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By André Mans, Frans B. Waanders

"Ferrosilicon (Fe-Si) is an important commercial material and it forms the basis of the powder used in dense medium separation (DMS) of various minerals in a minerals beneficiation process. Current losses of Ferrosilicon (Fe-Si), which is used in the dense medium separation (DMS) of iron ore at Kumba Resources, Sishen, South Africa occur due to adhesion to the separation products and also by being present in the effluent stream, due to abrasion. The losses contribute greatly to the running cost of the plant and the purpose of this project was to determine the characteristics of the unused Fe-Si and then to characterise the changes that occur during storage and the use thereof.A Scanning Electron Microscope (SEM) and Mössbauer Spectroscopy (MS) were used to investigate the characteristics of the fresh and used Fe-Si. The SEM analyses of the Fe-Si yielded a composition of 15 wt.% Si and 85 wt.% Fe with minor impurities of Mn and Cr (<1 wt. %), resulting in an ordered phase with a calculated composition of Fe2Si. The average density of the Fe-Si was found to be 7.177 g.cm-3 whilst the size distribution was determined with the d50 of the particles being approximately 30 µm. A slurry, containing 10% solids was prepared, which had a density of about 1.1 g.cm-3 and this slurry was used to conduct the various experiments under laboratory conditions at the university. Samples were taken at regular intervals from a storage container containing a lime solution as well as from a closed circulation circuit system, kept at a constant temperature of about 60°C. Mössbauer Spectroscopy yielded, for the new fresh Fe-Si-samples, a two-sextet spectrum with hyperfine magnetic field strengths of 19.9T and 30.7T respectively, and the yellow-brown froth was found to be akaganeite or ß-FeOOH.It was found that the biggest loss of Fe-Si was due to the abrasion of the particles during the DMS process. A possible change in magnetic properties was also observed, leading to further losses that could occur during prolonged use of the medium. No clear changes to the Fe-Si occurred during correct storage methods, as was initially thought."

Jan 1, 2003

By Thomas M. Turner

Open pit mining, always a demanding task, faces two relatively new problems today: 1. Availability of equipment. Moderate to large draglines can take as long as 6 years from date of contract to date of operation. 2. Environmental restrictions. Strip mining in the minds of environmentalists compares unfavorably on the scale of social desirability to the activities of Jack the Ripper and Attila the Hun. Specifically, lowering of the water table to allow strip mining in the dry is being looked upon with increasing disfavor. The modern dredge offers relief in both problem areas. Delivery on a major dredge might run 18-24 months rather than 60; and lowering of the water table is precluded, thus minimizing environmental objections. In addition, a lower first cost and potentially increased efficiency may offer real advantages to the miner who is forced away from his traditional mining methods. This talk is dedicated to acquainting the miner with dredge types, advantages, and limitations.

Jan 1, 1975

By Martin C. Kuhn, Lawrence G. Stevens, J. Mark Richardson

The majority of the world&apos;s known and anticipated reserves of nickel ores are lateritic deposits At present, there are several different process alternatives for recovering nickel and other desired metal values from laterite ores An overview is given of the selective reduction roast/ammoniacal leach process, one of the processes in commercial operation.

Jan 1, 1981

By Bension Varon

Como parte de la crisis de energía( petróleo), los países en desarrollo enfrentan una perspectiva de costos de combustible mucho más altos en los próximos años, así como la contínua amenaza de que los suministros disponibles puedan ser retenidos, ya sea por razones políticas o en un proceso de un trato unilateral con los países productores claves en el actualmente famoso grupo de la OPEP (la Organización de Países Exportadores de Petróleo). En ese sentido, el presente texto cuestiona la transformación de uno o más minerales ampliamente comercializados no utilizados para combustibles. Para los países desarrollados, esta transformación significa una esperanza, una liberación del comercio, donde ellos pueden tener éxito en obtener de los países avanzados mayores recursos mediante las operaciones del mercado en circunstancias cambiables, y posiblemente debido a alianzas que emulan a la OPE.

