Search Documents

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011

Esso-BHP have installed a Production Supervisory Control System that is presently controlling the offshore oil and gas facilities on the Barracouta and Marlin platforms from an onshore master station. This control is achieved with a computerized master station onshore which uses a UHF radio system for telemetry and control. The system is designed to control, monitor, and gather data from a large number of oil and gas production platforms and has flexability to handle future variations in operating conditions. Thn -etom ..ill kn nvt,,ndnd to thn I-lalihn+ rJ,+f, rr , Into +hie -- -A +n the lei...,fieh .,lo+fnrmc A.,;- 1071

Jan 1, 1970

By S. Afshar, E. Dajoux, C. Allaire

For various reasons, molten salts, mainly chlorides and fluorides, are used in the aluminum industry. In the holding and melting furnaces, these salts may have different roles such as protecting the metal from oxidation, reducing the metal content of the skim or removing inclusions or impurities from the metal bath. However, the use of these salts may also have some undesirable effects such as easy attack of the furnace lining refractory materials by molten aluminum. The aim of the present investigation was to clarify and to compare the effects of chloride versus fluoride salts, on the corrosion process of the aluminosilicate based refractory materials. A laboratory test and procedure, simulating the conditions at the metal line in the aluminum treatment furnaces, was used. Different aluminum alloys (A1-5wt.%Mg, A1-5.5wt.%Zn and 7075 alloy) and chloride or fluoride salts (MgC12, KC1, CaCl2, NaC1, MgF2, CaF2, NaF and cryolite) were used as well as several aluminosilicate materials. Thermogravimetric measurements were also carried out in order to analyze the effect of the salts on the oxidation of molten aluminum alloys. The experimental results showed that fluoride salts are more aggressive than chlorides against the tested refractory products. It is postulated that the fluorides prevent the formation of a protective oxide layer on the metal surface, favoring at the same time the corrosion of refractories. Moreover, it was found that the presence of Na in fluoride salts increases significantly the aggressiveness of the aluminum alloy towards the refractory samples.

Jan 1, 2004

By M Haydon

How do you portray a large structurally and stratigraphically complex deposit to return a meaningful resource estimation, and produce a geological model that is useable for planning on a daily basis? The George Fisher Mine is located 22 km north of Mount Isa and forms part of XstrataÆs Zinc Group operations. It is currently a major producer of zinc, lead and silver in the region with an estimated total resource for all categories of 127 Mt at 100g/t Ag, 5.3 per cent Pb and 9.2 per cent Zn (June 2005). Production in 2005 totalled 2 647 492 wet tonnes for 317 699 kg Ag, 140 317 tonnes Pb and 230 331 tonnes Zn from underground operations. George Fisher (GF) consists of two deposits that are structurally complex on a mine scale, George Fisher North (GFN) and George Fisher South (GFS). Regional faulting has resulted in a 2 km long package of variably pyritic shale and siltstone that separates the deposits. This paper looks specifically at GFN. Distinct correlations exist between the two deposits based on stratigraphic matches; however, orebody characteristics, geometry and fault architectures differ significantly between the two. The deposits consist of multiple, sedimentary-hosted, stratiform orebodies from 2 to 25 m wide, separated by waste intervals of variable width. Each ore-waste interval is modelled as an individual geological domain. Structurally, George Fisher North (GFN) contains a series of major late-stage NE faults with dextral offset(s) of up to 130 m. Further complexity is added by NS, NW and NNE striking fault orientations that can produce either a loss or repeat of stratigraphy, local drag folding, orebody attenuation and block rotation. Due to this structural complexity and orebody offsets, domains at GFN are further divided into fault blocks (FB). The GFN model comprises eight FBs over a strike length of 1 km, all of which are modelled independently. As drilling progresses and additional resources are converted, further FBs will be added at major fault offsets to accommodate orebody and model expansion. This will be in addition to what is already a large and time-consuming data set to manage and update. For example, each FB has 18 domains each with two constraining wireframes (hanging wall and footwall). Each wireframe has several sets of point data depending on the type of data available, ie diamond drilling, mapping or interpretation points. This equates to over 1100 separate files to manage. Additional wireframes and files are also required for major structures, daily planning requirements and block model runs. In total some 1500 files are managed, updated and maintained for GFN alone. The ongoing need to expand as a business and optimise production in the current economic climate where there is a global demand for metal has led to an increase in production at GF. This has resulted in a rapidly growing data set and highlights the importance of practical and efficient modelling to achieve a meaningful resource estimate. This paper focuses on the geological modelling, modelling approaches and techniques employed for the GFN deposit.

