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As near-surface underground mines progress deeper, the inevitable question is whether to convert from truck haulage to shaft hoisting. The desire to defer capital expenditure frequently delays investigation of the shaft option, or deferral of a decision to start shaft sinking, unless the shaft option is clearly significantly better than trucking. By the time increasing depth makes trucking uneconomic, there may then be insufficient resource remaining to justify a shaft, and the mine must close. However, had the shaft been built earlier, its lower operating costs would have permitted the mine to continue to greater depths. This paper presents a methodology for investigating the shaft versus trucks decision. As well as the typical analysis of which option is preferable at the time the analysis is conducted, the process presented illustrates how the timing of the decision to sink a shaft is critical. The paper shows how to identify the latest date at which the decision to sink a shaft can be made, after which time the shaft option will not be economic. It also illustrates how to assess the resource that may be required to justify the shaft. Considering this in conjunction with the latest decision date, implications for the companyÆs exploration program are discussed.

Jan 1, 2005

By P J. Colbert, P D. Munro

OZ Minerals' Prominent Hill copper-gold concentrator in South Australia was built in 2008 with commercial production commencing in early 2009. In addition to recovery of valuable minerals, the flow sheet for this iron oxide-hosted copper-gold deposit has to address the issue of producing a good quality saleable copper concentrate by high selectivity against non-sulfide gangue. Detailed mineralogical studies integrated with the metallurgical test work highlighted that liberation of fluorine-bearing minerals and subsequent very efficient rejection in cleaner flotation was necessary to produce a commercial quality copper-gold concentrate. Bench scale laboratory metallurgical tests and mineralogical studies identified the need to regrind rougher concentrate to a P80 of 20 -25 microns or finer for adequate liberation of the fluorine-bearing minerals. Satisfactory separation of the fluorine-rich gangue material from the valuable copper sulfides requires highly efficient cleaner flotation. This is done by a combination of washed froth cleaning and conventional dilution cleaning. Proven equipment developed to meet similar taxing liberation and separation duties for the treatment of the refractory zinc-lead-silver ores of the Carpentaria-Mount Isa Mineral Province have been selected. The combination of Xstrata Technology's IsaMillÖ and Jameson Cell technologies addressed both the liberation and separation issues in the Prominent Hill concentrator. The energy efficient IsaMillÖ technology both regrinds the rougher concentrate while its inert grinding environment prevents contamination of mineral surfaces with 'debris' ensuring subsequent optimum flotation performance. Heading up the cleaner circuit with a 'scalping' Jameson Cell followed by conventional flotation equipment allows this section to take advantage of the Jameson Cell's high intensity flotation environment and froth washing capability to achieve maximum concentrate grade (at minimum fluorine levels) while maximising recovery through the use of conventional flotation machines. This paper looks at the development of the Prominent Hill flow sheet from the initial mineralogical and laboratory test work to the design, scale-up and early operation of the Prominent Hill regrind and cleaner flotation circuits. The mineralogically-based approach of domaining metallurgical ore types combined with the axiom of size-by-size mineral particle behaviour by liberation class gave a clear understanding of the liberation and separation issues involved in the processing of Prominent Hill ore. Technologies developed to meet much more onerous liberation and separation duties for the treatment of the refractory zinc-lead-silver ores of the Carpentaria-Mount Isa Mineral Province were successfully used to improve concentrate quality by rejecting non-sulfide gangue containing impurities. An IsaMillÖ and a Jameson Cell are included in the circuit for fine grinding and for additional concentrate cleaning. Plant performance since commissioning has justified the approach for metallurgical test work and equipment choices for the flotation circuit.

Jan 1, 2009

By Yoon R-H, Luttrell GH

A theoretical model has been developed to predict the probability of particle collection by air bubbles in a quiescent flotation pulp. The model considers the effects of both hydrodynamic and surface chemistry forces acting during the bubble-particle interaction. Hydrodynamic forces considered include the gravitational, buoyancy, streamline and film thinning resistance forces. The surface chemistry forces considered include the electrostatic, dispersion and hydrophobic forces. The hydrophobic force has been estimated from extended DLVO theory. The model is capable of predicting hydrodynamic and surface chemistry conditions under which bubble-particle adhesion is possible. Validity of the model has been verified experimentally.

