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By Norman B. Pilling

The technical difficulties hampering the metallographic analysis of silicon steels are chiefly the result of the extreme corrodibility of these alloys. The addition of silicon to iron in increasing quantities, up to about 6 per cent., rapidly increases the susceptibility of the alloy to chemical attack, not only in acid solution, but in water. This renders the preparation of metallographic sections very difficult, because of a non-selective attack upon the finely polished surface by the water used as a lubricant in polishing. This water attack masks the true structural details revealed by suitable etching reagents. It is thus necessary to use alcohol as a polishing lubricant in the last stages of preparation and to avoid all etching reagents having an aqueous base. A specific reagent for the identification of iron carbide in ferrous alloys, and the one hitherto used almost' exclusively by metallurgists, is an alkaline aqueous solution of sodium picrate, which stains this constituent selectively. Its application to silicon steels has not proved successful, as its distinctive selective action is more or less completely hidden by the general attack of the aqueous solvent on the silico-ferrite, greatly accentuated by the fact that this reagent must be used at its boiling temperature (105' C.). Thus, a powerful metallographic aid to the study of the higher silicon alloys, such as transformer steels, is lost. A new reagent has been developed for the purpose of overcoming this difficulty. It is with some hesitation that the list of etching reagents, already overburdened, is increased, but the properties of this new reagent are advantageous in several ways and a definite field for it may be found in the metallography of ferrous alloys. The reagent consists of a dilute solution of nitric acid and methyl alcohol in nitrobenzol. It is a great advantage to secure an anhydrous solution, as a tendency toward acidic etching has been traced to small amounts of water. A convenient method of preparation is to make an anhydrous stock solution of nitric acid in methyl alcohol in the proportion 20 per cent. acid by weight (12.5 per cent. by volume). The alcohol can

Jan 1, 1924

By B. K. Mishra

The motion of the charge inside a grinding mill is of considerable practical importance. The dynamics of grinding mills have been the subject of study by a number of workers because it can accurately predict: i) the power drawn by the mill, ii) the distribution of forces inside the mill, and hence the wear rate of balls as well as the liners, and iii) mass transport of milled product through the porous ball charge. Some of the earlier analyses of the motion of a charge of particulate material in a tumbling mill were reported by White (1904), Davis (1919), and Dyer (1945) and have been reviewed by Rose and Sullivan (1958). In these works, frictional force at the wall of the mill and between the colliding balls, and the interaction of different ball trajectories, was not considered. Moreover, it was assumed that the profile of the tumbling charge is independent of the degree of filling, which is generally not true. However, all this work led to the identification of so-called "equilibrium surface" which is the plane that separates the rotating charge into two regions. The inner region is static; here there is no motion relative to the mill shell. The other region is a shear region where either the balls flow down the surface of the charge (cascading motion), or are projected out of the surface and follow approximately parabolic paths (cataracting motion).

Jan 1, 1990

By R. Gampala

The consolidation of mom matrix composite monotapes occurs by the plastic (time independant) and creep deformation of monotape asperities. Past models of the process used seperate micromechanical analyses of the contact deformation by (rate independent) plasticity and power law creep (i.e steady state creep). These models are now used to simulate consolidation and to optimize/control consolidation process cycles so that the composite's microstructure is "steered" to, a user defined goal state. However, the models do not incorporate the sometimes dominant transient creep process and the instantaneous response of the plasticity mechanism causes finite discontinuities in the microstructure state vector field and therefore eliminates the possibility of using the powerful array of trajectory optimization schemes that all require continuous vector field for optimization and control. To overcome this problem, a inified creep/plasticity constitutive model that results in a continuous state vector field is used to rederive the contact deformation response during monotape consolidation. The contact blunting of a laterally constrained hemispherical asperity is first analyzed and its response represented by two coefficients; one relating the contact area to the blunting strain (C), the second, the mean contact pressure to the blunting rate (F).The C and F coefficients for this unified blunting problem are then obtained by finite element analysis, and detailed results presented for two composite matri-ces of topical interest (Ti-24A1-11Nb and Ti-6Al-4V).