Jan 1, 2006

By R. Benemelis

The existence of resins in some coal deposits in various parts of the world has been known for many years. These resins vary considerably in chemical structure and properties. The resin that is found in Utah coal, however, is rather unique, and has properties particularly attractive for the manufacture of printing ink mastics and adhesives. This resin is a rather dark, very high melting point, low molecular weight hydrocarbon resin. Its typical properties are shown in Table I. Its largest use by far, has been in the printing ink industry. The history of Utah coal resin is interesting, but unfortunately one of disappointment and failure.

Jan 1, 1990

This study introduces a new probabilistic approach to seismic stability analysis of embankments and slopes. The approach is based on Sarma's solution, which is modified through presentation of the seismic force by its horizontal and vertical components; i.e. the force may have an arbitrary inclination. The probabilistic modelling includes Monte Carlo simulation of the shear strength parameters of the soil mass, which are assumed to have a normal distribution. The probability of failure is determined based on the seismic co-efficient, which is treated as a random quantity. The probabilistic approach is illustrated through a solution of a numerical example from an opencast coal Mine.

Jan 1, 1992

By Rossen A. Halatchev

This study introduces a new probabilistic approach to seismic stability analysis of embankments and slopes. The approach is based on Sarma's solution, which is modified through presentation of the seismic force by its horizontal and vertical components; i.e. the force may have an arbitrary inclination. The probabilistic modelling includes Monte Carlo simulation of the shear strength parameters of the soil mass, which are assumed to have a normal distribution. The probability of failure is determined based on the seismic co-efficient, which is treated as a random quantity. The probabilistic approach is illustrated through a solution of a numerical example from an opencast coal mine.

Jan 1, 1992

By Khamis Y. Haramy

Curing temperature, density, and moisture significantly affect the velocity measured in the crosshole sonic logging, the rate of strength gain, and the final strength of concrete in drilled shafts and, thereby, affect their structure capacities. Non-destructive field measurements can enhance the QA/QC program by measuring temperature, density, moisture, and sonic velocity of curing concrete during the construction and curing of drilled shafts. The curing environment can greatly affect the concrete strength, and requires close attention during construction. This article shares the experience with the NDE technology used in the QA/QC program in the drilled shaft construction. To understand the mechanism by which a drilled shaft cures under field conditions, two newly constructed drilled shafts were monitored for up to seven days, immediately following concrete placement using the following geophysical logging methods: a) temperature logging; b) crosshole sonic logging; c) gamma-gamma density logging; and d) neutron-moisture logging. One additional drilled shaft was also monitored to a shorter duration. Temperatures were monitored using the sensor in access tubes and/or thermocouples embedded at the center of a drilled shaft and near its reinforcing cage. For a small shaft under 1m diameter, curing temperatures appeared to peak at 41° ? 68° C at different depths at around 24-hour curing time and decreased to and stabilized at around 23° ? 35° C in 6 days. The shaft curing rate varied with depth, shaft diameter, surrounding geo-material types, and the depth of ground water. CSL logging was performed in one shaft from top to bottom from six access tubes and limited monitoring in another shaft. The velocity increased with curing time till 4 to 7 days, and, at a specific time, the velocity appeared to be inversely correlated to curing temperatures. The gamma-gamma density log (GDL) results from 5 different depths were obtained at a source-detector separation of 355 mm. The average density was found to increase with curing time, but decrease slightly in 3 to 5 days. At a given time the GDL density curves seemed to correlate with the neutron monitoring logging (NML) moisture curve. The NML moisture was monitored from 1st to 6th day after concrete placement. The moisture was highest when surrounded by bedrock, then clay, and sand due to different hydration rates.

