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By J. J. Gilman, T. A. Read

S URFACE effects in the cleavage of brittle crystals have been known for some oftime,1, 2 but our knowledge of surface effects in the plastic deformation of crystals is of relatively recent origin. In 1936, Roscoe9 eported his observations comparing oxidized and clean cadmium crystals. He found that cadmium crystals 1/2 mm in diam when covered by an oxide film less than 1200 atoms thick had critical shear stresses about twice those for clean crystals. This effect is anomalous in that it cannot be caused by the inherent shear strength of a normal oxide film. Either an interaction between the film and the crystal causes the large increase in strength, or the oxide film has an abnormal mechanical strength. Several authors since Roscoe have studied surface effects in crystal plasticity. A complete review of the literature will not be presented, but most of the results may be summarized as follows: 1—The critical shear stress for slip is increased markedly by very thin oxide films on zinc4 and cadmium crystals;" ' also, the entire stress-strain curve is raised by an oxide coating;3,4 both effects increase with decreasing specimen radius. 2—Surface active substances such as oleic acid destroy the hardening effect of oxide films.4, 6-8 The time required for the reduction of the hardening effect to begin increases with the viscosity of the solvent4~ 3—There has been dispute in recent years about the effects of surface active substances themselves on plastic deformation. Rehbinder, Lichtmann, and Maslenikov9 state that surface active substances reduce the strength of metal monocrystals markedly and increase the number of slip lines per unit length at a given strain. The effect varies with orientation for tin crystals being smallest for x, = 0, largest for x, = 45", and intermediate as x, + 90°.10 Several workers claim to have disproved the results of Rehbinder')"." but Rehbinder and Lichtmann9 have defended themselves and Masing with his collaborators" has confirmed some of Rehbinder's results. 4—Immersion of metal specimens in electrolytes such as sodium chloride reduces their strength12,13' and subsequent cathodic polarization increases the strength reduction. For noble metals, the strength reduction occurs for both anodic and cathodic polarization," increasing with increasing polarizing voltage. 5—Electroplated copper coatings effect the creep rates of zinc monocrystals. Poly crystals are not affected." 6—Immersion in dilute acid destroys the hardening effect of an hydroxide film. When an acid solution is applied to a steadily creeping crystal, the creep rate jumps to a very high value and then drops gradually to a steady value which is higher than the initial steady rate.*' " If the hydroxide film to be removed is very thin (about 100A thick), the creep rate does not change measurably, but a small rapid strain-increment is observed when dilute acid is applied." 7—Crystal plasticity depends on specimen dimensions. This was observed by Lichtmann and Ven-stroml" for monocrystalline tin and by Andrade and Kennedy" for polycrystalline lead. 8—Immerson of copper crystals in mercury has no effect on their stress-strain curves.'" 9—Bombardment of creeping cadmium crystals with a particles which penetrate the surface to only 0.005 mm may increase their creep rates as much as five times.''' The experiments which will be described in this paper pertain to: (a) the effect of a crystal's shape on its plastic deformation, and (b) the effect of metallic surface films on plastic deformation. For the work pertaining to (a), crystals of zinc, tin, and lead were grown which had various shapes. These were tested in simple tension. Macroscopic rotations about the tension axis which are unpredicted by the classical theory of slip were observed, and serrated edges were observed in tin crystals. For the work pertaining to (b), the effects of evaporated and electrodeposited films of copper, nickel, gold, and zinc on the mechanical properties of zinc, tin, and lead crystals were determined. The films influenced both slip and twinning of the crystals in creep and tensile tests. Experimental Details Chemically pure zinc, tin, and lead were used in this investigation. The zinc was 99.999t pct pure;

Jan 1, 1953

By L. J. Prosser, A. T. Iannacchione

From 1991 through 1995, 44 miners out of a total workforce of less than 2,000 were fatally injured in the stone industry. Of these, 12 occurred at underground mining operations with nine deaths resulting from roof or rib falls. A safer environment can be achieved by evaluating the nature of the hazardous ground and by developing more efficient and effective ground-control strategies Roof and rib conditions were observed and assessed in 33 underground stone mines in Illinois, Indiana, Kentucky, Maryland, Missouri, Pennsylvania and West Virginia (Fig. 1). Hazard assessment indicated that the ground failures that occurred under moderate to substantial overburden. i.e., >30 at (100 ft), were caused by stress concentrations and geologic strictures. Ground failures near the surface are caused by solution (water) processes. Selection of the mining horizon and mine-layout decisions tremendously influence ground stability.

