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By Hämäläinen M., O. Hyvärinen, E. Jääskeläinen

HydroCopperTM is a new hydrometallurgical process for the treatment of copper sulphide concentrates, which has been developed by Outokumpu. The process includes chloride leaching of copper concentrate, solution purification and precipitation of copper(I) oxide, an intermediate product, which is reduced and cast into copper products. The reduction can be carried out by pyrometallurgical methods or hydrometallurgically in an autoclave. This paper discusses the thermodynamic and kinetic aspects of the hydrogen reduction of copper(I) oxide in an autoclave. The results of the laboratory tests are presented and discussed. Finally, the autoclave method is compared with other options.

Jan 1, 2004

By T. P. Riordon

"Major swings in the silver price since 1979, along with the ever constant fight to maintain ore reserves has forced United Keno Hill Mines Limited through several unique series of events in order to survive in the 80s.This paper is specifically meant to be a description of safety and productivity improvements achieved to ensure the survival of a silver mining community ill the Yukon. There are, however, other events and conditions that must be described to complete the story and this paper attempts to do that as well IntroductionUnited Keno Hill Mines Limited, a subsidiary of Falconbridge Limited, is the only silver producer in the Yukon. Operations are located in north central Yukon, in and around the small town of Elsa, latitude 62.5 °, about 275 road miles from Whitehorse. The Arctic Circle is about 185 miles due north of the town.Temperatures in 1986 ranged from a high of 28.5°C in July to a low of -37.0°C in November, however, much lower temperatures have been recorded in previous years. Due to the mountainous terrain the town of Elsa is completely in the shade from mid-November until early February, a period of about 12 weeks.The Elsa area, as is most of the north, is considered semiarid with an average precipitation level of about 15 inches. Vegetation, however, is quite abundant though slightly dwarfed at the townsite elevation of 3200 feet above sea level: Many of our operating and exploration portals as well as our open pits are above the tree line. Permafrost in the area has been recorded up to 400 feet below the surface."

Jan 1, 1988

By T. Gerritsen, C. Martinez, F. Stober, T Ma, J. R. Frias, M. Sedighy, J. Janzen

Electrode control systems regulate power by physically positioning electrodes. Due to the weight and inertia of the electrodes and hoist equipment, this is a relatively slow process where power fluctuations of less than a few seconds are not fully corrected. Nickel laterite AC furnaces operating in high voltage, shielded arc mode typically incur frequent power variations of approximately +/- 20% or more around the power set point. To provide enhanced power control, Hatch has recently supplied, at commercial scale, a thyristor-switched reactance system called an SPLC. The SPLC incorporates predictive control software to operate furnaces at the maximum transformer rating by reducing the large power swings experienced without the SPLC. The resulting higher average power enables higher production, without increasing transformer or power plant capacity. A 60 MW production version of the SPLC has been commissioned on Falconbridge Dominicana's laterite nickel furnace, yielding excellent results with a 3 to 1 reduction in power fluctuations.

