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By E. H. Denny

In discussing safety in Colorado metal mines there are two important points for metal -mining men to consider , namely , the direct and indirect cost of accidents and the possibility and means of preventing accidents . For statistics on Colorado metal - mine accidents , reference has been made to published reports of the United States Bureau of Mines on metal- mine accidents from 1919 to 1927. This period was considered because only with the year 1919 are complete figures on nonfatal accidents available and because these years represent postwar activities ; 1927 is the last year for which the U. S. Bureau of Mines has published accident statistics . During the nine -year period 1919 to 1927 , inclusive , 153 metal miners were killed by mine accidents in Colorado and 5,035 miners suffered lost - time injuries . The accidentfrequency rate of number killed per 1,000 300- day workers for this nine - year period was 4.68 as compared with the general average of 3.26 for all the metal mines of the United States for the same period . In other words , the fatality rate in the metal mines of Colorado for this nine- year period averaged 40 per cent higher than that of the metal- mining industry in the United States generally . In 1924 and 1926 the Colorado metal mines had a better accident record than the average of those of the United States , but 1927 was a bad accident year and the State Bureau of Mines figures for 1928 and 1929 showing respectively 18 and 23 men killed in and about the metal mines indicate a continuing relatively high death rate from accident . The cost of accidents to the miner for the period 1919 to 1927 can be estimated from the accident figures just given . The United States Bureau of Mines as well as other authorities assess 6,000 days lost time for every fatality and every permanent total disability . These authorities have also agreed that a permanent partial disability costs 800 days lost time to the worker over his working lifetime , that lost time injuries of less than 14 days average about 6 days lost time and lost time injuries not involving permanent disability but having loss of more than 14 days average 32 days lost time . On this basis the Colorado metal miners have suffered in nine years a gross loss of 1,214,146 days , or , at $5 per day , $6,070,730 . The miner receives about one -ninth of this amount in compensation so that the net loss to the metal miner in Colorado for this nine - year period was about $5,400,000 .

May 1, 1930

By Lichao Ding, Jingbiao Fan, Yunnen Chen

"With the development of industrial production, more and more wastewater containing high concentration ammonia nitrogen was discharge into the environmemt, which caused serious harm to the environmemt. Treating the wastewater has great significance to protect water resources. Using air-stripping combined with oxidation to uptake high concentration of ammonia nitrogen wastewater. The influence of operating parameters was investigated. Experimental results revealed that pH of solution, aeration time and aeration strength showed heavy influence on ammonia nitrogen removal. Air-stripping combined with oxidation can be considered as an alternative approach for the removal of high concentration of ammonia nitrogen from practical metallurgical wastewater. When pH was 11, aeration time 20 min, aeration strength 1040 Lh-1, and oxidation with 10 % NaClO solution 10 min, the initial ammonia nitrogen 2130 mgr1 could reduce to 12 mgr1. Other items could also be removed to meet the ""Integrated wastewater discharge standard (GB8978-88)"".1. IntroductionThe rapid development of human activities has caused a worldwide increase of nitrogen in rivers, lakes and coastal waters. It leads to considerable eutrophication and an increase in the frequency of toxic algae blooms [1,2]. The concentrations of nitrogen in the water of China are pervading high [3]. The discharge of wastewater containing high concentration of ammonia nitrogen is one of the most important factors. Great efforts have been devoted to the removal of ammonia nitrogen from wastewater. Traditional methods include biological denitrication [ 4 ], chemical precipitation with magnesium ammonium phosphate [5], electrochemical conversion [6], air-stripping [7] and so on. Biological denitrication is the most common process in the treatment of ammonia nitrogen wastewater. But the process is only suitable for the removal of relatively low ammonia concentration due to the requirement of appropriate C/N ratio [8]. Chemical precipitation needs additional reagents, which may introduce new pollutants to water body. Electrochemical method often uses expensive metal or metal oxide as electrodes, and also consumes large quantity of energy [6].Although air-stripping makes use of stripping tower and consumes energy, it is very suitable for the removal of relatively high ammonia concentration. Different air-stripping conditions would appear different removal efficiency. And only air-stripping the effluent can not be attained the ""Integrated wastewater discharge standard (GB8978-88)"". In this study, we use air-stripping and oxidation to removal high concentration of ammonia nitrogen from simulated and real ammonia nitrogen wastewater."

