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By Luis Felipe Morán G.

El objeto del presente texto busca difundir una manera de standarización en la formación técnica de los carbones peruanos, basándose en la standarización y desarrollo del mercado para antracita en Pensylvania. Asimismo se sugiere la introducción del sistema ASTM para de esa forma tener datos comparativos, con otros carbones en un sistema de difusión y aceptación. Para la utilización del carbón en el Perú y el extranjero, se requiere de un estudio que describa sus características físicas y químicas según el usuario y mercado, y siguiendo las pautas en que otros carbones fueron estudiados en las naciones industriales. En este sentido, los carbones más usados por los usuarios son las antracitas, cuya composición (volatibilidad, lustre, fiabilidad, facilidad de molienda), es similar a las de Pensylvania. De otro lado, no se encontraron estudios anteriores sobre las propiedades de carbón en aquellos yacimientos en exploración y reserva potenciales, excepto en las minas de actual explotación. Entre las propiedades del carbón está la volatiblidad, humedad, poder calorífico y ablandamiento de cenizas, mientras que la clasificación americana de la andracita debe basarse en el contenido de materia combustible y no por tamaños. En consecuencia, es necesario elaborar las pautas de conocimiento(características) sobre el carbón peruano, de forma que sirva de guía futura para el comprador y diseñador a nivel nacional.

Jul 20, 1959

By Robinson WB

An accurate and rapid assessment of coal resources, such as that provided by computer modelling, forms an intergral role in evaluating CSR's coal deposits for future development. An in-house system utilising a number of geological, engineering, costing and financial evaluation routines has been developed for DEC VAX computers. The system is currently being upgraded and enhanced to meet the demands at the various mine sites. Computer modelling of the geology is performed on encoded drillhole information and coal core chemical and physical analyses. A conceptual mine plan is formulated then digitized and superimposed on the geological model. Insitu and product coal reserves and qualities as well as overburden and parting quantities are then calculated for each strip or block. These strip parameters are then transferred to the mine scheduling routines to determine the most efficient mining sequence for the mine plan. Cost factors and scheduling data for equipment specified in the conceptual mine plan are used in the mine costing subsystem. The financial subsystem then evaluates the likely return on investment. Future enhancements to the system include improvements in the response time through the introduction of interactive graphics, the direct interfacing of geophysical and analytical data, and further development of a geotechnical'database.

Jan 1, 1983

By Boyes B. A, Haydon D. J

The Paddington project is a gold mining and processing operation located 35 km north of Kalgoorlie in the Eastern Goldfields region of Western Australia (Figure 1). The project, which is operated by Pancontinental Goldmining Areas Pty Ltd, treats 1.25 Mtpa of oxidised gold ore, derived mainly from open cuts adjacent to the plant, with minor tonnages from other pits in the region treated on a custom-milling basis. Gold is recovered using a conventional CIL process. The process raw water supply of 3 500 kUd is derived from the local groundwater system. Average salinity of the raw water is around 90 000 - 100 000 mg/L total dissolved solids. A small portion of the raw water is passed through a vacuum distillation desalination plant to produce the project's 200 kUd requirement for high quality water for potable use and gold recovery.

Jan 1, 1988

By Yuzura Sato

Viscosity has been measured for various molten binary alloys of nickel with iron, cobalt and chromium in order to clarify the behavior of viscous flow of molten nickel alloys. The entire concentration range for iron and cobalt and 0-67at% of chromium content were studied. The measurement method was an oscillating cup viscometry using an alumina crucible that was precisely machined. The temperature was up to about I 880K for all the measurements. The results represented good Arrhenian relationship although some measurements included overcooled temperatures. The isothermal viscosities increased monotonously with an addition of iron and chromium into nickel. The addition of cobalt increased after stationariness. The isothermal viscosities showed concave curves. Activation energies increased monotonously by adding all the elements into nickel. These phenomena were considered to be related to the thermodynamic properties 'such as the heat of mixing and the structures of mixture melts.