By S. Di Muzio

Sulphate Reducing Bacteria (SRB) are hetero-trophic anaerobic micro-organisms that can be used to remove sulphates and heavy metals from Acid Mine Drainage (AMD), heavy metal-bearing streams with high iron and sulphate contents and low pH, generated by sulphur bio-oxidation in abandoned mine districts. After the preliminary chemical precipitation of iron with carbonate stones (I step, chemical precipitation) SRB can be used to reduce sulphates to sulphurs then favouring heavy metal removal as sulphur precipitates (II step, biologically mediated precipitation). In this work the experimental results of heavy metal and sulphate removal from column tests were reported. Sulphate and heavy metal abatement in fixed bed column was performed using chemically pre-treated samples of synthetic AMD. Attenuation of toxic effects of treated samples was also ascertained by toxicological tests of germination and radical growth with Lepidium sativum.

Jan 1, 2006

By Ralph B. Stevens

The objective of this 20-month program was to define the relationships between mine ventilation, temperature, humidity, ore properties, material's used in mine operations, etc., and the spontaneous combustion problem in underground metal mines. Tradeoff studies of availability, reliability, cost, and maintenance of spontaneous combustion protection sensors and telemetry were conducted, after which a prototype system was selected from four design alternatives. This selected system was then laboratory tested and demonstrated in an underground copper mine.

Jan 1, 1979

By Harry Wolf

The chemistry of the element uranium enables industry to employ either an acid or alkaline carbonate leach solution for most uranium ores. Either method my be used for conventional, in-situ, or heap leaching. Uranium recovery in the leaching process depends both on the solubility of the uranium minerals and, on the access of the leach reagent to them. The uranium leaching rate is proportional to the liberated mineral surface area and the chemical reactions involved in the dissolution step. The dissolution of U(VI) and the oxidation of u(IV) to U(VI) are the basic chemical reactions in the leaching process. The active surface area is a function of the effective porosity and the particle size of the ore (1). Ore pieces, with a high porosity and high permeability, may provide a large active surface area even in coarser fractions. This type of ore might be suitable for heap or in-situ leaching techniques. Nonporous and impervious ores are usually more amenable to conventional milling where the active mineral surface is exposed by grinding the ore down to the liberation size of the mineral.

Jan 1, 1981

By A. D. McMahon

This survey is one of a series of Bureau of Mines publications designed to serve the needs of Government and industry for comprehensive information on mineral commodities and activities. Copper, a versatile metal, has been vital to all civilizations from pre-historic times to the present. Its essential value in antiquity and until the nineteenth century arose from its malleability and ease of working, its corrosion resistance and durability, its attractive colors in alloyed and unalloyed forms, and, of course, its availability. The principal uses were for tools, utensils, vessels, weapons, pipe, statuary and other objects of art, and for building and architectural purposes where formability, permanence, and beauty were necessary qualities. Utilization of copper based on these physical and mechanical properties has grown tremendously for commercial, structural, mechanical, architectural, and art items; and its capacity for forming numerous alloys has led to a myriad of applications from miniature copper and brass eyelets to huge bronze battleship propellers. The early nineteenth century marks the epoch of the greatest use of copper, transmitting electrical energy. This particular property of copper is fundamental to the spectacular growth of the electrical industry and all associated industries relying on electricity for power, light, and heat. More than half of all copper produced is used for transmission of electricity.