Jan 1, 2011

By Frank A. Aplan, Barbara J. Arnold

INTRODUCTION Coal flotation is a fine cleaning process usually present in all but the older preparation plants. It is typically used to clean either the -28 mesh (-500 pm) or - 100 mesh (- 150 pm) raw coal fines, and it is the only commonly used preparation method that can effectively recover coal particles finer than, say, -200 mesh (74 pm). To place coal flotation into its proper context, it should be noted that the bulk of the raw coal sent to preparation plants is treated by gravity concentration. On a worldwide basis, from 0 to 40% of the raw feed to a preparation plant is treated by flotation, while in the US only about 10% of the raw coal feed is floated. Roughly, 50% of US preparation plants use flotation to process at least a portion of the raw coal feed, although most of the newer plants incorporate flotation into their flowsheet. Historically, the process has only been used to treat the raw coal fines naturally occurring after mining and a minimal amount of crushing at the preparation plant. This is in sharp contrast to ore flotation where, typically, the entire tonnage is first ground and then floated. As a consequence, of the approximately 500 Mt of raw coal treated by preparation in the US yearly, it is estimated that only about 40 Mt are sent to the flotation circuits (producing -30 Mt of clean product).'O1 This small tonnage compares with about 400 Mt of ores treated annually in the US by flotation. By analogy to ore flotation, where it is an effective, large tonnage, low cost, easy to operate process, its potential in coal preparation should be great. Reasons why it has not achieved a greater potential in coal preparation have been attributed by Aplan 102 to: 1. Indifferent results in removing sulfur and ash. 2. Difficulty in floating low rank and oxidized coals. 3. Inability to make clean separations with the finer sizes. 4.Inability to clean slurries with a high percentage of clay. 5. Problems with water chemistry. 6. Competition with effective, gravity coarse-cleaning methods. 7. Low value of coal historically. 8. Dewatering problems. 9. Transportation and storage problems with coal fines. 10. Marketing problems with coal fines. 11. Inadequate attention to the process in the plant. 12. Inefficient use of capital and operating monies. Inadequate attention to procedures, machines, and processes.

Jan 1, 1991

By R. F. Botha

I want to thank you for inviting me to deliver this, the closing address at the final plenary session of the 15th Congress of the Council of Mining and Metalurgical Institutions. Your Council has an impressive title, and justly so. Consider the expertise, the skill, the capacity, the achievement, that is gathered together here in this room this afternoon.

Jan 1, 1994

WE the undersigned, being all persons of full age and citizens of the United States, and a majority residents of the State of New York, desiring to form a corporation pursuant to the provisions of the Membership Corporations Law for the purpose of incorporating, as provided in Section 6 of Article I. of said law, the existing unincorporated association known as American Institute of Mining Engineers, do hereby make, acknowledge and 6le this Certificate for that purpose, and do Certify as follows: I. That the American Institute of Mining Engineers is an unincorporated association organized and existing with the object of promoting the arts and sciences connected with the economic production of the useful minerals and metals and the welfare of those employed in these industries by means of meetings for social intercourse and the reading and discussion of professional papers, and to circulate by means of publications among its members and associates the information thus obtained. 11. That the persons duly appointed or designated to manage the affairs of said association are designated by the rules thereof Members of its Council; that the under- signed are all members of said Council as the same was constituted on the 29th day of December, 1904.

