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By James R. Hein

Manganese nodules form at the sediment surface of abyssal plains throughout the global ocean at water depths of about 4000-6500 m. The nodules form a continuum from purely hydrogenetic (all metals from seawater) to purely diagenetic (all metals from sediment pore waters), which will determine which metals of potential economic interest are enriched in the nodules. Another important factor in metal enrichment is whether diagenesis in the bottom sediment is oxic or suboxic. There are several nodule fields in the deep ocean that have received much attention with regards to economic potential, the most important being the Clarion-Clipperton zone (CCZ) in the NE Pacific, where the International Seabed Authority (ISA) has signed 12 contracts for exploration areas, each spanning 75,000 square kilometers. Those nodules are rich in nickel (mean 1.3 wt. %), copper (mean 1.1 %), and manganese (28%), with moderate amounts of cobalt (mean 0.2%), molybdenum (587 g/t), and lithium (129 g/t). A conservative estimate is that there exists 21,100 million dry tonnes of nodules in the CCZ, yielding more manganese, twice the nickel, three times the cobalt, and four times the yttrium than the entire land-based reserve base (economic plus marginally economic plus subeconomic reserves) for each metal. Total rare-earth elements (REEs) as oxides average 0.09% in CCZ nodules, a potential byproduct even at that grade because the heavy REE complement averages 26%, compared to less than 1% for the large land-based carbonatite REE deposits. The price for HREEs is much greater than for the light REEs. For comparison, the REEs in deep-ocean ferromanganese crusts are 3 to 5 times greater than nodules and the HREE complement averages 18%. Of the 12 CCZ contracts, 7 are with States (China, France, Germany, Japan, Korea, Russia, and a group of States (IOM); and 5 are with companies: G-Tec Sea Mineral Resources NV, Nauru Ocean Resources Inc. (NORI); Tonga Offshore Mining Ltd (TOML), UK Seabed Resources Ltd (Lockheed UK), and Marawa Research and Exploration Ltd. Three other nodule fields that have received attention are in the Peru Basin, which has nodules very rich in manganese (34%) and lithium (mean 311 g/t), the Penrhyn Basin (Cook Islands Exclusive Economic Zone), with nodules very rich in cobalt (mean 0.4%); and the Central Indian Ocean Basin (CIOB), where India has an exploration contract with the ISA. CIPB nodules have mean nickel, copper, and manganese contents of 1.1%, 1.0%, and 24% respectively.

May 1, 2013

By L. A. M. Castro

As Canadian mines progress to greater depths, magnitudes of induced stresses increase, becoming high enough to cause rock mass damage and failure during excavation. In addition, depending on the orientation of key geological structures in relation to the in-situ stresses, induced shear loading can be developed on these structures, creating the potential for: a) remobilization of existing geological structures, b) formation of new seismically active structural zones, created through rock mass damage and coalescence along such structural zones, and/or c) interaction between existing and newly created structures. Numerical analyses were carried out to investigate four possible factors that might cause fault slip on controlling structures, namely: (a) unclamping, (b) day-lighting, (c) stress rotation and (d) pillar shear. Application to an underground mine in the Sudbury Basin allowed verification of these factors and the proposal of two alternative mine planning methods to limit fault slip on key structures: (1) pillar clamping and (2) stope sequencing.

