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By Lucas van Latum

A Model for Safety Swiss cheese metaphor of safety layers Image »Multiple layers with independent, often transient failure modes »For a loss to occur, all layers must fail independently and simultaneously ??Latent? failures are due to inherent system flaws ??Active? failures are due to unsafe acts

May 1, 2011

By Ramesh Subramanian

Overview Background / History Undergraduate Programs Mining Engineering Chemical Engineering Mechanical Engineering Graduate Programs and Research Student Enrolment (2002 -) Future Plans

Oct 1, 2010

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

The bath level measurement is applied in many furnaces to keep control of the level of slag and metal or matte inside. The BLM is used mainly in bath processes, and has not seen much evolution in its basic functionality. For a closed DC FeCr furnace, special demands based on the furnace design and extreme process conditions were considered for the design of a bath level measurement in order to collect valuable information about the furnace operation. This paper will describe these demands and the solutions for them, followed by some of the uses for the BLM in a closed FeCr furnace. Some of the future developments on the BLM conclude this presentation.

Jan 1, 2015

By L. Voisin, G. Damm

"In order to develop a new pyrometallurgical process for eliminating detrimental arsenic and antimony from the impurity-rich matte produced from copper concentrate, and for treating the occasionally generated speiss in nonferrous smelting processes, the phase relations in the Fe-Cu-S-As-Sb system saturated with carbon at 1473 K were investigated. The distribution of elements between the condensed phases at the miscibility gap, where three equilibrated phases of iron-rich alloy, copper-rich alloy, and matte coexist, were also studied. The investigation was carried out by performing a series of laboratory scale experiments in an electrical furnace at 1473 K, followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Inductively Couple Plasma (ICP), Atomic Absorption Spectroscopy (AAS) and Carbon Infrared Spectrometry (CIS) techniques.The results were compared with previous investigations for the Fe-Cu-S-As-C and Fe-Cu-S-Sb-C systems and discussed on the basis of the molar fraction distribution for both arsenic and antimony in the matte phase at five different matte grades. It is expected that by using this phase separation technique it might be feasible both, the cleaning of a complex copper matte and the elimination of arsenic and iron together with an acceptable amount of antimony into the iron-rich alloy phase, which can be discarded as a harmless and smaller deposit."

Jan 1, 2014

By J. W. Smith, J. G. Eacott, D. H. Napier

"Three hydrometallurgicat processes (Noranda chloride leach, B. C. Research biological leach and Sherritt-Cominco activated oxygen leach) and the Noranda pyrometallurgical process have served as the basis for design projects in the final year of the chemical engineering program at the University of Toronto. Each member of a team of five or six students devotes about 200 hours to the project and the final report is expected to include an economic analysis.None of the processes has been developed to full- scale plant, nor, in the case of the B.C. Research and Noranda processes, were pilot plant data available. Nevertheless, the designs developed provide a useful basis for a preliminary estimate of capital and operating costs and for a preliminary assessment of project feasibility.This paper discusses the approach used in the design projects with respect to engineering and economic aspects, and outlines the educational features and benefits of such a program as well as some of the problem areas that arise.IntroductionAs part of the undergraduate degree course in chemical engineering at the University of Toronto, students devote some 200 hours to a design project in their final year. Hydrometallurgical processes, not yet proven at the commercial scale, have been selected for study. The students are required to develop laboratory and / or pilot scale results into a conceptual plant design, using sound engineering principles. Capital and operating costs are then determined and a preliminary feasibility study and economic analysis are carried out."

Jan 1, 1986

By Richard Wells

Peabody Energy is the largest pure-play publicly traded coal company in the world. We have been in business 129 years and like most of the coal mining companies in the United States, since 1969 the majority of our safety improvement efforts had been driven by compliance with the various versions of the Federal Mine Safety and Health Act and the supporting federal regulations. In 2004 Peabody Energy management came to the understanding that in order to achieve our goal of zero incidents, that focus must change. This paper will describe the elements of the journey we began at that point to make the transition to a behavior and systems-based approach to safety management and our efforts to win the minds and hearts of our employees. This journey is undertaken with the goal of making safety truly a way of life for all Peabody Energy employees.

