Search Documents

By M. Arvola, A. Mäkinen, N. Isomäki

Arsenic is a compound that has no significant market value. However, it needs to be removed from ores, concentrates and other process streams because of environmental or technical processing concerns. A wide range of arsenic containing minerals exists in nature, and in many instances these minerals are also associated with the ones that have commercial value. For example, sulfide copper ores are normally closely associated with minerals like enargite, Cu3AsS4 and tennantite Cu12As4S13. After mineral processing these arsenic sources can report to the waste waters and these effluents need to be treated before discharge or recycling. Ferric arsenate precipitation is a well-established method for stabilizing arsenic in effluents. Electrochemical arsenic removal utilizes the same adsorption/precipitation ideology as ferric arsenate precipitation. Electrochemical arsenic removal, even though it is a simple process in terms of equipment, is a complex system involving chemical and physical mechanisms taking place simultaneously to remove dissolved and/or solid arsenic components from wastewaters. The whole process can be described by the following three steps: 1) electrolytic oxidation at a sacrificial anode (dissolving electrode metal, iron for example), 2) chemical reaction between dissolved iron and arsenic to form a solid precipitate and 3) aggregation of the particles to form flocs, which can be removed by known solid/liquid separation methods. Electrochemical arsenic removal is a very efficient way to remove arsenic from different waters to very low residual concentrations.

Jan 1, 2016

With the employment of a system of ore pillars to support the hanging wall during the mining operations at the North Mine, it was found that, when the stopes were worked out and the pillars remained intact, the main footwall drives developed an undulating longitudinal section due to the shrinkage of the filling in the worked out stopes.These depressions collected water, which made the footwall drives very wet under foot, and everitually worked its way into the pillar workings and the levels below.Water was also finding its way into the shafts because of the silting-up of the level drainage systems and, as both the shafts are down-cast, this tended to increase the humidity of the air entering the mine.To overcome these troubles it was decided to try a system of siphons as a method of subsidiary drainage.SYSTEM AT PRESENT IN USE.All drainage water is collected as near to its source as possible, run into a sump in an adjacent low lying part of the level, and continuously removed from these sumps by a siphon system.Each level has its own system. Water is collected from the sumps by a 1-in. pipe and delivered to a pipe running the length of the level along the back of the footwall drive. At the shaft the pipe is increased to...

Jan 1, 1938

By Konstantinos Modis

According to recently established theoretical analysis and under certain conditions, a critical sampling density can be determined for an earth-related space-distributed natural variable. Sampling above this critical limit adds little to the mapping results. The objective of this paper is the application of the above theory to the Sesklo clay quarry in Greece, where Heracles General Cement Company had conducted a sampling campaign to estimate its reserves. The structural analysis of Al2O3 values generated a variogram model, from which the critical sampling density was identified. This critical number was by far lower than the existing sampling density. Clay reserves were then estimated using geostatistics and inverse distance squares in different data schemes with variable densities. The results of the comparisons between the various models revealed that, when the sampling density was greater than its critical value, geostatistics and deterministic interpolation gave similar estimations, which is also in agreement to the theory. The optimal sampling grid finally proposed here, will result to significant cost savings in the next drilling program which is now in plan by the company.

Oct 1, 2009

The Resource Management Act 1991 (RMA) and the Crown Minerals Act 1991 (CMA) both came into force on 1 October 1991. The purpose behind RMA was to integrate the existing laws dealing with town and country planning, land subdivision, water and soil, minerals and energy resources, coastal management, air pollution and noise control into one omnibus Act. Originally, there was a section in RMA dealing with minerals. However, this section was taken out of RMA and a companion piece of legislation - namely CMA - was passed with RMA.

Jan 1, 1994

By P. J. N. Pells

A good thing is becoming a bad thing. Rock mass classification systems, that are so excellent for communications between engineers and geologists, and that can be valuable in categorizing project experience, are emasculating engineering geology and rock mechanics. Some engineering geologists have been sucked into thinking that Q and RMR values are all that is needed for engineering purposes, and seem to have put aside what can be learned from structural geology and geomorphology. Many rock mechanics engineers seem to have forgotten the scientific method. This paper attempts to redress the situation by showing how mechanics can be used in rock engineering to design with a similar rigour to that used in the fields of structural engineering, hydraulics and soil mechanics. It also attempts to remind practitioners of what can be achieved by skilled engineering geology.