Jan 1, 2007

By T. Yoshioka, Paul A. Beck

SILICON, germanium, and tin occur with both the white tine-type structure and the diamond cubic structure. In the latter form these elements are semiconductors; in the former they are metallic. The metallic form of germanium and silicon is obtained only under high pressure.' For all three elements the transition from the semiconductor to the metallic state is accompanied by a decrease in the atomic volume of somewhat more than 20 pctily2 Table I. At such a large compression the widening of the s and p bands is sufficient to make the energy gap of 1.1 ev, or less, of the semiconductor disappear, giving rise to the metallic state.*

Jan 1, 1965

By R. Bhima Rao

Performing a magnetizing roast in a furnace or kiln is a well-established technology. However, the use of microwave heat for the magnetization of hematite in the beneficiation of ferruginous bauxite is a new approach. This paper reports on an investigation of this procedure, which is followed by comminution and magnetic separation. The results of this investigation indicate that a nonmagnetic product containing 80% A1203 and 2.5% Fe203 with a recovery of 80% can be made from a crude bauxite ore containing 55.9% A1203 and 5.6% Fe203. This product is suitable for refractory use. The mechanism is explained by the ability of the microwave radiation to heat specific points within the bauxite. These heat-specific points are at the location of iron minerals. In a reduced atmosphere, the microwaves promote faster conversion of the iron minerals to a magnetic phase, which improves the magnetic-separation process.

Jan 1, 1997

By Louis A. Carapella, William E. Shaw

MAGNESIUM and its alloys have long been characterized as possessing limited capacity for mechanical forming at atmospheric temperatures prior to rupturing despite their outstanding performances in this respect at elevated temperatures. Responsible for this behavior are the fundamental facts that these hexagonal-type metals have comparatively few slip elements at low temperatures for any extensive deformation and that, at high temperatures, additional slip elements become operative, thus enhancing greater plasticity under strain. The transitional point has been set at 225°C by Schmid1 for single crystals, and at 250°°C by Morell and Hanawalt2 for extruded magnesium metal. In a recent X-ray investigation on polycrystalline magnesium-alloy sheets, Barrett and Haller3 have revealed that, below the transitional temperature, the initial plastic deformation proceeds mostly by a twinning action; that, above such a temperature, the action is mostly by slip. The deep-drawing performance of the magnesium + 1.5 pct alloy sheett over a wide range of temperatures has been investigated by Weber and Vanden Berg,' and their results are presented in Fig r. It should be noted from this work that a maximum drawability of about 25 pct at room temperature has been obtained on this alloy under the conventional deep-drawing operations. For the same alloy, it is now possible to augment the cold drawability to about 40 pct by a process to be disclosed. Hitherto, this value has been obtained only by deep-drawing the alloy at around 230°C. That greater plastic flow is attainable at atmospheric temperatures on magnesium under certain deformational techniques was discovered by the authors6 in their analyses of plastic-deformational behaviors of pure magnesium. This fact is best illustrated in Fig 2 from the Hargreaves analysis6 performed by the authors under two different modes of loading. For direct test, a separate unstrained specimen was used for each load duration, whereas for the integrated test the same specimen was employed for all the five intermittent loadings so that the load duration was made additive throughout the investigation. The higher plastic flow-rate at room temperature, as designated by the Hargreaves constant S, was obtained by the integrated or intermittent loading procedure. The authors5 in further tests showed that, under such a procedure greater plastic flow was also realized with a progressive increase in deformational loads. These findings have been applied

Jan 1, 1947

By C. Doyle, J. Brennan, C. Díaz, J. Hrepic, K. Cushnie

"In 1991/1992, INCO undertook a successful R&D program aimed at extending the lining lives of the top blown rotary converters (TBRCs)at its Copper Cliff Nickel Refinery (CCNR) and the electric furnace at INMETCO. At the laboratory scale, this effort was divided into three phases. In the first part, mineralogical work was performed on six refractories that were either currently being used to line these vessels or were considered suitable alternatives. In the second part, this mineralogical knowledge was used to help determine the compositions of slags that would not corrode the bricks at the operating temperature (1600°C) of the above furnaces. Finally, several important properties of the six refractories were measured to complete their evaluation as candidate linings. This paper reports the results of all three phases of the laboratory scale R&D work.The mineralogical work showed that rebonded fused grain magnesite-chrome (RFG-MC) bricks consist principally of periclase with minor amounts of free chromite and trace quantities of silicates monticellite and sometimes olivine. The bricks are principally held together by periclase-periclase direct bonding. Of note, the bulk of the chromite exists as exsolved precipitated blebs within the periclase grains. These likely redissolve at high temperature.Slags on the periclase liquidus coexist stably with these refractories. Examples are presented using CaO-MgO-Al2O3-SiO2 slags at~1600°C.Finally, the two refractories manufactured using close to 100% fused grain material generally outperformed the others in terms of physical properties and certainly were superior in their resistance to slag penetration damage."