Mar 1, 1976

By John Birkinbine

An unusually large number of crystals of magnetite obtained in the exploitation of a deposit of magnetic iron-ore of remarkable purity, encouraged the preparation of this paper, and its presentation at this time, that the matter might go on record in the Transactions. To make this record more complete, a preliminary statement is offered concerning the district and locality in which the ore is found. To the northeastern portion of the State of New York the United States is indebted for a large percentage of the iron-ore which has assisted in developing the resources and industries of the nation. As early as 1804, iron-ore was mined between Lake Champlain and the Adirondack mountains, and this district has since been an important and continuous contributor to our iron-ore supply. The production of the Lake Champlain district for the last, eleven years is as follows: Years. Gross tons. 1879,...........420,341 1880,...........531,000 1881,...........637,000 1882,...........675,000 1883,...........500,000 1884,...........504,894 1885,...........379,077 1886,...........588,752 1887,...........768,852 1888,...........789,419 1889,...........750,230 Approximate total,.....6,644,565

Jan 1, 1890

By Nekitel S, Arumba J, Kopi G, Findlay RH

The Kainantu area lies within the composite Scrapland terrane which is composed of Mesozoic metamorphic and intrusive units, overlain by Cenozoic marine sediments, volcanic and intrus-ive units and Quaternary fluvial sedi-ments.Four deformations (Dl, D2, D3, D4) are recognised within the Mesozoic sequences, which consist of greenschist to amphibolite facies schist derived from felsic to intermediate pyroclastic rocks and pelitic sediments. The second, third and fourth fold events are present in the Cenozoic sequence, and these rocks are broken by thrusts related to northwest trending D3 folds. South-dipping, possibly lystric, normal faults are recognised and may be related to uplift and exposure of the metamorphic rocks as core complexes.Known mineralisation in the area consists of gold and copper skarn deposits, porphyry copper deposits, shear-hosted gold deposits, epithermal vein deposits and gold placer deposits. Over 35 hard rock and 18 gold placer deposits are known within the area. Of significance are the Kathnell shear-hosted auriferous quartz veins; such structurally controlled veins may be more widespread than proposed prev-iously and offer a new exploration target.

Jan 1, 1994

By J. R. Campbell

IN order to discuss the subject intelligently, it will be necessary to touch briefly on the forms in which sulphur is supposed to exist in coking coal to be carbonized in beehive or byproduct ovens. Sulphur is known to exist in coal as sulphides and sulphates, as can be determined experimentally. Then there is the so-called organic sulphur, i.e., sulphur in combination with the carbon, hydrogen, and oxygen of the coal, about which much has been written, but nothing definitely proven in an experimental way. In fact, so far as we know, there never has been developed a satisfactory and conclusive method in the laboratory for the direct determination of organic sulphur. For most coking coals, it can be safely assumed that the preponderance of sulphur is in the form of pyrite (FeS2). When exposed to comparatively low temperatures during the coking process, it loses its sulphur according to the following chemical reaction: 7FeS2 = Fe7S8 + 6S. It will be seen, therefore, that six out of the 14 atoms of sulphur (or 42.8 per cent.) are expelled, or volatilized. Fe7S8 remains in the coke as pyrrhotite, or magnetic sulphide of iron; this accounts for the highly magnetic properties of the powdered coke. A more commonly accepted reaction is FeS2 = FeS + S, in which the straight sulphide of iron is produced with 50 per cent. volatilization of sulphur. In the beehive methods of coke making, air is introduced in sufficient amounts to carry on the distilling and the coking processes, and the sulphur is oxidized along with the other volatile products: First, into sulphur dioxide (SO2), known by the pungent and suffocating odoremitted from the trunnel head; second, into sulphuric anhydride (SO3); and, finally, into sulphuric acid, as it comes into contact with the air and moisture. In a properly regulated draft on a beehive oven, there is never complete combustion of the gases. In other words, the coking process should be carried on in a reducing atmosphere, and a low-grade producer gas kept issuing from the trunnel head. For coals of about 30 per cent. volatile matter, the ratio of air to gas is 3 ½ to 1. In complete combustion, the ratio is 6 to 1, producing an extremely high temperature

Jan 1, 1916

By Franklin J. A, Tam C. Palangio, N H. Maerz

WipFrag systems I, II and III have become the world standard in photoanalysis systems to measure particle sizes. Mines, quarries and excavating contractors can now easily measure blast results and track the progress of optimization efforts. This technology was developed and evolved ~to allow automatic measurements of the size distribution of particles on moving conveyors, in truck boxesand on crusher feeds. Production machinery can now be controlled by photoanalysis results and multiple cameras allow various locations to be monitored by a single system. Blast designs can, be monitored on a shot by shot basis. Changes in delay times, explosives, patterns and hole sizes can be quickly evaluated. Along with this measurement capability has come a heightened awareness of the importance of “optimum size” and uniformity of particles for lowest cost production and material handling efficiency. In the past, savings in the “drill / blast” cycle of the operation were sometimes overshadowed by downstream production costs related to fragmentation. Now total production costs can be compared with fragmentation sizes, which will immediately show the trend towards optimum size for economical production. No cost reduction program can be complete without this critical information.

