in the beginning of 21st century. In this case, application of ammoniacal cyanidation process for this type of mineral raw materials deserves special attention. Irgiredmet Institute has carried out a wide range of studies on ammoniacal cyanidation process and evaluated the possible commercial use of this process for Russian operating plants. Copper gold-bearing ore from a current Russian deposit was studied. The content of gold and copper in the ore is 9.4 g/t and 0.4%, respectively. Based on the results of preliminary test work, a flow sheet was developed. It included gravity concentration followed by cyanidation of the gravity tailings using CIP. The flow sheet provides sufficient total gold recovery (91.5%). However, this technology has disadvantages, such as high specific consumption of reagents: 4.5 kg/t NaCN and 13.5 kg/t Ca(OCl)2 the ore and the increased gold grade in the liquid phase of the tails slurry (0.2 g/t). In order to improve cyanidation process parameters, test work on gravity tails processing using ammoniacal cyanidation was carried out. After the test work was completed, ammoniacal cyanidation flow sheet for copper gold-bearing ores was developed. Leaching conditions were optimized using recycled process solutions. Recommendations on gold recovery from the solutions and tails detoxification are given. The proposed flow sheet provides 91.5% gold recovery. In this case, compared to the conventional option, the consumption of cyanide decreases by 3-4 times.INTRODUCTION The technology of precious metals recovery from gold-bearing ores is based on cyanidation. This accounts for up to 90% gold recovery and the significant portion of silver (Lodeischikov, 1999). However, there exists the category of so called refractory ores. They are not amenable to direct cyanidation (without using additional expensive processes), or they are characterized by low indices of metals recovery and high consumption of reagents. The latter also include copper gold ores. Their deposits can be found extensively both worldwide and in Russian Federation. A feature of these ores is that they contain not only gold but also copper. It is considered not only as a valuable component but also as a harmful mineral impurity that hinders gold cyanidation, gold precipitation from the solutions by cementation onto zinc dust and adsorption onto activated carbon (CIL, CIP-processes), detoxification of cyanide bearing effluents."

Jan 1, 2018

By Mario Gerards, Sergej Podkow, Marco Steinberg

"The JONES® WHIMS technology is based on the magnetic separation process and is widely used for the recovery of magnetically susceptible iron ore particles. The conventional machine design is well-known within the iron ore beneficiation industry for more than 50 years and recognized to be highly reliable, robust and extremely compact with the advantages of high capacity and selectivity. In 1981 Rana Gruber AS, Norway bought 14 JONES® WHIMS DP 317 separators when the magnetic separation plant was built and erected. Today, 11 of these old machines are still operating profitably and efficiently. The former supplier was the coal and minerals division of Klöckner-Humboldt-Deutz (KHD) which is today MBE Coal & Minerals Technology GmbH (MBE). This paper outlines a detailed description of the project of revamping the above mentioned old machines and describes the challenge of incorporating enhanced and newly developed technology into an existing processing plant. Further it gives an overview of the recent developments on the design of the JONES® WHIMS. In order to meet modern product requirements and to increase and secure plant productivity, in 2012 Rana Gruber AS settled a contract covering two new designed JONES® WHIMS DP 317 HFR separators to be implemented into the existing building and the upgrading of all 11 older JONES® WHIMS under the use of as many refurbished items as possible. The two new machines were fully developed by the product specialists of the supplier in cooperation with the operator Rana Gruber AS, thereby taking advantage of their great experience. The design of the new machine is based on the conventional design, i.e. the general operating mode as well as the overall dimensions are identical. Finally this paper gives an overview about the erection and commission phase of the two new machines and gives a detailed comparison between conventional and enhanced WHIMS technology."