Jan 1, 2008

By K. Lundholm, M. Andersson, L. Nevatalo, Å. Holmström, L. Hedström

"Several copper deposits have the arsenic bearing minerals enargite (Cu3AsS4) and tennantite (Cu12As4S12). Since this mineral contain both arsenic and copper, it is not possible to remove the arsenic by selective flotation. Partial roasting is a method to clean the concentrate from arsenic and thereby produce a suitable raw material for the copper smelter. Also mercury is commonly found in copper bearing minerals. In the partial roasting process both arsenic and mercury are volatilized, while part of the sulphur is used as energy during the roasting. This gives a calcine suitable as feed to a smelter, much like an ordinary copper concentrate. A typical analysis of calcine would be: S content 18–22%, As content below 0.3%, Cu content – not affected, grain size – not affected. However, if the concentrate contains mercury, the mercury will be volatilized during the roasting process. This will lead to very high mercury contents in the subsequent process of sulphuric acid, unless the SO2-rich process gas is pre-treated by the Boliden/Norzink process that recovers mercury as calomel, Hg2Cl2. The volatilized arsenic in the gas phase can be recovered either by dry or wet methods. However, one problem is that arsenic also contaminates the fine grained calcine dust that is captured downstream in the gas cleaning system. The calcine dust contains valuable metals such as copper, gold and silver that needs to be separated from the arsenic. The ultimate aim is to stabilize the recovered arsenic as a compound with minimum impact on the environment and recover the valuable metals. By using wet recovery methods it is possible to selectively precipitate copper, gold and silver as sulphides while arsenic is kept dissolved in the liquid. The precipitated metal sulphides can be mixed with the calcine and sent to the copper smelter. The dissolved arsenic is sent to effluent treatment and is further treated in Outotec ferric arsenate precipitation process, where arsenic is precipitated as the stable compound basic ferric arsenate, formula FeAsO4·xFe(OH)3. All concentrates containing arsenic are unique and the process design of a roaster plant must be based on relevant process data. The process data is collected during tests in lab scale and pilot scale, where the influence of critical process parameters on the quality of calcine is studied. The ability to run tests both in lab scale and pilot scale is crucial to the development of the correct roasting process. Outotec is well equipped for this."

Jan 1, 2014

By David S. Yang, Osamu Taki

The innovative Soil-Cement Mixing Wall Technique, developed independently in Japan, consists of mixing in-place soils with cement grout using multi-axis augers and mixing paddles to construct overlapping soil-cement columns. The applications of overlapped soil-cement columns include cutoff walls for groundwater control and structural diaphragm walls for excavation support. The special features of this technique include water tightness, versatile strength design, and efficient installation in subsurface materials varying from clayey soils to cobbles or soft rocks. Through the introduction of two recent subway projects in Japan, this paper presents the design parameters, construction procedure, quality control and performance of soil-cement wall for excavation support and groundwater control.

Jan 1, 1989

By R. N. Powell

The Pipeline ore body was discovered in March 1991. The construction of the new mine and mill did not start until early March of 1996. Upon completion of permitting and corporate project approval, the 289 million USD project was “fast tracked”. The commissioning began 11 months after start of construction and the project ended 40 million USD under the budget figure. The objective of this paper is to review and highlight the Pipeline Project history from discovery, design, lawsuits, permitting, and re-design through to current - 1998operating practices. Particular emphasis will review the process design, design mistakes, and design successes. The paper will review project history, feasibility, design concepts, operator training, construction, financial and the current operation. Additional discussion will review what design features worked and which did not work within the process plant.

Jan 1, 1999

By D. A. Donato

It is often necessary for a mining company to extract coal from a seam underlying a previously mined coal seam. The impact of the overlying mine workings on the stress distribution within the underlying mine workings is very difficult to assess without the use of numerical modeling techniques. This paper demonstrates the usefulness of applying numerical modeling to evaluate alternate startup-room locations for a longwall panel considering the effects of multiple seam interaction. MULSIMIPC, a code adapted by the former U. S. Bureau of Mines, was used to compare stress patterns in two proposed startup-room locations. These model results were not only compared to each other, but also to results from a model with no overlying mine workings to provide baseline criteria for evaluation of the two proposed startup-room locations. The numerical modeling study was successful in providing useful information to the coal company and the regulatory agency (MSHA), resulting in a mine design that was both safe and efficient, and prevented the sterilization of a large volume of coal reserves.