Jan 1, 1998

By J. E. Zeilinger

This Bureau of Mines study was conducted to determine the sulfur reduction potential attainable when washing fine-size coal on a spiral concentrator. Crushed samples of Middle Kittanning and Bakerstown bed coals washed on the spiral provided pyritic sulfur reductions of up to 90 percent for the plus 200-mesh material. Pyritic sulfur reductions on the minus 200-mesh material seldom exceeded 30 percent; consequently, this material would require further treatment. The capacity of the spiral was 2 tph per unit when washing l4-mesh by 0 coal. The ability to remove pyrite combined with the higher-than-expected capacity makes the spiral worthy of consideration as a rougher-cleaner in new fine-coal desulfurization circuits.

Jan 1, 1976

By Alfred E. Hunt

Professor EGGERTZ first published a method based upon the fact that, when steel is dissolved in dilute nitric acid, and heated until the separated flocculent carbonaceous matter goes into the solution, the liquid assomed a brown color proportionate in intensity to the amount of the combined carbon in the steel. This method has been so variously modified that at present but few chemists use exactly the same procedure. It is the object of this paper to present

Jan 1, 1884

By A M. van Niekerk, W Mey

Coal mining has an impact on the water management of the water scarce Upper Olifants River Catchment. A prefeasibility study was carried out by Anglo Coal and Ingwe Collieries Limited to establish the water supply and demand in the catchment. A geohydrological model was used for the coalfields to determine the stored water and excess water available. Two distinct collective and treatment systems were proposed for the Witbank and Middelburg municipalities to treat excess water from the Anglo Coal and Ingwe Collieries Limited. The Emalahleni Water Reclamation Project for Witbank was initiated first. Water management and treatment experience gained at Anglo Coal was the cornerstone to develop the collection, treatment and distribution system. A full enquiry was issued to Keyplan, Veolia, Bateman Africa and IST Technik to construct, commission, operate and maintain a 20 ML/day desalination plant to treat acidic, saline mine waters to a South African National Standard (SANS) 0241 Class 0 potable water. After the technical and financial adjudication, Keyplan were awarded the contract. An integrated regulatory process was adopted through consultation with all the relevant regional and head office staff of the Department of Minerals and Energy, Department of Water Affairs and Forestry and the Mpumalanga Department of Land Affairs via an authorityÆs steering committee. A rock engineering evaluation was done to select both the plant and waste disposal sites as all possible sites are undermined. Various contracts are required with the individual mines for water supply, the Emalahleni Local Municipality for the delivery of potable water and for the disposal of wastes.

Jan 1, 2006

By D. Boreck

The Bureau of Mines is conducting research on the feasibility of incorporating in situ stope leaching into active underground metal mines. Stope leaching, a modified in situ leaching technique, proposes to recover metals by leaching fragmented ore in existing underground openings and collecting and processing the metal-bearing solution to recover the valuable metals. If leaching solutions escape from the stope, either through geologic discontinuities or highly permeable zones in the rock, valuable metals dissolved in the solution may be lost. Escaping solutions may also contaminate ground waters. Consequently, in fractured rock, the characteristics of the fractures in the vicinity of the leaching stope must be understood before introducing actual leach solutions into the stope. Effectively characterizing a rock mass requires the integration of several disciplines including structural geology, borehole geophysics, hydrology, geochemistry, and mining engineering. This paper will focus on the general geologic and geophysical techniques that can be used to characterize the rock mass at an underground simulated stope leaching site. The results of several geophysical logging methods, tested at the site, are compared to the geologic core descriptions. Then, the? effectiveness of the different geophysical techniques in delineating fracture zones will be assessed. Knowledge gained through the geologic and geophysical analyses can be used to supplement results from hydrologic testing. This information can also be utilized in designing blast patterns and developing strategies for controlling or blocking movement of escaping leach solutions.