Jan 1, 2005

By W. P. Clement, M. C. Bell

"PT International Nickel Indonesia, a subsidiary of Inco Limited, mines and processes nickel laterite ores for the supply of nickel matte, primarily to the Japanese market. It has large ore reserves and a substantial portion of its energy requirement is supplied from its own hydro-electric plant. Since the early 1980s, the company has increased its production level and has dramatically reduced its unit costs. Projects are in progress to further decrease costs and recently a major expansion - 31% increase in nominal capacity - has been undertaken, consistent with marketing opportunity in Japan. The expansion project, which has a low capital cost per unit of production, is outlined in this paper.IntroductionPT Inco is a fully integrated mining and smelting facility located in Indonesia on the island of Sulawesi, and is based on a very large, world class nickel laterite orebody located 60 km inland from the Gulf of Bone. Construction of a single furnace line plant started in 1973. Complete supporting infrastructure of townsite, hospital, schools, shopping centres, road systems, and an airport, all had to be built. Prior to completing the first phase, the decision to expand the plant to a three kiln-furnace line was made. A major factor in the decision was the ability to develop the hydroelectric potential of the nearby Larona River. This involved construction of a 30 m high dam, and a 7 km surface canal to the generating station. The penstocks drop 150m to three 55 Mw turbines. The power generated is sufficient to supply the entire electrical load for the complete smelting complex and town site. The unique capability to supply the high smelting energy requirements for a lateritic nickel ore by fully captive hydro power, has, over the past decade insulated PT Inco from the large upward swings in oil prices suffered by other lateritic nickel producers.Wet ore is first partially dried to 20% moisture in two co-currently fired rotary driers, screened on an internal trommel, and delivered to two dry ore storage buildings. The partially dried ore is calcined at 750°C and partially reduced in three large 100 m by 5.5 m kilns. Reduction is accomplished by lancing bunker C oil onto the ore bed at the discharge end of the kiln. The kilns are equipped with five air pipes with onboard blowers to gradually bum the combustible gases generated by the lance oil. The kilns were also originally equipped with two side burners to supply additional heat close to the feed end of the kiln. Calcined ore is transferred by 20 ton refractory lined containers to the furnace feed bins at the top of the smelter. Smelting is carried out in three 18 m diameter furnaces powered by 45 Mw transformers. Slag is skimmed at 1550°C through water cooled breast plates and removed to the slag dump by Haulmaster Carriers. Matte of 25% Ni, 1O% S, 65% Fe is tapped at 1350°C into the converter aisle. The iron is slagged in converters to produce a nickel sulphide matte at 80% Ni. Three rotary Kaldo converters were initially installed. The product matte is granulated, dried, and shipped in returnable rubber bags to Japan. Most of the matte is fluid-bed roasted to nickel oxide and then directly reduced in a second reducing fluid bed reactor at our facilities in Japan.The smelting complex was designed to smelt two million tonnes of dry ore per year, equivalent to 34 000 tonne nickel production at an ore grade of 2% Ni. The cost of the entire project including working capital was $900 million."

Jan 1, 1990

By G. Itoh, S. Fukasawa

The Al-Zn-Mg alloys have been known to be susceptible to stress corrosion cracking (SCC), which is based on intergranular cracking arisen from hydrogen embrittlement (HE). The mechanism of HE has not been fully understood yet. In order to elucidate the mechanism of HE, we need to investigate the behavior of hydrogen in the alloys. In this paper, behavior of hydrogen in an Al-5.8%Zn-2.4Mg alloy was investigated by means of hydrogen microprint technique, a method to visualize location of hydrogen emission from specimen surface as silver particles. One side of the tensile test pieces was electrolytically polished and then covered with photographic emulsion. Hydrogen was pre-introduced into the test pieces from opposite side by cathodic electrolytic charging for 30min. Then, the test pieces were stretched with continuing the charging. After that, the specimen was fixed, rinsed, dried and observed with a scanning electron microscope. As a result, silver particles were observed on some grain boundaries.

Jan 1, 2015

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005

By T. Senga, T. Namihira, S. Terada, S. Owada

"Electrical disintegration (ED) has been well known as a good comminution method to improve liberation of compositional phases because it was reported that electron avalanche could occur preferentially at phase boundary. But the detailed mechanism of the ED has been still not known. This paper describes the results of ED experiments using synthetic binary sample, copper/resin, under the conditions of various distance between electrodes, and discusses the energy distribution in the three kinds of phenomena in the ED process, which are(1) streamer progression in water, (2) electron avalanche in water, and (3) electron avalanche in solid sample, by measuring current and voltage with elapsed time. Then, it has been found that the energy distribution in the phenomenon (1) is quite low and that the distribution in the phenomenon(2) had a considerably large compared with that in the(3), which indicates that the shockwave generated in water could contribute much to the sample breakage.INTRODUCTIONElectrical disintegration (ED) has been well known as a specific comminution technology which enhanced selective breakage at phase boundary and lead to a good liberation among compositional phases1-6),but the detailed mechanism has not been clarified yet. This study describes energy distribution among the phenomena in the ED process by using a synthetic binary sample, copper/resin, the phenomena of which are (1) streamer progression in water, (2) electron avalanche and shockwave generation in water and (3) electron avalanche in solid sample usually at phase boundary. The energy distribution could be calculated from ED experiments and from voltage-current changes between electrodes as a function of elapsed time.SAMPLE AND EXPERIMENTALSampleThe sample used in this paper was a synthetic binary solid of copper/resin as shown in Figure1.Cut and polished pure copper lump was put into silicone mold and melted epoxy resin was poured into it and cooled, then, finally the binary sample was polished and molded in the form of 10 mm * 10 mm * 10 mm."