Jan 1, 2003

ALABAMA Altoona -Cain, J Anniston-Cowie, L K Hermrod, A A White, H E Bessemer -Abbott, C E Ball, E M Mitchell, F R Thompson, N E Birmingham -Adler, J E Aldrich, T H Aldrich, T H, Jr Blackburn, A R Bush, M W Clark, G H Cowrn, P G Crane, W R Crawford, G G Crockard. F H

Jan 1, 1923

By Drury SA, Williams RD, Nind DC

The Airborne Thematic Mapper is an eleven channel digital scanner which acquires image data in the visible, near infra-red, short wave infra-red and thermal infra-red wave- lengths. A description of the system is presented which includes details of the operating wavelengths and performance parameters of the scanner. Consideration is also given to the aircraft installation requirements. During January 1984 the scanner surveyed the mineral rich areas of Leonora, Laverton and Kalgoorlie in Western Australia. This is a region of intense exploration activity for gold and base metals. Some 30,000 square kilometres were systematically surveyed in a period of ten days. This scanner was flown at 7,000 metres altitude giving a ground pixel size of 17.5 by 17.5 metres. The flight line spacing was 8 kilometres. The overall project took some thirty days from conception to completion. The planning and execution of this operation are described in detail. The resulting magnetic tapes provided 11 channels of digital image data over a 30,000 square kilometre area and a variety of image processing techniques were employed in order to capitalise fully on the results. The imagery provides a powerful tool for the geological mapping of the terrain. The data can also be used to monitor the environmental effects of mining operations.

Jan 1, 1986

By D. N. Collins

A sampling program was conducted in which both spoon and isokinetic sampling techniques were used to collect samples from the reaction shaft. The samples were then characterised by chemical, XRD and mineralogical analysis. Further information was acquired by measuring the oxygen potential and temperature at the bottom of the shaft using disposable probes. Comparison of the results of the two sampling methods showed that the spoon samples were devoid of material less than 25 m. Sulfur analyses on the samples provided information on the extent of reaction, plume shape and recirculation patterns. Disposable probe measurements showed the measurable particle temperatures ranged from 1150 to 1700 °C and that the material falling into the bath had a normalised oxygen potential similar to the slag. These latter measurements combined with the sulphur elimination and mineralogical analyses provided further information on the extent of reaction and enabled the reaction sequence to be ascertained.