Jan 1, 2014

The introduction and subsequent ascendancy of autogenous and semi-autogenous milling for comminution circuits has undoubtedly lead to many economic advantages. From a process viewpoint, however, at least one downside has been the sensitivity of these machines to process input variations. Foremost among these is ore competence, though feed size comes a close second. This sensitivity is due to the reliance of ag/sag mills on the feed ore for their grinding media competence and size. Autogenous (ag) mills are the most sensitive in this respect with semi-autogenous (sag) mills being increasingly less so as the ball charge is increased. Increasingly designers and operators are recognising the importance of feed size and the benefits of manipulating it to improve performance. This has been achieved by installing additional crushing/screening capacity ahead of the ag/sag, better operation of the primary crusher, better control of segregation cased by stockpiles and bins and by changing blast design/practices to modify the ROM size distribution. This paper describes the influence of feed size distribution on ag/sag mill performance with reference to a range of plant data. It particularly concentrates on how changing blasting practice to modify ag/sag feed size can have a considerable overall benefit.

Jan 1, 2003

By Georg Unland, Thomas Wegner

"Different types of impact crushers use the physical effect of impact to crush rocks. The rocks can vary from soft to hard and from ductile to brittle but they should never be abrasive. Since the principles of impact crushing of larger rocks are hardly investigated these crushers are still sized rather by empirical than by scientific approaches.In order to investigate the principles of comminution by impact of large rocks a test rotor was developed and rocks of different dimensions were tested. The integrated measuring devices of the rotor enable the recording of impact forces and of absorbed impact energy with high resolution during the contact time.Since impact crushers stress the rock particles with a defined velocity the main crushing properties are gained as a function of the applied velocity and the particle size of the rock: likelihood of breakage, contact time, maximum crushing force, mass specific crushing work, surface related crushing ratio and crushed fragment shape distribution."

Jan 1, 2003

By Wantae Kim, Hoon Lee, Kwanho Kim, Sangbae Kim

Mechanochemical activation of starting minerals and their effect on the solid-phase synthesis and properties of ceramics with lower thermal expansion coefficient was examined. The mineral mixture, pyrophyllite-gibbsite-lithium carbonate, was prepared for the synthesis of ?-eucryptite (Li2O•Al2O3•2SiO2). Dry grinding using a planetary ball mill promoted the amorphization of the starting mixtures. XRD and FT-IR results showed that the crystallization of the target materials occurred from the ground mixtures by calcination. The crystallization of them increased with increment of grinding time and calcination temperature. In the synthesis, the trace of undesired phases such as quartz and cristobalite once formed during calcination at the temperature range from 750 to 850 °C almost disappeared and monophase ?-eucryptite was formed in the ground mixture at 950 °C. The lowest liner thermal expansion coefficient (TEC) of ?-eucryptite prepared was -2.5x10-6•°C-1. The thermal expansion behavior characteristics of the calcined

Jan 1, 2014

By Francis Pitard

"The optimization of metallurgical processes requires an in-depth understanding of the heterogeneity carried by any constituent of interest. It emphasizes that knowledge of the Theory of Sampling (TOS) is the necessary step to ensure that valuable and valid research programs, pilot plants, feasibility studies, plant design and plant operations have been set on solid foundations. Too many publications today are solely based on the properties of the sample, with no mention of how this sample relates to anything in the environment where it was collected. Unfortunately sampling is an error-generating process that leaves no apparent tracks of its shortcomings. Indeed, it is easier to track down analytical errors than sampling errors. Consequently, bad sampling practices plague the scientific community and the industry and are responsible for severe money losses, unsatisfactory science and processing, and sometimes litigation. A point-by-point strategy is presented addressing sampling problems in early stages of a project. Sampling system requirements for metallurgical accounting and process control are listed. The use of Chronostatistics is suggested to determine if sampling systems are performing satisfactorily and to identify the various types of process variability that may not be easily detected by a conventional inspection of available chronological data. This strategy will help engineering firms, manufacturers, managers and supervisors to provide, install, use and maintain key sampling systems located at very important points in a process. Equipped with the appropriate sampling and statistical tools it becomes easier to minimize reconciliation problems with the mine, with suppliers and with clients. Contrary to the beliefs of many people, good sampling systems are not expensive because in the long run they help to reduce hidden cost and better regulate plant productivity; they most certainly minimize the number of unnecessary meetings looking for solutions where there are none. The suggested strategy will help specialists to extract maximum information from the available data, as large investments and crucial decisions depend on it."