Jan 1, 2017

By Hiwa Salimi, Foley. Stephen R, Loghman Moradi

Common water-miscible organic solvents including DMSO, DMF, methanol, ethanol, acetone and THF in combination with HCl and low concentrations of H2O2 were investigated for dissolution of gold. THF showed the best result demonstrating that gold powder could be completely dissolved in 1.5 hours in 1.0 mol/L HCl and 0.2 mol/L H2O2. No complete gold dissolution was observed for the rest of solvents even after 24 hours. The rate of gold dissolution was measured by dissolving gold wire in THF/HCl/H2O2 mixture. The rate of gold dissolution in optimised condition was 75 g m-2 h-1 at room temperature and significantly increased to 590 g m-2 h-1 by raising the temperature up to 60 oC. Although a THF/HCl/H2O2 mixture showed a slower dissolution rate in comparison with aqua regia, however the applied conditions are considerably milder which is highly promising for gold leaching in an industrial scale.

Jan 1, 2015

By A. Miura, G. Granata, C. Tokoro, A. Fuwa

"The high copper demand as well as the lack of new high-grade deposits, are pushing the copper industry to process low-grade and refractory ores containing chalcopyrite. However, for a quantitative dissolution of copper from the chalcopyrite, the leaching performances still need to be improved. In the present research, we studied and optimized the iodide-assisted leaching of chalcopyrite in H2SO4-Fe2(SO4)3 media. The evolution of surface species during leaching was determined by x-ray photoelectron spectroscopy (XPS) and mineral liberation analysis (MLA). Inductively-coupled plasma spectrometry (ICP-MS) was used to determine the dissolved copper. Significance of experimental results was assessed by statistical analysis while a kinetic analysis of the leaching process was performed by fitting the experimental data with the Shrinking-core model. Results showed the significant positive effect of iodide on copper extraction rate. In the presence of KI, the dissolution rate of copper was almost double than in the parallel experiments without KI. Whether using KI or not, elemental sulfur was generated on the surface of the leached chalcopyrite. Nevertheless, in the presence of KI, the passivation layer did not arrest the leaching. Analysis revealed that the leaching rate was limited by the chemical reaction control step.INTRODUCTION Due to the large demand of copper, processing low-grade ores containing copper sulfides such as chalcopyrite (CuFeS2) has become unavoidable (Watling, 2013). Since ores with CuFeS2 may also contain appreciable amounts of arsenic that cannot be smelted, and because low-grade ores are uneconomic to smelt, the hydrometallurgical technologies are crucial for recovering the copper (Dutrizac, 1978). Sulfate-based processes are attractive because of the lower operating costs and because the sulfate ion is more suitable in case copper would be recovered via electrowinning. In ferric sulfate solution, chalcopyrite undergoes oxidation due to the large amount of Fe(III) and dissolution due to the presence of the sulfate ion (Majima, et al., 1985). The leaching reaction in ferric sulfate medium can be represented as in (1):"

Jan 1, 2017

By T. G. Phillips

"This paper gives an inside look at a bulk terminal and describes the preparations that must be made by a company in developing such a terminal and its position in today's traffic pattern. The following headings cover the subject material: (a) Traffic pressures, their detection and measurement, (b) position in the traffic flow -selection of site, (c) transportation connections -present and possible future routes, (d) engineering studies and costs, (e) contracts, the basic material for insured traffic, (f) financing, (g) budgetary control, (h) development of new techniques, (i) growth into new cargoes or cargo-handling methods and (j) consolidation."

Jan 1, 1968

By Michael Moser, Brighty Dutta, David Dreisinger

"Molybdenum is widely used in the industries as an alloying element in the manufacture of steels and super alloys. The widespread use of the element encourages a growing need to develop extraction processes for recovery from both primary and secondary sources. The Solvay Group has developed a solvent extraction reagent named CYANEX®600 for the recovery of molybdenum from acidic solutions originating from both low grade (e.g. copper solvent extraction raffinates, smelter dusts and slags) and high grade (molybdenite) molybdenum sources. CYANEX®600 is a purified form of CYANEX®272 with the active component bis(2,4,4- trimethylpentyl)phosphinic acid. The extraction behavior of CYANEX®600 towards molybdenum in sulphuric acid medium was evaluated. The uptake of molybdenum increased with the increase in concentration of CYANEX®600. The approximate stoichiometry of the extracted complex was: Mo: CYANEX®600 = 1:2. Efficient back-extraction could be achieved with 0.1 M disodium EDTA and 0.1 M (NH4)2CO3, thus providing the option of recyclability of the extractant. The detailed back-extraction studies are currently under progress to find out the possible option for complete transfer of Mo(VI) to the aqueous phase so that high purity Mo salts could be precipitated from the molybdate solutions.INTRODUCTION Molybdenum (Mo) is one of the world’s valuable metals and is highly sought after by researchers due to its versatile mechanical, thermal, chemical properties. Swedish scientist Carl Wilhelm Scheele demonstrated molybdenite to be a mineral sulfide in 1778. Peter Hjelm successfully isolated dark metal powder from the mineral sulphide and named it as ‘Molybdenum’ in 1782 (Gupta, 1992). Molybdenum is a refractory metal of silver gray appearance and is an important alloying element used in the manufacture of steels and super alloys. Molybdenum compounds are widely used in formulation of catalysts (Gupta, 1992). Molybdenum occurs in nature only in chemical combination with other elements. Several molybdenum bearing minerals have been identified, but the only one of commercial significance is molybdenite (MoS2). As molybdenum is a strategic metal for the industrial sector, its widespread use acts as a factor for depletion of the natural resources. Hence, there is growing need to develop extraction procedures for its recovery from both primary and secondary sources. United States, China, Chile, Canada, Peru, and Mexico are listed as the main producers by the U.S. Geological Survey, 2016 (U.S. Geological Survey, Mineral Commodity Summaries, January 2016)."