Jan 1, 1993

Ion exchange resins are an attractive alternative to activated carbon in both column and resin-in-pulp processes for the recovery of gold from cyanide solution. Resins are widely used for this purpose in the Soviet Union apparently in preference to activated carbons.A wide range of resins are available and the high level of resin technology is demon-strated in the resin processes used to recover uranium.The anionic gold complex, Au(CN) 2 , is selectively adsorbed onto weak and strong base resins. However other anionic cyanide complexes, cyanide ions and other anions from the process water are also adsorbed onto resin sites. Resin selectively for gold is not as high as it is for activated carbons. As a result similar gold loading capacities are obtained for resins and carbons when used in plant liquors.

Jan 1, 1984

By G Huggins

Excavation in underground jointed rock masses creates cavities into which the surrounding rock mass deforms. Deformations, besides intact rock deformation, include mechanistic deformations such as slip and rotation. In this paper deformational moduli were measured for prototype and blocky (jointed) models using elastic analogue methods for stopes from MIM LimitedÆs Lead Mine. The blocks for the models were defined in terms of the prototypeÆs joint sets, their spatial separations, orientations and average friction characteristics. From dimensional analyses, a relationship between prototype and model deformations was used to predict stope mid-span deformations. The results of this physical modelling work, conducted in the 1970s, motivated an investigation into the electro-treatment of tailings backfill to achieve improved strength and stiffness characteristics. Tailings backfill containing fines and having a high clay content can be electrically dewatered, and at times grouted, cemented, ion exchanged or agglutinated, to achieve relatively high magnitudes of strength and stiffness. These treated tailings stiffnesses can reduce the deformation magnitudes within a rock mass and, in doing so, reduce problems encountered in mine pillar extraction. The application of these tailings modification techniques is examined in relation to the elastic analogue methods.

Jan 1, 1998

By Palmer DJ, Bain JH, Pullen JB

Over the last ten years at Risdon, zinc production capacity has almost doubled. This has resulted in modifications, many of which have affected zinc deposition operating conditions in the cells. Some of these changes appeared to have affected average current efficiency to such an extent that a special investigation was initiated, using multiple regression analysis to assess historic cell unit operating para- meters. The study highlighted the importance of certain parameters in maintaining maximum current efficiency for zinc deposition from !Risdon purified solutions under conditions of !changing current density, acidity and zinc con- centrations. Maximum current efficiency was obtained only within a zinc to acid ratio in cell electrolyte of 0.45 - 0.55 and a residual zinc concentration greater than 48 g.1-1, irrespective of actual zinc concentration or The investigation also established: ieters giving minimum power consumption at termined current density; the effect of ntration changes in common impurities on nt efficiency; the existence of high s of some impurities in solids precipit- in the cells and pure solution tanks.

Jan 1, 1975

Both innovation and excellence are desirable attributes of education, as they are also markers in the progression of the human race, but how attainable are they? The interaction of minerals and humanity provides a special insight into the development of both criteria, from the discovery that chert cuts, through the Bronze Age and the first use of metal alloys for implements, to using coal, oil and uranium as sources of fuel. However, there have been many hiccups along the way, where excellence in one respect has meant disaster in another. Examples are in the exploitation of asbestos, and in traditionally poor work practices in mining, both contributing to the widespread public belief that minerals and mining are ecologically undesirable. Yet is this perception based on the unrealistic expectation of innovation and excellence being simultaneous qualities of any given process? Common sense born of experience indicates that the journey from one, to the other, is usually a long and often tedious process, with much trial and error before excellence is attained. In our time, the partnership between academia and industry is the usual pathway to achieve it. Even so, we should take care that innovation does not become overwhelmed by the pursuit of excellence: as history clearly demonstrates, humanity depends upon both.

Jan 1, 2004

Ranger Uranium Mines Pty. Ltd. operates an open pit mine and ore treatment plant in the Northern Territory designed to produce 3 000 tonne/yr of U308 in yellowcake from 3 500 tonne/day of mill feed. The construction of this project was completed in 1981, 12 years after the discovery of the orebody. Wright-Davy, a Joint Venture of Wright Engineers and Davy McKee Pacific, were the Project Managers and Designers of the $270 million ore treatment plant and associated infrastructure. The project was designed in Sydney in -an office integrated with the Client, staffed by 35 key personnel drawn from Wright Engineers and Davy McKee, supplemented by personnel hired for the project. The peak Wright-Davy workforce in Sydney of 200 contained 113 design staff. The design principle of using the best practicable proven technology resulted in a plant which easily produces its design output using ore types outside the design criteria. The structuring of the project systems and industrial relations policies contributed to construction being completed within time and under budget. The plant was built without any major industrial dispute occurring and no dispute arose due to the uranium issue.