Jan 1, 2014

By John Nell, Paul den Hoed

Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and high-titania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes. Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites. A reaction mechanism is presented; where possible, its validity is demonstrated by the support of empirical observations.

Jan 1, 2003

By P. Condori

In spite of the importance of the slurry transport and discharge in autogenous and semiautogen-ous (AG/SAG) mills, it is evident that a more comprehensive and useful model is still required. Semi-empirical models used up to now have many limitations and cannot be used beyond the ranges in which they were developed. The breakage of particles as they are transported along a mill com-plicates the experimental analysis and the modelling of the transport process within the mill. The interaction of the grate discharge and the pulp lifters, with the added issue of backflow from the pulp chamber into the mill, makes the discharge modelling process difficult. In order to overcome these difficulties, a mechanistic approach has been applied. The general transport and discharge model was subdivided into four independent models: Flow through the charge, flow through the grate, flow in the pulp lifter, and flow-back. This paper gives an overall description of the modelling approach and discusses in particular the modelling of transport of fluids through the charge. In order to evaluate and calibrate the model, experimental work was carried out. To evaluate the gradient pressure under different conditions of charge packing and flow rate, a specialised experimental rig with a highly sensitive pressure gauge was used. Preliminary results identify the differences of the charge and grate on the restriction of flow. The existence of a dynamic voidage in our particular system was more evident and as a result, a semi-empirical correlation for the voidage was developed. In general, results show that the me-chanistic model derived from Ergun?s equation for flow through a packed bed can be satisfactorily adapted.

Jan 1, 2014

By J. C. van Dyk

In a previous study by Van Dyk, et al., (2006) and Van Dyk et al. (2006), a FactSage model was developed to understand the chemistry and interpret mineral matter transformation during a fixed bed counter-current gasification process. It was concluded that the FactSage model developed, compared with HT-XRD experimental results and that the FactSage thermodynamic modeling sup-plies insight into specific mineral reactions and slag formation. The specific value for Sasol in using FactSage, in combination with HT-XRD is that it can be used to analyze equilibrium conditions for reactions occurring between inorganic and organic materials together, as well as to provide insight into mineral transformation and slag formation. The purpose of the present study was to improve the current FactSage modeling approach, by combining specific zones in the gasification process. This can improve and speed-up the interpretation of mineral matter transformations and flow properties of reacted mineral matter in coal and assist in identifying and quantifying slag formation in the gasifier operation at temperatures not reflected by normal AFT analyses. The updated and improved FactSage model compared favorably with the original model as well as with HT-XRD results and thus will be able to supply results in a faster and more convenient manner. In the new FactSage model, supported by HT-XRD experimental findings, it is indicated that feldspar formation (including anorthite) correlated with slag formation at temperatures around 1000°C and no slag formation in the base case coal was observed in the drying and devolitilization zone, as was to be expected. Feldspar is one is the mineral species which has the lowest AFT causing the most slag-liquid formation and forms probably as a product between the SiO2, Al2O3 and Ca-containing species. In the gasification zone it was clear that slag-liquid formed at a temperature of 1000°C, with a decrease in the feldspar content. Mullite formation was also observed in the base case sample in the temperature range 1000°C and 1100°C. The decrease in the amount of SiO2 at 1100°C is related to the formation of mullite, but also that the slag-liquid phase also contains an amount of SiO2 in the molten form.

