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By C Grobler, M Recklies, G Jiang, I Taylor, M Morgan, G MacDonald, L Smith

The resource estimation of lateritic deposits, such as Aurukun, presents specific issues related to the lateral changes in thickness and elevation of the various horizontal layers (or zones) within the deposit where the x and y dimensions are orders of magnitude greater than the z dimension. The objective was to develop a three-dimensional (3D) block model that retained the vertical and lateral variation inherent in deposits of this type to allow full optimisation of the production plan without prior selection of an economic portion (enriched bauxite layers) of the profile at the resource estimation stage. The Aurukun bauxite deposit is held by Chalco Australia Pty Ltd (Chalco) and forms part of the world-class Weipa bauxite province, Cape York Peninsula, Queensland, Australia. The bauxite is predominantly pisolitic with an upper boehmite-rich zone and lower gibbsite-rich zone. The bauxite consists of both in situ and reworked domains, is overlain by a thin soil horizon and has kaolinite clay as a transitional base. A portable infrared mineral analyser (PIMA) was utilised on site, in addition to elemental assay, on each drill sample to determine the mineralogy, in particular levels of boehmite, gibbsite, kaolinite and reactive silica. As part of the scope of work, a field program was undertaken using large diameter Boart Longyear sonic drilling to acquire detailed density measurements across the deposit to allow compliance with Joint Ore Reserves Committee (JORC) reporting requirements. Interpretation of the stratigraphy was conducted on a hole by hole basis with definition of the zone layering based on stratigraphy, geochemistry and mineralogy. The zone boundaries were then modelled as 3D surfaces and used to constrain a block model. The block model estimation used the ordinary kriging method, with the estimation done in unfolded space and then refolded, therefore maintaining the zones irrespective of thickness or orientation. The unfolding process converts the real-world positions for both blocks and informing samples to a scaled position relative to the roof and floor of each zone. Analysis of the data and variography were also undertaken in unfolded space. The x and y dimensions are unchanged, but the z dimension is a relative position. The effect of the unfolding and limits on number of samples per hole is to æpushÆ the informing sample search sideways but within the stratification, rather than vertically. This honours the strong vertical zonation within the bauxite profile. The JORC Code requires that the stated resource must have æreasonable prospects for economic extractionÆ. This is a qualitative rather than quantitative definition. A number of selection criteria to define a resource roof and floor were developed in consultation with the project engineers and owners to meet these criteria. The vertical selection of material to include in the resource highlights the variation in the development (and destruction) of the bauxite profile from area to area within the deposit.

Jan 1, 2009

By A. C. Bonnier

"INTRODUCTIONI have been asked to make available our method of determining the ""Live Inventory"" within a gravity type thickener. The ""Live Inventory"" being that tonnage compatible with the optimum underflow density that satisfies the process requirements.One prerequisite of the calculations is the proper determination of the final pumpable underflow density. A further requirement is that, prior to shutdown, the thickener has been operated properly, particularly that it has not been operated for storage capacity.Until recently I had few chances to check the method. However, I was most fortunate to have had a recent opportunity covering several months on a 300 ft diameter thickener at a plant in the U.S.A., wherein the method was tested and verified many times. The method proved accurate in that our calculated tonnage checked with the actual dried physical inventory of the drying facility.At the precise moment that the feed to the thickener was shut down, a per cent solid determination was made at the critical place and the tonnage in ""Live Inventory"" determined. Let us say that at the moment the thickener U' Flow solids was 20%. The thickener then was allowed to cperate until the U' Flow solids dropped below 20%, at which time the thickener was deemed to be relieved. Anything much less than 20% was not suitable to the subsequent centrifuge operation.Most large metallurgical thickeners have a configuration of three slopes at the thickener ""bed"". These slopes are dictated by the raking blades and are shown on the manufacturers' erection drawings. The first slope is from the outer periphery and generally takes up a distance of about 60% of the radius, the second slope generally taking up the remaining 40%. Within this 40% area, there is usually another slope taken up by the cone on ""B"" type thickeners or an actual steeper inner slope on ""C"" type thickeners."