Jan 1, 1983

Methods of measuring the frictional properties of rock surfaces, both by direct sliding and in triaxial apparatus, are described. It was found that for some rocks the coefficient of friction remains reasonably constant as sliding is continued but for others it increases considerably.The effect of fluid pressure in the surface of sliding was found in all cases to be adequately represented by the effective stress criterion. Some observations on sliding on two conjugate planes showed that the motion on the two planes may be very different, depending on small differences in the constraints.The coefficients of friction of natural open joints in bore core were found to lie in the comparatively narrow range 0.32 to O.68 although surface coatings were very diverse.A set of diagrams on the equal area projection is given which enables a rapid determination to be made of those planes on which sliding is possible in a given three-dimensional stress field. The influence of the intermediate principal stress on this is of considerable importance.

Jan 1, 1969

By R P. Langford, T A. Moore

Over the last 15 years Indonesia has experienced a surge in coalexploration, which has led to the development of a major export industry. This coal exploration has improved the understanding of the geology of the Indonesian coal deposits. The main economic coal deposits are of Eocene and Miocene to Pliocene age, which mainly occur in Kalimantan and Sumatra and were formed from peat deposits in an equatorial paleoclimate similar to that prevailing today. Some of these peats were domed peats, which grew above the normal water tables, under a climate of year-round rainfall; these peats grew above the level at which waterborne mineral matter can enter the system, resulting in low ash and sulphur, and locally very thick coal. It is believed that such peats have formed the unusually thick, low ash, and low sulphur Miocene coals of Indonesia. Coal deposits of Eocene age are typically characterised by thinner seams, with relatively higher contents of ash and sulphur. The Miocene coals and Eocene coals both appear to have formed in lacustrine, coastal plain or deltaic depositional environments, similar to the modern peat-forming environments of eastern Sumatra and parts of Kalimantan. The Eocene coals formed mainly in extensional tectonic settings. Miocene - Pliocene coal deposits formed in a range of tectonic settings.

Jan 1, 1999

By Teague JK, Read HW

The relationship between the maceral composition of coal and the strength of the coke produced from that coal has received a great deal of attention in recent years. Studies using two Bulli Seam coals, and blends of Bulli and Wongawilli Seam coals, from the Illawarra Measures of the Southern Coalfield of New South Wales were carried out. The optimum range of vitrinite was found to lie between 45% and 60% (mineral matter free). Above and below this vitrinite range coke strength deteriorated. I Coke strength indices increased with rank and the optimum vitrinite content increased with an increase in rank. These changes will require confirmation as trends by testing a third level of rank. It was noted that vitrinite content decreased with an increase in the specific gravity of separation of the coal. . T Use of- petrographic analyses will increase confidence in choosing coals for coking, provided the coals are well known. Such analyses offer the possibility of greater flexibility in coal purchases and the possibility of producing a marketable blend from coals, which have limited market potential. Critical base coals for blends can be conserved. Significantly more work is required before coal reserves can be utilised to optimum advantage. This work would require extension of-the studies discussed in this paper and, in particular, the testing of a wider range of rank.

Jan 1, 1970

By G Chitombo

Mass mining methods have become the mining industry’s preferred way of extracting most of the world’s most important metal and mineral commodities. Given the rapidly increasing global demand for commodities, the requirement to increase the contribution of some of these (eg copper and gold) from underground sources also continues to grow. In the case of copper this contribution is needed by a number of major producers to supplement production from their ageing deep open pits. Satisfying this increased demand will require the design, construction and operation of more effective, higher capacity and larger scale mines which, in turn, will require enhanced mass underground mining techniques such as block caving (BC), panel caving (PC) and sublevel caving (SLC).It is now widely accepted that future discoveries of orebodies, which will be developed using these methods, are almost certainly to be much deeper than the deposits presently being mined in this way and made more challenging because of the likelihood that the associated grades may be much lower than currently mined. The design and mining of future large-scale cave mines (supercaves) will become crucial in order to extract full value from such deposits. An essential prerequisite of this will be a much improved knowledge of the deposit, ie Total Deposit Knowledge. In this context, Total Deposit Knowledge is the characterisation of the ore deposit and its surrounds at all scales and includes; rock type (lithology), the spatial orientation of a range of geological features or discontinuities, rock mass fabric knowledge, metal grade and distribution data, geometallurgical data (including alteration), geo-hydrology, permeability and porosity. This is the information that will be used, as now, to delineate geological and geotechnical domains and construct models, but with outcomes superior to those presently available. From this information better-informed feasibility study design decisions and performance predictions must be made. In summary more geological information and analysis is required and this needs to be aligned to potential mining and processing requirements much earlier in the project than commonly occurs.