Jan 1, 1996

A method has been developed to remove calcite from the leaching circuit in the uranium in situ leaching system. The process involves injecting the leachate and a pH control agent tangentially into an inverted cone reactor containing calcite seed catalyst. The leachate can be treated at high throughput to obtain clear effluent containing 5 ppm or lower Ca. Both lime and ammonia are effective pH control agents and consumed according to stoichiometry.

Jan 1, 1985

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Jan 1, 1938

By C. J. Newman, R. J. St. Eloi, G. Macfarlane

"The Kidd Creek copper smelter has been expanded from its original design of59000 tonnes of copper per year to over 120 000 tonnes per year. Modifications to the process gas handling system and acid plant have been made to accommodate this higher production rate and, generally, to optimize the operation.The gas handling system associated with the continuous smelting process is discussed in terms of boiler accretions and modifications to minimize their impact on operations; design changes to effect reductions in high pressure drop duct configurations; material changes to overcome corrosion and plant additions to improve gas cleaning capability. The acid plant is reviewed with references to changes made to accommodate the increased S02 gas strength resulting from the higher smelting rates. IntroductionThe Kidd Creek Division of Falconbridge Limited is a base-metal mining and metallurgical complex located in Timmins, Ontario. The discovery of the original copper-zinc-silver orebody was announced in April 1964. Mining operations began in 1966 with a 9000 tonnes per day (t/d) concentrator corning on stream in November of that year. In April 1972, a 108 000 tonnes per year zinc plant was conunissioned. Over the years the facilities have been expanded, such that the concentrator now has the capacity to process 13 000 t/d of ore. To expand zinc production, the world's second installation of the Commco/Sherritt pressure leaching facility was completed in 1983 to bring total zinc production capacity to 136 000 tonnes per year. In 1973, serious planning for a smelter operation began. In early 1975, after studying both continuous smelting and flash smelting processes, a decision was made to proceed with the technology offered by Mitsubishi Metal Corporation of Japan. The Mitsubishi Continuous Smelting Process was to be used for the smelter and the Onahama No. 3 tankhouse technology for the copper refinery."

Jan 1, 1994

By Jean P. Murray

The extractive metallurgical industry is a major consumer of high-temperature process heat. It is, consequently, a major contributor of C02 emissions and other greenhouse gases derived from the combustion of fossil fuels for heat and electricity generation, or from the process itself. These emissions can be substantially reduced by replacing fossil fuels with solar energy as the source of process heat. Concentrated solar radiation can supply a large amount of thermal energy to endothermic reactions at temperatures exceeding 2000 K. Another potential for C02 emission reduction exists as well. Thermodynamically, the total amount of energy required for metal production at any given temperature is the enthalpy change of the reaction, AH. Of this total, an amount equal to the Gibbs free energy AG must be supplied as high quality energy in the form of electrical work or by using a reducing agent. Many conventional metallurgical electrolytic processes and reducing furnaces are unable to add only the thermodynamically required electricaVchemical energy due to process inefficiencies. Electrical work in excess of AG for the reaction may be used to supply process heat, or excess chemical reducing agent burned to supply process heat. Besides the thermodynamic and economic drawback, this inefficiency results in excess C02 emissions derived from the combustion of fossil fuels. With these practices, energy becomes an important cost element of the metal produced. Highly-concentrated solar energy has the demonstrated potential to separate these two forms of process energies, allowing the addition of only the thermodynamically required high-quality energy while high-temperature solar process heat is provided to the reactor. Examples of metal oxide reduction processes that have been studied experimentally in solar furnaces include the production of Fe, Al, AI/Si alloy, Mg, Zn, Tic, Sic, CaC2, TIN, Si3N4, and AIN by carbothermic reduction of their oxides, and the high-temperature solar- electrothermal reduction of ZnO.