Jan 1, 1989

By Amr Sallam, Ahmad Mohamed, Mohamed Alrowaimi

Renewable energy, in the form of wind and solar, has emerged as main source of energy in the modern society. The wind industry has substantially grown over the last two decades to become a key player in providing energy to public. Wind turbines are getting larger, taller, and more efficient every year. The foundation is a major component of the wind turbine system. The wind turbine foundation must provide short and long-term stability for the overall turbine to allow continuous and safe turbine operation for energy production. The turbine serviceability and stability requirements must be geotechnically and structurally satisfied. In North America, major foundation types currently utilized in the wind industry include gravity spread foundation, mono pier foundation, and pile foundation. In this case study, a Post Tensioned Pile Cap (PTPC) foundation was used to support a 3.15-3.4 Megawatt turbine with 125M Rotor supported on 87.5M-hub-height tower. Soil anchors in the form of Auger-Pressure-Grouted-Displacement (APGD) piles and Continuous Flight Auger (CFA) piles were utilized. Four distinct subsoil conditions were identified, and for which four pile designs were adapted. Due to the occasional encounter of stronger soils at 50 to 55 feet (15.2 to 16.7 m), shorter pile design was preferred. To satisfy the design uplift load, pile post grouting were utilized to increase the shaft capacity of the piles. In this paper, the pre-production pile load test program will be described. The pile load test procedure, analysis, and results will be presented. A discussion will be provided, which led to the selection of the optimum pile design to support the high tension loads taking into consideration pile length limitations.

Poor ground conditions associated with historical workings have presented significant challenges to the drilling of production downholes at the Sons of Gwalia Mine. The combination of foam and polymer drilling, the use of Aquacrete to drill through voids and the practice of lining completed holes has allowed downholes to be effectively drilled and blasted in delaminated ground.

Jan 1, 2002

By C. R. Keyes

Discussion of the paper of C. R. Keyes, presented at the Chattanooga meeting, October, 190S, Bulletin No. 26, February, 1909, pp. 119 to 166. E. R. BUCKLEY, Flat River, Mo. (communication to the Secretary*) :-Some statements in the paper of Mr. Keyes relative to the nature and formation of the Ozark lead- and zinc-deposits seem to me erroneous and misleading, and I respectfully present the following criticisms, placing Mr. Keyes's original statements in quotations. Referring to the Ozark dome: (P. 127.) "It is a region that has been repeatedly upraised and planed off, until in the middle portion the oldest known' rocks only are exposed." Does he mean that the St. Francois mountains, which have always been considered as lying on the eastern flank of the Ozark dome, are the middle of the dome? Or does he mean that the Cambrian rocks of the generally-accepted middle are the oldest known rocks ? Certainly not the latter, and if the former, his idea of the middle of the dome is not in accord with that of others who are familiar with the region. (P. 138.) " . . . the ore-deposits are definitely associated with, or localized by, geologic structures of some kind that .produce in effect basins in which' the underground waters are impounded, or their flow retarded." This statement does not appear to be altogether consistent with the facts, since the ore- bodies of the Joplin district, as the rule, occur in those parts of the Mississippian formation which have a tendency to accel¬erate the flow of ground-water rather than retard it. I might name the open, breeciated ground near Joplin, Webb City, and Oronogo as especially noteworthy illustrations. The ore-bodies, everywhere, occur in positions where there must have been a free and copious circulation of dilute lead- and zinc-solutions in the presence of reducing constituents. The inequalities in the distribution of the ore-deposits are

Oct 1, 1909

By Dave Thomas

?Uranium is a common trace metal at the earth?s surface, but these are amazing super-high grade (up to 25%) pods, veins and disseminated uraninite (UO2) near unconformities between Proterozoic siliciclastic red beds and metamorphic basement with graphitic metapelite and radiogenic granite. ?Pitchblende fills extensional features in reactivated fault zones and replaces matrix in sandstone ?One mining district in Canada ?the Athabasca Basin ->30 deposits /prospects -most in eastern ¼of basin -produces 1/3 of world?s U -employs northerners -VERY high tech -VERY high safety standards Unconformity-associated uranium depositsUnconformity-deposits