Jan 1, 1996

The development of Western Mining Corporation's first commercial gold heap leaching operation is described. The laboratory testwork requirements for determining the amenability of ore to heap leaching techniques is discussed. Heap construction and operating practices are described; and production statistics and operating parameters are presented. It is shown that for a specific low grade gold ore a treatment cost optimization can be performed. Taking cognizance of the ore grade, percentage gold recovery, operating costs, and the gold sale price, it can be determined whether Carbon-In-Pulp (C-I-P) or Heap Leaching should be employed as the extraction process. The examples presented in this paper refer specifically to Kambalda and should not be used in themselves as generalities.

Jan 1, 1987

By I. W. Farmer

Weightings and water inflows into longwall workings often occur together, giving rise to discussions on their relative genesis. Case histories are introduced which indicate that most water inflows are associated with heavy weightings. Resultant large releases of energy can lead to extensive vertical fractures, which can drain water from aquifers or other sources, such as separation accumulations, onto the face. Effectively control of water inflows in these cases depends on face support and weighting control.

Jan 1, 1996

In the course of work being carried out in the Lubricants and Bearings Section of the Council lor Scientific and Industrial Research on the production of copper4ead 'bearings for 'use in aircraft, it has been found necessary to develop special metallographic methods. For proper control of the production of steel-backed copper-lead bearings it is necessary to adhere to rigidly controlled conditions, and it is essential that a method of examination be adopted which will readily detect actual defects or any variations in quality. Some defects can be observed with the naked eye, whilst others are detected by radiographic examination. This latter method is invaluable as a rapid, reliable test in the production of aircraft bearings, but it is necessary to observe the structure of the alloys under the microscope, both to be able to interpret the radiograph correctly and to determine what has occurred to the metal during and after solidification. The use of a sound metallographic technique is'particularly important in developmental work and research connected with these bearings.Polishing TechniqueCopper and lead are practically immiscible in the solid state, but whilst they are miscible only in certain limited proportions in the liquid state; consequently "alloys" of copper and lead consist of a mixture of the constituent metals. The metallographic difficulties are obvious. Copper is a relatively tough metal, although it readily scratches, whilst lead is extremely soft and easily deformed. It wouId be expected if any normal polishing technique were applied that the lead would be readily torn out of the surface being prepared, and, in addition, that the lead would tarnish very easily.Grange(2) has described a method by which these difficulties can be overcome. The method involves an etch-polish procedure using "chrome regia" as an etchant for the copper. The chrome regia was a solution of chromium trioxide and hydrochloric acid in water. This type of etchant has been adopted, but it was found necessary to make certain changes.The method now adopted in this laboratory is as follows: The specimen (which is usually mounted in bakelite) is wet ground in a series of successively finer Hydro-Durexsil emery papers down to 60.0· grit paper.The specimen is then etched in the chrome regis, etchant (the composition of this etchant will pe discussed later) for approximately five seconds.Most efficient etching is obtained by swabbing the surface of the specimen...

Jan 1, 1944

By William J. Purdy

Successful design, operation and completion of a surface waste management facility for a diamond mine located in Canada?s northern environment requires careful planning to minimize short and long term environmental impacts. As part of the mine development application process, best practice standards were applied using conventional engineering to reduce the environmental effects of the mine waste facility at the Snap Lake Diamond Project. This paper presents the design criteria, site conditions, material characteristics and engineering management objectives considered for optimization of the development plan. Insight into the engineering analyses, development alternatives, monitoring program and reclamation strategy plan to be undertaken during mine operations to provide opportunity for adaptive management and to minimize environmental impacts is provided.

May 1, 2004

By G. V. Sullivan, B. E. Davis, T. O. Llewellyn

The Bureau of Mines, US Department of the Interior, conducted studies to recover phosphate from four dolomitic southern Florida deposits not currently mined. The samples contained 5.8-10.2% P205 and 1.7-4.8% MgO. Chemical analyses of sized fractions indicated that no pebble concentrate, +1.2 mm (+14 mesh) could be produced from these samples. A scheme was developed that consisted of desliming, grinding, scrubbing, and redesliming the ore to produce a flotation feed. Conventional one-step fatty acid fuel oil batch flotation tests on the samples resulted in concentrates containing 29.0-31.3% P205 at flotation recoveries ranging from 72.4 to 96.1% of the flotation feed. The MgO content of the concentrates ranged from 0.47 to 1.36%. Continuous flotation of the Manatee No. 2 sample indicated that commercial-grade phosphate concentrates analyzing 31.3% P205 and 0.55% MgO could be produced with a flotation recovery of 89.9%. The MgO content of concentrates obtained from the Manatee No. 1 and Hardee samples was 1.20 -1.36 %, respectively. Leaching with aqueous SO2 reduced the MgO content of these phosphate concentrates to 0.5 and 0.8%, but with a concomitant loss in phosphate recovery of about 10%.