Jan 1, 1999

By T. C. -M. Cheng

Iron removal and disposal in zinc plants has imposed a major environmental challenge to the industry. Among the existing options of precipitating iron as jarosite, goethite, and hematite, the Hematite Process seems to be the best candidate for the future development of a waste-free technology, because of its potential of producing saleable iron oxide residues for feed in iron-steel making industry. Unfortunately, under the current practice of the Hematite Process, it is not possible to produce iron residues clean enough to meet the specifications of the said industry. In this paper, the practice of industrial hematite precipitation and the relevant technical literature are reviewed with the objective to identify the critical processing parameters which are responsible for the contamination of hematite, particularly with sulfur and zinc. The analysis is conducted from a crystallization theory standpoint with emphasis given to the role of supersaturation with respect to the cleanliness of hematite precipitates.

Jan 1, 1997

By Aspinall T. O, Loch R. J, Bell L. C

Design of reshaped spoil surfaces is an important pan of rehabilitation of spoil piles resulting from open-cut coal mining. To achieve the optimum design, it is necessary to make accurate predictions of soil losses from spoil piles. Predictions can be based on data gathered using laboratory and field rainfall simulators and field plots. These data are used to derive input parameters for erosion prediction models. Model input parameters include rainfall erosivity, spoil erodibility, sediment size distribution, runoff, soil loss and peak runoff rate. Model outputs can be used in design and include predicted sediment size distribution and predicted soil loss.The traditional method of gathering input data is monitoring field plots. This method is very expensive, must be done on a long-term basis and is affected by irregular rainfall. Long-term field plots are necessary to obtain data that can be applied to empirical prediction models such as the Universal Soil Loss Equation (USLE).

Jan 1, 1992

By P. Grotjohann

In processing heavy mineral sands, the low feed concentration and respective high value of the desired minerals require high capacity production and sharp classification/separation techniques to reduce the specific production costs. The allflux® separator, a new process system introduced to the heavy mineral industry, meets these criteria in an economical way. Its two-stage process, a combination of rising current and fluidized bed technology, allows the treatment of extremely high massflows in a single unit. Using concepts that have proven successful in processing concrete sands for many years, testwork in coal, iron ore, and heavy minerals looks very promising.

Jan 1, 1998

By S. S. Klima, A. L. Mazzella, J. S. Driscoll, T. W. Beck

Previous testing was performed by researchers at the National Institute for Occupational Safety and Health (NIOSH) to improve longwall dust control using underside shield sprays with a longwall directional spray system. This testing provided encouraging results toward respirable dust exposure reductions for longwall personnel, achieving as high as 99% dust reduction at some sampling locations along the longwall personnel walkway. Additional laboratory testing was conducted to test these underside shield sprays in conjunction with a shearer-clearer spray system located on the longwall shearer body. The purpose of this testing was to determine if the underside shield sprays interacted positively or negatively with the shearerclearer sprays. Results from this testing indicate that while the shearerclearer system influences where the respirable dust particles are directed, underside shield sprays can still lower respirable dust exposure for longwall personnel.

Mar 2, 2022

By A. Bilodeau

A new hydrometallurgical process for the production of refined gold and the recovery of palladium and platinum from silver anode slimes has recently been developed and installed at the, CCR Division of Noranda Inc. The process, which facilitates the production of gold of >99.99% purity in the face of increasing palladium receipts comprises; leaching silver anode slimes with hydrochloric acid and hydrogen peroxide at 95°C to solubilize gold, palladium, platinum and base metals while simultaneously rejecting silver as insoluble silver chloride; precipitating gold from the leach solu¬tion with sulphur dioxide gas in two stages to produce a first-stage high purity gold product and a second stage impure gold which is recycled to the leach; washing, melting and casting of the pure gold; precipitation of a palladium-platinum concentrate from the gold-free solution by reduction with sodium formate at pH 4 and 95°C; and neutralization of the palladium precipitation effluent to pH 10 with lime. The results of laboratory and pilot plant studies leading to the adop¬tion of this process are discussed, and data are presented for each of the unit operations. Details of the engineering of the commercial plant are given, and plant start-up experience is described.