Jan 1, 1936

By J. W. Pamplin

SOME 40 miles east of Tampa is the center of the Florida pebble phosphate deposits. These are of Pliocene age and consist of several members of the Bone Valley formation.' Physically the phosphate-bearing formation, locally called the “matrix," varies in thickness from nothing to about 25 ft., usually averages 10 ft., and consists mainly of clay, quartz and phosphate pebble, the latter particles varying in size from colloidal to one inch diameter. The pebbles range in color from dark gray, through white, to cream, and in hardness from that which must be broken with a hammer to that which can be scratched with the fingernail. They assay from 66 to 80 per cent bone phosphate of lime (called "B.P.L." in the trade) or tricalcium phosphate (Ca3P2O8) and are secondary apatites. They form from 15 to 50 per cent by weight of the matrix. Over the matrix lies a varying thickness (5 to 40 ft.) of overburden composed of quartz and clay. Briefly, mining consists of two operations2 in open pits about 200 ft. wide by ½ mile or more in length. In the first step overburden is removed by large electric draglines at the rate of about 700 cu. yd. per hour. This is followed closely by hydraulic mining of the matrix at the rate of about 300 cu. yd. per hour. This matrix yardage is moved from an improvised sump in the floor of the pit to an ore-dressing plant, some- times a mile distant, by one, two or three "pit-cars" (pumping units) working on a 12-in. pipe line called the "rock line" to distinguish it from the high-pressure water line feeding the hydraulic giants, which is known as the “hydraulic line." This 700 yd. of overburden and 300 yd. of matrix-1000 yd. in all- amounts to about 1500 tons of material moved each hour. The over- burden is dumped into the mined-out pit alongside the pit being mined. The matrix moves to the ore-dressing plant at the rate of about 7 ½ long tons in 4000 gal. of water per minute-a ratio of approximately one to two by weight, or one to six by volume. This constitutes the "mill heads," but in the pebble district it is called the "matrix."

Jan 1, 1938

By X. Shi, N. S. Dala, V. Vallaythan

"Cellular damage induced by silica dust is known to be associated with increased fragility and destabilization or destruction of the cell membranes. The mechanism by which silica dust effects biological membranes is still unknown. Using the ESR spin-trap methodology, we find that hydroxyl radicals are generated in aqueous suspensions of freshly ground silica. The amount of the radicals generated depends on the extent of grinding and ""freshness"" of the dust. Using linoleic acid as a model lipid, we show that the silica dust causes lipid peroxidation via ·OH, 02-, or linoleic acid related radicals as intermediates. Catalase and superoxide dismutase inhibit the formation of these radicals. The results suggest that free radicals associated with freshly ground silica and the related lipid peroxidation of the memberanes may be the starting point of the silicotic processes.INTRODUCTIONDespite considerable-effort over the years, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrosis are still not fully understood (1,2). It is generally thought, nevertheless, that the interaction of the quartz particles with the cell membranes is the starting point of the silicotic process (3). We felt that the mechanism of the membrane damage by quartz might involve oxygenated free radicals because (a) a suspension of quartz particles in contact with alveolar macrophages has been reported.(4,5) to initiate an enhancement of lipid peroxidation, defined broadly as the ;oxidative deterioration of polyunsaturated components of lipids, and (b) hydroxyl (·OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (6) and initiating lipid peroxidation in lysosomal membranes (7). Moreover it is known that exposure of cell membranes, fatty acids and unsaturated food oils to ionizing radiation, which generates ·OH. radicals, causes rapid peroxidation (6). Earlier studies o~ the aqueous chemistry of quartz suspensions have reported detection of HzOz (8), implicating the formation of ·OH radicals as transient species, but, we are not aware of any report of the detection of ·OH radicals in quartz suspensions and this provided the motivation for the present undertaking. Since it is known that, because of their high reactivity (hence short life time) in aqueous media, the ·OH radicals cannot be detected via electron spin resonance (ESR) directly (9,10), we have used ESR combined with the spin-trap methodology (9) for studying the •OH formation."