Jan 1, 1964

To explain in any depth the industrial relations of Broken Hill I believe that it is necessary to trace some of the many happenings that created the present industrial climate. While appreciating that our relations with the local industry are relatively good, it must be pointed out that to preserve and improve this present situation a duty is owed to everyone connected with the industry (workers, share- holders, etc.) by management and unions to see that just and reasonable agreements are found for any disputes. If the companies ever take the local position for granted it would soon die, killed by someone who may get some short term benefit, but who would lose something of incalculable worth in the long run. Similar- ly if the unions were to adopt some of the "wild cat" methods adopted in other parts of

Jan 1, 1975

By J. M. Avasthi

Gulf Research & Development Company conducted the nation's first underground coal gasification test in steeply dipping beds near Rawlins, Wyoming. The geotechnical considerations played a major role in the initial site selection. The test plan included a detailed geotechnical program for site evaluation, test design, permitting, and environmental studies before the burn. During burn, the geotechnical activity continued in the form of monitoring surface subsidence and acoustic emission. The postburn evaluation included studies of the drill cores obtained from the burn zone and effects on the surrounding rock mass.

Jan 1, 1981

By Gunther Schimmel

Ag exudation in four different alloys (Ag-Cd, Ag-Sn, Ag-Sn-In and Ag-Zn) is characterized. The amount of exuded material is correlated with the volume increase due to oxide formation in dependence of the alloy concentration and different densities of the oxide and matrix phases. It is shown that all four alloys show similar amounts of volume increases, but different amounts of exuded material. It is concluded that internal stresses due to the volume increase cannot be the dominant driving force for Ag exudation. A gradient in the chemical potential of Ag that originates from the O concentration gradient inherent to internal oxidation is suggested as driving force. The exudation behavior is thus governed by the variation of the activity of Ag in the Ag fcc phase in the Ag-Me-O system that differs between the alloying systems.

Jan 1, 2010

This paper is a summary of the general theory of sampling published by the author in 1975. Sampling is a random process and its the- ory is a study of the, numerous errors liable to take place in the course of its realization. A complete sampling scheme is a sequence of sampling (proper) and preparation stages . At each stage, the total error ET is the sum of : -.Sampling errors EE arising from the selection process itself. -Preparation errors EZ arising from the operations (crushing, transfer...) sup- ported by the sampled material. ET a EE + EZ . At each sampling stage, the (total) sampling error EE is the sum of seven inde- pendent errors : - Weighting error ED resulting from the non-uniformity of the density or rate-of-flow of the sampled material. - Integration error EI1 resulting from the long-range distribution heterogeneity of the sampled material. - Periodicity error EI3 resulting even- tually from periodic quality variations of the sampled material.

Jan 1, 1976

By Filippo Vallianatos, Michael Verigakis, Vasili Saltas, Kosta Kaklis, Stelio Mavrigiannakis, Zach Agioutantis

"Development of failure in brittle materials is associated with microcracks, which release energy in the form of elastic waves called acoustic emissions. This paper presents results from acoustic emission measurements obtained during three-point bending tests on Nestos marble under laboratory conditions. Acoustic emission activity was monitored using piezoelectric acoustic emission sensors, and the potential for accurate prediction of rock damage based on acoustic emission data was investigated. Damage localization determined based on acoustic emissions evident in the critically stressed region in the form of scattered events or stresses below and close to the strength of the material.IntroductionNon-destructive testing (NDT) has gained popularity in recent years due to commonly available sensors, devices and software tools. Although the majority of such testing still occurs under laboratory conditions, the ultimate goal is a direct field application, especially in the case of underground mining. NDT, if properly applied, may be used to directly provide material property values and characteristics that can be used to determine rock mass or soil mass behavior, with a direct impact to mine design (Iannacchione et al., 2003).AE is generally defined as the high-frequency transient elastic waves originating from the sudden release of energy at localized points within a loaded material (Nomikos et al., 2010). The field of Acoustic Emissions (AE) due to compressive, tensile or other types of loads is a promising research area due to its wide application. The accurate identification of failure precursors stemming from AE is still an open research topic (Lei et al., 2004).Rock is a typically inhomogeneous and anisotropic material that contains several natural defects with various scales such as grain boundaries, microcracks, pores and joint inclusions (Jing, 2003; Read, 2004). Damage induced by microcracks is an essential mechanism in many brittle rocks subjected to stresses. An applied stress induces microcrack growth and damage is distributed uniformly throughout the sample. Finally, the microcracks coalesce and the damage is localized to a shear band, leading to strain softening and macro-scoping failure (Dragon et al, 2000)."