May 1, 2009

By G. M. Ross, J. A. Scott, C. A. Laamanen, H. Shang

"Indirect recovery and use of waste heat contained in smelter off-gas is proposed to expand regions available for year-round, on-site production of micro-algae–sourced biodiesel, a fuel that could be used in underground machinery. A dynamic model of an off-gas heat exchanger describes capture and distribution of heat into open, external, rectangular micro-algae ponds. Smelter off-gas contains sufficient energy to maintain large-scale micro-algae cultivation pond temperatures above 15°C, even with winter ambient temperatures below –15°C. Results highlight opportunities that could lie in tapping these heat resources to produce renewable biofuels on-site and sequester CO2 while leaving the industrial process unaffected.RÉSUMÉ On propose la récupération et l’utilisation indirectes de la chaleur résiduelle contenue dans les dégagements gazeux des fonderies pour développer les régions se prêtant à une production toute l’année durant et sur place de biodiesel à partir de micro-algues, carburant dont on pourrait se servir pour le matériel d’exploitation souterraine. Un modèle dynamique d’échangeur de chaleur contenue dans les dégagements gazeux décrit le captage et la distribution de la chaleur dans des bassins rectangulaires ouverts de micro-algues en extérieur. Les dégagements gazeux des fonderies contiennent suffisamment d’énergie pour maintenir les températures des grands bassins de culture de micro-algues au-delà de 15°C, même avec des températures ambiantes en hiver inférieures à –15°C. Ces résultats soulignent les possibilités que pourrait offrir l’exploitation de ces sources de chaleur pour la production de biocarburants renouvelables sur place et pour la séquestration de CO2 sans que cela n’ait d’incidence sur le procédé industriel.INTRODUCTIONMicro-algae that grow in water can efficiently convertsolar energy and carbon dioxide into biomass. This biomass can be up to 50% oils (lipids), which can be extracted and converted into biodiesel through transesterification (Demirbas, 2008). Compared to terrestrial plants that produce similar oils (e.g., jatropha, soybean, and rapeseed), micro-algae represent an order of magnitude increase in areal productivity, do not require arable land, and can be continuously harvested (Rawat, Ranjith Kumar, Mutanda, & Bux, 2013). The potential advantages through the production of biodiesel from micro-algae also include sequestration of carbon dioxide, reduced reliance on fossil fuels, and the co-production of other value-added bioproducts."

Jan 1, 2017

Agenda ?The Context ?The Challenge ?The Solution ?Benefits and lessons learnt from pilots ?Next Steps The Context ?Facilitate management decision making process by supporting the development of value/risk based business cases. ?Large scale investments by extractive industries are expected tobring broad-based benefits to local communities (e.g.: health, education, jobs, infrastructure) ?Investors continue to expect the demonstration of social performance?Specific interventions bring direct value to companies (e.g. skills development) ?Social Investments are key to protecting a company?s license to operate ?Quantifying the value of these investments and planning accordingly, however, has long posed a challenge for the extractive industries and community development practitioners

May 1, 2011

The tensile test results of as-cast A356.2 grain-refined alloy castings show that the tensile strength can be improved by strontium modification (`SrM'), superheating at 900°C OM, and melt thermal treatment of the Sr-modified alloy melt (`SrMTT'). Both SrM and SrMTT processes can greatly improve the ductility (percent elongation) of the as-cast alloy. During solution heat treatment at 540°C, eutectic Si particles undergo fragmentation, spheroidization, and coarsening, thereby affecting their morphology. The effects of solution heat treatment on the tensile properties of the variously treated A356.2 alloy castings can be summed up as follows: the yield strength of the castings is significantly improved after 8 h solution heat treatment due to the precipitation of Mg2Si, after which it remains more or less the same with the further increase in solution treatment time up to 80 h; the ultimate tensile strength is also greatly improved within the first 8 h of solution heat treatment and then remains at the same level thereafter, up to 80h of solution treatment. The improvement in UTS is attributed to Mg2Si precipitation, dissolution of Si within the aluminum matrix, and changes in the Si particle morphology (spheroidization). The ductility of the as-received grain refined non-modified (`NM'), grain refined and superheated at 900°C (`SH'), and melt thermal-treated grain refined (`MTT') A356.2 alloy castings can be improved considerably with solution heat treatment e.g. from ~6% in the as-cast non-modified casting to ~10% after 80 h solution treatment.