Aug 1, 2013

"Coupon testing has been used to investigate stress corrosion cracking (SCC) of rockbolts in a laboratory based experimental program. This program has focused on the use of ASTM G39 three- and four-point bent beam coupon specimens, immersed in an acidified sodium chloride test solution containing hydrogen sulfide. The specimens were loaded to a range of stresses from zero, to just above the materials yield strength. It was found that only specimens above an applied stress of 580MPa failed by means of SCC, showing that rockbolts loaded to near their yield strength may be susceptible to SCC in-situ.INTRODUCTIONStress corrosion cracking (SCC) is a failure mechanism that affects material through the growth of hairline cracks when exposed to a corrosive medium while under stress (Jones and Ricker, 1999). SCC has been found to affect rockbolts in the Australian underground coal mining industry and has the capacity to cause the catastrophic failure of ground support systems, potentially leading to falls of ground in underground excavations, injury or death to mine personnel, damage or loss of equipment, and loss of productivity through the loss of roadway access (Crosky et al, 2002).Coupon testing utilises small scale samples that are intended to be indicative of the behaviour exhibited by a material in-situ (ASTM G39). The small scale, and usually high surface area to volume ratio of coupon specimens mean that they corrode at faster rate proportional to their mass, greatly reducing testing times. The small scale of the specimens allows them to be more easily prepared and handled, loaning them to mass manufacturing techniques.A previous study conducted by Vandermaat et al (2012b) into the use of three- and four-point coupon testing in-situ in an underground coal mine failed to result in SCC of the specimens. This paper serves as a follow up laboratory investigation in order to understand why these specimens did not fail. Previous studies into the SCC in rockbolts carried out by Gamboa and Atrens (2003) determined that rockbolt steel has a critical stress threshold of approximately 90% of the material ultimate tensile strength (800-900MPa). This study will focus on this critical stress threshold as a possible explanation for the lack of failure in the in-situ specimens (Vandermaat, 2012b)."

Jan 1, 2015

By T. A. Wheat

"The presently increasing world-wide interest in advanced ceramic materials is generally focussed on their exploitation in both structural and functional applications. With the opportunity to engineer microstructures and thereby closely control and tailor the final properties, there are many new applications being made for these materials in both areas.The scope and some of the applications for functional ceramics are reviewed and examples of the present Canadian activity in this field are discussed.BackgroundThere has been progressively increasing international interest in the development and exploitation of ceramic materials in the last five years. The stimulus for this interest arises from several quarters, each of which are independent of the other.• There is a growing awareness of the strategic nature and vulnerability of supply of the raw materials used to produce high performance metal alloys.• The metal alloys are reaching the upper temperature limit for their performance as structural components in engines.• The dramatic increase in oil prices during the late 1970s focussed attention on the need for reduced consumption in many sectors, i.e., there is a need for more efficient engines that operate at higher temperatures - above those tolerated by the present superalloys.• A number of ceramics, especially the structural materials such as SiC, A120 3, AI20rSi02, Si3N4 and the Sialons are produced using non-strategic raw materials and they can exhibit startling performance-auto turbo-rotors are in production mad e of Si3N4 that operate up to 190000 rpm at 600°C, 150000 rpm at 900°C.• Ceramic s are generally of lower density - significant in the weight-reduction of automobiles such as the replacement of a 20-kg five-segment steel leaf spring with a single segment carbon-fibre reinforced unit of 3 kg. • Ceramics also offer major ad vantages in generating, monitoring or controlling the electromagnetic spectrum whether in bulk or thin-film devices that exploit optical, magnetic, pyroelectric, piezoelectric, electronic and I or ionic conductivity characteristics.The opportunity to combine several of these char acteristics in a single material by composition, processing and microstructural design has resulted in an advanced ceramics industry that had world-wide sales in 1980of $4.2 billion (U.S.)(I) and is predicted to grow to sales in the range $7 to $10 billion by 1990 and $16 to $24 billion by the year 2000(2). However, at present, advanced ceramics account for less than 20010 of the total ceramic market."

Jan 1, 1987

By Tom Shumka

INTRODUCTION ?The Electro-Magnetic Crack Detection (EMCD) technique is an electromagnetic inspection method used for detecting and sizing surface breaking flaws. ?It works well on structural material or welds, ferrous or non-ferrous metals. ?EMCD?s rapid scanning is achieved using a hand-held probe. ?EMCD provides reliable crack detection and sizing (length and depth). Cracks can be sized accurately. ?EMCD dramatically reduces most cleaning requirements as there is no need to clean to bare metal. ?EMCD is capable of inspection through thin metallic coatings, or through non-conducting coatings up to 10mm thick. ?EMCD allows full data storage for back-up, off-line view and audit purposes.