Jan 1, 2015

By Roger G. Rowe

The Crandon deposit, located in northern Wisconsin, is a 65.8 million ton Precambrian volcanogenic massive sulfide deposit which averages 1.4% copper and 5.8% zinc. The deposit is classic in origin, mineralogy and shape. Comprehensive understanding of the geology of both the deposit and the project site has been fundamental to the credibility and success of Project feasibility studies and regulatory permit preparation. Mine development in the current investment and regulatory climate requires thorough and timely application of geologic tools. From 1977-1980 geologic activities were focused on the typical objectives of orebody delineation, reserve estimation, depositional geology, and general site investigation. Results from these programs formed the basis for the Project's preliminary feasibility studies. Since 1981 further geologic investigations have provided criteria for project design, site management, and operational permitting. Activities have included mine entry position definition drilling, developing geostatistical reserve modeling, large diameter (150 mm) core drilling for mill pilot samples, rock mecha¬nics testing, and evaluation of the glacial overburden/deposit geohydrology for computer simulation.

Jan 1, 1983

By Michael J. Pyrcz, Clayton V. Deutsch

Strategic project decisions are based on the distributions global variables, for example, total mineable resource, or recoverable oil volume. These global variables distributions are very sensitive to the input one point statistic, that is, histogram and rock type proportions. Representivity in the one point statistic retains significance in all spatial models. Spatial sampling bias and nonrepresentative sampling complicate this process of building representative one point statistics. This work outlines the cause of bias, the inability of standard declustering to correct for this bias and two methods for correcting bias in the one point statistics: "trend modeling for debiasing" and "debiasing by qualitative data". An example is presented of each technique based on a poly metallic data set.

Jan 1, 2002

By Edward R. Bingham, John R. Suffron

A comprehensive program to rehabilitate waste disposal areas is in progress at the integrated primary copper production facility at White Pine, Michigan. The various aspects of the program are described, including cooperative studies with State and Federal agencies in revegetating efforts and wildlife management and also waste disposal practices as they relate to reclamation planning.

Jan 1, 1976

By James M. Barker

No commodity agreements now exist for sulfur and a lack of reference to sulfur commodity agreements exists in the literature. Law (1975) made a passing reference to sulfur as one of a group of commodities where "there have been additional control efforts of various types." Clearly, sulfur was a candidate, at least conceptually in the past, for some form of commodity agreement and the following discussion centers on the world sulfur market of the early 1980's in this context. GENERAL THEORY OF COMMODITY AGREEMENTS The upsurge in demands for commodity agreements seen in the last decade or so stems largely from agitation by the less developed countries (LDC) for better economic treatment by more developed countries (MDC). Several economic factors, real or imagined, adversely affect the LDC's as follows (MacAvoy, 1977): 1) variable demand in MDC's causes wide fluctuations in commodity prices which hurt the economies of commodity producers, who are often LDC's although consumer economies may also benefit from more predictable prices; 2) a general decline of commodity prices relative to the price of manufactured goods which hurts commodity producers in their balance of trade while their stocks and overcapacity rise; 3) instability of LDC economies enhanced by the above factors lowers internal stability, inhibits foreign investment, and retards economic growth; and 4) a lack of self respect when dealing with developed countries o, following the OPEC lead, LDC producers want the stature related to cartel market power.

Jan 1, 1985

By Satish R. Kate

Explosive is a chemical energy, which on detonation is released instantaneously with extremely high speed and under high pressure. It is used to meet the basic requirement for breaking of rocks. The productivity is the function of Drilling, Explosives and Fragmentation. Thus, the quality of explosives (energy content) is the key to get desired fragmentation. The variation in energy of explosives and volume of rock per hole have direct impact on fragmentation and cost of excavation (drilling and explosive costs). With the application of higher and higher energy content explosives, it is possible to expand the drilling patterns, i.e. volume in cum. per borehole. As such, higher drill productivity and higher production from the given number of holes can be achieved by adopting appropriate energy content in explosives, and suitable drill pattern for getting desired fragmentation.