Jan 1, 1985

By P. Wittke-Gatterman

ABSTRACT: A three dimensional constitutive law for swelling rock is presented. It can be applied to the osmotic swelling of mudstone as well as to the swelling of rocks containing anhydrite. It describes the development of time-dependent strains and stresses due to swelling considering elastic and viskoplastic behaviour. Furthermore an anisotropic swelling behaviour can be considered. This constitutive model was implemented within a numerical computation program according to the finite element method and calibrated on the basis of the results of measurements in the investigation drift of the Freudenstein tunnel which is completely located in the unleached Gypsum Keuper. A parameter combination could be found which results in a good agreement between numerical solutions and results of measurements. Therewith an analysis procedure which enables the design of tunnels in swelling rock is available. ZUSAMMENFASSUNG: Im vorliegenden Beitrag wird ein dreidimensionales Quellgesetz vorgestellt, das nach derzeitigem Kenntnisstand sowohl auf das osmotische Quellen von Tonsteinen als auch auf das Quellen anhydrithaltiger Ton- beziehungsweise Schluffsteine anwendbar ist. Das Stoffgesetz wurde in ein Finite-Elemente-Programm implementiert und anhand von Meßergebnissen des im unausgelaugten Gipskeuper liegenden Untersuchungsstollens des Freudensteintunnels kalibriert. Es ist gelungen, eine Kennwertkombination zu finden, mit der alle Meßergebnisse gut beschrieben werden können. Damit steht ein Bemessungsverfahren für Tunnel in quellfähigem Gebirge zur Verfügung. RÉSUMÉ: Dans l'article présent un loi de gonflement à trois dimensions est présenté, qui peut être appliqué aussi bien au gonflement osmotique de l'argile compactée q'au gonflement de l'argile compactée ou du limon compacté contenant de l'anhydrite. Le loi de comportement était implémenté dans un programme numérique d'éléments finis et calibré avec des résultats de mesures de la galerie de recherche du tunnel de Freudenstein, situé dans le Keuper de gypse non lessivé. On est réussi à trouver une combinaison de paramètres avec laquelle tous les résultats de mesures peuvent être bien décrits. Par ce moyen, une méthode de dimensionnement existe pour des tunnels dans de la roche capable de gonfler.

Jan 1, 2003

By Nicholas J. Grant, Ulf Kalling, John Chipman

D. E. Babcock (Republic Steel Corp., Youngstown, Ohio)—I would like to know what evidence you have to prove the MnO was pure MnO. I would also like to know whether you might not explain it on the basis of a temperature reversion; and, was it due to the oxidizing power of MnO? N. J. Grant (authors' reply)—Briefly, we have no proof that pure MnO was used. The manganese oxide was added as chemically pure MnO,. MnO is assumed as the oxide in the reacted slag following standard molecular slag theories, especially under the reducing conditions of these experiments. The noted sulphur reversion cannot by any means be explained on the basis of a temperature reversion since the temperature effect is shown in this paper to be very small. Until a more logical explanation can be offered, backed I hope by some experimental proof, we propose to explain this sulphur reversion as stated in the paper, namely, that it is due to the oxidizing effect of the added manganese oxide. Member—How did the oxygen in the slag give you a reversion of sulphur? What was the mechanism there?

Jan 1, 1952

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluorides1,2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02.SiO2) with the ammonium acid fluoride (NH4F.XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo¬dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012

