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By A. Siegmund, R. D. Prengaman

Lead anodes used in zinc electrowinning generally contain 0.5 - 1.0 % silver to reduce the rate of corrosion over the service life. For good quality zinc, the cathodes must contain less than 10 ppm lead. In order to reduce the lead contamination of the cathode, the lead anode must become coated with a protective layer of Pb02/Mn02. The formation of this layer may take as long as 30 - 60 days, during which time zinc production is substantially reduced and the cathodes are contaminated with lead. To improve the mechanical properties of Pb-Ag-anodes alloying elements such as calcium, strontium, barium and others are added. The production of cast lead-silver or lead-silver-calcium anodes often results in the formation of numerous holes, voids or laps in the anode surface that can initiate localized internal corrosion. Based on the experience as the major supplier of rolled anodes for copper electrowinning, RSR Technologies has developed an improved anode for zinc electrowinning. The anode consists of a rolled Pb- Ag-Ca-alloy with a controlled surface grain structure. It forms an adherent protective oxide coating within 2 - 3 days when placed in an electrowinning cell. The preferred calcium and silver contents of the alloy are 0.03 - 0.08 % and 0.3 - 0.4%, respectively. Rolling sheets significantly reduces the presence of internal porosity or laps. The lack of defects results in long anode life. The rolling also produces a uniform grain structure to which the corrosion product readily adheres, thus significantly reducing the conditioning period.

Jan 1, 2000

By J. `. Spitzinger

In situ recovery (ISR) of uranium alters the baseline groundwater geochemistry in order to mobilize and complex uranium to extract and concentrate it. ISR wellfield restoration is often challenging, and primarily relies on groundwater sweep, reinjection of treated permeate, and/or injection of reductants. Greater focus should be placed on injection-based approaches (using existing infrastructure) based on established engineering concepts used for in situ remediation of groundwater plumes. Such injection-based approaches could shorten restoration timeframes consequently reducing long-term operational costs. This paper addresses various types of injection-based approaches to wellfield restoration based on in-situ remediation success with other constituents that require similar treatment. This paper describes necessary design practices for injecting reactive chemicals (e.g., reductants or biostimulants), operations and maintenance (O&M) strategies to prevent fouling of the chemical delivery system and well network, and natural constraints to restoration. Best practices for successful biostimulation strategies that minimize residual uranium, radium, oxoanions, and other trace elements are as described. Advantages of such injection-based approaches could include significant reductions in restoration times, and consequently, lower restoration costs.

Feb 23, 2014

By Alvarez A. R, Garcia H. l

A fuzzy expert system, DIME, has been developed, under Matlab v 5.1. to assess the coal and gas outburst risk in underground mining. Expert systems and fuzzy logic are powerful tools to manage information represented by linguistic statements,

Jan 1, 1998

By A. D. Taylor

In recent years there has been an increasing effort to attract students into engineering. Obviously, the effort is necessary because young people find the image of the engineer unattractive. Some of the things they find unattractive are real, some are not, and part of the problem is too little knowledge of the field. First, I would like to comment on some of the ideas which appear to be justified. Engineering is a difficult course of study. True, and nothing can or should be done to change this. The education is continually being improved, but it is unlikely to be made easier.

Jan 1, 1970

By Kevin Phelps, Jason Baird, Philip Mulligan, Dominique Nolan

The basic metric for linear shaped charge performance is the amount of cutting distance that the charge can effectively yield given a specific standoff and target. Due to its size and restricted production runs the 10,500 grain/foot (2,232.25 grams/meter) linear shaped charge has had only limited studies that examine cutting performance and standoff. This article covers research regarding cutting performance verses standoff as the charge is applied to common structural steel. Specifically this study uses A36 mild carbon structural steel blocks of 10.16 cm by 11.80 cm by 35.56 cm and standoff distances of 0.5, 1.0, 1.5, and 2.0 charge diameters. Data presented includes the presentation of actual cutting performance numbers, comparison of that data to projected performance based on currently recognized industry guidelines, and a discussion of what may contribute to the performance found in this study.

Jan 1, 2013

By I. Dumitrescu

Since 1990, the entire Romanian mining industry has suffered a major restructuring, i.e. technical and economic. The large majority of the remaining active mines are these with a chance for economic comeback. This is also the case for the mines that belong to MINVEST Deva Company; most of the mines are closed, and are waiting to be reclaimed. The authors present the closing procedures of the former copper mining perimeters managed by MINVEST. It is well known that pollutants of concern for the environment must be monitored to obtain reliable information on the quality of ambient conditions and to minimize their impact on the environment. Consequently, the monitoring problems during the closing procedures will be presented.