Jan 1, 2014

By William Skinner, Jennifer MacCarthy, Jonas Addai-Mensah, Ataollah Nosrati

"Acid leaching in agitated tanks is central to hydrometallurgical processing for valuable metals’ (e.g., copper, gold, nickel and cobalt) recovery from low grade (e.g., < 2 wt.%) ores. In this study, atmospheric leaching behaviour of Australian saprolitic nickel (Ni) laterite ore using sulfuric acid was investigated under isothermal, batch conditions at pH 1. The effect of primary process variables comprising time (4 h) and temperature (70 and 95 oC) on the leaching mechanisms and kinetics was established for -2 mm, low grade (~1 % Ni) saprolitic ore dispersions at 40 wt.% solid loading. Leaching proceeded incongruently, reflecting the proliferation of gangue minerals’ constituent elements (e.g., Mg, Al, Fe) alongside Ni and Co in the pregnant leach solutions (PLS). Subsequent analysis showed that 89% Ni and 78% Co were extracted after 4 h at 95 oC whilst at 70 oC the recoveries of these metals were markedly low (< 25 %). Overall, 177 and 644 kg H2SO4 /t dry ore were consumed at 70 and 95 oC, respectively. Activation energy of 79.0 ±1.0 kJ/mol was estimated for the mechanism of Ni and Co leaching and associated kinetics. Particles size analyses indicated that when the breakage of frail laterite particles due to shear is taken into consideration, differences in feed and leached product particle size distributions were insignificant , despite a remarkable increase in BET specific surface area of the product. Mineralogical analyses of the feed ore and leached solid products revealed a sub-crystalline silica phase enrichment of the latter. The overall results suggest that the mechanism of acid leaching of saprolitic Ni laterite may be described by a chemical reaction-controlled, shrinking core model."

Jan 1, 2014

By Jacques Eksteen, Sharif Jahanshahi, Neill J. Bartie, Shouyi Sun

The gradual increase in Cr2O3 levels of UG-2 ores has become a matter of concern for platinum producers in South Africa due to the formation of chromite spinels in melters. The effect of bulk FeOx/MgO ratio, Cr2O3, temperature and oxygen partial pressure on phase stability and composition in the system FeOx-MgO-SiO2-Cr2O3-Al2O3-CaO has been studied between 1400°C and 1600°C using the drop-quench technique. An increase in temperature was found to result in a decrease in [Fe/Cr]spinel. This effect is shown in Figure 1 for the six slag compositions investigated.

Jan 1, 2003

By J. Drzymala

Ores and raw materials are subjected to mineral processing operations to increase the content of their useful components. Upgrading of these materials can proceed with different selectivity and therefore, there is a need to know and monitor the separation results of the process. The separation results can be evaluated using tables and graphs called upgrading curves. The course of lines in the upgrading curves is usually complex and depends on the graph type and process parameters. The Halbich grade vs. recovery plot is frequently used because is practical and it indicates several characteristic features of separation results. Separations by means of flotation of several different shale, dolomite and sandstone copper ores were performed along with determination of their mineral composition, copper content, liberation degree, and the maximum theoretical copper content in the first concentrate. These data, plotted as the Halbich upgrading curves, allowed to find other characteristic points such as practical maximum copper content in the first concentrate, maximum curvature coexisting with the liberation degree, maximum recovery of ore valuable components, and the slope the recovery-grade line at high recoveries as a measure of liberation. Correlations between theoretical and practical maximum copper contents in the first concentrate as well liberation degree and maximum curvature were also presented. They show that the ore type significantly influences the shape of the Halbich curve and its characteristic points.

Sep 1, 2012

By A. Kuriwada

Dolomite is a mineral, which consists of CaCO3 and MgCO3. In this work, a series of experiments were carried out in order to adsorb boron from a boron-containing solution using a calcinated dolomite sample, and then to desorb it from the loaded adsorbent. A particular modification on the surface of dolomite was observed when it was thermally treated at certain temperature, ranging from 750 oC to 1050 oC; in turn, it is the specific surface was increased. In other words, the experimental results suggested that the calcinated dolomite exhibited a high adsorption capacity for boron, indicating its effectiveness in effectively adsorbing boron from drinking water or wastewater.

