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By J. C. Ingles

"A new technique is in the process of revolutionizing inorganic chemical analysis. Galled atomic absorption spectrophotometry, it combines the use of a special light source, a flame, and the equipment of conventional spectrophotometry, to provide a quick, reasonably accurate method for the determination of a large number of elements.This paper outlines the principles on which it is based, describes the commercial instrumentation"" available for exploiting it, and. summarizes current applications in process metallurgy."

Jan 1, 1966

By Randolph A. Pax, Brian Cornish

The operation of grinding mills in an ore processing circuit is supported by monitoring the input and output variables. These can include the feed ore size distributions, ore feed and water addition rates. The outputs can include the discharge undersize density, oversize tonnage rate and the P80 of the discharge. The grinding mill performance is judged by the power draw, recycle rates and discharge grind size. Conditions inside the mill are inferred from loads cells or bearing pressures and past histories. An overall noise value is sometimes used to evaluate the load as well as the occurrence of excessive impacting of steel balls onto the liners/lifters of the mill. This paper presents results of the internal behaviour of a mill using non-contact stationary microphones located close to the mill outer shell (Pax, 2012). The noise generated by a mill can be attributed to a number of events that occur inside these mills and suitably analysed can provide real-time determinations of in-mill behaviour and can provide powerful insights into the operation of the primary comminution tumbling mills. The acoustically determined signals including a specific 'steel' signal, water hold-up, integrated area together with a classification of impact events. Specific results from case studies will show information of the trajectories inside a mill, steel to rock ratio as well as rheology effects. By incorporating a self-consistent understanding methodology for the in-mill processes from an array of microphones, the information can be used to diagnose the dynamic conditions inside a mill.

Jan 1, 2016

By Hoeve. J.

"In the unconformity-type uranium deposit at Midwest Lake, mineralization is associated with extensive host rock alteration, which affects the metamorphic basement as well as the overlying Athabasca Group sandstones. Host rock alteration is manifested by (I) transformation of clay minerals [kaolinite into illite and chlorite (sudoile)]; (2) bleaching due to removal of hematite from the lateritic paleoweathering profile and the overlying red bed, Athabasca Group sandstones; (3) loss of coherence of the sandstone resulting from corrosion of quartz cement; and (4) in the immediate vicinity of high-grade ore, development of a clay envelope due to residual enrichment of clay minerals caused by massive dissolution of quartz. Clay mineral transformation and bleaching are the most prominent and the most widespread alteration effects, forming haloes that extend for several kilometres along the strike of the mineralized structure and also constitute distinct alteration pipes that rise f or several hundred metres above the unconformity to be truncated at the present top of the bedrock.Although the two haloes are largely congruent features, cross-culling relationship s indicate that clay mineral alteration represents an earlier phase in the history of the deposit than the large-scale bleaching that gave rise to the superimposed bleaching halo.Because clay mineral alteration and bleaching are intimately tied to the mineralization and extend well beyond the limits of the actual orebodies, host rock alteration may be used as an ore guide in exploration and drill-hole evaluation. In this application a third hydrothermal discharge centre was identified, as yet untested for are, which is located between the hydrothermal centres associated with the two known orebodies of the deposit.It is estimated that host rock alteration may enlarge a potential drill-target by a factor 10 - 20X. Information on the configuration of bleaching haloes can be obtained from systematic core logging, whereas diagnostic clay mineral alteration is readily identified by means of automated, quantitative XRD techniques."

Jan 1, 1984

By D. G. Brophey, J. A. O’Neill

"High costs, both in terms of human resources and financial costs, have long been the end result of accidents involving vehicles which continue to occur too often throughout our industry.For example, radio remote control LHDs too often seriously injure their operators in underground operations. Costly efforts are required by mine owners to provide safety bays and platforms from which their operators can work safely. In open pit operations, large heavy haulers have too frequently backed over vehicles or turned into vehicles unfortunate enough to be situated in their large blind spots. These are just two examples of situations that have occurred again and again under similar circumstances.Meanwhile, electronic methods of detecting proximity to vehicles have continued to develop. The time has come for the industry to think “outside the box” to evaluate whether many of these new methods can solve these recurring problems.This note takes a look at various types of proximity detection technologies that are in use today in other industries, and discusses the various potential applications within our industry."