Jan 1, 2011

By Arthur. H. Winckers, Stephan L. Chryssoulis

"The deportment of gold in residue samples of cyanide leach tests of David Bell ore from level 6A block 13 was established using a comprehensive quantitative mineralogical approach. In every test the feed was first pre-aerated for 4 hours, followed by 48h cyanidation. Test no. 2 was done without lead nitrate and yielded a residue assaying 3.03g Au/t. In test nos. 4 and 9 lead nitrate was added before pre-aeration at 0.03kg/t and 0.3kg/t respectively yielding residues of 1.04 and 0.81 g Au/t.The mineralogical approach employed to establish the deportment of gold involved superpanning, to preconcentrate the free gold and assaying of the tailing fraction to determine the gold associated with quartz. It was thus determined that without lead nitrate added 47.2% of the lost gold is in the form of residual free gold particles less than 20 µm in size. It is this form of gold which is under represented in the residues of leach tests with lead nitrate added.Having eliminated coarseness of gold particles as a factor for lower recovery, it was determined that the residual gold particles have extensively contaminated surfaces. Amongst the deleterious surface contaminants identified: S, As, Ag, Sb and Hg, the two most harmful are S and Hg because of their concentration on the surface and rate of accumulation.Mercury and Ag are minor constituents of native gold at David Bell (average composition Au: 78.9 wt%, Hg: 18.5 wt% and Ag: 2.6 wt%) and they become enriched on the surface of residual gold particles because of their slower rate of dissolution in cyanide. The other elements absorb onto the gold particles from solution.The beneficial effect of lead nitrate was documented by comparative surface analysis of gold from residue samples of 48 hour leach testing with and without lead nitrate added and from time dependent (0-2 hour) leach tests in the presence and absence of lead nitrate. Lead nitrate accelerates the dissolution of gold by performing the following functions: (i) catalytic effect on the cyanidation of gold by accepting electrons; (ii) reaction with surface sulphur to form PbS which is then removed by oxidation; (iii) catalytic reaction on amalgam and Ag facilitating the cyanidation of Hg and Ag thus slowing down their build up onto the dissolving gold particles and (iv) the precipitation of sulphide sulphur from solution thus minimizing its build up on the surface of dissolving gold particles which is believed to facilitate the access of cyanide ions."

Jan 1, 1996

By M. Kawahara, H. Sunayama

Oxidation rates of the cubic specimens, which were prepared by cutting the shaped magnesia-carbon bricks, were measured continuously with a thermo balance in the temperature range from 1273 to 1 823 K in N2-02 and Ar-02 mixed gas with 2.1 x 104 and 3.7x 102 Pa of oxygen partial pressure respectively. The effect of the graphite content, the maximum grain size of magnesia clinker and the oxygen concentration in the atmospheric gas on the oxidation rate for the MgO-C refractory has been investigated. The value of effective diffusion coefficient of O2, which diffuses through the porous decarburized layer, decreased with the decreasing of the porosity and the oxygen concentration in the external gas phase. It was speculated that the dense layer formed easily due to the high tortuosity of pores and the low recession speed of the carbon interface in the MgO-C bricks.

Jan 1, 2004

By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By S. Parada, P. T. Jones, M. Guo, S. Smets, E. Boydens

The corrosion behaviour of a pitch-bonded MgO-C refractory in contact with a vacuum oxygen decarburisation slag with high Al2O3 content (12-17 wt%) is investigated under VOD process conditions by rotating finger tests in a vacuum induction furnace. The refractory degradation mechanisms are studied by the characterisation of the corroded microstructures using scanning electron microscopy, equipped with energy dispersive spectroscopy. The influence on the refractory wear of the process temperature, corrosion time and the Al2O3 content in the slag is discussed. The degradation mechanisms include slag infiltration, direct MgO dissolution from the refractories into the penetrated slag, erosion of magnesia grains at elevated temperatures, removal of carbon through the MgO-C reaction, and finally, oxidation of refractory carbon by reducible slag components. Both a porous MgO layer and a dense (Mg)(A1,Cr)2O4 spinel at the slag/brick interface were observed. Their formation mechanisms and industrial relevance are discussed.

Jan 1, 2004

By S. Khoshkhooei

In this research, the effects of rare earth elements addition on thermal fatigue behaviors of AZ91 alloy were studied. Repeated heating and cooling cycles were applied on the samples at 170°C and 210 °C to develop thermal fatigue cracks, Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy (SEM) as well as energy dispersive X-ray spectroscopy (EDS), Thermal fatigue behaviors were improved successively by addition of up to 2-wt% RE, This improvement is attributed to consummation of the aluminum of the melt by precipitation of the needle shape Al 11 RE3 phases, This process reduces the volume of Mg17Al12 phases and consequently decreases the brittle Mg/Mg17Al12 interfaces which are the main reason of weak thermal properties of the alloy at rather high temperatures, Further additions of RE, however, reduced the thermal shock resistance of samples by increasing in the mean length of the brittle needle shape phases.