Jan 1, 1991

By Donald L. Katz

The equilibrium constants developed by Souders, Selheimer and Brown1&apos; have been very useful tools in predicting vapor-liquid equilibria during the past five years. Their equilibrium constants were computed by assuming ideal solutions and recognizing the deviations of vapors from ideal gas laws. The same fundamental concepts were used by Lewis and co-workers8 for predicting vaporization phenomena by means of fugacities. The equilibrium constant is defined by equation 1: y\x =K [1] in which K = equilibrium constant, y = mol fraction of a constituent in the vapor phase, x = mol fraction of the constituent in the equilibrium liquid phase. The equilibrium constants are a function of temperature and pressure and might be considered as replacing the ratio of the vapor pressure to the total pressure of Raoult&apos;s law. They may be used to compute the vapor or saturation pressure of a liquid or the dew point of a vapor for any pressure or temperature from the analysis of the mixture much as Raoult&apos;s law is used. Likewise, the quantity of a mixture that will vaporize at any equilibrium temperature and pressure and the composition of the vapor and liquid may be calculated. The purpose of this paper is to review the available equilibrium data of interest in petroleum production, to discuss the auxiliary physical properties of the hydrocarbons, and to present typical uses of the equilibrium constants. The particular applications chosen are the computation of the results of stage separation of crude oil and natural gas, the calcula: tion of a pressure-volume curve of a crude oil-natural gas mixture, and information gleaned from a consideration of reservoir equilibria.

Jan 1, 1938

By Ning Liu, Xuming Wang, Yongqiang Lu, Jan D. Miller

Bench-scale flotation experiments have been conducted to study the effect of nonionic polyethylene oxide (PEO) polymer surfactants on the flotation of Florida phosphate rock. It has been found that PEOs having a molecular weight from 1,200 to 8,000 are effective. Flotation results demonstrate that the addition of nonionic PEO has a favorable effect on phosphate flotation, especially on the flotation of coarse phosphate feed. At about the same collector level, phosphate recovery can be improved by 10-30% with PEO addition. The surface chemistry of phosphate flotation using the fatty acid/fuel oil/PEO system has also been studied to better understand the phenomena involved. The increase in phosphate recovery with PEO addition has been attributed to improved dispersion of fatty acid, which leads to better froth stability and a more hydrophobic surface state.

Jan 1, 1999

By R. G. Zaripova, N. D. Ryan, H. J. McQueen

The austenitic and ferritic stainless steels do not undergo any phase transformation that induces very fine grains in the product through thermomechanical processing as practiced in most other steels. Considerable grain refinement can be achieved by intense multistage deformation descending through warm to cold working; notably multi-axial forging of bulk material can attain high strains with diminished risk of cracking. Hot working to improve ductility yields finer grain sizes as the T is reduced and strain rate E raised; increased strain has limited effect due to the steady state regime. Ferritic steels develop subgrains with size diminishing as E rises and T falls with the advantage of retained strain hardening; recrystallization delivers grains several times the cell size. In austenitic steels, dynamic recrystallization (DRX) provides finer grains at higher E and lower T with a lower limit due to intergranular cracking. The DRX grains contain a strengthening substructure that can easily be retained by quenching; if static recrystallization is allowed to occur the grain size rises markedly. Multistage rolling with diminishing T is able to provide grain refinement to the same degree as straining at the finishing T yet provides better ductility. grains on recrystallization. As a result of the strain induced transformation to martensite, small subzero deformations of austenitic or duplex steels produce very high dislocation densities that yield marked grain refinement when they revert upon reheating.

Jan 1, 2004

By R. M. Larsen

The Rocky Mountain region is defined with some variations for different purposes or by different organizations. For oil and gas development, Wyoming, Montana, Colorado, northwestern New Mexico, and Utah are included in the order of their apparent importance. Portions of adjoining states, such as North and South Dakota, Nebraska, Arizona, Nevada, and Idaho, arc attributary to this region, but have little or no oil or gas production. Nebraska and New Mexico are considered separately (see pp. 412 and 415), and most of the discussion in this report will be confined to Colorado, Montana, and Wyoming. Utah has produced about 200,000 bbl. of oil from the San Juan and Virgin fields, which are isolated and shut in at present. The Clay Basin field in northeastern Utah produces natural gas and distillate, and the Farnham field in central Utah produces carbon dioxide gas. Other Utah areas of some interest are listed in Table I. The Cedar Creek (Baker-Glendive) field in southeastern Montana extends into North Dakota, but is listed under Montana. The other states are in the main wildcat areas, and exploration in 1944 was at a minimum. However, geological and geophysical parties are reviewing them for further testing. Oil production in Colorado, Montana and Wyoming was 459,000 bbl. more than in 1943. Increases of 713,000 bbl. in Colarado and 731,000 bbl. in Montana offset a loss of 985,000 bbl. in Wyoming. This was the first decline in Wyoming since 1938. Field production figures and state totals are given in Table I. Total drilling activities in these three states and Utah increased from 687 wells making 1,442,511 ft. of hole in 1943 to 916 wells making 2,245,803 it. in 1944. Wildcat drilling increased from 163 wells making 331,193 ft. of hole in 1943 to 171 wells making 389,144 it. in 1944. These figures include all drilling wells making footage, not starts or completions, and represent an all-time high in drilling. The year 1944 witnessed the greatest concentration of seismograph activity that the region has had. The Rocky Mountain Oil Scouts Association reported that in 1943, the previous peak year, 91 crew months of work were performed; in 1944, the time was 254 crew months. About 67 per cent of the work was in Wyoming, 18 per cent in Montana, and 12 per cent in Colorado. Twenty-three blocks totaling 400,000 acres were reported assembled in Colorado, and 161 blocks totaling 4,000,000 acres in Wyoming. Information about other states was not given. Fourteen unit agreements were approved by the Department of the Interior, as compared with 13 in 1943. The 1944 agreements were all in Wyoming. In five of the unit areas, oil or gas discoveries were made, four were dry, and five were drilling Or pending&apos; Oil companies find it advantageous to unitize blocks containing any proportion of public domain. Units for