Jan 1, 1988

By Wilbur C. Helt

The United States is self-sufficient in bituminous coal and lignite resources to meet the high range of energy demands forecast for the remainder of this century and beyond. The known or proved recoverable reserves of energy from coal in the United States are estimated to be 88% of all fuel reserves, whereas the energy reserves for oil are estimated to be 276, gas 376, shale oil 5% and uranium 2% (as now used). The demand for all forms of energy used in the United States is increasing at a rate of 3% to 4% per year. Presently, coal is competitive on a supply and cost basis with other fuels in conversion to electrical energy and as a source of energy for converting raw minerals to metals and nonmetals, but it is not competitive in transportation and other uses that demand the high flexibility that oil and gas enjoy because of their form. Coal conversion to fluid forms is essential to make it interchangeable with gas and oil to meet the markets they now occupy. Essentially, the chemical constituents that make up coal are the same hydrocarbons that make up oil and gas; it is a matter of reconstituting the proportions of hydrocarbons to make coal interchangeable with the other fuels. The production of coal has fluctuated widely between the peak production of 631 million tons in 1947 to a low of 403 million tons in 1961. Throughout this period, the total value of the production, f.o.b. mines, has averaged more than $2 billion annually. Beginning with 1962, there has been a steady upward trend in coal production with only minor fluctuations that were mainly caused by labor disputes. Output for the latest typical year, 1970, was 588 million tons. Production in 1971 was affected by a major strike and dropped to 548 million tons. Exports of coal from United States to foreign countries have increased steadily and developed into a substantial annual market for over 71 million tons per year. About 56 million tons of this is suitable for metallurgical purposes, and the remaining 15 million tons is exported for electric power generation. The largest single-industry demand for coal is in the electric generating industry, Fig.1. Roughly, the production of electricity has doubled every

Jan 1, 1973

By Jozef S. Stachula

"INCO Limited operates eleven under-ground mines in the Sudbury area. The mines are located on the rim of the Sudbury Basin, an oval with the axis in the range of 27 km and 60 km. The ore dips to at least 3000 m below surface. The ores are mined primarily for nickel and copper. Total ore production from underground is in excess of 55 000tonnes per day.Over 40 surface fans have been installed since the late 1960s. All of the fans are adjustable pitch, axial flow units. A major factor influencing ventilation design in the last 30years has been the introduction of diesel equipment underground. Volumes per fan have ranged from 60 m3/sec. to 330 m3/sec., with motors from 100 hp to 2500 hp.Fans of the axial flow type have been commonly used for main fan installations at Canadian mines for many years. The standard arrangement has been to mount these fans horizontally, i.e. with the fan shaft and the long axis of the housing horizontal. This is a natural arrangement for an underground fan, but for a surface installation, a vertically mounted fan has definite advantages.The surface area taken up by a typical vertical fan installation is generally about one quarter that of a horizontal fan of the same capacity (Rutherford, 1957). This is not a problem with isolated fans and fat surface out crop sites, but where the installation is to be near existing buildings, or where there are poor surface soil conditions, space and cost considerations greatly flavour vertical fans."

Jan 1, 1996

By Robert S. Shoemaker

Receiving the Richards Award is undoubtedly the most memorable event in my entire life. There should, however, be more names engraved on it. These are the names of men who were my teachers (but not all of the academic variety) and my friends, each of whom had a part in my ever continuing education and thus have a part of this award. There was Bill Caldwell who made me into a chemist, and Will Shorey who added a lot of ore dressing. There was Rush Spedden who put me to work in his minerals research lab, Joe Brennan who made me turn my research into plant practice, and Tom Meek who sent me all over the world on metallurgical jobs. Bob Cheatham and Abe Dor taught me to try to give the client what he needs rather than what he wants, while Ed Malouf and Casey Davis always gave their particular brand of advice at exactly the right time. And, lastly, there was Leo Abell and Frank McQuiston, both fine metallurgists and the best friends a man could have. In addition to those I have mentioned, there are literally scores of others I would like to acknowledge with my sincere appreciation.