May 1, 2006

By Charles A. Ashburner

At the Philadelphia meeting of the Institute, held in February, 1881,I had the honor of reading a paper on "A New Method of Mapping the Anthracite Coal Fields of Pennsylvania."* At that time the State appropriation for the Second Geological Survey had just expired, and, as a new appropriation was not assured, no detailed plan had been adopted by Professor Lesley, State Geologist, for the practical examination of the mines, and the solution of the geological structure of special localities, or the representation in sections, vertical and columnar, of the general structure of the coal basins and coal beds. I had merely proposed a plan of mapping, as the material for the construction of maps was most available, and it was at that time uncertain what money the Survey would have to enable it to extend the surface and underground explorations, in order to make the examinations complete. After a continuation of the Survey was authorized until January, 1884, by the legislature, in May, 1881, the Anthracite Survey was regularly organized, and a plan adopted for a systematic and exhaustive geological and mine examination of the region. This plan provided for such work, other than that of mapping, as was necessary for a complete and practical geological and mining survey of a coal field. To do any geological work, of however general a character, it was absolutely. necessary that the members of the Survey Corps should obtain unrestricted access to all the mining records of the operators, which have been made with great care and accuracy and at an enormous expense during the past thirty years and more. The unanimous and generous support of the individual and corporate coal operators, of the plan of carrying on the Survey, was promptly assured, on condition that the results should be of such a character as to render them of practical utility to the property-owners and those directly interested. It was hoped

Jan 1, 1883

By Persifor Frazer

The '(author's edition" of the following paper, "subject to re vision," was received by him, and copies sent to Professor Geikie and others about two weeks before the date of the meeting at which it was to be read. A telegram, and subsequently a letter (both of which unfortunately arrived too late), apprised the present writer that the Director General objected to certain views ascribed to him as the reverse of those which he really held. These views, however interesting, had no very important bearing on the object of the fol lowing notes, which, as must be evident, are devoted to the conside ration of the close analogies between the Welsh and American rocks. Without being able, therefore, to account for the circumstance which Professor Geikie has mentioned, it is thought better in the present revised edition to omit all allusion to Professor Geikie, or Mr. Peach, or their views, except in this place, where I desire to thank them for their courtesy during the time which I had the pleasure of spending in their society. It appears sufficiently throughout the body of the paper that the writer had not the slightest intention of entering the controversy, which was about to commence, concerning the proper horizons of the St. David's rocks, for many reasons; and amongst others because he did not feel that a sojourn of a few days in a difficult region, which had been already studied by many of the foremost geologists of England, would warrant him in adding to the literature on the sub ject. The discussion of the analogies between these rocks and those of the Eastern Appalachians, which he has studied for twelve years, of which eight were spent in the service of the Second Geological Survey of Pennsylvania, was much more to his taste as it was more within his ability, and if he has added anything to the evidence of these analogies, the paper, however imperfect, will not have been written entirely in vain. Right or wrong, he assumes the entire responsibility of what follows.

Jan 1, 1883

CONCLUSIONS: Our experience, where we attempt to remove a continuous face with a seam more than six and one-half feet in thickness, has been rather disastrous. We have been able to open up faces and retreat for a distance of 75 to 100 feet in this particular character of coal, but after the supporting timbers have been removed for the second or third time we have found that the roof has a tendency to ride over the props and break off at the face of the coal support. However, where our coal is below six and one-half feet in thickness we have had very good success in handling the roof and breaking it off systematically with our break line of props, which are usually from 12 to 15 feet from the face of the coal. Our practice in to set props at about two-foot intervals in each direction and remove two sets of props, at the same time two additional sets are placed along the coal face. At all times we are very insistent that all props be removed from the gob and that entire coal be taken out so that it is possible for the roof to break freely and all come down, not having any supporting pillars in the gob. The conclusion of our experiments to date is that if all the supports beyond the breaking line of props are taken out as the long face retreats and the closer the breaking line of props is kept to the face the better the results will be. We have never felt it safe to have less than four rows of props to protect the machinery and men working along the coal face. We feel that the time element as to the rapidity with which these faces are advanced or retreated, is of vast importance, but to date have not had an opportunity or experience enough to reach any conclusion as to what time element is proper here with us. We feel that the crushing strength of the overlying strata will govern this to a large extent, and as ours varies considerably, it is going to he very difficult for us to reach a definite conclusion. My opinion is, that conditions may be such that rather than have a short face and retreat rapidly, it will be found that a longer facewith a slower retreat will work out better. Such a condition might give the overlying strata time to settle. The caving of roof or of control of this caving, with us, is quite closely associated with the ventilation. We find that the places where the strata overlying the coal are composed of shale, that the effect of the air on this is of very great importance. It is our endeavor, at all times, not only to remove obnoxious gases, but to keep a current of fresh air moving along the face and, of course, a portion of this travels over the gob and comes in contact with the roof and overlying strata. This, we find, helps materially in keeping the roof on the move. As it is our practice to keep water for sprinkling purposes at all places, we also use this water to keep the roof wet back in the gob. The effect of water on the shale is to cause it to disintegrate quite rapidly. MR. HOLMAN (Concluding): If there are any questions about this, I will be glad to answer them. I have some prints and also some pictures of the scraper loader and the shaking conveyors (distributes.) PRESIDENT MOSES: We wish to thank you, Mr. Holman, and also wish that you would thank Mr. Dupont for his paper. Are there any discussions? Do you wish to ask Mr. Holman any questions? (No response.) PRESIDENT MOSES: Mr. Holman, I would like to ask you how you take the photographs; were they taken by flashlight, or were globes used, or how were they taken, in a gaseous mine? MR. HOLMAN: Our mines being gaseous, we do not use the ordinary flashlight for taking underground photographs, but we have had considerable success, I think, with underground pictures by means of electric lights. We use 250 watt globes. We have six of these rigged up with tin reflectors, 18 inches in diameter, on standards, and we carry two or three hundred feet of wire connected with these six lights, and they can be turned on in the room where we take the photograph, by means of this extra wire. We set the kodak up and arrange the picture and take a long time-exposure. We usually take an