Jan 1, 1997

By J. A. Luppens

Five years ago, Phillips Coal Company decided replacing mainframe/workstation programs with a new package of PC software was clearly the best solution for computer reserve modelling. The system chosen was actually three programs distinguished by their power, cost, flexibility and integration, and ease of learning and use. Phase I involves the use of the "StratiFact" program for borehole data management and seam correlation. This phase is probably the most neglected, yet critical aspect of reserve evaluation. Phase II employs the "PC/Cores" package for modelling and volumetrics. Phase m is "PC-Cut" which provides mine planning tools including an automated cut generator.

Jan 1, 1996

By Joseph A. Kantor

Several wall rock porphyry or pyrometascmatic copper deposits occur within the metamorphosed Paleozoic formations along the northern and eastern flanks of the Little Dragoon Mountains. Rocks ranging in age from Precambrian to Recent occur in the area. The Tertiary age Texas Canyon Quartz Monzonite intruded the sedimentary section in the eastern half of the range metamorphosing the Paleozoic carbonate units to tactites composed of garnet, diopside, and tremolite. Copper, zinc, and molybdenum minerals deposited in sites which are structurally controlled and stratigraphically favorable. Because the deposits are covered by alluvium, the information on structure, alteration, and mineralization is based upon a study of the diamond drilling programs. The mineralized district can be divided into four areas: 1) The Johnson Camp copper-zinc deposits; 2) The Dragoon copper deposit; 3) The I-10 copper-molybdenum deposit; 4) The Strong & Harris copper-zinc deposit. On the southwest end of the range beneath alluvial cover, the Cretaceous Bisbee Group was thrust over Precambrian and Paleozoic formations. The Tertiary Texas Canyon Quartz Monzonite intruded and metamorphosed them. In the upper plate, the Cretaceous sediments near the intrusive were metamorphosed to metaquartzite and andalusite and sillimanite schists. In the lower plate the Martin and Horquilla formations were marbleized. The lower Abrigo was metamorphosed to epidote rich calc-silicate tactites and biotite hornfels. A composite geologic cross section, based upon diamond drilling,, through the Dragoon copper deposit is shown in Fig. 1. The geologic events which formed this deposit are: 1. A faulted section of Precambrian Pioneer formation and diabase and Cambrian Bolsa and Abrigo formations was thrust over Pennsylvanian Horquilla formation. The Dripping Spring quartzite if present, has not

Jan 1, 1977

By Walter von der Linden

A description is presented of the mining conditions of four longwall shield type support installations in the Pittsburgh seam in northern West Virginia and southwestern Pennsylvania. Details of roof control and operating procedures, production and performance data, and equipment description and basic engineering specifications are given for these four longwall installations. The range of mining heights was between 150 and 250 cm (60 and 95 in.). The major accomplishment of the shield supports in all four faces was the provision of an almost 100% availability for coal cutting; i.e., the face-down time due to roof control problems and support maintenance requirements was minimal.

Jan 1, 1978

By Wiraseranee. Chompunoot, Kazuki Morita, Toru H. Okabe

"Aiming at the development of more effective recycling processes, dissolution behavior of rhodium into molten slag was investigated. Using a pure rhodium crucible and Na2O-SiO2 slag system, equilibration experiments were carried out for 18 h at 1423-1623 K under various oxygen partial pressures of 0.005-1 atm with varied slag basicity. Rhodium solubility increased with increasing oxygen potential, slag basicity, and temperature. Rhodium dissolved into slag as rhodate ion ([RhO2]-) by the endothermic reaction: Rh(s) + 3/4O2(g) + 1/2O2-(in slag) = [RhO2]-(in slag). In the dissolution reaction, the “rhodate capacity” of slag is newly-defined. The correlation between rhodate capacity and optical basicity is reported.IntroductionDue to its high chemical resistance and outstanding catalytic properties, rhodium (Rh), one of the platinum group metals (PGMs), is utilized in various applications such as catalysts, molten glass vessels and containers, and electronic devices. Owing to the rarity of Rh resources in nature, recycled Rh from scraps such as spent automobile catalytic converters is currently considered as an important source of Rh supply [1]. According to the recycling practices, Rh is currently mainly recovered from scraps along with other PGMs such as platinum (Pt) and palladium (Pd) by a dry process (e.g., smelting), a wet process (e.g., leaching and subsequent separation of PGMs from aqueous solution), or a combination of both processes [2]-[4]. Among these processes, smelting is commonly applied because PGMs can be effectively separated from a relatively large amount of various impurities coexisting in scraps. In the smelting process, Rh and other PGMs are collected in the collector metal (e.g., iron and copper), and impurities in scraps are removed into slag [4]-[6]. The process may be carried out at a temperature range of 1573-1973 K, in either an oxidizing or reducing atmosphere. Due to the high oxidation resistance at high temperatures, Rh is expected to be collected efficiently in the metal collector rather than being oxidized and forming RhOx in a molten slag. However, Rh loss into slag does occur in this process [7]."