Jan 1, 2017

By Iain Sommerville, Hugh Mountford, Dawid D. Smith, Claude Dube, Brett Hixson

JW Aluminum use lean and Six Sigma techniques to continuously improve their target of reliable, repeatable and reproducible (3R) manufacturing. Six Sigma’s second stage gate, known as "Measure" involves identification and qualifying appropriate measuring systems. Metal quality (inclusions) are known in the industry to be an important element in 3R casting. The measurement of inclusions at JW Aluminum historically depended on outside vendors. In order to establish real time inclusion measurement ability within JW Aluminum, inclusion measurement systems in the marketplace were investigated. The qualification of a MetalVision MV20/20 ultrasonic inclusion analyzer are discussed as well as the subsequent application of the system in melting and casting improvement projects.

Jan 1, 2015

By J. Mizera, J. Zdunek, K. J. Kurzydlowski, A. Dobkowska

This work concerns comparison of corrosion resistance of the aircraft aluminum alloy composed of Al - 2.3%Li - 0.1% Zr. The alloy was hot rolled (HR) from 13 mm to a thickness of 4 mm (e = 2.4) and 1 mm (e = 5.2). Corrosion resistance was investigated by Potentiodynamic Polarization Test. The investigation relied on exposure samples in two different corroding medium: 0.5 M NaCl solution and 0.01 M Na2SO4 solution with added 0.01% of Cl- at room temperature. Furthermore, the microstructure was analyzed using the optical microscope with polarized beam. The hardness was measured on lengthwise profile. It was stated that alloy after the largest deformation (equivalent total strain e = 5.2) is characterized by the best mechanical properties and the best corrosion resistance. The alloys in initial state and after deformation to 4 mm (e = 2.4) are characterized by worse corrosion resistance. It is associated with microstructure and density of dislocation in analyzing material.

Jan 1, 2015

Presentation Outline ERM ? corporate profile Background to sustainability reporting GRI G3 Guidelines (Oct 2006) Best practice examples Contact information ERM ? corporate profile Over 35 years of experience World?s largest all-environmental consultancy* 130+ offices in 40+ countries; 3,200+ professional staff Worked with >50% of the Global Fortune 500 (FY07) Annual turnover > US$500 M (FY07) 2008 Environmental Advisor of Year** Offices/Staff ? Canada (5/50) and US (65/1,350) *Source: Engineering News Record: July 2, 2007 ** Source: Acquisitions Monthly: December 2007

May 1, 2008

By A. Hartikainen, M. Rinne, F. Johansson, R. Yorke, L K. T. Uotinen, E. Korpi, J. Antikainen