Jan 1, 1998

By X. -G. Chen, J. Qin, K. Liu, D. Racine

"Understanding the thermo-mechanical fatigue (TMF) behavior of materials plays a significant role in the safety design of critical components used in aerospace and automotive industries, such as engine blocks and cylinder heads, which undergo the cyclic change of temperature and stress. However, the cyclic changes of temperature, stress and strain make it difficult using the traditional testing methods to accurately simulate the TMF process. In the present work, the Gleeble® 3800 system was successfully applied to develop a reliable procedure to measure the TMF behavior of aluminum alloys. The modified setup together with the new designed program allows the Gleeble system to precisely simulate the cyclic profiles of temperature and mechanical strain. The novel procedure includes the calibration and verification of the TMF setup to ensure the test validity with Young’s modulus measurement, multi-cycle measurement of the thermal strain and zero stress adjustment followed by online monitoring the TMF cycles. The results of the TMF testing of an AA6061 alloy under cyclic temperatures (60–300°C) and various strain amplitudes (0.2–0.6%) were demonstrated. Its TMF behavior was characterized by the typical hysteresis loops and cyclic stress-strain response.INTRODUCTION The thermo-mechanical fatigue (TMF) behaviour becomes increasing important to evaluate the elevated-temperature properties of materials used as the critical components in automotive and aerospace industries, such as the gas turbines (Hu, Shi & Yang, 2016; Moverare, 2007; Segersäll et al., 2015) and engine blocks (Grieb, Christ & Plege, 2010; Javidani & Larouche, 2014). During the cycles of start-up and shutdown of the engines, these components undergo a complex change of loading. Meanwhile, a dramatic temperature gradient exists on the components due to the cooling system. Therefore, the cyclic changes of load and temperature can give rise to the TMF and may limit the use life of such components (Hu, Shi & Yang, 2016; Javidani & Larouche, 2014; Moverare, 2007). Hence, performing the TMF tests to precisely simulate the cyclic changes of load and temperature to understand the TMF behaviours of materials is playing a significant role in the safety design of these components. For TMF tests, two principal types of cycles are generally employed, including the in-phase (IP) cycle where the load and temperature are at the same phase (i.e. maximum load at highest temperature) and out-of-phase (OP) cycle where the maximum load is applied at minimum temperature (Kliemt, 2012; Miller, 2014). The most significant damage mechanisms in engine components are reported to be OP TMF cycles (Javidani & Larouche, 2014; Kliemt, 2012)."

Jan 1, 2018

By P. Zhang, K. Liu, L. Ou

"The strength and mechanism of Portland cement prepared from stone coal vanadium slag were studied in this paper. Initially, the slag was used as silicon raw materials to prepare clinker. By blending the prepared clinker with gypsum, waste, and fly ash, a series of different grades cement got well prepared. All of performances of the cement were up to the requirements of China’s national standard. The hydration products and microstructure of cement were identified and analyzed by X-ray diffraction and scanning electron microscopy. With the comparison of cement hydration characteristics at different ages, the strength formation mechanism of cement was clarified. The experimental results suggested that adding the fine materials (mainly waste and fly ash) to replace part of clinker would accelerate cement hydration, as it provided additional surfaces for the nucleation and growth of hydration products. And the hydration products were similar to ordinary Portland cement, mainly containing the amorphous calcium silicate hydrates (C-S-H), acicular ettringite (AFt) and portlandite (CH). With hydration time increasing, the hydration products continuously covered the cement particles, resulting in a thicker surface layer. As a result, it gradually condensed into a dense structure block with small pores and smooth surfaces, which led to higher strength. In conclusion, using the vanadium slag to prepare Portland cement can realize the utilization of solid mineral wastes, which will bring huge ecological and economic benefits.INTRODUCTIONWith the development of China’s mining industry, more and more mineral waste residue is discharged every year. These solid wastes cause varieties of resources and environmental problems on people’s living area. While at the same time, the demands of cement are increasing with the remarkable development of the construction industry. Thus, in recent years, utilization of proper solid waste to prepare cement has become an efficient way to deal with the solid mineral wastes problems (Boncukcuoglu, Kocakeri?M, & Tosunoglu, 2002; Simatupang, Hanafi, Purwasasmita, Imran, & Pane, 2012; Tsakiridis, Papadimitriou, Tsivilis, & Koroneos, 2008; Yun, Yong, Choi, Lee, & Lachemi, 2009)."