Jan 1, 1926

By J. T. Eash, E. M. Wise

In a previous communication1 the improvement in slrength, harden-ability and color, occasioned by replacing gold in a typical gold-silver-copper alloy by various amounts of platinum, or palladium, was discussed. In the present paper the results of further studies upon the constitution and the nature of the hardening transformation in these alloys are presented. This research may be summarized as follows: 1. The liquidus and solidus have been determined for the alloys of the palladium and platinum series. Cooling curves were utilized for determining the liquidus of the palladium alloys but this method proved unsuitable for the platinum alloys so that a novel quenching method was utilized for the latter. Both the liquidus and solidus of the palladium alloys increase steadily with the palladium content. The liquidus of the platinum alloys increases rapidly with the platinum content, while the solidus temperature increases with the platinum content up to about 14 atomic per cent platinum, but suffers no further increase with additional increments of platinum up to 20 atomic per cent at least, owing to a peritectic reaction. 2. Palladium, and even more effectively platinum, reduces the rate of grain growth. Owing to this fact and to the increase in the solidus temperature, "overheating" does little or no damage to alloys containing reasonable quantities of these elements. This is confirmed both by tensile tests and metallographic examination. 3. The excess phase present in one of the high-platinum-content alloys has been isolated and chemically analyzed and was found to consist almost wholly of platinum, gold, and copper, evidently derived from the compound AuCu, by the partial replacement of gold by platinum. 4. The variation in the solubility of this platinum-content phase in the alpha solid solution with the temperature has been determined. This

Jan 1, 1933

By J. P. Kimball

INCIDENTAL to a description of the hytlrographical basin of the Quemahoning in Somerset county, Pa., as a coal-field, I have, without a personal survey of the whole county, taken the pains to collate a synopsis of' leading facts, so car as available, relating to its coal resources. This is here presented, in view of an interest in the subject, growing out of a nearly central traverse of the county, in common with the southern tier of counties of the State, west of Blue mountain, by a new trunk line of railway—the South Pennsylvania. The political east-and-west boundaries of Somerset county, Pa., following the bold topography of Allegheny mountain and Laurel hill, are in common with the east-and-west boundaries of the First Bituminous Coal-basin formed by these ridges respectively, except the southeastern townships which lie on the eastern slope of Allegheny mountain. The nearly parallel anticlinals of Negro mountain and the so-called Viaduct axis stratigraphically divide the basin into three sub-basins, which, in order from east to west, are known as follows, viz. : I. Berlin-Salisbury (Eustern) Sub-basin : Between Allegheny mountain and Negro mountain, embracing the Berlin section of Barren coal-measures, the Salisbury section of Upper Productive coal-measures, and the Meyersdale and Garrett sections of Lower Productive coal-measures. 11. Somerset (Middle) Sub-basin: Between Kegro mauntain and the Viaduct axis, so called from the viaduct on the Conemaugh river, which there crosses it; embracing the section of Lower Productive measures of Mineral Point and Casselman on Castlenlan river, and of Somerset. 111. Johnstown- Confluence (Western) Sub-basin: Between the Viaduct stratigraphical sub-axis (which is less strongly marked topograpically in Somerset county as a ridge than in Cambria county), and the Laurel Hill graud axis. The synclinal of this sub-basin is crossed by tile Conemaugh near Johnstown, and by the Castleman