Jan 1, 2008

By K. Mukai, M. Ishihara

This report is a brief discussion of the impurity levels both in primary aluminum and super-purily alnminim in connection with raw materials and proc-essing methods. Particularly, truce amounls of im-purities were analyzed by introducing nittss-speclro-gruphy and nenlron-aclivalian analysis techniques. Vanadium and gallium content in primary aluminum metal corresponded to theor amounls in anode coke. but the nickel content in primary aluminum was hide-pendent oj its amount in the anode cake. Sulfur in the anode colic might result in an increase of the iron content in the molten metal in the reduction cell. The content of sodium and calcium increased with increasing bath ratio. In the holding furnacc sodium content decreased rapidly, and nonmetallic inclusions merit separated front the mollen metal. Three-layer elctrolysis was effectire in eliminating many impuri-ties with the exception of copper, aluminum oxide. aluminum nitride, and some rare-earth elements. THE amount of impurities and nonmetallic inclusions in aluminum metal depends on impurities in the raw materials and various production processes. This paper presents an investigation of the behavior of impurities and nonmetallic inclusions in aluminum during the electrolysis process, the period in the holding furnace, and the process of three-layer electrolysis. Chemical analysis and emission spectrometric analysis have generally been used as methods to determine small amounts of impurities in both primary aluminum and super-purity aluminum; however. mass spectrography and neutron-activation analysis have been recently introduced into this field, and trace amounts of impurities can accurately be determined by these latter methods. EXPERIMENTAL WORK Common impurities were determined by means of absorptiometric. polarographic, flame-photometric. and emission-spectrometric methods. However, in the determination of trace amounts of impurities and non-metallic inclusions, the following methods were applied. In the analyses of trace impurities by mass-spec- trographic analysis, samples were exposed in the vacuum spark of double-focus ing Mattauch-Herzog type mass spectrograph (Japan Electron Optics Laboratory, Ltd.). Ilford Q2 photographic plates were used as ion detectors. Fe was used as the internal standard, and the atomic concentration of each element was calculated by the following expression and converted into the weight concentration: where E, and Ei are the exposures (coulomb) when isotopes of the internal standard and impurity elements (on which the estimate is based) show the same density, X is the percent (atomic) concentration of the standard, IF and Ii are the percent abundances of the isotopes of the standard the impurity elements (on which the estimate is based), and Ms and hfi are the mass of the isotopes of the standard and impurity elements (on which the estimate is based). The coefficient of variation in this method is about 40 pct in the range of 0.1 to 1 ppm. In neutron-activation analysis, irradiations were done in the nuclear reactors TRIGA-I1 (neutron flux: 4.7 x 10 11 n per sq cm per sec; Rikkyo University) or JRR-2 (neutron flux: 2 x 1013 n per sq cm per sec: Japan Atomic Energy Research Institute). After the chemical separation, a NaI (3 by 3 in.) scintillator connected to a 256-channel y-ray spectrometer (R.C.L.) was used for counting and recording various activated impurities. The coefficient of variation in this method is about 20 pct. In the analyses of nonmetallic inclusions, aluminum-oxide determination was carried out according to Fischer's method, 3 as follows. A slice of sample was cut off and the surface was cleaned. It was dissolved in bromine-methanol. The solution was filtered and the residue was washed. The residue was fused with potassium bisulfate flux. Then it was dissolved in weak acid, and oxine solution was added. The aluminum oxinate was extracted with benzene. Finally, aluminum was determined absorptio-metrically. Aluminum nitride determination was carried out as follows. A slice of sample was cut off and the surface was cleaned. It was put in the distillation apparatus and decomposed with sodium hydroxide solution. The solution was distilled. Then ammonia was absorbed and

Jan 1, 1967

By Cledwyn Mangunda

Mining operations generate Acid Mine Drainage (AMD) that poses a significant threat to the natural environment. AMD treatment using Ca(OH)2 leads to the precipitation of a sludge dominated by a mixture of ferri-oxyhydroxides. This sludge has poor dewatering tendencies and is deposited in landfills with potential for metal remobilization. This study investigated the dewatering behaviour of a precipitate formed during elevated temperature treatment of a primary, pre-settled sludge from the neutralisation of aqueous acidic Fe2(SO4)3 and Ca(OH)2 solutions in an MSMPR reactor. The resulting treated precipitates were analysed for micro-properties, with results showing that an increase in the secondary reactor temperature from 25 °C up to 50 °C led to an increase in mean particle size, a decrease in the number of particles and improved dewatering behaviour at a ferric concentration of 300 mg/L. This was ascribed to the attainment of a circum-neutral surface charge that favoured agglomeration and a change in micro and nano-structure that allowed for better water passage.