Jan 1, 1998

By William P. Blake

In a former paper read at the Washington meeting of the Institute, February, 1881,' I presented a general view of the geology and veins of Tombstone as then developed. Considerable additions have been made to our knowledge of the oredeposits since that date, nearly all the mines having been worked down to the general wster-level of the district. This water was a bar to further progress in depth and costly pumps were erected at the Grand Central mine and at the Contention. By the united action of these pumps the water was gradually lowered, not only in these two mines, but in all the important mines of the district. Pending a consolidation of interests, or an equitable distribution of the cost of unwatering, both pumping-plants were destroyed by fire, and the mines were closed

Jan 1, 1904

The title of this paper implies, and the text explicity states, that Sen and Spottiswood (1984) have found a new mineral species related to geocronite and jorganite. I believe that there is inadequate justification for this claim.The X-ray powder diffraction pattern reported by the authors exhibits a close similarity to that of geocronite, as stated by the authors, which suggests a close structural relationship at the very least. It is therefore reasonable to recalculate the results of the microprobe analysis reported by them to atomic proportions on the basis of the geocronite formula. This calculation, whether based on the formula used by Sen and Spottiswood (1984), or on one derived from a crystal-structure analysis (Birnie and Burnham, 1976), namely Pb18 (Sb, AS)11S46, with a total of 86 atoms, gives the results shown in Table 1.

Jan 1, 1985

By Edward B. Hughes, Frank G. Norris

OXIDATION is characteristic of all processes for making steel from pig iron. This thought has been aptly expressed by H. W. Graham13 in the most recent Howe Memorial Lecture, "The process of steel-making consists of using iron oxide to reduce the carbon content of the pig iron to the desired level." Direct oxidation refers to the reaction that results from introducing oxygen either alone or mixed with other gases directly into the steel bath. In working a heat, oxygen in some form is added to the steel to remove the undesirable constituents as oxides. There are two general methods of supplying this oxygen to the open hearth bath. The method in which the oxygen is added as a, compound such as C02-or iron ore is designated an indirect method because the steel bath must first decompose the compound to attain oxygen in a usable form. The other method in which oxygen is added to the bath in the elemental or gaseous form, more or less diluted by other gases such as nitrogen, is a direct, method because no decomposition is necessary before the oxygen reacts with iron to form FeO which is dissolved in the bath in a usable form. Bubble formation (at least of a macroscopic size) presents no problem in case of direct oxidation because the reacting agent (oxygen) is in the form of bubbles when entering the metal. Regardless of whether oxygen is introduced into the bath directly or indirectly, several reactions proceed concurrently. In the presence of the bath of molten iron, FeO is formed either by oxidation of iron by oxygen or reduction of oxides by iron. This FeO dissolved in the molten iron is the source of oxygen for the oxidation of manganese, carbon, silicon, and phosphorus if these are present. The oxidation of carbon from steel is the controlling steelmaking reaction. The introduction of oxygen into the bath, its reaction in the elimination of impurities, and its control by the use of de-oxidizing additions have been subjects of importance since steel was first made by the bessemer process. Direct oxidation is, in a sense, an application of the bessemer principle to the open hearth process. Graham13 states: "The use of oxygen or air jets introduced into the metal bath is essentially an effort to approach in the open hearth the turbulence, rapid interface reaction, and high production rate per hour that exists in the bessemer process." The general subject, "Oxygen in Steelmaking," was given new life by the studies of Herty and associates starting about1925. The current interest in elemental oxygen is intimately related to the large scale production of oxygen developed during the war period. Some of the first applications were made during the early summer of 1946 at the Steel Co. of Canada using oxygen with the fuel. Such a use is of considerable interest and importance in contributing to faster heats but is not the subject of the present discussion which deals entirely with the introduction of elemental oxygen directly into the open hearth bath. A recent article12 reviewing the current

Jan 1, 1948

By Moorrees C

The end uses of magnesia are determined by both its chemical and its physical proper- ties. There is seen to be an increasing need for products of high chemical purity. Prod- ucts containing 90-95 per cent MgO can be routinely produced by physical beneficiation and calcination of most magnesite ores, the dominant source of magnesia. However, pro- duction of grades containing more than 98 per cent MgO with low impurity levels is not readily achieved physically. Such products can only be readily produced by chemical processing techniques. This presentation outlines the types of impurities present in magnesite deposits and the general concepts that are involved in chemically upgrading them. Of the potential leachants, only hydrochloric acid and aqueous carbon dioxide appear to be commercially attractive.

Jan 1, 1987