Aug 22, 2011

In current mining practices it is desirable to bring about a substantial increase in both rate of face advance and productivity, thus compelling the mine engineer to consider better and more productive ways of mining. Transportation plays a vital role in achieving improved productivity. This paper focuses on horizontal transportation systems. Horizontal transportation is defined from the shaft station area to the end of the stope cross-cut. Traditionally, horizontal transportation is inefficient in comparison to vertical transportation efficiencies and accounts for a high proportion of South African mine accidents. Thus, the role of horizontal transportation has been investigated in detail, as it offers the greatest chance for improvement. The purpose of the paper is to provide a best practice guideline for the design of horizontal underground transport systems. It is intended that the document be used by mine designers and planners as an aide memoir during the design process and benefit may well be gained from retrofit and reorganisation activity. The paper looks at transport systems suitable for deep level gold mining in South Africa and evaluates such items as management, scheduling, and haulage systems. Current transportation systems for personnel, material and rock transportation are evaluated, gaps in technology highlighted, and recommendations made.

Jan 1, 2003

The process of refurbishment is not a precisely defined one. It is under- stood to mean an upgrading of a plant which is normally performed only once. The application of refurbishment in the field of materials hand- ling equipment poses particular problems because complex plants con- sist of individual components having quite different remaining service lives. For this reason, a systematic, proven procedure is proposed for the refurbishment of large materials handling equipment, designed to ensure economic implementation in accordance with the company goals. Rheinbraun2 has been using materials handling equipment since 1900, the largest units today being bucket-wheel excavators with a daily capacity of 240,000 bank cubic metres of overburden and a service weight of up to 13,500 t (metric tons). Since 1975, more than 50 large-scale refurbish- ment projects have been carried out in the company. In the process, refur- bishment has turned out to be the proven alternative to replacement of large materials handling equipment. Rheinbraun Engineering,3 a Rhein- braun subsidiary, carries out planning, consulting, and supervising work in the implementation of refurbishment projects in Germany and abroad. The most recent example is the refurbishment of Dredger 11 of the State Electricity Commission of Victoria in cooperation with Krupp-Australia, Melbourne.

Jan 1, 1989

During October 1947 an Authority to Prospect was granted by the Minister of Mines to lVIount Isa Mines Limited over an area of approximately 75 sq. miles to the north of Mount Isa.Application for the Authority to Prospect had been made after Zinc Corporation Limited had been granted prospecting rights over two areas, one of 1,265 acres immediately to the north of the Mount Isa Mines leases and the other of 1,960 acres adjoining the south end of Mount Isa Mines leases.METHODSAs a means of providing a cheap map of sufficient accuracy on which to plot geological features, both Mount Isa Mines Limited and Zinc Corporation Limited agreed upon aerial photographs and the two companies shared the cost of an aerial photographic survey by Adastra Airways of 130 sq. miles which covered the prospecting areas held by both companies.The photographs were on a scale of 800 ft. to I in. with 60% overlap on the north-south runs and 25% overlap east-west. A set of alternate prints enlarged to 400 ft. to 1 \in. were obtained for field work. The 400 ft. to 1 in. scale unglossed photographs (size 18 in. x 18 in.) were taken On to the field and rock outcrops, and uncorrelated structures were plotted directly on to them in red crayon pencil. The geological observations were then transferred in the office to a tracing on which accuracy of azimuth and scale was controlled by use of a photo mosaic and ground surveys.