"In order to determine the in-situ shear strength of rock joints, large scale testing is required. However, this is both expensive and difficult to execute. One possible method to overcome this may be to use photogrammetry to capture large joint surface roughness in-situ and downscale it to replica samples, which could be sheared in laboratory. In this paper, as a first part in such a method, a technique to digitize surface roughness and to produce replica samples for laboratory shear testing from a larger joint sample are presented. First, a thin granitic rock slice with dimensions of 1.75 m x 0.95 m of granitic intact rock was chosen for the study. The joint surface is fresh and created through tensile induced splitting. The large joint sample is digitized using photogrammetry. Then, one fullscale 1.7 m x 0.6 m geometry is cropped from the digitized joint geometry and then subsamples at 10x, 7.5x, 5x, 2.5x and 1x scales. All sub-geometries are scaled down digitally to produce 0.17 m by 0.06 m geometries. The geometries are used to make casting molds both positive and negative to produce samples with perfect matedness. The casting molds are 3D printed in polylactic acid plastic and C60/75 concrete is cast to produce a replica series. In addition to the creation of this replica series, two pilot replicas are also tested using a portable shear box with a 0.5 MPa normal pressure. The results from the pilot rounds are presented and discussed. Finally, suggestions for future research are given.INTRODUCTIONThe rock mass strength is in many cases controlled by the shear strength of rock joints, especially in hard rock masses. The shear strength is generally found to be influenced by several parameters, including normal stress, the basic friction angle of the intact rock, the joint surface roughness, the joint wall compressive strength, the matedness of the joint surfaces, weathering and infilling. The effect of these parameters for the joint shear strength can be evaluated in laboratory scale. However, the shear strength is known to be scale dependent. How the scale effect influences the strength is not fully understood. The general consensus is that the shear strength decreases when sample size increases, i.e. a negative scale effect (Bandis et al. 1981). However, some studies have presented contradictory results, see for example Hencher et al. (1993) and Kutter & Otto (1990). The extent and nature of the scale effect is still a question of debate (Tatone & Grasselli 2013)."

Jan 1, 2015

By A. Tohn, K. Adham, R. Lu, D. Lemieux

"To remove sulphur, carbon and arsenic from the gold concentrates of Dundee Sustainable Technologies (DST), Hatch has designed a demonstration plant roaster using the fluid bed technology. The fluid bed was selected for its ability to maintain stable temperatures and uniform reaction conditions. Data points from a small pilot plant (operated by DST) were used for setting the parameters of the demo plant roaster.The DST demonstration plant is being built to further prove their patented gold extraction process at an industrial scale. Their gold extraction process is based on halogenation at atmospheric pressure and relatively low temperatures. Before the halogen leaching, most of the sulphur, carbon and arsenic should be roasted out of the feed concentrate.The Hatch fluid bed roaster design includes a moist feed introduction system, simple bed cooling for temperature control, and cyclone fines recirculation. The demonstration plant roaster is planned for construction in 2014, and the performance results will be presented in a future paper."

Jan 1, 2014

By H. P{ops

This paper summarizes important developments that have occurred in the mining and subsequent production of copper into rod and wire from 9000 B.C. until the present time. Principles and practices associated with continuous rod production are discussed from a metallurgical perspective, and include the effects of oxygen content and impurities. A brief historical review is also given of important wire drawing events dating back thousands of years. Finally, predictions concerning the future of the wire and cable industry are presented with particular emphasis upon copper wire, technology in this market, and competitive materials.

Jan 1, 2007

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015

The Curtin University Gold Technology Group has been involved in surveying, modelling and optimisation of batch centrifugal concentrator type gravity circuits and CIP/CIL circuits for nearly two decades. The most commonly asked question regarding gravity recovery is, “What is the benefit of a gravity circuit”, which can be hard, if not impossible, to quantify. With the help of the AMIRA P420 Project’s Integrated Liberation Leach Model (ILLM) it is now possible to evaluate the effect of gravity recovery on total gold recovery when changes are made to the grind size, gravity and/or leach/adsorption circuits. This paper demonstrates how the ILLM can be used to determine the net benefit of introducing or modifying a gravity circuit and assess the effect of operating conditions (grind size, coarse gold size distribution, leach residence time, carbon activity, etc.) on plant performance.

Jan 1, 2017

By M. Nakai, G. Itoh, R. Yamada, A. Kurumada

In order elucidate the mechanism for poorer fatigue properties of 7000 series aluminum alloys than those of 2000 series alloys, the effect of the test environment on the fatigue crack growth of the two series alloys was investigated, considering the relationship to hydrogen embrittlement. Two 7075-type and four 2024-type alloys were T6-tempered and T4-tempered respectively, and subjected to fatigue crack growth tests in moist and dry environments. When tested in moist air, fraction of intergranular crack path was higher in the 7075-type alloy with coarse equi-axed grains than in the 2024-type alloy with similar microstructure. This was in accord with the larger crack growth rate in the 7075-type alloy. Both the intergranular crack path fraction and the crack growth rate were decreased by changing the environment to the flow of nitrogen gas. Thus, the large fatigue crack growth rate of the 7075-type alloy is attributable to hydrogen embrittlement.

Jan 1, 2015