Oct 1, 2010

By T. Johnson, K. Lambrych, D. Kelley

Materials for construction of equipment used in hydrometallurgical plants are selected based on a combination of their ability to perform as required in aggressive process environments as well as their cost. As a material of construction, fiber reinforced plastic (FRP) has been shown to provide equal if not improved durability relative to alternative materials such as corrosion resistant alloys at a considerably lower cost. This is particularly true in the case of equipment used in acid leaching processes for copper, cobalt, nickel and rare earth elements. The selection and extensive use of FRP over alloys in new hydromet plant construction in North and South America illustrates this advantage of FRP effectively. This paper will compare corrosion performance and cost of plant equipment fabricated with stainless steel alloys and FRP made with Epoxy Vinyl Ester thermoset resins. Real world case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment.

Jan 1, 2015

By Wei Yun-Jie

Columnar jointed basalt is a fractured rock, with a lot of small spacing structural planes and poor integrity of the rock mass. On the basis of the comprehensive study of the columnar shape of Columnar joints, rugosity of the fracture surface and the chemical composition of basalt, columnar joints of Bai hetan dam area were formed as a result of the cooling and shrinkage effect of magma. Columnar joints basalt are mainly chlorite, kaolinite, epidote, tremolite chemical reactions and the content of columnar joints are mainly chlorite by slice identification and chemical analysis. Columnar joints basalt showed high uniaxial tension test, low coefficient of friction and high cohesion by indoor physical and mechanical test. Columnar joints rock mass showed high strength and large deformation by field shear test and deformation test. Columnar joints basalt can be used directly as a foundation of dam as long as we follow the rules and reduce disturbance strictly.

May 1, 2009

By Randy McMeekin, Chris Twigge-Molecey, J. Peter Blake

The business objectives of a metallurgical project determine targets and constraints, such as the range of products, production capacities, in-service dates, and capital and operating cost parameters. Permitting is usually left to the project team, as are decisions regarding site location, technology, and construction approach. Success requires an orderly methodology, represented in this book by front end loading (FEL) phases: FEL1 examines several alternative approaches; FEL2 ranks and eliminates less economically or technically attractive options; and FEL3 develops the preferred option to the point of major permit completion, with defined scope, schedule, and cost to submit for approval to proceed with implementation in FEL4. Working through FEL1, FEL2, and FEL3, the project definition improves, estimates become more accurate, and project risks are reduced. The project design basis at the end of FEL3 is the control document for project implementation in FEL4.

Jan 1, 2015

By J. Bigu, M. G. Grenier, S. Hardcastle

"This study was undertaken in a belt conveyor drift of an underground hard rock mine. The conveyor transported ore or waste from a crushing operation located upwind from the drift sampling locations. A 250 m section of this drift was selected and several types of measurements were taken. Average respirable concentrations in the drift were 0.43 mg/m3 and 0.19 mg/m3 for total and silica dust, respectively. From the respirable dust concentration profile along the drift, it may be possible to estimate the contribution from extended sources such as dust produced by the belt and return idlers.The airborne dust in the drift had an average mass-median aerodynamic diameter of 4.2 micron. A continuous dust monitor showed that the crushing operation produced fairly high dust concentrations (sometimes greater than 4 mg/m3) over short periods of time.IntroductionAirborne dust in the respirable range is known to be the cause of various forms of lung ailments . In underground mines, respirable dust sources are created at many stages of production. All mining operators are responsible for de signing and establishing means of reducing airborne dust. In some cases, sources of dust are well defined and suppression methods are standard.In the case of interest here, the airborne dust cloud was formed from the contribution from many sources, which may be either discrete or extended. At the experimental site, the discrete or point sources were the crushing operation and the belt conveyor transfer point (tail pulley). These sources may be controlled by proper dust capture and scrubbing systems as well as dilution ventilation. Examples of extended dust sources in the area include dust produced by the re-entrainment of settled particles along the drift. Ventilation air movement and vehicular traffic both contribute to this phenomenon. Dust produced by the conveyor is another example of an extended dust source. Caked deposits on the return strand and idlers as well as the transportation of dry material on the belt, can be major contributors. Proper wetting of roadways and muck as well as proper belt cleaning techniques can help reduce these emissions. The cleaning apparatus, used on the belt where these experiments were conducted, is shown in Figure I. These and other belt cleaning techniques are described in more detail elsewhere."