Jan 1, 1999

By Jacques Steininger, Robert E. England

Single crystals of ZnTe and ZnTe1-,Sex with x up to 0.13 have been grown from the elements by temperature gradient solution zoning using excess tellurium as a solvent. Best results have been obtained with charges with the compositions 45/55 at. pct Zn, Te, for ZnTe and increasing amounts of selenium for ZnTe1-xSex. The temperature in the molten zone was maintained at about 1070°C with a gradient of about 10°C per cm. Chemical analyses of quenched ZnTe ingots show tellurium concentrations in the molten zone as high as 70 pct with concentration differences across the zone of 1 to 2 at. pct Dark dots which are observed by transmitted light microscopy in as-grown crystals can be removed by annealing in zinc vapor at 900 C. INTEREST in wide band gap semiconductors has led to a new study of ZnTe and ZnTel-xSex crystal growth. ZnTe is the only II-VI compound with a wide band gap (2.3 ev) that can be made p type with low resistivity. Attempts to make it n type with low enough resistivity to be useful for p-n junctions have so far been unsuccessful.1 ZnSe has a band gap of 2.65 ev but can be made n type only. However, ZnTel-xSex solid solutions with x as low as 0.36 have been made both highly n and p type2 with a minimum band gap around 2.12 ev3 at room temperature and appear to hold the best promise for efficient injection electroluminescence in the visible. ZnTe has the lowest melting point of the zinc chal-cogenides (1295°C) and consequently attempts have been made to grow crystals from both the liquid and the vapor phase.4 Complicated apparatus is required for growth from stoichiometric melts because of the high vapor pressures of the elements at the melting point of ZnTe and because of the problem of quartz devitrification. Small crystals have thus been grown in high-pressure equipment by Fischer5 and by Narita et a1.6 with pressures of the order of 50 atm of argon to prevent excessive evaporation from the melt. Large crystals of ZnTe can be obtained by growth from the vapor phase4 but they often present numerous dislocations and inclusions. An improvement in the quality of vapor- grown ZnTe crystals was reported by Albers and Aten7 by equilibration of mixtures of small crystals with compositions lying on either side of the solid single-phase field at fixed temperature. The same technique was later applied by Aten8 to the growth of ZnTe1-xSex crystals with less than 1 pct inhomo-geneity. Because of the higher liquidus temperatures of the solid solutions and the high vapor pressure of selenium, previous attempts to grow ZnTel-xSex from the melt have been limited and unsuccessful.9 The phase diagram of the Zn- Te system is reproduced in Fig. 1, based on data from Kobayashi10 and Kulwicki.11 Carides and Fishher12 have reported lower liquidus temperatures on the tellurium-rich side, but their data would require confirmation. The liquidus temperature on the tellurium-rich side decreases rapidly with increasing tellurium concentration and the Te2 vapor pressure over the liquidus also decreases accordingly.'3 The decrease in liquidus temperature and vapor pressure therefore makes it possible to use conventional apparatus if there is a sufficient excess of tellurium in the melt. Single crystals of ZnTe have thus been grown by Kucza,14 in a modified Bridgman technique, from solutions containing up to 60 at. pct of Te by lowering unsupported quartz ampoules through a temperature gradient at about 1200°C. Under these conditions, the phase diagram indicates that the entire charge is initially molten. Crystal growth can therefore proceed by normal freezing and rejection of excess tellurium into the melt. The modified Bridgman technique has several major limitations. Because of the rejection of excess tellurium into the melt during freezing, the melt composition and the temperature at the growth interface vary continuously. They tend to follow the liquidus until the eutectic which is very close to pure tellurium (447°C, >99 pct Te). Since the solidus composition also varies with temperature,15 crystals grown by this method are inhomogeneous. They present small variations from stoichiometry which may affect their structure and physical properties. The simultaneous increase in tellurium content and decrease in melt temperature also combine to reduce the rate of diffusion of tellurium away from the growth interface, thereby causing constitutional supercooling and possibly dendritic growth. To minimize these effects, the initial melt composition is in practice kept relatively close to stoichiometry (less than 60 pct Te). This however limits the possibilities of operating at low temperatures and pressures. This paper describes a modified method of crystal growth by temperature gradient solution zoning (TGSZ) which is an adaptation of the temperature gradient zone-melting technique developed by pfann16 and of the traveling solvent method of Mlavsky and weinstein.I7 The TGSZ method now applied to the growth of ZnTe and ZnTel-xSex crystals is characterized by its very simple experimental arrangement and sample preparation technique. Unlike the modified Bridgman technique, there is no increase in the tellurium concentration in the melt and therefore it is possible to operate at lower temperatures and pressures. This method is also suitable for maintaining a constant temperature at the growth interface.

Jan 1, 1969

By Walter E. Dean

Deep-sea manganese nodules are considered to be potential ores of manganese, nickel, cobalt, and copper. Considerable time, effort, and funds have been applied to the study of Se distribution of nodules on the sea floor and the location of economically important areas, but little effort has been spent in understanding the origin of nodules. Most theories that have been proposed to explain the origin of manganese nodules have been based on inorganic physicochemical processes. It is not by coincidence, however, that the area considered to be most economically feasible is in the zone of high biological productivity in the eastern equatorial Pacific Ocean and underlain by siliceous biogenic sediment. The genesis of manganese nodules and the concentration of many trace elements are intimately associated with biological processes.

Jan 1, 1982

By Elliott J. Roberts

In spite of the fact that the percentage of true colloids in an ore grind is very small,' these pulps exhibit many of the properties of true colloidal suspensions. A quartz particle, appreciably finer than 10 microns in diameter, has a settling rate so low that at a dilution of 5:l or over, the capacity of a settling tank to settle such particles would be uneconomical if the individual particle rate prevailed. However, by grouping the finer particles into aggregates or flocs, the settling rate can be increased to an economical value. The colloidal chemistry of pulp thickening is thus chiefly concerned with particles having diameters of between 1 and 10 microns, although particles as coarse as 40 microns in diameter are more or less involved. These particles must be associated in such a manner that they settle at an economical rate and give a clear, supernatant liquid or overflow. The treatment of the subject may be divided into three phases, cach phase having a more or less different colloidal aspect. The first phase is the problem of getting the pulp or suspension into the proper condition of flocculence; the second is the behavior of the flocculent pulp in its initial and intermediate stages of settling; the third is the behavior of the flocs in the find period of settling or thickening stage. Let us look first into the methods and mechanism of obtaining the flocs and then consider their behavior and properties. Flocculation Colloids are merely ordinary substances reduced to a very small particle size, the upper limit being placed by definition at 1 micron (0.001 mm.) diameter by the soil chemists and at from 0.2 to 0.1 micron by various other colloid chemists. The lower limit is reached only when the particles approach molecular dimensions. The term L'colloid" should not necessarily imply lack of crystallinity. Particles as small as 0.01 to 0.02 micron give perfect X-ray patterns, while with 0.005 micron particles the bands on the powder photograph are merely broaderled and diffused.2