Sep 1, 2012

By A. Boehm

Mineral selective flash roasting (Steiner process) in oxidizing atmosphere was tested successfully for the efficient low intensity magnetic separation of siderite from ankerite and other gangue minerals within the ore of the Steirische Erzberg, Austria. The calcium, magnesium and manganese containing siderite turns selectively into a ferromagnetic oxide phase while ankerite remains paramagnetic. The expulsion of CO2 increases the volume specific surface depending on the selected temperature. Unlike pure iron oxides absorbing SO2 below 530°C, the calcined siderite (enriched in the magnetic product of the Steiner process) acts as a sorbent for SO2 between 500 and 820°C. The effect was studied by thermogravimetric analysis and particle bed tests complemented with neutron thermo diffractometry (D20/ ILL). The energy input was simulated with the help of a tube furnace. The composition of the artificial combustion gas permeating the bed was close to that measured in pilot scale tests (6 % CO2, 12 % O2, 700 vpm SO2). The evaluation of data relating the SO2 variation in the off gas monitored by electrochemical cells to the actual phase composition revealed an intermediate ferrite phase as absorber. During the rapid decomposition in oxidizing atmosphere starting at 500°C the occurring siderite alters to a (CaO, MgO, MnO)Fe2O3 ferrite as an intermediate phase accompanied with sudden SO2 absorption. SO2 disintegrates the ferrite structure forming MgSO4 and MnSO4, taking Fe2O3 as a catalyst. Ankerite (enriched in the non magnetics of the Steiner process) starts to absorb at temperatures above 1000°C forming gypsum. The findings support the SO2 controlled operation of the Steiner process by ?autodesulfurisation?. It explains aspects of the SO2 implementation reactions within off gas recycling in Austrian sinterstrands. Keywords: magnetising flash roasting, neutron thermo diffractometry, SO2 absorption, siderite, ankerite

Sep 1, 2012

By A. Kamali Moaveni, A. Boehm

"The current research study addresses a physical separation process of basic oxygen furnace slag “BOF-Slag” (also called Linz-Donawitz “LD” slag) for the removal of phosphorous. In order to recycle the LD-Slag into the steelmaking process, the physical dephosphorization methods are considered. The systematic geometallurgical investigation carried out on particle classes of decreasing size, which were further subdivided into susceptibility classes, shows intimate intergrowth beyond 40 µm due to slag´s fast cooling rate. Generally, LD-slag is constituted of oxide and silicate phases, among which di-calcium silicate “C2S” dominates. About 0.5 mass% of phosphorous was detected in the LD- slag, which is exclusively situated in the lattice of the C2S. The comparatively high grinding resistance (Rittinger index 12.9 cm²/J) of the LD-slag reflects the energy demand to liberate the phosphorous carrying phase from the iron containing minerals, while separation efficiency decreases in the very fine particle size range. Hence, the conversion of the phase intergrowth pattern was considered alternatively to re-build the mineral phase structure of the material to a separable interlock pattern. Carbon dioxide, as the most convenient substance in the steelmaking plants, was applied to digest the C2S in the presence of water and to reduce the basicity of the slag slurry. As a result of C2S-CO2 chemical reaction, calcite and calcium silicate are precipitated at the surface of the oxide particles and carried between 25% and 75% of the total phosphorous, respectively. Accordingly, the mobility of the phosphorous content phase to the top of the grains serves the possibility to separate the precipitated layer by mechanical attrition process. This paper is focused on the impact of the intergrowth pattern alteration on the slag´s separability characteristics. Moreover, the operating conditions of the carbonization process, such as temperature and pressure, on the deconstruction kinetics of the C2S and the generated products will be considered. INTRODUCTION The steelmaking BOF-Slag is a stony aggregate waste from the steel manufacturing process. The investigated slag by the current research work was provided by voestalpine steelmaking plant in Linz, Austria. The current legislative situation in Austria restricts the historical application of slag as construction material, due to the high level of heavy metals content and corresponded land-filling and transportation costs of slag, therefore the demand for recycling of BOF-Slag to the steelmaking process has raised, as an alternative application. Statistically, voestalpine steelmaking plant produces about 130 kg BOF-Slag per ton of final steel product, which serves annual BOF-Slag production of 700,000 ton, approximately."