By R. C. Amero

FULLERS earth is a general name applied to claylike minerals that have high natural ad-sorptive powers. They are usually distinguished from ordinary clays by a higher content of combined moisture and a lower apparent density. The definition is based on the ancient use of the material for fulling, or cleansing woolen cloth of oil and grease; a more modern definition should mention the ability to decolorize oil and should differentiate between fullers earth, which is naturally active, and certain bentonites which only develop decolorizing power after being leached with strong mineral acids. The distinction between fullers earth and activable bentonite is not a sharp one, since all types of intermediate clays can be found that are more or less naturally active, yet more or less responsive to acid treatment. The differences seem to depend somewhat on the amount of leaching that has been effected by natural ground waters. Physical Properties The principal mineral constituent of activable bentonite is montmorillonite, a hydrous aluminum silicate to which the following formula is generally assigned: Al,Si,O,, (OH), • 12H,O Fullers earth, as well as bentonite, is usually composed of some variety of montmorillonite, but in the United States the largest tonnage of fullers earth is mined from deposits of attapulgite. Attapul- gite is a clay mineral composed of monoclinic crystals of colloidal size, having a fibrous shape similar to that of asbestos. A sectional model of the attapulgite "molecule" is shown in Fig. 1. A single unit is about 18.0 A wide and 12.9 A high. The length of the molecule is variable, but this same molecular pattern is repeated to form needlework crystals, rather than flakes, as is characteristic of the montmorillonite crystals. Attapulgite has been assigned the following formula,' although actually, the magnesia has been largely replaced by alumina: (0%) . (OH), • Mg, . Si, • Olp . 4H20. The fibrous nature of the mineral is clearly shown in the electron micrograph, Fig. 2. Although the deposits contain 5 to 30 pct quartz and carbonate minerals, impurities in the commercial products are held at a low level, principally by selective mining on the basis of oil decolorizing efficiency. The particle size distribution of this fullers earth has been estimated from settling rates, using sodium citrate as a dispersing agent.' Since Stokes' law only applies to spherical particles, the equivalent particle diameter calculated below is probably more nearly an index of diameter rather than length of the needlelike crystals: Eqnivalent Arbitrary Particle Distribution, Size Diameter Pci Classil3catian 0.05 mm 0.80 0.80 pct sand 0.05-0.02 mm 10.96 0.02-0.01 mm 9.65 42.10 pct silt 0.01-0.005 mm 11.40 0.005-0.002 mm 10.09 2-0.5 micron 10.61 0.5-0.2 micron 29.09 56.58 pct clay 0.2-0.05 micron 14.86 0.05 micron 1.96 The differential thermal analysis shown in Fig. 3 is unique and supports the theory that this is a distinct mineral species.' ~ Other general properties of the mineral as shown in Table I.

Jan 1, 1952

By Duncan Chalmers, Rob Nowell, Miguel Araos

Australian underground mines produce in excess of 60 mtpa of coal. Most of these use the longwall method, and they require the use permitted explosives (which are called “permissible” in other countries) for challenges that appear during the day-to-day activities. To obtain the approval for these explosives, they should pass Testing Memorandum #2 (TM-2), which sets out the test required for each category of permitted explosive. These categories are P1, P3, and P5. With P5 being unrestricted use and P3 and P1 have conditional use in underground mines. The TM-2 test was originally set up for NG-based permitted products around 1900. With the closing of NG plants around the world, ammonium nitrate explosives were the natural replacement, and therefore these explosives need to pass the TM2. Australia does have a P1-emulsion based explosive available. For high-risk scenarios (like blasting coal), no P5 explosives are available. The lack of P5 explosives has been prolonged for more than 25 years, since the phasing out of nitroglycerine-based permitted explosive products around the world. The main problem has been that when emulsion based permitted products are tested in the deflagration cannon, the results obtained were not considered in the TM2 criteria and therefore the tests were invalid. A research work on permitted explosives began in 2005 funded by the Australian Coal Association Research Program (ACARP). The aim of the project was to address the lack of P5-type permitted explosive (and, potentially develop them further, i.e., develop safer explosives) and understand the behaviour of emulsion explosive and the results they presented in the tests. Both bureaucratic and technical barriers appeared along the way. On the bureaucracy side, the facility was shut down, reopened, and shut down again. In view of these difficulties, assistance was sought overseas. On the technical side, from the very start the results of the tests when using emulsion-based permitted explosives were not established in the criteria, ignitions occurred for trial samples that were expected to be P5-type, etc. The aim of this document is to present the painful journey in the Australian industry to have a P5-type emulsion-based permitted explosive, for use in UG coal. Also, the technical learning acquired about emulsion explosives and the ignition path of mixtures methane / air will be shown.

Jan 21, 2025

Throughout history, many of the world's achievements, conflicts and problems can be traced to the demand for minerals. With the rapid expansion of our industrialised society in recent years the demand for minerals has grown to such an extent that uncertainties about availability and cost have arisen, especially in the case of energy minerals.Minerals have acquired a new dimension for governments as the availability of these resources is interwoven with the ability of governments to achieve their developmental goals on national and international levels. Accordingly, the supply of minerals will increasingly be affected by social and political factors.

Jan 1, 1986