Jan 1, 1935

By E. E. Caba

Copper smelter flue dusts containing arsenic are hazardous materials requiring environmentally accept-able disposal, preferably with re-source recovery under the RCRA and CRCLA regulations. However, the known resource recovery processes entail capital and operating costs greater than can be justified by the revenue of the recovered metal. Consequently, the smelting industry is tending to forego resource recovery in favor of encapsulation and storage in a certified class I hazardous waste site, or in a dedicated facility located at the source Superfund site. Order of magnitude costs for this option with portland cement encapsulation are estimated at $100 per ton, not including transportation. Industrial adoption of a new resource recovery process re-quires that its cost, including capital amortization, exceed the cost of encapsulation and storage only by the amount of the offsetting revenue from sale of metal. The lime-roast/ammoniacal leaching process is expected to meet this goal.

Jan 1, 1992

ALABAMA Aldrich -Thomas, D A Altoona -Cain, J Anmston-Cowie, L K Walmsley, W N White, H E Bankhead -Terentieff, V E Bessemer -Abbott, C E Ball, E M McKenzie, W C, Jr Mitchell, F R Morgan, C Thompson, N E Birmingham -Adams, J H Adler, J E Aldrich, T H Aldrich, T H , Jr

Jan 1, 1923

By G. L. Hopps

Various chemicals, including compounds of copper and lead, were added to a mixture of No. 2 and No. 6 fuel oils that was fired in an experimental furnace. Tests were made to determine (1) the effectiveness of these chemicals in removing soot deposits on probes devised to simulate heat-transfer surfaces in boilers and (2) the effectiveness of the chemicals in preventing the deposition of soot on the probe surface. Test conditions were regulated so that the temperature of the products of combustion adjacent to the probes was in the range of 625° to 700° F. The clean-metal temperatures of the air-cooled probes were comparable with the water-tube temperatures in boilers operated at 40 to 100 p.s,i.g. The dosages of the fuel oil additives used in these tests were generally larger than those usually recommended for most proprietary compounds.

Jan 1, 1962

By F. X. Ferney

The centrifuge which will be reviewed in this dis¬cussion is the continuous solid bowl typo. As there are presently approximately 2000 of these units operating in our country, and about 200 of these in use in the coal industry, I expect that most of you are acquainted with its operating principle. How¬ever, for those who are not familiar with the machine a brief introduction is in order. The continuous solid bowl centrifuge was first successfully marketed, worldwide by the Bird machine Company in 1934. The successful development of this unit was based primarily on the invention of a drive mechanism to properly control the differential speed between the two rotating elements. This centrifuge was introduced into the coal industry immediately following the second World War. Today there are five or six additional firms' selling this machine in our country, and approximately twenty others in Europe, England and Japan.

Jan 1, 1965

By Wang Haibei

China is the important country in terms of Ga, Ge reserves and products. These elements usually associate with lead and zinc ores such as in Fankou, Dachang and Lanping mines. Until now these metals could not be extracted from zinc residues effectively. The main reason is that it is difficult to separate zinc and iron. BGRIMM has carried out considerable research on this subject and some hydrometallurgical processes were developed. Zinc residues were pressure leached with a reducing agent such as zinc concentrates or SO2 at 110~130C. The final concentrate of H2SO4 was 30~50g/L. The metals such as Zn, Fe, Ga and Ge were dissolved into solution. In the leaching residue Pb and Ag could reach 20% and 2000g/t. The feed of solvent extraction was prepared from the leaching solution by pre-neutralization ? precipitation of Ga, Ge and acid dissolving. Then Ga and Ge were extracted by solvent extraction through P204 and G315 produced by BGRIMM. After stripping, metallic Ga was produced by electrowinning. GeO2 was produced by precipitation. The iron in raffinate was removed by the hematite process. The solution after removal of iron came back at the zinc neutral leaching stage. In 2003-2004, pilot tests were finished in BGRIMM in cooperation with Fankou Lead and Zinc Mine Ltd. And the extraction rate of Ga and Ge in the leaching stage was 94% and 83% respectively. The total recovery rate was 90% and 80%. It is estimated that the technology has a wide commercial use in the coming five years.