Discussion of the above paper by G. J. van JAARSVELDt Mr Ortlepp's paper is important, and deals with a subject towards which much controversy and insufficient basic scientific logic, in my opinion, have been directed. He attempts to remedy some of our unscientific popular misconceptions, and for this we thank him. However, I regret to say that experience has shown that some of his statements cannot be allowed to pass unchallenged. Author's reply Mr Van Jaarsveld's contribution is welcome because it provides an opportunity for me to clarify certain points that were perhaps not adequately explained in the paper.

Jan 1, 1979

By Cyril Stanley Smith

Although not of the same importance as electrical conductivity, the capacity for conducting heat is nevertheless a very important property of metals and alloys. A knowledge of thermal conductivity is of value in selecting alloys for many purposes and in the calculation of the efficiency of apparatus which is being designed. Unfortunately, the determination of thermal conductivity is extremely slow and tedious, consequently few data have been obtained. A further reason for the lack of information is that there has long been an impression that the thermal conductivity of an alloy is directly proportional to the electrical cónductivity and that it can therefore be calculated from the latter. The Wiedmann-Franz-Lorenz law of constant ratio of the two conductivities holds with a considerable degree of precision for all the pure metals, but appreciable deviations occur in certain alloys—particularly those containing nickel—and it seems difficult to predict exactly what the ratio will be. Therefore direct determinations of thermal conductivity should be made whenever the results are needed with any accuracy. This research is intended eventually to cover all the alloys of copper that are of commercial importance, including the binary alloys of copper with zinc, tin, aluminum, nickel, silicon, manganese, cadmium and phosphorus, and the ternary alloys copper-nickel-zinc, copper-nickel-silicon, copper-manganese-silicon, copper-zinc-tin, etc. Most of these alloys are customarily used in the wrought condition and therefore were tested in the form of annealed rods. A limited number of sand castings were also obtained and examined. This paper contains a complete review of all the previous work that has been done on copper alloys, and includes a detailed description of the apparatus and method of procedure used in the present research, together with the new results obtained on the copper-zinc series, which is the only one completed at the present time. Subsequent papers describing the other alloys will contain the experimental results and discussion only. Previous Work Copper The conductivity of copper has been studied by many observers since the pioneer work of Wiedemann in 1859. The majority of these measure-

Jan 1, 1930

By E. D. Goddard

There are similarities, and differences, in the surfactants used in cosmetics and detergents. In both applications anionic surfactants constitute the major category. Their main function is to clean, i.e. remove grease and particulate matter from fibrous or hard surface substrates. Cationic surfactants are used for conditioning substrates. Nonionic surfactants can function as a substrate cleanser but are seldom used as such in cosmetics; however, selected non-ionics are often employed as a primary emulsifier. Several specialized nonionic surfactants are used as a secondary surfactant in formulations to promote foaming and emulsification. Specific examples and modes of action of surfactants will be presented.

Jan 1, 1988

By Hans von Michaelis

Welcome to RANDOL GOLD FORUM 88. It is clear from the list of delegates and speakers that this conference will lead to excellent discussions of the latest developments in this fast-moving industry. Less than a year ago Randol International Ltd. published an eleven-volume report titled "Innovations in Gold and Silver Recovery - Phase 111". In the short space of time since then, many new developments have been noted, many of which will be described in this Forum. I believe that some of the more significant innovations currently under development are those that address the following:

Jan 1, 1998

By J. M. Hemstock, H. L. Ames

THESE forums have been held annually since they were introduced by Mr. L. E. Djingheuzian in 1957. The response of millmen to questionnaires such as the one this year is ample evidence of the interest these create. This year's topic is unlike those of past years since it is an attempt to understand a new concept of grinding rather than to improve the old. Before, we were thinking in terms of 2-5 cents improvement in grinding costs, now we will be discussing savings of 15-2 5 cents. As a background for this forum we will begin by summarizing the major controversial issues relating to grinding with steel, many of which will undoubtedly apply to pebble milling. Our •task to-day is to learn what has already been done in pebble milling and obtain a fair overall view of this method of grinding.