Jan 1, 1884

By E. V. Potter

For a nurnber of years, it has been known that manganese made by electro-deposition under certain conditions is ductile while under other conditions it is very brittle. The ductile metal is gamma manganese normally stable only between 1100 and 1138°C1; the brittle metal is alpha manganese, stable up to 727OC. The ductile metal is not stable, but gradually changes to the brittle form; the time required to complete the transfornlation is about 20 days at room temperature. Other observations have indicated that the transformation is completed in 10 to 15 min. at about 125°C, while at — 10°C, no appreciable change occurs in 9 months. The properties of gainma and alpha Illanganese in the pure state are ordinarilj difficult to determine because the gamma structure cannot be retained by normal quenching procedures and alpha manganese is so brittle, it is difficult to obtain specimens free from flaws. In a recent investigation2 some properties of gamma and alpha manganese were determined by studying the ductile electrolytic metal and determining the changes in its properties as it transformed to the brittle alpha form. These investigations provided an excellent opportunity for following the progress of the transition and studying its mechanism. The results of a series of such investigations are reported in this paper. Procedure Various properties of manganese were determined starting with the metal in the original ductile gamma form and following the subsequent changes in its properties as the metal transformed to the brittle alpha form. These observations were made at various temperatures, the data providing information regartling the mechanism of the transformation as well as the effect of temperature 011 the transition rate. Structure and resistivity values gave the most significant results, so this paper is concerned primarily with them. The structure was studied microscopically as well as by X ray diffraction. The resistivity was determined on strips of the metal by measuring the potential drop across a given length of the specimen. Current was passed through the specimen by wires soldered to its ends, and the potential connections were made by wires looped around the specimen near its center. The current was determined by the potential drop across a standard resistor connected in series with the specimen, the potential drop being measured on a potentiometer. In the temperature range from room temperature to 100°C an ordinary drying oven was used to heat the specimen. This was entirely satisfactory except at 100°C, where the time required to heat the specimen was long compared to the transition time, making the initial section of the resistivity curve unsatisfactory. To overcome this limitation, at 100°C and higher a thermostatically controlled oil bath was used to heat the specimens. The block on which the specimen was mountetl was plunged into the hot oil at the start of each test. The heating time was thereby reduced from 5 min. to about 6 sec, and dependable resistivity values could be obtained through 160°C. At this point the whole transition, including the warm-up time for the specimen, required only about 20 sec and it was not considered worth while trying to extend the temperature range further. Aside from the heating problem, the problem of making a sufficient number of accurate resistivity determinations became more and more difficult as the temperature was raised. Using the manually operated potentiometer, 100°C was about as far as it was possible to go. At this temperature and above, a self-balancing photoelectric recording potentiometer was used. Its response was quite rapid, and it proved to be entirely satisfactory all the way through 160°C, where the tests were stopped because of the specimen heating problem rather than any limitation of the potentiometer recorder. The metal used in these tests was prepared at the Salt Lake City laboratory of the Bureau of Mines. The method of preparation is discussed in a paper by Schlain and Prater.3 The sheets were about 2 3/8 by 5 3/16 in. and varied from 10 to 16 mils in thickness. They could be cut readily into pieces suitable for the various tests. X ray and microstructure determinations were made on pieces about 1/8 to 1/4 in. wide and about 1 in. long, while resistivity measurements were made on strips as long as possible and about 55 in. wide. The thickness of each sheet was not uniform over all its surface. This had no bearing on the X ray and microstructure determinations, but sections as nearly uniform and free from flaws as possible were chosen for the resistivity determinations. The gamma manganese was electro-deposited at 30°C, the time of deposition ranging from 5 to 12 hr for each sheet. Whenever possible, the tests were started directly after the metal was stripped from the cathode; otherwise the sheet was placed immediately

Jan 1, 1950

By A. LA. Salama, D. B. Hyma

"The Western Research Centre (WRC) of CANMET located in Devon, Alberta, is a modern research facility offering services ranging from fundamental research to pilot plant investigations. Recently, a 0. 76 metre diameter by 7.9 metre high Flotaire column flotation cell was installed as a demonstration unit for Canadian coal producers. Because the column cell is intended to be used for research, development and demonstration, WRC recognized that additional sensing equipment and improved process control would be required to generate good data for subsequent column scale-up and engineering design.A low cost, personal computer based control system was, therefore, designed and installed. This paper describes the stepwise procedure in developing the control strategies, selection of system software and hardware, and installation and configuration of the system.Preliminary performance data on a western Canadian coal sample are also presented. Future testwork is planned on additional coal samples to expand upon existing database."