Jan 1, 2006

By G. G. Oberfell

THOUGH the largest volume use of natural gas has been, is. and in all probability will continue to be as a fuel for domestic and industrial heating, it has various market outlets, both as a fuel and as a raw material for the chemical industry. Natural gas is a preferred type of fuel where ease of control, fuel uniformity, and freedom from ash are of primary importance. Other industrially important uses are as a source of carbon black and as a fuel in various low-cost heating operations. Many other uses are of varying importance and new potential uses are continually being uncovered, some being of economic importance to the gas indus¬try as a whole, but most of them involve such small volumes of gas that they are only of passing interest. Since various products extracted from natural gas and recovered as by-products from petroleum refining, such as liquefied petroleum gas and fuel oil, are being utilized in many industrial and domestic heating applications, some consideration will have to be given such materials in order to present a reasonably complete story of the importance of natural gas. Some of these materials may prove to be transient competitors and will not be available when more profitable uses are found for them. Meanwhile, however, the potential volumes of such materials available, the current volumes being marketed, and the nature of the utilization are considered as constituting an essential part of the over-all fuel picture.

Jan 1, 1946

By Richard E. Barrett

SOME YEARS AGO I was associated with a mining operation which, because of its isolated location, burned wood for heating purposes. Year after year the tractors and tucks hauled the cordwood in from the edge of the ever-growing clearing. Each year the cartage costs became greater. The degree to which transportation distances affect the economics of fuels obviously varies with many factors, but the main criterion is the amount of heat a unit weight of the fuel will produce. For in-stance, wood is limited in most cases to a haulage distance of a few miles. Coal can be shipped hundreds of miles, whereas petroleum and gas ?can be transported thousands of miles. The world is now on the brink of having a new fuel -uranium. It has the virtue of being so concentrated that transportation costs can, for all practical purposes, be disregarded.

Jan 1, 1958

This Bureau of Mines report summarizes the research, development, and evaluation demonstrations conducted by the Bureau of Mines under the Health and Safety Act of 1969 to improve the means of notifying miners underground, who are away from their own phone, that they are being called.

Jan 1, 1977

By John Demol

Monazite, a rare earth and thorium phosphate mineral, is one of the major minerals processed for extraction of rare earths. Industry practice for treating monazite concentrates is to use either a sulfuric acid bake or caustic conversion route. In the sulfuric acid bake, monazite concentrate is mixed with concentrated sulfuric acid and roasted. The rare earth phosphate mineral is converted to rare earth sulfate which dissolves in a subsequent water leach. As the bake temperature increases above 300 °C, thorium becomes less soluble. Although acid baking is practised in industry, the bake reactions are not well understood. A combination of chemical analysis, XRD and SEM-EDS was used to identify reaction processes occurring during sulfuric acid baking of a 93 wt% monazite concentrate between 200 °C and 800 °C. The effects of these reactions on the leachability of the rare earths, thorium and phosphate were also examined.

By John A. Wolfe

The concepts of sea floor spreading and plate tectonics provide more logical explanations of some geologic processes than were possible a few years ago. I plan to premise my discussion of the regional features of Philippine porphyry copper deposits on this tectonic basis, recognizing that parts of the picture can be explained in other ways, but in the belief that this is the best explanation of the whole. The sequence of events which results in the formation of Porphyry deposits (Figure 1) can be summarized as the result of collision of crustal plates, subduction of the oceanic plate, emplacement of a serpentine ultrabasic diapir, formation of a dioritic magma at depths of 300 to 500 km, rise of the magma to a sub crustal or intra-crustal chamber, eruption of andesitic volcanoes, emplacement of diorite or differentiation of the magma into more acidic products, multiple intrusion of hypabyssal rocks and hydro-

Jan 1, 1973