Jan 6, 1974

By M. K. Jain, Z. T. Xu, M. Bruhis, V. Hegedekatte

"Strain rate and temperature dependent deformation conditions are present during elevated temperature forming of aluminum and other metallic materials. While many constitutive laws have been proposed to represent such deformation conditions, a closer investigation often reveals their limited applicability in terms of fit to the experimental data, and interpolation within and extrapolation outside of the range of experimental stress-strain curves. This is often because material-specific primary deformation mechanisms of temperature-dependent strain and strain rate hardening are poorly captured. In the present work, the Voce-Kocks constitutive model based on mechanics of dislocations storage and annihilation has been found to be suitable for many metallic materials. The model was modified to include the effect of temperature dependent shear modulus. The modified model is then employed to represent the experimental data obtained from uniaxial tensile tests on AA7075-O sheet at elevated temperatures and strain rates. Also, hot gas bulging tests were conducted to verify the applicability of this model. Further, finite element simulation of the hot gas bulge test was performed by incorporating the model as a user material subroutine. Good general agreement was observed between the experimental and FE model predicted results. Some sources of discrepancy in the prediction are also discussed.INTRODUCTION There has been much interest in light-weighting of automobiles from automotive related industries to reduce overall carbon footprint and increase energy efficiency of the vehicles. Aluminum alloys, and especially the medium-strength 5xxx and 6xxx series alloys, have been the primary focus in the last 3 decades to reach the above environmental goals (Huo, Hou, Zhang, & Zhang, 2016) whereas aerospace industry has traditionally focused on high strength 7xxx series aluminum (Al-Zn-Mg-Cu) alloys for structural components (Deng, Yin, & Huang, 2011). Recently, there has been much interest in high strength 7xxx series aluminum as a replacement for heavier steel automotive structural parts such as A-pillar, B-pillar, side impact beams etc. (Harrison & Luckey, 2014). This is both interesting and challenging since the above aluminum structural parts will need to not only meet impact safety standards but also possess sufficient formability for manufacturing such complex parts. Since the formability of high strength 7xxx series materials is quite poor at room temperature, much interest has focused on improving both formability and final part strength via high rate hot stamping, in-die quenching, and subsequent artificial ageing process steps (Kumar & Ross, 2016)."

Jan 1, 2018

By Chikabumi Yamauchi, Masami Tashiro, Toshiharu Fujisawa, Hiroyuki Snano

"Rare earth metals usually contain large amount of oxygen because of their reactiveness, and therefore oxygen removal is one of the major problems on the purification of rare earth metals. In the present research work, halide flux treatment at high temperature under inert gas atmosphere was applied to the oxygen removal from neodymium. NdF3 was used as a halide flux. Deoxidation reaction and its mechanism were discussed based on the experimental results. Halide flux treatment is very effective for oxygen removal from rare earth metals.IntroductionSolid Sate Electrotransport (SSE) process has been successfully applied for the elimination of interstitial gaseous impurities from chemically active metals[l]-[5]. However, to achieve a higher effectiveness of the SSE process, it is required a very low initial impurity content in the metal. In case of rare earth metals, it is known that they usually contain large amount of oxygen that should be lowered as much as possible before applying the SSE process. In addition, if effective oxygen removal is achieved by simple process, it is significant also from the industrial viewpoint. In the present work, the application of a halide flux treatment is investigated to remove oxygen from neodymium by using NdF3 as a flux. At first, deoxidation reaction and its mechanism were discussed based on the phase diagram of the Nd-NdF3-Ndp3 quasi-ternary system. Based on the results, oxygen content in deoxidized neodymium was calculated theoretically and it was verified by deoxidation experiments."

Jan 1, 1998

By William Crowe Kellogg

By now the term AFMAG has been fairly well introduced to the mining industry. Several papers have been presented and published concerning AFMAG (references 1 and 2). However, the term AFMAG remains rather new to the industry, and the exact place which AFMAG occupies in the minerals exploration field is still somewhat uncertain in the minds of many who may have use for this new and interesting method of electromagnetic exploration for conductive minerals. It is the purpose of this paper to again review the basic theory of the AFMAG system, to describe and - illustrate the equipment and data presentation as used in aerial surveying, and to provide some idea of the cost and nature of airborne AFMAG surveys. This paper is primarily of a general descriptive nature and presents AFMAG theory in a schematic rather than mathematical form; emphasis is placed on the equipment, the present method of data presentation and survey operations, since it is believed that such, information will now generally best serve to inform the mining industry of the characteristics of the AFMAG system.

Jan 1, 1960

By A. O. Bartell

Do you know that valuable clues to the geology and mineralization of a district can be found in a handful of sand from a stream bed draining the area? This handful of sand has a story to tell to those who have a little patience. The handful of sand may contain tiny specks of valuable minerals (gold, scheelite, cinnabar, chromite, tourmaline-to mention a few), that will lure you upstream with the hope of uncovering a new deposit. More practically, this handful of sand can indicate the type of rocks that are exposed by the drainage system. Any mineral that has a specific gravity of 3.5 or higher can be separated from soil by panning. Garnet and pyrite, for example, can indicate an outcrop of metamorphic rock. In one district where the writer prospected, small boat-shaped orthorhombic crystals of topaz always indicated the presence of andesite outcrops.