Jan 1, 1987

By Cheryl Devine, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg

The microbial-mediated recovery of valuable metals locked in mining wastes presents an economical alternative to conventional hydrometallurgical processes. The present study investigated the bioleaching response of a low-grade nickeliferous pyrrhotite tailings (0.6 wt% Ni) and an upgraded pyrrhotite tailings (1 wt% Ni) produced by Vale Base Metals in the Sudbury Basin of Ontario, with the ultimate aim of maximizing Ni recovery. The initial part of the study focused on the bacterial adaptive evolution protocol, by repeatedly sub-culturing an indigenous culture from an acid mine drainage site on 2% (w/v) pyrrhotite tailings. The results showed that the extent of Ni dissolution is positively correlated with microbial activity. Microbial profiling revealed A. ferroxidans to be the dominant member of the microbial consortium. The enriched culture was used for optimizing the growth medium by varying the concentration of essential growth nutrients. Finally, an aerated biotic and abiotic leach of a 10% (w/v) upgraded pyrrhotite tailings with and without pH control, showed a higher recovery of Ni in the pH controlled experiments. These results demonstrate that a high concentration of the oxidant Fe3+ in solution promotes the dissolution of Ni. Furthermore, the sulphide conversion into So was found to be higher in the pH controlled experiments (32%), relative to the experiment without pH control (10%).

Jan 1, 2015

By Jo Render

Expectations of your management approach ??Life of mine applicability ??Tailor scale of activity to scale of project ??Assess impacts, risks, and opportunities ??Use global good practice, backed up by rigorous analysis ??Support with trained monitoring and evaluation team ??Information infrastructure to allow ongoing trend analysis and tracking of progress ??Public reporting using standardized indicators Yes, we are talking about a ?management system?

May 1, 2011

"The Val d'Or Division now comprises the Lucien C. Beliveau Mine and Concentrator (formerly the Pascalis, described below) and the Chimo Mine. Cambior acquired an initial 50% interest in the Chimo Mine in May 1989 and the remaining 50% in April 1990. Cambior's share of 1989 production was 2121 ounces; the company expects to net 23 750 ounces from Chimo in 1990. Pascalis MineUPDATERenamed the Lucien C. Beliveau Mine at its official inauguration in September 1989, the mine is exceeding forecasts, producing over 11 500 ounces of gold in the first half of 1990. Cambior expects 1990 production to total 34 000 ounces.IntroductionThe Pascalis Mine is located 16 miles east o f Val d'Or, Quebec, and is accessible by a three mile gravel road off highway 117 (Fig. I).The property is wholly owned by Cambior.The Pascalis gold deposit consists o f a sub-vertical diorite dyke 1000 ft long by 30 ft wide containing quartz and tourmaline veins with inclusions of pyrite and native gold . Three vein systems ca n be seen in the deposit , the most important being tensile veins oriented at a right angle to the direction of the dyke and inclined at 40 degrees. These overlapping veins vary in thickness from 4 in. to 40 in. and occur at intervals of six to ten ft. The deposit is, therefore, very difficult to evaluate; a complete evaluation would require drifts over the whole width of the dyke combined with relatively short drill holes (Fig . 2)."