Jan 1, 1953

Magnetic Separators have a wide application in dry separation processes, frequently in conjunction with High Tension Separation. Dry processes can frequently be superior to established processes in more commonplace mineral associations. A system of dynamics is postulated and the forces operating ar'e examined, together with a method of evaluating the effect of operating variables. Practical applications of these theories to obtain optimum results on an individual separator, and various separations using a laboratoryroll type separator are described.Practical Flowsheets are of two main types, the first consisting of a series of scalping operations, the second for rougher, cleaner, and scavenger operations with middling recirculation. Some common separation problems with certain mineral associations illustrate the need for different approaches for different mineral associations. A table of mineral separation characteristics is appended, from which amenability may be tentatively estimated.INTRODUCTIONMagnetic separators are widely used, either alone or in conjunction with other wet and dry concentration devices, for the upgrading of a variety of minerals. The high standards of efficiency attainable in dry mills, together with reduced operating and labour costs, are slowly becoming apparent in a wide variety of plants. The combination of wet and dry concentration plant familiar in beach sand mining is finding application for such processes as upgrading a crushed chromite product, and production of clean scheelite,cassiterite, and other concentrates. Other dry beneficiation processes (such as the high tension beneficiation of iron ore, and the benefiGiation of asbestos) avoid the use of wet processes completely.Dry separation processes are likely to be applied more widely as their possibilities become more generally known.

Jan 1, 1958

By Rienks, Wyborn D

The Ravenswood Batholith in the Charters Towers -Ravenswood area of north Queensland, was formed by three main episodes of granitoid emplacement between the Early Ordovician and the Early Permian. Granite to granodiorite plutons of the first phase of intrusions in the Early to Middle Ordovician, probably formed by partial melting of a thin continental crust as a result of the emplacement of mafic material derived from the mantle. Some of this mafic material subsequently intruded the Ordovician granitoids as gabbro to diorite complexes. The early granitoids were deformed and metamorphosed prior to emplacement of second phase granodiorite to tonalite plutons in the Late Silurian to Early Devonian. These later plutons have generally not been deformed or recrystallised. Geochemical and isotopic data suggest the Siluro-Devonian plutonism may have been generated by a partial melting of the tholeiitic material emplaced in the lower crust during the Ordovician. A third intrusive phase consists principally off Late Carboniferous to Early Permian gabbro-granite complexes, high level granite to granodiorite complexes, and rhyolitic plugs and diatremes near the batholith margin. Gold mineralisation in the batholith is associated with two major events: mesothermal vein formation in the Early Devonian and porphyry types in the Late Carboniferous to Early Permian.

Jan 1, 1990

All companies and individuals who embark on a business venture incur costs. For the most part these costs can be conveniently categorised, firstly into capital and operating costs and then into the various elements of these major cost centres. Although the nature of expenditure naturally differs as between industries certain broad cost types are characteristic of all heavy industries. The capital costs of gaining access to an orebody, equipping a new mine, building a treatment plant and perhaps refining and smelting facilities are likened to capital expenditure by a manufacturer on new plant and equipment required for an expansion or new product innovation. Similarly the day to day costs of labour and materials employed in the running of a mining operation can be likened to similar costs in other heavy industry. There is another group of costs that are not so easily categorised. Most industries incur unavoidable costs that do not form part of the direct or capital costs of physical production. These costs include taxes and other payments to government and research expenditure. The mining industry has a particularly heavy burden of non-production costs and it is the objective here to highlight and analyse a few of them. These costs are exploration expenditure, infrastructure expenditure, royalties and income tax. This is not to suggest that these are the only major non-production costs that the mining industry needs to bear. The industry may incur significant costs for environment protection, land tenure maintenance and on liaising with Government on a wide variety of matters. It is for reasons of subject manageability that the list is confined to the four costs mentioned. For the mining industry, exploration and infrastructure expenditure, royalties and income tax have several distinguishing features. Firstly, they are generally proportionately large costs. Exploration and infrastructure expenditure for example, could well exceed mine development costs. Depending on how royalties are levied, they may be very high in relation to profits earned and many in fact exceed profits. Secondly, except for income tax, they are costs that are generally not payable by other industries. Exploration expenditure is in some respects comparable with industrial research and development. However, because mines are wasting assets exploration is necessary for survival, and it is likely to form a larger part of costs per dollar of profits or sales than R&D. It can therefore be said that exploration is of far more significance to the miner than R&D is to the typical industrial company. Furthermore, unlike exploration expenditure, R&D results are transportable and patents permitting, transferable. The infrastructure burden that miners must carry is unique to the industry. Whereas urbanised industry is not usually liable for the capital cost of power, water, transport, townships and community facilities, the miner must finance these projects himself. Neither the payment of royalties, nor of course, income tax are unique to the mining industry. Royalties are more properly described as a unique charge on some primary industries but however described, they are a charge that manufacturing and service industries do not have to pay. Whilst we all pay income tax, the mining industry's uniqueness derives from the special problem that the industry has in arriving at annual net income in view of the capital intensity of the industry, partly due to expenditure on infrastructure, the indefinite life of capital equipment and its unpredictable residual value, funds expended on exploration and long lead times associated with a mine development. The third distinguishing feature of these costs is that, with the possible exception of exploration expenditure, they are heavily influenced by the policies and actions of Government. As such the industry has a responsibility to promote the industry by emphasising its potential to improve national product including exports and by requesting that the Government provide for the industry in its long term planning and seek its co-operation to prevent the industry incurring inequitable penalties relative to other industries.Finally, exploration and infrastructure expenditure are significant because they are front-end charges on a project. When due allowance is given the time value of money and the deferment of income from a mining development to which they relate, exploration and infrastructure expenditure assume greater importance than the raw money expenditure suggests. For all these reasons, exploration and infrastructure expenditure, mining royalties and mining income tax are worthy of detailed study. This is the purpose of this paper. The objective is to examine the determinants that give rise to them and provide some thoughts on their impact on on-going and potential mining developments and, where relevant, to make some suggestions as to how they may be minimised.