Jan 1, 1948

By E. N. Levchenko, K. V. Bulatov, G. I. Gazaleeva

"The article highlights the new procedure of choosing special methods of disintegration for very complicated rare ores. Especially, there is a complex approach to criteria of comparing different types of crashing machines. Criteria are as follows: degree of crashing, degree of grinding, degree of slime creation and the new creations criteria for selection. The procedure is tested on tantalium and zelestinium ore. A new methods was shown the preference impact crashing machine MD-7 for zelestinium ore. In product of crashing 0,050 mm size are 9.4 %, 0,005 mm size – 2.5 %.This is gut result, and show the best indexes of slime creation. The check of the proposed new methods was done when comparing the crushing of tantalium ores of the Otboynoe deposit in cone inertial and centrifugal impact crushers and roller press. A research was conducted different crashing machines under laboratory and semi-industrial conditions. Different operation modes of crushers were also checked. The comparison of the crushing selectivity criterion and degree of crashing showed that the centrifugal impact crusher (CC) and roller press (RP) has the lower indexes than the cone inertial crusher (CIC). Degrees of crashing for different crashing machines are:centrifugal impact crusher – 10.1;roller press – 10.8;cone inertial crusher – 14.2. The crusher CC the selection criterion is 0,632 units, RP – 0.730, where as for the crusher CIC – 0.848 units. The best crushing mode for the crusher CIC-300? is as follows: turning angle of debalance is 0°, peripheral speed of a cone rotation – 1420 r.p.m, specific energy consumption- 4.99 kW*t/t. Crusher CIC-300? is the best for tantalium ores of the Otboynoe deposit. The new methodic are verification.INTRODUCTION Rare metal concentration circuits are complex, energy-intensive, and costly. The reasons for this include the multimetal nature of the rare metal ores, their volatile material composition and low grade. That is why careful selection of ore preparation circuits is of great importance for minimizing the energy inputs and maximizing the liberation of the valuable minerals. Recent research (Khopunov, 2011, Gazaleeva, 2015) has demonstrated that the most efficient comminution processes available to the mineral processing industry are selective disintegration, crushing and grinding, allowing to liberate the mineral particles along the cleavage in the comminution process. These methods are indispensable for the processing of finely disseminated refractory ores prone to slime formation. Many rare metal ores found in Russia are of this type."

Jan 1, 2018

WE the undersigned, being all persons of full age and citizens of the United States, and a majority residents of the State of New York, desiring to form a corporation pursuant to the provisions of the Membership Corporations Law for the purpose of incorporating, as provided in Section 6 of Article I. of said law, the existing unincorporated association known as American Institute of Mining Engineers, do hereby make, acknowledge and 6le this Certificate for that purpose, and do Certify as follows: I. That the American Institute of Mining Engineers is an unincorporated association organized and existing with the object of promoting the arts and sciences connected with the economic production of the useful minerals and metals and the welfare of those employed in these industries by means of meetings for social intercourse and the reading and discussion of professional papers, and to circulate by means of publications among its members and associates the information thus obtained. 11. That the persons duly appointed or designated to manage the affairs of said association are designated by the rules thereof Members of its Council; that the under- signed are all members of said Council as the same was constituted on the 29th day of December, 1904.

Jan 1, 1941

By E. Baliktsis

PPC (Public Power Corporation) operates a new power plant at the South-West part of Crete. Recently the extension of the Power Plant started. ATHENA SA the main contractor of the project assigned to EXORIXI SA the implementation of a blast vibration monitoring program and prevention-evaluation of risks caused by construction blastings inside or very close to the operating part of the power station. The blasting parameters and characteristic elements that had been evaluated, the measures that had been taken and materialized, the overall risk management and the results of the whole program are presented in this paper.