Jan 1, 1990

By D. R. Lentz, C. J. Beaumont-Smith, S. H. Mcclenaghan

"Abstract - The Louvicourt Au-Ag-Cu-Zn-Pb sulfide deposit is hosted by a Middle Ordovician calc-alkaline sequence of aphyric rhyolite flows and associated fragmental rocks at the top of the Flat Landing Brook Formation. The Zr/TiO2 (average = 0.110) and Y/TiO2 (average = 0.021) ratios in the footwall felsic volcanic rocks are consistent with known values for the Reids Brook member. The deposit consists of two concordant lenses of semi-massive to massive sulfides, approximately 150 m long and up to 9 m thick, which represent a fold repetition of a single exhalative horizon. The deposit contains a geologic resource of 136 000 tonnes grading 1.2% Pb, 1.0% Zn, 0.4% Cu, 90.9 g/t Ag, and 0.96 g/t Au; the deposit locally contains elevated Au (2.9 ppm) and Ag (320 ppm) contents. A laterally continuous iron formation that contains barite caps the deposit, and is gradational vertically and laterally into laminated siltstone. The exhalite confirms the stratiform nature of this deposit, but a large percentage of sulfides occur as late replacements of altered felsic fragmental rocks in the footwall. Abundant examples of colloform pyrite and perlitic and spherulitic textures in volcanic clasts are well preserved. The base- and precious-metal content of the Louvicourt deposit is atypical of the Bathurst Mining Camp (BMC). Reported assay data (n = 27) indicate an average Pb/Zn ratio of 2.6, the highest in the BMC (average = 0.39). Lead exhibits a strong Spearman Rank correlation (r' = 0.92) with base metals throughout the sequence, indicating a preponderance of galena in both the stockwork and stratiform zones. The Ag and Au contents in this deposit are among the highest in the BMC and exhibit a Au-Ag- Cu-Pb association. Barite-rich exhalative pyrite exhibits a moderate Au correlation with Ag (r' = 0.77; n = 10) and Cu (r' = 0.76) and occurs in portions of the exhalative sulfides that are enriched in Pb. Chemical exhalative rocks are conformably overlain by trachy-andesitic volcaniclastic (possibly pyroclastic) rocks that are assigned to the Little River Formation. These are enriched in Nb (average = 38.4 ppm) and P2O5 (average = 0.17 wt.%), and have much lower Zr/TiO2 (average = 0.056) and Y/TiO2 (average = 0.0062) relative to rocks higher in the hanging wall. The intermediate volcanic rocks are conformably overlain by massive to pillowed basalt flows and related hyaloclastite that have Nb/Y = 0.60 and high TiO2 contents (average = 2.8 wt.%). This chemistry is consistent with rocks of the Brunswick Mines member (Little River Formation), except that these rocks are considerably enriched in P2O5 (average = 0.82 wt.%). This syngenetic exhalative deposit is unique for the BMC with a high Pb/Zn and elevated Au and Ag contents, as well as an epithermal signature (Sb-Ag-Au-Tl-Hg), analogous to high sulfidation volcanogenic massive sulfide deposits. Its intimate relationship with an emergent felsic dome (Flat Landing Brook Formation), chlorite-silicate-oxide-sulfide exhalite (locally hematitic), and the abundance of barite are classical features of many of the Kuroko deposits."

Jan 1, 2006

By Sandeep Singh Sandhu, Karanvir Singh Ghuman, Manjit Singh

"Cobalt based super alloy stellite 6 was weld cladded on AISI 304 L stainless steel using SMAW process in order to improve the wear resistance for tyre crusher blades. Microstructure characterization and micro hardness testing was performed on stellite 6 cladding. The suitable parameters viz. 80 Amp current with arc weaving technique was selected by performing bead on plate experiment were further used for depositing multipass multilayer cladding to achieve full filler chemistry at the top surface. Further GTAW process was used for re-melting the top surface of the cladding. Comparative evaluation of the claddings showed that TIG re-melting resulted in increased microhardness and wear resistance in comparison to as cladded specimens even with lesser deposition of material. It was observed that TIG re-melting improved the hardness from 603 HV0.5 kg to 712 HV0.5 kg. Micro structures of stellite 6 contained cobalt solid solution matrix along with inter dendrite chromium carbides which resulted in the increased micro hardness values. Pin on disc abrasion tests were carried out at room temperature and the worn out surfaces were characterized using SEM and EDS.INTRODUCTIONThe crusher blades are used in many industries for crushing various types of material and its wider applications in tyre rubber crushing mills, metal-powder crushers industries etc. Most of the crusher blades are damaged by the wear and impact loading conditions. It is because of metal to metal abrasion and the temperature also plays a vital role in blunting the cutting edges of these blades. The wear is the major cause which leads to loss of material and thus the productivity that can never be recovered (Kotechi et al., 1992). The wear can be reduced by coating of various super alloys which could reduce the behavior of metal degradation even in aggressive environments. Cladding of cheaper low alloyed material with expensive superalloys to enhance the performance of components at low cost has been investigated by many scholars (Deng et al., 2010, Kennametal, 2007, Lolla et al., 2014, Singhet al., 2014, J.N et al., 2003, Ramkumar et al., 2012). Many researchers have reported that cladding is an application of build-up deposits of specialized alloys to resist abrasion, high temperature corrosion and impact loadings. Cladding is used for providing required mechanical strength properties as well as inhibition of oxidation and other corrosive degradation. Coatings are used to protect the heat affected areas like tubes of fluidized bed combustor etc. (Kirchbner et al., 2008, Wang et al., 1994, Hocking et al., 1993, Ananthapadmanabhan et al., 1991, Staia et al., 2001). Coating techniques are widely used for the protection of turbine engine and boiler tubes against high temperature corrosion attack, power generation equipment, chemical process equipment, aircraft engines, pulp and paper processing equipment, bridges, rollers and concrete reinforcements, orthopedics and dental, land-based and marine turbines, ships. Coatings of stellite 6 are widely used in steam turbine blades and boiler tubes for power generation because of an excellent combination of impact, wear and other properties. It can maintain its properties even at high temperature and in harsh environments (Kobayashiet al., 1999, Alam et al., 2009, Munehru et al., 2009). The loading and unloading conditions experienced by the material may induce the surface cracks which lead to its breakage and leaving large pits in the surface (Meng et al., 1995). Many researchers have reported that the properties of cladded layers can be increased by various techniques such as controlling the current variations, dilution, heat input, laser and other re-melting processes, addition of special alloying elements, speed of weldingetc(C.M Anaet al., 2002, Kumaret al., 1999, Luo et al., 2012, et al., Madadi et al., 2011, Shin et al., 2003, Kuzucu et al., 1997, Sudha et al., 2008, Sawant et al., 2017, Houdkova et al., 2016, Ciubo"