Jan 1, 1945

The Bulli Seam, New South Wales, cenprises middle to high rank bituminous coal, generally of coking quality. It is worked over an area embracing 300 square miles.Variations in several factors are presented:The seam is somewhat. disturbed and &apos;dissected by various structural features. This structure, and present topography, have resulted in depths of cover from very shallow to approaching 2, 000 ft in the presently, Worked area. Wide variations of seam thickness occur. Gradations of, rank occur from-place to place. Variations in seam gas content and pride variations in seam gas composition are experienced. Variations in coal strength occur. The influences of these factors on the occurrence of stress and gas phenanena in mining exploration are considered.

Jan 1, 1963

By Nguyen V. V

The development of structural defects in the overburden material immediately behind a production blast was studied using surface and subsurface techniques. A significant increase in vertical and horizontal fracture intensity was recorded. The extent of fracturing into the highwall appeared to be dependent on the structural and petrologic characteristics of the various lithological units and the relative position of the explosive charges. A shallow zone of disruption to a depth of 10 m and extending to around 30 m from the newly formed highwall crest was recorded. Horizontal fractures in lower units of the overburden sequence were recorded at distances up to 50 m from the new highwall Face.

Jan 1, 1981

By L. A. Johnson

This Bureau of Mines report presents the analysis of three cores from the Asphalt Wash area of the P.R. Spring tar sand deposit of northeastern Utah. Two tar sand zones are indicated in the Asphalt Wash Area. Total net thickness of the tar sand ranges from 23 to 39 ft, with occurrences between 56 and 263 ft in depth. The sand has average porosity of 24.7 pct of bulk volume, average permeability before and after extraction of 87.5 and 596 md, respectively, and average oil saturation of 58.1 pct of pore volume. Oil gravity averages 10.9° API.

Jan 1, 1975

By Daiki Takano, Naoki Takahashi, Hidenori Takahashi, Ikuo Towhata, Yoshiyuki Morikawa

"The method in this study, in which cement-treated piles are installed into the ground to decrease the amount of liquefied lateral flow, has been studied. The authors are also investigating the most effective arrangement of piles to optimize cost-effectiveness. In their investigation, they propose shifting the position of the piles to prevent lateral flow in various directions. The present study conducted centrifuge model tests to clarify the improvement effect of piles against the lateral flow of liquefied soil and the effect of the pile arrangement. Then, numerical fluid analyses were conducted to consider the improvement mechanism. As a result, the model tests and numerical analyses showed that the pile improvement dramatically reduced the lateral displacement and that the average total flow velocity decreased in the irregular case.INTRODUCTIONLiquefied ground subjected to seismic motion loses its stiffness and strength, and lateral flow often occurs in sloping areas and backfill areas behind collapsed quay walls. In the Hyogoken–Nanbu Earthquake in 1995, the reclaimed island that was surrounded by collapsed quay walls expanded toward the sea and the amount of displacement reached a few metres (Hamada et al., 1996). Two countermeasures can be considered to guard against lateral flow: preventing liquefaction and reducing lateral displacement. The former method is ideal; however it is costly and time-consuming. Based on these considerations, the authors (Takahashi et al., 2013; Morikawa et al., 2014) are currently studying a method in which cement-treated piles are installed into the ground (see Fig. 1) to decrease the amount of liquefied lateral flow. The countermeasure cost using this method is relatively low because of the low replacement ratio. The authors are also investigating the most effective arrangement of piles to optimize cost-effectiveness. It has been proposed that the position of the piles should be shifted so that lateral flow can be prevented in various directions, as described in Fig. 2."

Jan 1, 2015