Jan 1, 2018

By G. V. Sedelnikova

Biohydrometallurgical studies were performed on the sulfide gold-arsenic concentrate obtained in treatment of refractory ore from a deposit located in northern Russia. Gold is disseminated in sulfides-arsenopyrite, pyrite and antimonite (their content is 10.0%, 30.4% and 0.7%, respectively). Gold extraction is only 11.8% by cyanidation. Results are given for test bacterial oxidation of the concentrate in continuous mode at temp. = 28~32°C using mesophilic bacteria and at temp. = 32~38°C using the association including moderate thermophilic bacteria. The paper shows that the use of moderate thermophilic bacteria allows to speed up sulfide biooxidation and reduce its time to 96 hours compared to leaching at temp. = 28~32°C for 110~120 hours. The optimal range of pH = 1.5~2.0 of biooxidation process was determined where bacterial solutions are produced with the molar ratio Fe:As > 3 necessary for precipitation of hard-to-solve, environmentally safe arsenical precipitates. Electron microscopy showed that sulfide biooxidation results in liberation of disseminated gold with nanoparticle-level sizes. High sorptive activity of carbonaceous matter and other compounds of bacterial residues cause low gold extraction into cyanide solution ? 28.7%. 10% resin load makes it possible to extract 88.1% Au. Aeration of pulp in calcareous medium enhances extraction to 95.7% and decreases cyanide consumption from 17kg/t to 8 kg/t.

Jan 1, 2014

By Jiongtian Liu, Jianjun Wu, Yongzhou Wan, Li Feng

"Mechanical Thermal Expression (MTE) is a developing non-evaporative lignite dewatering technology. It has been shown to effectively dewater high moisture content in low rank coals via the application of mechanical force and thermal energy at elevated temperatures. In this paper, the dewatering behavior of Yunnan Xiaolongtang lignite during the MTE-process was studied. Furthermore, how variations in temperature and pressure during the MTE process affect the surface oxygen functional groups and pore structure were also discussed using Fourier transform infrared spectrometer (FTIR) and mercury intrusion porosimetry (MIP). Increases in MTE temperature and pressure resulted in significant reductions in residual moisture content and moisture holding capacity, along with the increase of fixed carbon content and reductions of other elements content, especially oxygen content, which have been largely attributed to the destruction of the surface oxygen functional groups and porosity in lignite. The optimized technology conditions are temperature 150~220°C and pressure 7~10MPa. The residual moisture content of the lignite treated by MTE under the conditions of 200°C and 10MPa is decreased to 8%, while the dewatering rate exceeds 76 % and the calorific value approaches 22 MJ/kg. The experimental results offer a deeper understanding of the influence of process parameters on the lignite stuctures and properties. The reduction in residual moisture content, surface oxygen functional groups and pore volume under increasingly severe MTE conditions are suggestive of the structure changes that accompany increased coalification (rank) within the lignitic range."

Jan 1, 2014

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"INTRODUCTIONThe objective of this work was to deport silver into a residue suitable for subsequent extraction without compromising the high base metal extraction during the pressure oxidation.RESULTS AND DISCUSSIONThe complex sulphide from the tailing pond of Cannington mine, Australia, was re-grounded and a bulk concentrate was recovered by flotation. The major economic sulphides are galena and sphalerite. The chemical analyses revealed 17.22% Fe; 4.88% Zn; 8.22% Pb; 9.49% S2- and 422 g/t Ag. The baseline cyanidation yielded 36.60% of silver at high cyanide consumption (24.17 kg/t NaCN). Pressure oxidation at 150°C (in the absence of iodide), followed by cyanidation of the residue yielded 8% silver extraction. Pressure oxidation was carried out at 110-150°C in sulphate media with additions of potassium iodide and the resulting residue was subjected to cyanidation. High recovery of silver was achieved because its incorporation into lead-hydronium jarosite during the pressure oxidation was minimised, while its deportment into the cyanide-soluble silver iodide was favoured (Figure 1). Silver recovery decreased slightly at high temperatures (140° and 150°C) because of the enhanced stability and kinetics of leadhydronium jarosite, but this could be overcome by increasing acidity and iodide concentration of the slurry."

Jan 1, 2003