Jan 1, 1993

By M. Tokumasu, T. Mutoh, Y. Sugawara

"In October 1986, a process computer was introduced in order to achieve an optimum combustion of pulverized coal at the reverberatory furnaces. The secondary combustion air volume is controlled based on the nitrogen oxide concentration of the off-gas from the reverberatory furnaces. The carbon monoxide concentration has strong relation with the concentration of nitrogen oxide under the situation of using alternative fuels, such as chipped tires and p,ulverized coal. Using this computer aided combustion control system, both nitrogen oxide and carbon monoxide concentrations were stabilized and conventional monitoring and controlling apparatuses were absorbed into this computer system. Due to this easily operated system, labor cost was reduced and the operation of the reverberatory furnaces and the off-gas treatment plant became stable.IntroductionOnahama Smelter and Refinery started its operation in April 1965 as a large scale copper smelter and refinery in Japan. The green charged reverberatory furnaces were introduced and bunker C oil was chosen as the fuel for the reverberatory furnaces. After the oil crises, Onahama was forced to use cheaper fuels such as coal and waste tires, i.e., alternative fuels instead of the expensive oil. As the amount of the alternative fuels fed to the reverberatory furnaces increased, the concentrations of nitrogen oxide and carbon monoxide in the off-gas became unstable. Consequently, the fluctuation of the combustion condition became not to be negligible in view point of a combustion efficiency and pollution regulations. A process computer has been introduced to overcome these off-gas troubles and to reduce the operating cost of the smelter.Outline of Operation HistoryInitially, the operation started by one reverberatory furnace and then the capacity was expanded almost twice by additional furnace in December 1972. As shown in Figure I, the smelting throughput was depressed after oil crises in 1973 and 1978. From 1983 to 1985, some copper mines stopped their operations because of low price of copper metal. During this period, Onahama suffered from the shortage of concentrate production levels were depressed."

Jan 1, 1989

A review of the most widely used global extraction sequences in sublevel is undertaken. The review includes techniques used to extract massive as well as single or multiple steeply dipping tabular orebodies. The paper also deals with thick flat lying orebodies suitable for open stoping. Techniques used to minimise the effect of stress redistributions on a global scale are discussed for all the extraction sequences analysed.

Jan 1, 2003

By J. Andres, M. Cross

"Freeport-McMoRan’s Sierrita operations has two natural gas-fired molybdenum roasters for converting molybdenum disulfide into molybdenum trioxide. When these roasters were compared to other similar units within the company during a benchmarking exercise, it showed that increased throughput from the roaster units at Sierrita was possible. A team of site metallurgists, technical experts from other sites, and engineers from the Climax Technology Center was formed to study the potential in more detail. The team investigated many parameters in the roaster, including temperature profiles, roaster chemistry profiles, rabble and drop hole patterns, and operational strategies. The results of these studies and the associated throughput improvements are described in this paper. INTRODUCTION Molybdenum, a vital component for the steel industry, is typically found in nature as molybdenum disulfide (MoS2). MoS2 is typically recovered via flotation processes and is purified through leaching processes. While molybdenum disulfide is a commercial product, it is not the form of molybdenum that the steel industry requires. They require molybdenum in the form of molybdenum trioxide, MoO3. There are multiple ways to refine molybdenum disulfide into molybdenum trioxide. The primary method is the oxidation of molybdenum disulfide in a multiple hearth roaster. The chemistry of converting molybdenum disulfide to molybdenum trioxide is very favorable at increased temperatures, oxidizing the molybdenum through a range of exothermic reactions to ultimately produce MoO3. The chemical reactions that occur in molydenum roasting occur in three zones. These three zones correspond with four different reactions."