Jan 1, 2005

By O. Lashkari

Swirled Enthalpy Equilibration Device (SEED) is a new patented Slurry-on-Demand, SoD, processing route. The semi-solid slug preparation is carried out by off-center swirling of aluminum melt in a metallic mould. As part of the current research program on the semi¬solid processing of aluminum alloys, the morphological evolution of 356 aluminum foundry alloy microstructure is reported here. Semi-solid slugs were prepared using two different pouring temperatures of 645°C and 695°C respectively. Morphological evolution of the semi-solid microstructure was characterized using image analysis through measuring of primary a-Al particle size, number density, aspect ratio and sphericity. The possible relationships between microstructural features and process parameters were also investigated. The current report covers the effect of pouring temperature on the morphology of primary a-Al dendrites and attempts are made to explain the differences between the predicted percentage primary a-Al phase and those of the actual values in the as-cast slugs.

Jan 1, 2004

By D. L. Johnston

"The avenues and degree of participation by aboriginals in the Canadian minerals industry have changed significantly during the thirty years of the author&apos;s career in that industry.The typical 1950s cycle of mineral industry involvement of a local non-Europeanized aboriginal was as an individual employee. The employment relationship would begin with the best of intentions by both parties of permanence and terminate when the pioneering employee was unable to reconcile the attendance behaviour required by the employer and the social-sharing behaviour demanded by family and friends.Cominco Ltd. has been a mine operator and developer in the North since the 1920s. Cominco&apos;s early experiences with employment of non-Europeanized natives at the Con Mine in Yellowknife, Northwest Territories from 1938 to 1986 was a negative experience from both the employee and employer ends. A series of classic failures in employment of individual aboriginals was a large part of the history. A few Metis or natives from other areas were the permanent aboriginal employees at Con (2010). Racial prejudice was overt on the street in Yellowknife and, it can be assumed, in the workplace, as well.The history of aboriginal employment at the Pine Point, Northwest Territories operation (1964 to 1988) was somewhat better but also frustrating. The mine was equidistant (80 km) from the Dene communities of the Hay River Indian Reserve and Fort Resolution, both on Great Slave Lake. Despite a large aboriginal presence and many well-intentioned efforts, employment of aboriginals at Pine Point never got much beyond ten per cent. These would have been half local and half northern prairie aboriginals. One continuing success story was the railcar loading and covering crew led by Ed McKay, a local aboriginal. This predominantly aboriginal crew did its own recruiting and several are on Cominco pension."

Jan 1, 1995

By Robert D. Brown, Robert B. Parsons

"Careful tax planning and proper attention to the regulations can result in an optimum deduction ""of the 25% federal resource allowance. Introduced in the Income Tax Act in1976, in part to compensate for the disallowance of provincial mining taxes and royalties. the 25% ""resource allowance"" is a permitted deduction in computing taxable income from mining and petroleum. However, the rules relating to the deduction are complex, and the importance of the deduction which can readily exceed 25% of net income- is frequently underestimated. This month, Tax Notes discusses the basic rules of calculating the resource allowance, and suggests some tax planning aspects which may warrant consideration.May 6, 1974 - "" .. . our provinces have adjusted royalties, mining taxes and other arrangements to derive what they perceive to be a fair share for the benefit of their people. However, a provincial resource is also a national resource... I am proposing that revenues derived by provincial governments in respect of production from a… mineral resource should no longer be.\ deductible in computing the income of the operator. .. I am proposing that. .. there be an extra abatement from federal income tax in respect of taxable production income.. .fifteen points in the case of mineral profits. .. "" - The Honourable John N. Turner, Minister of Finance. June 23, 1975-"" &apos;"" to meet, at least in part, the request for some form of deductibility in the tax system for provincial resource levies... to offer more incentive to those who explore and develop in Canada. .. I am now proposing, the extra fifteen point abatement of federal taxes would be withdrawn... at the same time, I am introducing a new resource allowance, which would be an extra deduction from income equal to 250/0 of production income.. ."" - The Honourable John N. Turner, Minister of Finance."