Jan 1, 1987

By R. C. Philp, Allan Gibb

The term a matte " is applied to smelting-products so extremely diverse in composition and physical properties that it appears impossible to devise any generic formula to represent, chemically, the manner in which the varied proportions of the almost unlimited possible constituents combine with each other. Mattes produced in copper-smelting, in distinction from those produced in smelting-operations in which the recovery of cop per is secondary to that of other metals, cover a narrower range in composition. The copper-content of such mattes vary from 20 to 80 per cent., and even this range is much smaller in general practice since it is found advantageous, when possible, to produce mattes with about 50 per cent. of copper in the first operation. Further, it is unusual that arsenic or antimony occurs in copper-ores in sufficient proportions to form arsenides or antimonides in such quantities that they will separate out from the furnace-products, as is common in lead-smelting. Generally, the mattes produced in copper-smelting are composed mainly of copper (usually greater than 35 per cent.), iron and sulphur, the remaining elements being usually in proportions sufficiently small to allow of their treatment as impuritiee, rather than as essential constituents of the mattes. In modern practice of smelting copper-ores in blast-furnaces the tendency is to approach pyritic smelting as nearly as possible, the furnaces being low and the air supplied being largely in excess of that required for complete combustion of the carbonaceous fuel. Hence, the atmosphere of the blast-furnace thus used is usually oxidizing or nearly neutral, and, as a consequence, the reduction of metallic iron that was a necessary evil of former practice is of unusual occurrence in operations where the main object is the recovery of copper. Hearth-accre-

Jan 1, 1906

By William E. Frazier

The presence of minute amounts of sulfur (10ppm) in nickel-base superalloys has been associated with reduced oxidation resistance and the premature spallation of protective coatings. Removal of sulfur by annealing these alloys in a hydrogen atmosphere has been successfully attempted by several researchers. This paper examines the fundamental thermodynamics and kinetics governing hydrogen desulfurization of elemental nickel. Limiting conditions for successful desulfurization are delineated. Assuming that the diffusion of sulfur is the rate limiting process of desulfurization, the effectiveness as well as time associated with hydrogen desulfurization is explored.

Jan 1, 1994

By William H. R. Gibney

Pine Point Mines is located in the Canadian Northwest Territories about 1,200 kilometers north of Edmonton, Alberta, close to the south shore of Great Slave Lake. Originally staked in 1898 by prospectors en route to the Dondike gold rush, it was not until the mid-1940's that large scale exploration was undertaken and Pine Point Mines Limited was formed. Work was suspended in 1954 while studies were made to resolve one of the main problems, transportation. In 1961, under the Canadian Government "Roads to Resources" program, agreement was reached for the construction of the Great Slave Lake Railroad and plans made to put the property into production. A townsite was established in 1963 and plant construction commenced. The first production was in the form of high grade ore which was shipped to Kimberley, B.C. for concentration starting in late 1964. The Pine Point concentrator started up in late 1965 when hydroelectric power became available. Initially designed for 4,540 metric ton per day, facilities were expanded to a designed 7,250 metric ton per day in 1969. Problems associated with mining operations at Pine Point are not unique but are augmented by the isolation, climatic conditions, topography, high water table and spread out nature of the operation. Maintenance of a reasonably stable work force is the number one problem but this is gradually being overcome as more local people are trained and oriented from a nomadic type life to an industrial society. The purpose of this paper is to give a general description of the mining operations of Pine Point Mines Limited and to review some of the problems encountered in the operation along with problems associated with northern operations.

Jan 1, 1970

By J. D. Vincent

The Henderson mine site is located at Red Mountain on the eastern slope of the Rocky Mountains, approximately 50 miles west of Denver, Colorado. The mill site is on the west slope of the Rockies and mine and mill will be connected by an underground railroad. All designs were for a 30,000 ton per day molybdenite processing plant with provisions for future expansion up to 50,000 ton per day if required. This plan did not just happen, but slowly evolved over the course of about three and one-half years. Many plants cannot afford such a delay, but the Henderson project will take about 10 years from the time it was first discovered until production starts, and these 3 !1 years were well spent in determining the best possible plant site and flowsheet. This paper describes some of the problems and the decisions made in arriving at the final location and flowsheet. The paper does not go into the specific details of how protection of the environment went hand-in-hand with all other project considerations. This particular aspect of the planning has been well-reported on other occasions and considerable information on it is readily available.