Jan 1, 1961

By M. G. Maruma, L. A. Mampuru

"Mill liner wear is a major cost item in the mining industry and there is continuous research to prolong the life of the liners. Over the years it has become apparent that even though high-chromium white cast irons are highly efficient as abrasion-resistant materials, a combination of wear resistance and fracture strength remains difficult to achieve. Increasing the hardness of the high-chrome white cast iron (HCWCI), which improves the resistance to abrasion wear, is often accompanied by a deterioration in fracture strength. Operational conditions inside the mill require that the liner should be made of highly wear-resistant material with some fracture strength. Vanadium additions ranging from 0.2 to 3 wt% were made to HCWCI in an attempt to refine the microstructure. It was found that an increase in vanadium content promotes grain refinement. A content of 1.5-3 wt% gave the best results as measured by the maximum breaking strength.IntroductionOver the years it has become apparent that even though high-chromium white cast irons are highly efficient abrasion-resistant material, a combination of excellent wear resistance and fracture strength remains difficult to achieve. The exceptional wear resistance of highchromium white cast iron (HCWCI) is attributed to hard chromium carbides embedded in an austenitic/martensitic/pearlitic matrix. When the chromium contents exceed 12 wt%, interconnected MC3-type carbides of conventional cast irons are replaced by rodshaped and isolated M7C3 carbides (Powell, 1980), leading to an improvement in the impact toughness, ductility and fatigue resistance. However, the main M7C3 carbides in HCWCI are hard and brittle and can provide an easy path for crack propagation. This limits the applications of HCWCI, particularly in severe impact conditions. Most operations involving HCWCI are in crushing and grinding and the life of a part/liner is limited by its wear resistance. However, improving the wear resistance of HWCI comes at the cost of a significant reduction in fracture strength. Concerns about premature failure of HCWCI mill liners in the mining industries prompted a study to improve the wear resistance and mechanical properties of HCWCI."

Jan 1, 2016

By W. A. D. Edwards

"The Edmonton region accounted for 40% of Alberta's sand and gravel production in 1981 (about 12 million m3). Most of this production was by commercial operations (75%) for use in essential public works projects (64% in road and asphalt production).Although the Alberta Geological Survey delineated 1157 million m3 of gravel, a number of areas are considered to be in short supply. An econometric model was used for forecast demand in the region. Predictions, based on this forecast and estimated supply, are that 15% of the region's gravel and 3% of the sand will be consumed by the year 2010.The City of Edmonton is the largest consumer of aggregate in the region. Approximately 40% of the gravel in Edmonton's current supply area (about 55 km radius) will be used by 2010. These estimates are considered optimistic because the supply figures do not account for sterilization of deposits - some has already taken place in the region. If 25% to 50% of Edmonton's current supplies (one major deposit) were sterilized it would result in $1,000 million of additional cost due to increased haulage alone.Information on the value of aggregate resources, the location of sand and gravel deposit s and forecast demand has been made available to all municipalities in the region to aid planners and regulators in effective future use of this important resource.INTRODUCTIONAlberta is the second largest producer of sand and gravel in Canada at ab out 50 million tonnes annually. Value of provincial production exceeded $120 million in 1985. In Albert a, aggregate is used primarily in road and building construction (about 50% and 15%, respectively) and is important in such activities as petroleum exploration, oil sands development and the forestry industry.The Edmonton region (Fig. I) accounts for about 40% of provincial production and has a per capita consumption rate of about 13.4 m3 of sand and gravel per annum. Although Edmonton dominates, with approximately 50% of regional production going into the city, aggregate is produced in every county and municipal district in the region.Sand and gravel is essential to the current way of life in the Edmonton region. The resource is valuable and dwindling. The Alberta Geological Survey (a department of the Alberta Research Council) has collected information on aggregate in this region for the last decade which ca n aid government planners and regulators in pre venting sterilization and misallocation of this critical resource. This paper is a summary of that information."

Jan 1, 1989

By J. A. Herbst, Y. C. Lo

This paper attempts to answer whether or not the mill performance at Bougainville could have, in fact, been predicted by the population balance approach, or whether other special considerations are required to explain their behavior. In recent studies, the plant tests were performed at Bougainville and batch tests were carried out at the Utah Comminution Center. In all tests power measurements were made and several levels of energy input to grinding were evaluated. Also, tracer tests were performed for mill residence time determination. The performance of Bougainville's 5.5x6.4-m mill has been very successfully predicted by population balance methods. The prediction errors are only about 1% on product size distribution and 4% on power with a mill volume scale-up of 3790:1. It is significant that this approach will reduce the risk of failure in large mill design that has been recognized in traditional methods.