Jan 1, 2016

Evolution of Maintenance Practices. Mechanization processes in underground mining operation became stronger in the 70?s - 80?s. Did maintenance practices changed over the years ? What are the the major differences of today?s practices? Speaker, Robert Hamilton Working at different positions into maintenance organization since over 25 years, Robert has accumulated a various and rich experience of ways to maintain equipment. He started as mechanic on construction projects and open pit mines. Early in his career Robert had supervision's responsabilities. He started in open pit operation (QCM) and after in underground operation with Lac Minerals, working at Bousquet, Doyon and Louvicourt mines, as U/G mechanical foreman and mechanical general foreman, and Maintenance superintendant with Cambior . He also experienced the underground mines equipments supplier's side working with Sandvik Canada.

Feb 1, 2008

By Greg Gosson

These materials are provided for general information purposes only and do not constitute legal advice. Readers are advised to seek specific legal advice from their own counsel in relation to any decision or course of action contemplated. Outline ??What is meant by a ?current technical report? under NI 43-101? ??When is a current technical report required? ??Who makes the decision regarding whether a technical report is current? ??Examples of the types of information that make a technical report no longer current for securities filing purposes.

May 1, 2009

By Ken G. Kress

Syphons can be a simple, reliable and proven alternative to otherwise more complex pumping systems or low level outlet works. In a simple form they consist of a pipeline constructed over the top of an embankment or high topographic feature, connecting a source pond to a receiving pond or channel (see Photograph 1). The syphon action is initiated by removing air from the pipeline (priming) using simple devices which can be purchased ?off the shelf?. Once primed, the syphon flow rate can be controlled or stopped using conventional gate, valve, orifice plate or other devices. Repriming is not required even if the flow is stopped, provided the syphon is not drained. A limiting factor in considering a syphon as a design option is the maximum lift (i.e., vertical distance from source pond level to summit of syphon) which is approximately 9 metres, or less, dependent on syphon pipe features and site conditions. Pipeline syphons can be quickly constructed from readily available materials including steel, polyethylene and PVC pipe. They are particularly well suited to many of the unique conditions often encountered at minesites. This paper identifies situations that can sometimes be best resolved using pipeline syphons. It provides basic principles for pipeline syphon design and includes case histories of their successful application.

May 1, 2001

By T. R. C. Aston, C. M. K. Yuen, J. L. Gilby

"The access tunnels for the Donkin-Morien Mine in Cape Breton, Nova Scotia, comprise two parallel tunnels driven through a sedimentary sequence of sandstone, siltstone and mudstone to intersect the Harbour Coal Seam under the Atlantic Ocean, approximately 3.5 km offshore (Fig. 1). The No. 2 tunnel was driven a total distance of 3579 m using a 7.6 m diameter Loyat full-face tunnel boring machine (TBM) and was supported by steel sets. The No. 3 tunnel was initially driven a distance of 1027 m using drill and blast methods (dimensions 7.6 m wide by 5.3 m high) supported by rock bolts and shotcrete. This tunnel was then completed (front March 1986 to February 1987) using the tunnel boring machine to a distance of 3573 m.During the period May 1983 to December 1984, a major geotechnical research program was undertaken in the Donkin-Morien tunnels by Golder Associates in conjunction w,ith CANMET and the Cape Breton Development Corporation (Yuen et al., 1985). The research program included the monitoring of the performance of the TBM and drill and blast drivages, and the study of the thrusting characteristics and rock-interaction of the TBM excavation. The main emphasis of the research program was on the collection of field data which was to be made available in the form of a comprehensive report for the future use of others who might wish to carry out a detailed interpretation and analysis. The information gained from the program was also used during the tunnel"