Jan 1, 1972

By Edward Medina Bárcena

El proyecto minero Cerro Lindo, luego de haber aprobado los estudios de factibilidad técnica-económica, inicia su fase de construcción en el 2006 y culmina en el 2007. En ese sentido, el presente texto describe el incremento de la producción y expansión. Para esta nueva expansión, se realiza un estudio de factibilidad, donde se determinan CAPEX y OPEX. Además, se determina la rentabilidad del proyecto y de un periodo de recuperación del capital invertido (US$ 168 millones). El período de construcción se inicia en junio de 2011 y culminará en diciembre de 2012.

Oct 1, 2012

By Thomas E. Marshall, Timothy Batchler, Anthony T. Iannacchione

As the amount of new fractured surfaces or "damaged rock layers" within roof rock increases, the stability of the rock mass decreases. While direct measurements of this phenomenon are not easily made, there is good circumstantial evidence to support this hypothesis. For example, it is common to observe increased cracks or fractures in the immediate mine roof rock before a roof fall. Likewise, roof drill holes placed in areas that later fail often reveal increased numbers and/or separations of fractures within the rock column through time. And finally, the frequency of microseismic activity, representative of rock fracturing, increases before a roof fall. For this study, more than 700 microseismic emissions were collected from two underground limestone mine roof fall areas in southwestern Pennsylvania. Microseismic events were located and magnitudes determined using the moment magnitude technique. Moment magnitude is based on the event seismic moment, which is a measure of the seismic deformation. The amount of new fracture surface length was calculated based on the stored strain energy within the rock prior to fracture. In the two case studies presented, a significant amount of microseismic activity was observed as much as two days before the first signs of failure in the roof fall areas. Additionally, results from this analysis reveal much about the behavior of strata prone to failure and allows for the construction of hazard maps based on microseismic emissions. The potential use of this technique as a means of anticipating roof falls is analyzed and discussed.

By Robert J. Hundhausen

The Young America lead-silver-zinc mine in Stevens County, Wash., was investigated by the Bureau of Mines during parts of 1946, 1947, and 1948. Results of the investigation are described herein. The mine is 1/4 mile northeast of Bossburg, Wash., the nearest railway station. An excellent paved highway (No. 22) connects Bossburg with Colville, Wash., 23 miles to the south. The property was located in October 1885. It is credited with a production of 2,178 tons of shipping ore since 1901. The shipping ore averaged 7 percent lead, 7.7 percent zinc, and 16.1 ounces silver per ton. The property is under lease and option to Walter E. Morris and Perry Leighton of Colville, Wash. The deposit crops out on a steep limestone bluff overlooking the Columbia River. The country rock is a highly metamorphosed, brecciated, marbleized limestone (Northport formation).

Jan 1, 1949

By N. H. Wetzel

Railroads, attempting to increase their tonnage without adding new lines, have for some time realized there is a definite relationship between increasd haulage efficiency, and constant communication with each moving unit that operates along their roadbeds. Elaborate radio communication equipment has been devised for this purpose, and is rapidly being installed. Coal mines are faced with similar haulage problems and have sought this constant contact through the use of telephone systems, and dispatcher stations. Often the fixed mine telephone system is unsatisfactory, since the desired person is not present at the phone when needed. Dispatchers lose contact with a motorman as soon as he is out of sight, until he calls in from another telephone. The recently developed frequency-modelated radio phone which makes use of the trolleywire network in a mine as a carrying medium, permits instant and continuous contact between dispatcher and locomotives. The motorman can immediately contact another motor or the dispatcher regardless, of his motor's position on the trollywire system, whether moving or standing.

Jan 1, 1948