Jan 1, 1977

'Industrial Minerals - their mining and use in New Zealand' is the theme of the 1978 Annual Conference of the New Zealand Branch of The Australasian Institute of Mining and Metallurgy. This paper describes the use of phosphate rock, sulphur and potassium chloride (potash) - three industrial minerals which have enabled the farmers of New Zealand to increase production to current levels. The growth of imports of these raw materials for the New Zealand fertiliser industry is well documented in NZ Fertiliser Statistics 1977. This is the most recent of the Ministry of Agriculture and Fisheries annual publications on this Subject prepared from the detailed returns of fertiliser manufacture and sales from each fertiliser works. There are now 12 of these works in New Zealand one of the most recently established being in Whangarie where this conference is being held. Its capacity to manufacture superphosphate will shortly be 300 000 tonnes twice that when it opened late in 1964. New grinding and manufacturing equipment comes on stream early in 1979. This paper illustrates the interdependence of two primary industries, agriculture and mining. New Zealand's economy in the foreseeable future will be based on agriculture so that our standard of living is dependent on the overseas prices and freight costs of the bulk raw materials from which our fertilisers are made. For the year ended 31 March 1978 New Zealand's total exports were $3395 million, of this total $2413 million (71%) came from the products of pastoral agriculture (wheat, wool, dairy and other animal products), $291 million from forest products and $501 (15%) from manufactured exports. Approximately half of the pastoral receipts can be attributed to the fertilisers applied at a total cost of about $200 million including subsidy.

Jan 1, 1978

Scale build-up in titanium palladium alloy spent electrolyte heat exchangers in the residue treatment plant commissioned at Risdon, Tasmania in 1971 was shown to be a mixture of manganese dioxide and anhydrite (CaSO4). The manganese dioxide was deposited as a result of thermal decomposition of permanganate ions present in the spent electrolyte. It was shown that deposition of manganese dioxide and associated anhydrite scale could be prevented by prior reduction of permanganate ions to the manganous (Mn++) state by the addition of ferrous ions. In the plant this was conveniently accomplished by injecting into the inlet line to the heat exchangers sufficient zinc plant solution containing ferrous sulfate to decolourise the spent electrolyte. This action prevented deposition of such scale for another 21 years, until the heaters were finally decommissioned in March 1992. Measurements indicated that addition of the reducing solution lowered the anodic potential of the titanium alloy by 200 - 300 mV (depending on the solution resistance), but that it was still +300 to 400 mV with respect to a standard calomel electrode. It was shown that, if necessary, a small impressed current could be applied to provide anodic protection. Before scale deposition was overcome by the addition of ferrous sulfate solution, badly scaled heat exchangers were cleaned by recirculating a solution of hydrogen peroxide in spent electrolyte or dilute aqueous sulfuric acid, after laboratory testing of a variety of possible solvents for the scale. Corrosion tests indicated that attack on the titanium alloy by the acidic peroxide cleaning solution was insignificant.

Jan 1, 2005