Jan 1, 2015

By B. W. Howlett, M. B. Bever, Somnath Misra

The heats of Formation of the compounds Sb2Se3, Bi2Se3, Sb2Te3, and Bi2Te3 and the heats of solution of tellurium and selenium in liquid bismuth have been measured in a liquid metal solution calorimeter. The heat capacities near the melting point, the heats of fusion, and the melting points of the two tellurides have been measured in a constant temperature gradient calorimeter. The thermo-dynamic quantities are interpreted in relation to the stability of the compounds and the nature of the solid-liquid transition. THE selenides and tellurides of several elements of Group VB of the periodic system are of interest because of their electronic properties. The compounds Sb2Se3, Bi2Se3, Sb2Te3, and Bi2Te3 are semi- conductors; they also have gained prominence in the fields of thermoelectricity and photoconductivity. However, little is known about their thermody-namic properties. As part of a research program on the thermo-dynamic properties of intermetallic compounds, the heats of formation of the compounds Sb2Se3, Bi2Se3, Sb2Te3, and Bi2Te3 were measured in a liquid metal solution calorimeter. The heat capacities near the melting point, the heats of fusion, and the melting points of the two tellurides were measured in a constant temperature gradient calorimeter. The results, in addition to their intrinsic interest as thermodynamic quantities, contribute to an understanding of the stability of the compounds and the nature of the solid-liquid transition. 1) EXPERIMENTAL 1.1) Materials. Samples of the compounds SbzSe3 and Bi2Se3 were prepared by melting the elements in stoichiometric proportions in evacuated Vycor capsules followed by quenchinn in water. They- were then annealed in vacuum for 12 hr at 550°C. A sample of Sb2Te3, consisting mainly of one large grain, supplied by the Lincoln Laboratory,

Jan 1, 1964

By James M. Barker

Sulfur is a nonmetallic element of great physical and economic importance to the world. It is widely but sparingly distributed throughout the hydrosphere, lithosphere, and biosphere. Sulfur is the tenth most abundant element in the universe and eighth most abundant in the sun. In the earth's crust, which is mainly igneous, it ranks 14th, but is eighth or ninth in sediments (Kaplan, 1972; Stanton, 1972). It apparently is very abundant in the core of the earth, because it is a strong chalcophile, and it is fifth in abundance in stony and iron meteorites (Field, 1972) where it occurs as trolite (FeS). In ancient times sulfur was called brimstone, literally "burning stone." Today the term brimstone is used interchangeably with the term elemental sulfur. Shelton (1979) summarized most of the common definitions of terms, grades, and specifications for the sulfur industry as follows (with minor additions): Sources of Sulfur: Combined sulfur-Sulfur that occurs in nature combined with other elements. Cupriferous pyrites-Pyrite containing relatively minor amounts of copper sulfide minerals. Hydrogen sulfide-A toxic gas (H2S) occurring in natural gas and petroleum. Involuntary sulfur-Sulfur produced primarily as a result of legislative or process mandates. Native sulfur-Sulfur that occurs in nature in the elemental (uncombined) form. Nonferrous metal sulfides-Copper, lead, zinc, nickel, and molybdenum sulfides that are processed for their metal content. Organic sulfurs-Complex organic sulfur compounds occurring in petroleum, coal, oil shale, and tar sands. Pyrites-Iron sulfide minerals that include pyrite, marcasite, and pyrrhotite. Sulfate sulfurs-Sulfur in anhydrite and gypsum. Voluntary sulfur-Sulfur produced in response to market forces. Basic Sulfur Products Produced and Marketed: Acid sludge-Contaminated sulfuric acid usually returned to acid plants for reconstitution. Brimstone-Synonymous with crude sulfur. Bright sulfur-Crude sulfur free of discoloring impurities and bright yellow in color. Broken sulfur-Solid crude sulfur crushed to -8 in. Byproduct sulfuric acid--Sulfuric acid produced as a byproduct of a metallurgical or industrial process, generally relating to combined sulfur sources. Crude sulfur-Commercial nomenclature for elemental sulfur. Dark sulfur-Crude sulfur discolored by minor quantities of hydrocarbons ranging up to 0.3 % carbon content. Elemental sulfur-Processed sulfur in the elemental form produced from native sulfur or combined sulfur sources, generally with a minimum sulfur content of 99.5%. Formed sulfur-Elemental sulfur cast or pressed into particular shapes to enhance handling and to suppress dust generation and moisture retention. Frasch sulfur-Elemental sulfur produced from native sulfur sources by the Frasch mining process. Hydrogen sulfide-Associated with natural gas or petroleum and produced at refineries and coke oven plants; used to make sulfuric acid or recovered sulfur. Liquid sulfur-Synonymous with molten sulfur. Liquid sulfur dioxide-Purified sulfur dioxide compressed to the liquid phase. Molten sulfur-Crude sulfur in the molten phase.

Jan 1, 1983

Jan 1, 1953

Jan 1, 1953