Jan 1, 2017

By E. Eccleston, E. Gardner, F. Letarte, R. Schonewille

"In 2005, after nearly a decade of process development and feasibility work, the commercialization of the Falconbridge Nickel Smelting Technology (NST) began in earnest with the design and construction of a grassroots ferronickel plant at Koniambo Nickel in New Caledonia. The NST process was developed as an alternative to the conventional Rotary Kiln-Electric Furnace (RKEF) process for production of ferronickel from saprolitic nickel laterite ores. The NST process promised environmental and energy efficiency advantages over the conventional route. A key step of the NST process involves fluidized bed pre-reduction of calcined laterite ore using direct injection of pulverized coal as the reductant. Two parallel fluidized bed reduction roasters (FBRs) were installed at Koniambo Nickel, each designed for a maximum capacity of 4,200 MTPD of calcined nickel laterite ore. This paper describes the process development and scale-up of the fluidized bed pre-reduction process, the design challenges associated with the prototype commercial units, and the current status of the FBR operation at Konaimbo.INTRODUCTION In the mid-1990s, Falconbridge began to develop a new flowsheet for production of ferronickel from nickel laterite ores. The process that developed came to be known as the Falconbridge Nickel Smelting Technology (NST). The flowsheet, which is particularly appropriate for saprolitic ores, involves several major unit operations, including: drying in a hammer mill-flash dryer, calcination and preheating in a flash calciner, pre-reduction in a fluidized bed reactor, and smelting in a DC arc furnace to produce the ferronickel product. This paper focuses on the fluidized bed pre-reduction step of the process and provides an overview of the process chemistry, laboratory and pilot plant development work, scale-up and commercialization of the pre-reduction step, and the results obtained in the prototype commercial units."

Jan 1, 2017

By E. Ghali, A. D. Bas

There is a lack of electrochemical studies of oxidized gold ores since the majority of previous studies were conducted with sulphidic gold ores. In this study, the influence of agitation and iron oxide minerals, i.e. magnetite, hematite, and maghemite on gold leaching was investigated by means of galvanic and passivation phenomena. Cyclic voltammetry studies of Roasted Gold Ore (RGO) in de-aerated electrolyte have shown one oxidation and one reduction reaction while three oxidation and one reduction peaks were observed with gold electrode. Galvanic coupling results by Zero Resistance Ammeter (ZRA) mode indicated that magnetite showed a negative effect on gold dissolution while maghemite and hematite showed a positive effect, relatively, as a result of higher galvanic corrosion rates. Generally, gold dissolution was found to increase in the initial 15 minutes. Increasing agitation speed from 100 to 400 rpm resulted in higher galvanic corrosion rates for RGO, magnetite, and maghemite electrodes, while 250 rpm was found to be optimum for hematite electrode. Passive products such as silver and iron-oxide were identified by XPS and SEM-EDS analysis, respectively.

Jan 1, 2015