Jan 1, 2011

By William L. Crentz

Late in the nineteenth century en active coal-mining industry was begun in the Lower Freeport bed near Reynoldsville, Pa., where the bed thickened to more than 10 feet in places . The coal was readily accepted as an excellent steam fuel. Much of the thick coal his been depleted, but there are many areas where the deposit averages about 14 feet in thickness. As the more desirable mining sites were worked out in the Lower Freeport bed, other beds were exposed from which will come the county's major cowl production in future. The Lower Freeport bed is still the most important bed in Jefferson County from a production standpoint. The Lower Kittanning bed is second. Sporadic mining is being done in the Upper Freeport, Upper Kittanning, Middle Kittanning, Clarion, and Brookville beds. Strip mining has permitted recovery of much coal that could not be mined profitably by conventional underground methods.

Jan 1, 1953

By Vincent Castranova, Jane Y. C. Ma, Joseph K. H. Ma, Chang-geng Mo, Carl J. Malanga

"A group of bisbenzylisoouinoline alkaloids has been shown to exhibit various degrees of effectiveness in preventing silica-induced fibrosis in animal models [1, 2]. The objective the present study was to characterize the binding of several of these alkaloids to phosphatidylcholine vesicles and rat alveolar macrophages using fluorometric and equilibrium dialysis methods, respectively. The lipid binding affinity of these alkaloids was found to depend upon several structural factors including hydrophobic substitutions, chiral configurations, and double oxygen bridge-restricted conformation of the benzylisoquinoline moieties. Tetrandrine, which is a highly effective agent in preventing fibrosis, showed strong binding to both lipid vesicles and alveolar macrophages. In contrast, certain analogues of tetrandrine such as curine and tubocurine, which have little or no effect on silicosis, exhibited only weak binding to lipid vesicles and almost no binding to cells. The moderate binding affinity of fangchinoline to vesicles and cells corresponded to a moderate effectiveness of the compound as an antifibrogenic agent. Methoxyadiantifoline, an alkaloid of unknown antifibrogenic potential, also exhibited high binding affinities for lipid and cells. In conclusion, the results of these studies indicate that alveolar macrophages exhibit large binding capacities for certain members of this class of bisbenzylisoquinoline alkaloids. A positive correlation was observed between binding affinity to alveolar macrophages and the reported antifibrotic potency of these compounds. These data also suggest that the ability of these drugs to interact with alveolar macrophages may be a key step in inhibition of the progression of silica-induced pulmonary disease.INTRODUCTIONInhalation of crystalline silica is associated with the development of silicosis. This fibrotic disease is characterized by the appearance of concentric hyalinized nodular lesions in the lungs with the progressive development of pulmonary dysfunction [3, 4]. Many theories concerning the etiology of silicosis involve silica-induced activation of alveolar macrophages. Evidence indicates that in vitro silica exposures result in the generation of chemiluminescence, and the release of superoxide and hydrogen peroxide from alveolar macrophages [5]. Activation of alveolar macrophages has also been demonstrated after intratracheal instillation or inhalation of silica [5, 6]. Such excess release of reactive products from pulmonary phagocytes has been associated with damage to the lung parenchyma [7, 8]. In addition, silica exposure results in the release of mediators from alveolar macrophages, which enhance proliferation of fibroblasts and collagen synthesis by these pneumocytes [9-12]."

Mar 1, 1992

By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003

By Pragna N. H. Bhakta

The minerals industry is under political and economic pressure to reduce its processing wastes and minimize their impact on the environment: Recycling is one of the means by which the minerals Industry can reduce the quantities of effluents and residues that are discharged to the environment. The wise use of available resources is not only an environmental necessity but also an economic benefit as natural mineral resources are depleted and/or become more complex. The purpose of this paper is to review the technical and regulatory issues that will help shape the future of minerals recycling over the next ten years. Research and development to address technical issues will be discussed with emphasis on the Bureau of Mines recycling research program.

Jan 1, 1992