Jan 1, 1987

By Richard A. Grieve

A 63.5 metric tons per hour (70 TPH) demonstration coal preparation plant was constructed on the Iowa State University campus, Ames, Iowa, as a part of the Iowa Coal Project funded by the state of Iowa and administered through the Energy and Minerals Resources Re-search Institute. Processing equipment in the plant circuit includes a heavy media separator, concentration tables, separating and dewatering screens, and conveying equipment. Coal samples of size 907 metric tons (1000 tons) with sulfur contents ranging from 2.5 to 8.75% sulfur from seven mines in the state of Iowa have been pro-cessed in the plant. Sulfur reductions have averaged 35%. With ash reduction averaging 45%. Equipment for advanced fine coal beneficiation research is currently being installed in the plant to include a slurry pretreatment circuit, froth flotation, oil agglomeration, pelletization, hydrocyclones, advanced design thickener and disc filtration.

Jan 1, 1978

By Yadong Xue, Fei Wang, Hongwei Huang, Yan Sun

"Increasing attention to subway tunnel maintenance is being paid with the high speed development of urban rail transit system in China. A novel moving tunnel inspection equipment based on machine vision is developed in this paper. High resolution image acquisition system is proposed for tunnel crack and leakage inspection. The main components of this image acquisition system includes high speed CCD cameras, linear lights and high performance computer. To inspect the crack less than 0.3mm with a 3-5km/h speed in subway tunnel, we need to consider resolution and line rate of camera, pixels of cameras, range of inspection and illumination intensity of lights simultaneously. The optimization design is proposed to make the equipment more convenient for tunnel use. Entire tunnel situation can be detected and recorded in a single inspection process. This equipment has already been verified in Shanghai subway tunnel for defects inspection.1. INTRODUCTION In China, the quantity of subway tunnel has reached a large scale in recent years. Until 2014, there had been more than 2300km of subway tunnel in China which accounted for nearly three quarters of Chinese urban railway system (Zhang Chen,2015). In some metropolises like Beijing and Shanghai, most of the metro tunnels has already run over 20 years which within maintenance phase. This has brought about plenty of inspection work and maintenance work to guarantee the tunnel under the serviceability limit states. The increase of running mileage of subway tunnels in China has been displayed in Fig 1."

Jan 1, 2016

PROFESSOR CECIL H. DESCH of Sheffield Univer-sity is to give the sixth annual Institute of Metals lecture in connection with the A. I. M. E. meeting in February. Professor Desch is well known to metallur-gists in this country not only from his books on metal-lography, intermetallic compounds, the physicist in metallurgy, and the chemistry and testing of cement, but also by his many published papers in the technical journals. Professor Desch is the third distinguished foreigner to lecture before the. Institute of Metals under its pro-gram which calls for an annual lecture by a distin-

Jan 1, 1927

By R. W. Balluffi, B. H. Alexander

RELATIVE diffusion rates of copper and zinc in a brass have been measured in a vapor-solid type of couple with which the amounts of copper and zinc diffusing past inert Kirkendall markers can be obtained by means of a few simple experimental measurements. If inert markers are placed on the surface of copper which is then exposed to zinc vapor from a brass chips, the particles become buried due to outward diffusion of the copper, as shown in Fig. 1. A schematic diagram of such a couple after diffusion is shown in Fig. 2. Consideration of the diffusion flow of copper and zinc shows that the entire hatched area, including the cross-hatched area, is proportional to the amount of zinc diffused inward past the markers and that the smaller cross-hatched area is proportional to the amount of copper diffused outward past the markers. These areas are completely determined by the expansion of the couple, the depth of the buried particles below the surface, and the chemical composition at the specimen surface. As Darken1 has shown, the ratio of diffusivities of copper and zinc is then given by the ratio of these two areas. Polycrystalline copper and two copper single-crystals made by the Bridgman method were prepared in the form of 1.5 cm diam disks approximately 0.5 cm thick with faces plane and parallel. Tungsten particles approximately 0.001 cm in diam were bonded to the surface of each disk by heating 5 hr at 1060°C in vacuo. Each specimen was next

Jan 1, 1953