Jan 1, 1988

By T. Alan O'Hara

"Annual mining revenue can be computed by formulae relating metal prices, smelting schedules, concentrate grade and recovery to known ore grade and an assessment of core samples. Operating costs at different daily tonnages are related to orebody shape, mining method, milling process and general plant services. Capital costs are related to sizing of mining equipment, mine development, plant-site topography, climate and accessibility, plant services and personnel housing. IntroductionA crude guide to the average 1978 cost of mine projects is shown in Figure 1, but the costs of many mine projects have differed widely from the graphed average costs of $800,000 T0.6 for underground mine/mill projects and $400,000 T 0.6 for low-grade open-pit mine/mill projects.High mine project costs and high operating costs are characteristic of open-pit mines with high stripping ratios, underground mines with thin orebodies, mills with complex metallurgy, and projects located in isolated regions with severe climate, mountainous topography, and lacking access to existing roads, towns and electric power. When none of these adverse conditions prevailed, the mine project cost was typically much less than the graphed average cost. Virtually all the conditions likely to cause high capital and operating costs are known from knowledge of the local topography, climate or accessibility, or can be assessed by tests on core samples, as soon as the orebody has been outlined by drilling .A more accurate estimate of over-all project capital cost and operating cost can be made from a summation of items of cost after judging the effect of specific local conditions on each item of capital and operating cost. This paper offers guides in judging the effect of local conditions on the sizing and 1978 cost of specific items of capital cost and operating cost and operating cost of mine projects. When the specific items of capital cost and operating cost are totaled and measured against expected net revenue and taxes over the life of the mine using the net-present-value or discount-cash-flow methods, the result should show whether the mine project development is clearly feasible, doubtfully feasible or clearly uneconomic. If the development of the mine project is clearly feasible, or probably feasible, a detailed feasibility study by experienced consulting engineers should be commissioned before any financial commitments are made; but if project development appears to be uneconomic, the time and cost of a detailed feasibility study is not warranted."

Jan 1, 1980

By Hilden. M.

"As the Cadia mill was the first 40ft diameter SAG mill, commissioned in 1998, its performance, liner and discharge design attracted considerable international attention. Twelve years on, the liner design and the control philosophy are being readdressed to further improve the mill’s performance. A comprehensive series of 3D liner scans, over life of the liner, have been used to calibrate liner mass loss and progressive changes in the liner profile. This data is being used to provide true charge mass and mill filling, plus progressive trajectory profiles over life of liner. This information, along with measures of mill performance over liner life, is being used to select the optimal operating conditions as the liner wears, and hopes to inform future liner design. INTRODUCTIONSince the Cadia mill was the first 40ft diameter SAG mill, its performance, liner and discharge design has attracted considerable international attention, as reported in previous SAG conferences. The mill experienced particular challenges with regard to pebble and slurry discharge, which necessitated a discharge redesign, incorporating a considerably greater pebble port open area and curved pulp lifters (Hart, Valery, Clements, Reed, Song & Dunne, 2001). Packing between lifter bars on the shell liner was found to dramatically reduce mill throughput over the first half of the liner life. In response, the liners were redesigned to a 2/3 spacing so as to open up the space between lifters. Due to ongoing high liner wear issues, the liner was redesigned based on the discrete element modelling (DEM) of Conveyor Dynamics conducted by Nordell and Potapov (2001). This aimed to maintain mill throughput with new liners and provide an extended liner life. This design was kept proprietary for many years, so has not been open to review."

Jan 1, 2012

By D. C. McKechnie

To the examining engineer, the ever-recurring problem involving the valuation of ore in a prospect presents at different times highly divergent aspects- some entirely physical or mathematical, others essentially personal. The majority of the problems discussed in this paper are obvious to the engineer, and need little elaboration. By the prospector and the general public, however, a number of these questions are often and completely over-looked, or else approached in such a way as to produce final results which are, to say the least, misleading and at times decidedly erroneous. While the purpose of this paper is to deal with prospects or potential mines, many of the problems considered apply equally well to mines with developed ore reserves. As the usual showings on a prospect consist chiefly of a few open-cuts and a limited amount of underground development work, an estimation of the actual ore reserves is a question of minor import, and seldom enters appreciably into an estimation of the probable value of the particular property. The physical valuation of a prospect mainly involves the consideration of such subjects as the general geological features exposed, the strength and type of mineralization, the width and persistence of any associated veins, shear zones, fractures or contact zones, together with the possible grade, size, and continuity of any ore-bodies that may there occur.