Jan 1, 2006

By O. Ozcan, J. D. Miller, Z. S. Nickolov

The production of soda ash from trona (sodium sesquicarbonate, Na2CO3•NaHCO3•2H2O) resources has completely displaced the production of synthetic soda ash in the USA. Further, the utilization of other trona resources is under consideration in China, Turkey, etc. Recent research has been concerned with the development of flotation technology for the trona industry. In this regard studies on the flotation behavior of sodium carbonate salts: trona, sodium carbonate monohydrate and decahydrate, as well as the flotation behavior of sodium bicarbonate, are reported for both cationic (dodecyl ammonium hydrochloride) and anionic (sodium dodecyl sulfate) collectors. It has been found that strong flotation of sodium bicarbonate (NaHCO3) can be achieved with 100% recovery, while the other sodium carbonate salts do not float well. These results have been explained by FTIR analysis of aqueous solutions of Na2CO3and NaHCO3in a range of concentrations from very dilute to saturated conditions. The changes in the shape of the O-H stretching band of water are correlated with the flotation behavior of Na2CO3salts and NaHCO3. In addition, the absorption band of the carbonate ion at ca. 1385 cm-1is used to monitor its interactions with water and/or other ions in solution. The infrared results demonstrate thatNa2CO3acts as a water structure maker, leading to an extensively hydrated surface that accounts for the poor flotation of most sodium carbonate salts. In contrast, NaHCO3does not have this characteristic and consequently complete flotation is possible with both cationic and anionic collectors. These results support the previous water structure analysis for soluble salt flotation of alkali halides and other oxyanion salts.

Jan 1, 2003

By H. D. Colson, Robert A. Rapp

When a binary alloy is oxidized to form simultaneously an internal oxidation zone and an external scale which grows at a constant rate, the oxidation should reach a condition of steady shale, in which the internal oxidation zone is maintained at a time-independent thickness. Assuming an ideal model for the steady-state oxidation, the diffusion equation is solved for the steudy-state concentration profiles for oxygen and alloying- element in the metal. A theoretical prediction of' the steady-state thickness of the internal oxidation zone is made in terms of the experimental parameters. FOR the oxidation of binary alloys, Rhines, Johnson, and Anderson,1 as well as Mask: have derived equations describing the kinetics for the simultaneous formation of an internal oxidation zone and an external scale which was assumed to mow according to a parabolic rate law. Experimental determinations of internal oxidation zone thicknesses beneath a Cu2O scale for Cu-Be and Cu-A1 alloys3,4 have shown some deviation from Maak's theoretical expressions, because the ideal model assumed for the calculation is not met experimentally. Some pure metals, such as columbium and tantalum oxidize at elevated temperatures and high oxygen pressures to form nonprotec-tive external scales which thicken at a constant rate. If such a base metal is alloyed with a solute element which may form a more stable oxide than the solvent oxide, then internal oxidation of solute may occur beneath the growing external scale. A review of the internal oxidation of alloys has been published recently.5 The purpose of this paper is to analyze theoretically for a binary alloy the kinetics for the simultaneous formation of an internal oxidation zone and an external scale which grows at a constant rate. Consider an alloy A-B in which A is the more-noble solvent and B is the less-noble solute. The solute oxide is assumed to precipitate in internal oxidation as stoichiometric particles of BO, which are assumed to have a negligible solubility product in the A matrix. It is further assumed that the diffusion of oxygen through the zone of internal oxidation is not impeded by previously precipitated BO, particles. The specimen is assumed to be sufficiently thick so that the solute content in the center of the specimen does not change. For consistency: the following notation of Maak2 has been used:

Jan 1, 1967

By W. G. Lawrence

The rapid development of science and technology in Russia has been the result of well laid plans since 1918. At that time the Institute of Silicates was established is Moscow and later the establishment of similar more specialized institutes for the study of cement, glass, refractories, construction ceramics, electrical ceramics, building materials and asbestos provided the necessary research facilities for studies related to all types of ceramic inorganic materials. The' Institute of Ceramics and the Institute of Silicate Chemistry, Academy of Sciences, USSR, were founded in Leningrad. The work now going on in these various research' institutes covers every branch of silicate science and ceramics The impetus behind such establishment of special¬ized laboratories is no doubt due to the 5-year plans and the necessity of improving the scientific knowledge regarding the materials being used and the products being manufactured.

Jan 1, 1960