Jan 1, 1980

By J. Gillies

"Those of you who were at last years C.M.P. meeting are aware there was discussion at that meeting concerning the best method of assisting the assayers of metal mines to exchange new ideas and methods of assaying. The opportunity to advise you of what came of that discussion is very much appreciated.There are several societies, including the Chemical Institute of Canada, the Spectroscopy Society and others that could be of some assistance to assayers. However, since these societies cover a rather broad field and not many mine assayers have the opportunity to attend their meetings, it was felt that an organization oriented to the specific needs of the mine assayers would be of more value to them.Several years ago an attempt was made to hold meetings for the benefit of assayers in conjunction with the Conference of Metallurgists held each year by the Metallurgical Society of the C .I.M.M. This did not work because very few of the mine assayers attended the meetings.With the very evident success of the type of meetings the C.M.P. have and the excellent groundwork done by your secretary, Mr. Stevens, in talking about this to mine management and assayers at many mines across the country, it was decided to hold a meeting at Noranda on October 8 to discuss how best we could help ourselves solve our problems.For the initial meeting it was felt that perhaps it would be better to start with a smaller group, so invitations were sent to mines in Ontario and Quebec that were geographically fairly close to Noranda."

Jan 1, 1970

By S. Balideh

A good understanding of the behavior of broken rock helps to make more informed decisions regarding slope stability and waste dump issues in mines. The cohesion coefficient of rock has little influence on the strength of broken rock; therefore, a criterion based on friction and cohesion of intact materials does not provide an accurate analysis for the strength of broken rock. This paper illustrates the effective strength of broken rock through a brief literature review about failure of intact rock and rock masses. The complete stress- strain curve and some important points of residual strength of rock are summarized in this paper.

Jun 1, 2012

By Douglas Lay

Attention has been drawn in the publications of the Department of Mines to the view that veins of two different ages occur in the Cariboo district, namely, those of Jura-Cretaceous age and those of pre" Mississippian age. It has been further pointed out that while there is doubtless a wide distribution of veins of pre-Mississippian age in and about the Barkerville and Stanley areas, and in the vicinity of Round Top mountain and Yank&apos;s peak, there is no such wide distribution of veins carrying gold values of commercial significance. Veins of the latter type discovered to date occur almost exclusively within one or other of two comparatively narrow zones, both trending northwest and southeast, the one extending from Island mountain co Round Top mountain, and the other from a point somewhat north of Stanley co Yank&apos;s peak. In addition, there is some evidence of a third zone trending northwest from Spanish mountain, at or near the contact of the pre-Cambrian and Mesozoic rocks. In short, all the evidence from prospecting and lode-mining operations to date indicates that values are mainly restricted co zones having marked directional distribution. Moreover, it can be demonstrated that the placer deposits resulting from the erosion of the pre-Mississippian veins have a similar directional distribution, allowance being made for modifications due to glaciation. The observations offered in this paper are of the nature of a generalization which seeks to explain certain anomalies both in the vein-mineralization and in the -important auriferous-pyrite replacement deposits in limestone which have recently been discovered. For the sake of brevity, the Island Mountain-Round Top Mountain zone will be referred to as Zone No. 1, and the Stanley-Yank&apos;s Peak zone as Zone No. 2.