Jan 1, 1930

By Daniel Hodouin, Robert Lanthier, Yve Dube

"A procedure f or constructing a grinding mill dynamic model is proposed. This model is used in a dynamic simulator of are grinding circuits. The simulator is designed for flexible flow sheets involving different grinding mills and particle classifiers and is able to accept several single variable PID control loops. The dynamic model is validated on a laboratory ball mill, and calibrated to an industrial installation. The simulator is used for characterization of grinding circuit dynamic behaviour and tuning of control strategiesIntroductionThe ore grinding operation is a critical step of the ore preparation process because it is the last comminution stage before the separation of minerals. The properties of the ground minerals to be concentrated, control the quality and efficiency of the separation process. This is why it is important to control properly the operation of the last grinding stage, commonly constituted of a closed circuit ball mill with classifier . To provide an adequate fine product, the grinding operation should compensate for the perturbations of the feed characteristics (size analysis, grindability, etc.). The main objective is to maintain a constant size distribution for providing stable operating conditions to the separation units. Simultaneously another usual objective is to operate the grinding circuit at a maximum capacity.Automatic control applied to grinding circuit s is the appropriate approach to improve its operation. Most frequently average optimal operating conditions are determined from steady -state performances of the circuit , and the automatic control is used for stabilizing the operation at selected values of the process variables . In the traditional approach, one or several single input! single output (SISO) control loops are implemented and empirically tuned. Advanced control practices'!' are based on a quantitative analysis of the circuit dynamics, which could also give a basis for the tuning of conventional SISO 100ps(2)."

Jan 1, 1987

PROFIL D'ENTREPRISE Léandre Gervais & Associé(e)s est une société d'experts-conseils en ingénierie de la structure, de la mécanique & de la tuyauterie, et de l'électricité et de l'instrumentation. Nous offrons des services hautement spécialisés à notre clientèle des secteurs industriels des mines et de la métallurgie, au Québec, au Canada ainsi que dans plusieurs autres pays du monde. Notre mission est d'assurer à nos clients un ensemble de services d'ingénierie de haute qualité contribuant à la mise en oeuvre et à la réalisation de leurs projets d'affaires. Léandre Gervais & Associé(e)s emploie 36 employés à temps pleins et opère à partir de Val-d'Or, province de Québec. SERVICES OFFERTS Nous avons réalisé de multiples mandats pour notre clientèle de différent pays du monde dans les domaines d'expertise les plus variés : ?Études de faisabilité ; ?Ingénierie conceptuelle ; ?Ingénierie de détail ; ?Gestion de projets ; ?Ré-ingénierie de la maintenance.

May 1, 2001

By Robert B. Parsons

"The Department of Finance introduced draft amendments to the resource allowance regulations on July 23, 1992 that effectively nullify the decision in the Gulf Canada Limited case. Prior to the amendments it appeared that only ""directly"" related general and administrative, capital cost allowance and scientific research expenditures had to be deducted from resource profits. Now ancillary expenditures are required to be deducted. Consequently, the ability of taxpayers to claim the resource allowance is curtailed.IntroductionOn October 25, 1990 it was almost certain that taxable mines were going to get a break. The Federal Court-Trial Division had just decided in Gulf Canada Limited's favour to allow it to claim resource related tax benefits larger than what Revenue Canada evidently wished. Revenue Canada appealed first to the Federal Court of Appeal and then to the Supreme Court of Canada. On January 10, 1992 the Federal Court of Appeal agreed with the Federal Court decision and on July 2, 1992the Supreme Court declined to hear any further appeal. A mere three weeks later, on July 23, 1992, the Department of Finance issued draft ""clarifying"" measures to amend the calculation of the resource allowance. These measures effectively nullify the benefits that arose under the decisions of the Federal Court."

Jan 1, 1992

By M. W. Gilmore, J. Ndlovu, T. Sepoloane, Anglo American Platinum, L. R. Nelson, R. N. Varty, L. J. Bryson, B. Peyper, J. P. Hagemann

"As part of Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) expansion, a new Nickel Electrowinning Tank House, with a nameplate capacity of 32 400 tons per annum, was constructed. Commissioning of the new electrowinning technology, which involved world first full deposit plating, commenced in 2011.The old nickel electrowinning process at the RBMR used starter sheets which, along with a divided cell configuration, was very labour intensive and exposed operators to high levels of aerosols that contained both nickel and acid. To overcome this problem two key design intents of the new technology are aerosol abatement and minimising labour in the electrowinning cell environment, with a design target to reduce the nickel occupational exposure limit (OEL) to half the legislated limit of 0.1 mg.m-3.Commissioning of the new technologies adopted to achieve mist abatement is described, together with a review of technical and operational challenges relating to the titanium blank edge strips, blank roughness and sandblasting optimisation, blank quality control, electrode spacing, polyconcrete cell dimensional stability and cell top furniture. The impact of these on process performance is presented and the development of fault checking and rectification methods, to maintain high process performance, is explained.INTRODUCTIONThe expansion of Anglo American Platinum’s Rustenburg Base Metals Refinery necessitated the construction of a new Nickel Tank House to achieve two primary objectives, namely increasing the nickel electrowinning capacity from 22 500 tons per annum (tpa) to 32 400 tpa nickel, and a design to reduce the nickel aerosols to 0.05 mg.m-3 as a time weighted average over 8 hours, which is half of the legislated occupational exposure limit (OEL) of 0.1 mg.m-3."

Jan 1, 2016

By Xiang Yu

Hong Kong has a dense distribution of utility services laid under its road network. Utility undertakers frequently demand road openings to install new services and/or maintain existing ones. Road openings can cause troubles to the road network and negatively impact the public interest. Highways Department is responsible for managing road openings in Hong Kong under the Land (Miscellaneous Provisions) Ordinance. Highways Department has spent a lot of efforts to computerize excavation permit processing and utility management. The computerized system has gone through several generations and the current one is called the excavation permit management system (XPMS). On the one hand, the XPMS handles various excavation permit processing functions including permit application/approval/refusal/issuance/extension/termination, fees/costs, permit conditions, and permit period assessment; on the other hand, the XPMS accounts for some important utility management issues such as spatial check, coordination of multiple openings, traffic management, audit inspection, and defect liability. This paper discusses how the application, coordination, and other administrations of an excavation permit are eased by using the XPMS in Hong Kong. Background information such as the governing legal and regulatory framework, and Highways Department?s administrative structure is introduced. The system architecture and advantages of the XPMS are presented. The work procedures and various functions of the XPMS are studied in detail.

Aug 1, 2013

By B. J. McKay, K. Schneider, H. B. Nadendla

"A series of experiments were conducted to assess the impact of zinc additions on the morphology and soundness of the interface of Al-Mg compound castings. It was found that high amounts of zinc (>15wt%) are necessary to affect the morphology and microstructure of the interface. At these zinc concentration levels, the formation of the zinc-rich phases t1 and ? were observed along with the Al-Mg intermetallic phases ß and ?. The micro hardness of all phases across the interface was found to be similar, ~200 Hv. This even hardness gradient is thought to avoid mechanical failure in the interface under load. In samples containing large concentrations of zinc (>15wt%), the formation of bubble shaped voids as well as the complete transformation of the aluminium alloy was observed. While the exact mechanism causing the voids has not been identified it thought to be connected to the Kirkendall effect. INTRODUCTION Conventional single material components are increasingly failing to meet the demands, in terms of cost and performance, of the transport industry. Compound castings have been identified as a promising alternative as they possess a number of benefits (Bührig-Polaczek, Röth, Baumeister, Nowack, & Sussmann, 2006). Compound casting is described as a process in which a metallic melt is cast around a solid metal shape. Preliminary research has concluded that for the stability of such a resultant hybrid structure it is imperative that both metals form a sound connection via form closure, force closure, or material bonding. A continuous material bond between the two metals is also highly desirable as the formation of a crevice between the metals could lead to galvanic corrosion, particular in a humid environment (Lao, 2013; Rübner, Günzl, Körner, & Singer, 2011). Even though Al-Mg compound castings could offer the biggest potential in terms of weight savings to date only a limited amount of research concerning such structures exists."

Jan 1, 2018

By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016