Jan 1, 1936

By A. Alfantazi, E. Asselin

"The corrosion of commercially pure titanium (CP-Ti) was studied from room temperature up to medium temperature (~160°C) under conditions relevant to medium temperature chalcopyrite leaching processes. The corrosion rates were measured by immersion and electrochemical tests in sulfuric acid. The influences of chloride, cupric and ferric ions on the corrosion rate and behavior were also investigated. Corrosion of the CP-Ti did not account for the total current density measured by linear polarization tests. The corrosion rates of CP-Ti under medium temperature leaching conditions were surprisingly high. The corrosion rate measured in ferric containing solution at 160°C was approximately 20 mm/yr.INTRODUCTIONTitanium exhibits excellent corrosion resistance in many aggressive environments because of the formation of a very chemically stable, highly adherent, and protective oxide film on its surface (Mitsuo et al., 2002). Because titanium is the only metal available at a reasonable cost that resists the high temperature corrosive slurries in many leaching processes, it is often chosen as autoclave liner material where it is subjected to severe conditions of acidity, temperature and pressure (Grauman and Say, 2000).A number of distinctly different hydrometallurgical processes for the pressure leaching of chalcopyrite have been developed and patented by various companies and they can be classified into low, medium and high temperature regimes (McDonald and Muir, 2007). For example, chalcopyrite concentrate may be processed at medium temperatures (115-175°C) and pressures of 800-2200 kPa (Dreisinger, D., 2006; Sahu and Asselin, 2011). The lixiviant may contain 20 to 55 g/L sulfuric acid, 8 to 12 g/L chloride ions, 10-25 g/L Cu2+ (Jones, 1995, 1997, 1999), and less than 1 g/L Fe3+ (Defreyne et al., 2005). The amount of these additions is determined by the grade of the ores and details are shown in Table 1."

Jan 1, 2012

"Batch flotation testwork demonstrated that a low-grade chromite ore from Bird River, Manitoba, was best floated at pH 2 using Armac C (coco amine acetate) collector and sulphuric acid as pH modifier. A grind of 100% minus 150 um was necessary for liberation, and flotation selectivity was greatly enhanced by prior desliming. A concentrate analyzing 24.2% Cr203 with a recovery of 90.2% was obtained, after three cleaning stages, from ore grading 6.05% Cr203. Total rougher collector concentration was 500 g/t and cleaner collector concentration 380 g/t. Similar grade and recovery were obtained during the pitot-plant evalualion, when a concentrate analy zing 22.3% Cr203 with a recovery of 93% (based on deslimed feed) was obtained for a total collector addition of 630 g/t.Selective flotation in a region of positive surf ace charge implies anionic activation, and a possible flotation mechanism is suggested.IntroductionIn an earlier study(1) of the beneficiation of chromite ore from Bird River, Manitoba, several methods of beneficiation were explored. These included ore sorting, heavy-media separation, and gravity concentration with flotation using Armac C (coco amine acetate) collector at pH 2, and sulphuric acid as pH modifier. Because flotation was not fully evaluated, a laboratory study was undertaken to determine the optimum parameters of chromite flotation. Optimization of parameters was established first on a laboratory scale followed by confirmation a t the pilot -plant level. Flotation of chromite using Armac C and sulphuric acid as a pH modifier has been reported as being selective for low-grade chromite ores(2)."

Jan 1, 1990

By R. A. Gannicott

Trend surface analysis was used to investigate the geochemical dispersion patterns of Si, Ai, Fe, Mg, Ca, Na, K, Ti and Rb in the footwall of the Seneca massive sulphide prospect in southwestern British Columbia. Surfaces for various element ratios were also produced to see if the distributions of the elements are related to each other. Trends developed by the elements redistributed during hydrothermal alteration may be difficult to detect for various reasons, such as too few and widely separated sample points, random analytical errors or local variations in rock chemical composition that are not related to regional trends. Trend surface analysis is useful to distinguish regional trends from local fluctuations. The computer program used in this study is capable of calculating surfaces up to the 6th degree polynomial, but provides for automatic termination when the variables in the equation for successive surfaces become effectively collinear. With the relatively small number of data points used (21 samples) in this study, such termination occurred after the quadratic surface. Results show that, at the Seneca prospect, Mg and K increase, and Na and Ca decrease, toward a common centre which corresponds closely with the best drill-core intersections of ore. The centre is interpreted as a volcanic vent and as the source of mineralization . Quadratic surfaces for element ratios show that K/Ca decreases and Fe/Mg increases away from this vent. Thin-section and X-ray diffraction analyses indicate that these variations reflect sericitization of plagioclase and an increase in the Mg content of chlorite near the vent. The mineralization , rock types and element dispersion patterns at the Seneca prospect are similar to those reported for volcanogenic massive sulphide deposits at Bathurst, New Brunswick, and in the Hokuroko district of Japan.

Jan 1, 1979