Search Documents

HAVING told you about steel in the previous chapter, it seems to me necessary to speak here of brass for the same reason, for it bears the same relation to copper that steel does to iron. It is the opinion of some concerning both of these that they are true minerals because Pliny in his Natural History calls it aurichalcum and says that it has its own ore; he does not say, however, where it is found, and I have not heard from anyone else that it has been found anywhere, and, surely, if it had been found when he wrote, it would also be found today. Since I have no knowledge other than that gained through my own eyes, I tell you as a certainty that just as steel is iron converted by art into almost another kind of metal, so also brass is copper given a yellow color by art. Surely it was a splendid discovery, for which we must praise the alchemists,* although perhaps whoever discovered it was deceived, thinking that he had made gold from copper. Now, in short, this work requires infinite labor, and is carried out in various places, for instance, in Flanders, Cologne, Paris, and in many other countries, and also in the city of Milan in Italy, where I have seen a

Jan 1, 1942

By W. C. Zhu, C. H. Wei, L. L. Niu

With an increase of mining depth, a series of mining-induced hazards such as rockburst, coal and gas outburst, roof collapse, and water burst are getting more serious and more frequent. The intrinsic mechanism responsible for the occurrence of mining-induced hazards is the damage and unstable failure of rockmass or coal seam. The most distinct difference between deep and shallow levels is the so-called three ‘high’ (H3) conditions, i.e. high geo-stress, high fluid pressure and high geo-temperature. Therefore, the response of rock or coal to the deep mining operation is a phenomenon involving thermal (T), hydraulic (H), and mechanical (M) processes. Most importantly, mining excavation may vary the rock stress condition greatly, which may be a key factor to trigger the mining-induced hazards such as rockburst. In this regard, it is of great significance to clarify the damage and failure mechanism of rock and coal under coupled THM conditions, in order to clarify the rock failure mechanism responsible for the occurrence of mining-induced hazards. Thereafter, the mining-induced hazards cannot be predicted with confidence by considering each process independently. Of course, the requirement to include coupling of these processes depends on the specifics of the mining-induced hazards under consideration. For example, the water inrush is considered as a coupled hydro-mechanical (HM) process, in which the unstable failure of rockmass occurs under the combined contribution of geo-stress and water pressure. As for the coal mining at depth, in addition to high geo-stress and gas pressure in coal seam, the high geo-thermal condition that may greatly change the adsorption / desorption of gas and gas flow should be taken into account. Firstly, a general-purpose mathematical model for rock damage and failure process under coupled THM conditions is formulated based on damage mechanics principle, and it is solved by finite element method (FEM). In this model, the deformation and damage of rock, fluid flow and thermal transfer in rock would interact with each other, one process affects and initiation and progress of another. Then, the model is used to predict the mining-induced water outburst, where it is simulated as coupled hydro-mechanical (HM) problems. Based on the numerical simulation, the dimension of water-proof pillar is designed. Finally, the gas drainage from deep coal seam is numerically evaluated, where the coupled coal-gas interaction considering the effect of gas adsorption/desorption, gas flow in coal seam and geo-stress and geotemperature, is comprehensively taken into account. The proposed model could be used for clarifying the mechanism of mining-induced hazards in deep-level mining.

Jan 1, 2015

By C. W. Davis

This is the first of a series of papers being; prepared as the work progresses in a study of the hydrometallurgy of manganese. The investigation is being made in an endeavor to make possible the utilization of lour-grade domestic manganese ores. The value of a hydrometallurgical process for manganese depends on the present and future uses for manganese products.

Jan 1, 1930

By M. J. Blackburn

The ordering reaction and its effect on dislocation awangements in alloys based on Mg3Cd has been studied by transmission electron microscopy. Ordering occurs by the growth of ordered domains until they impinge, thus producing an antiphase domain boundary (APB) network. In the disordered alloy, slip is confined to the basal plane while in the ordered condition slip occurs on the basal, prism, and pyramidal planes. Superdislocations have been identuied on these planes and their origin and expected spacings are discussed and compared with the observations. The APBs between the dislocation pairs have been resolved and have proved useful in the identification of superdislocations. Observed slip structures are related to the changes in mechanical properties produced by ordering. At high temperatures magnesium and cadmium form a continuous series of disordered hexagonal solid solutions. At lower temperatures three ordering reactions occur; two based on the compositions Mg3Cd and MgCd3 are transformations to DO19-type superlattices while alloys based on the composition MgCd transform to a B19 lattice. The ordering process in alloys near the composition Mg3Cd has been studied by several workers'-4 and it has been shown to be a first-order type transformation. The variation of mechanical properties with the degree of order and temperature have been reported in some detail by Stoloff and Davies.5 It was shown that the disordered alloy was stronger and less ductile than the ordered alloy, the differences being attributed to changes in the number of active slip planes and to the presence of short-range order in the disordered alloy. In this investigation the ordering reaction has been qualitatively followed by transmission electron microscopy. The effect of this ordering transformation on the dislocation arrangements in deformed specimens has been studied in some detail. EXPERIMENTAL Alloys were melted in a stainless-steel crucible under a flux and chill cast; both melting and casting were performed in an argon atmosphere. The ingots were hot-rolled and tensile specimens cut from the resultant strips. Some large-grained specimens were grown by the strain-anneal method. Heat treatment was carried out in inert atmosphere furnaces and in oil baths at the lower temperatures. Thin foils for transmission electron microscopy were produced by electropolishing in a cooled solution (temp = -40°C) containing 50 cu cm of nitric acid and 180 cu cm of methanol at a potential of 10 v. The ordering reaction was followed by transmission electron microscopy, X-ray, and electrical resistivity measurements but this paper will be concerned chiefly with the electron-microscopy results. Much of the work described in this paper was performed on an alloy containing 26.10 at. pct Cd although two of the micrographs are taken from work on a 25.55 at. pct Cd alloy. RESULTS i) The Quenched Solid Solution. Specimens which were quenched from above the critical temperature showed diffuse superlattice reflections. sark-field analysis on these reflections failed to reveal the presence of ordered domains and thus the superlattice reflections were assumed to arise from regions of short-range order. Quenching from temperatures of 400" to 450°C results in the formation of dislocation loops and helical dislocations. Such defects have been observed and analyzed in detail in several hexagonal metals6-' and as the crystallography and interactions of such loops appear similar in this alloy they will not be reported in detail. Fig. 1 shows a high density of loops

Jan 1, 1968

By Gaifeng Xue, Lei Zhang, Xia Liu, Lina Wang, Pu Liu, Benquan Fu

"Experiments were conducted to investigate the behavior of the integrated process with a three-dimensional electrode reactor combined with Fenton process for coking wastewater treatment. Effects of initial pH value, reaction time, H20 2 dosage, Fe2+ dosage on Total organic carbon (f OC) removal rate were investigated. The kinetics of degradation of TOC from coking wastewater by three-dimensional fluid bed electrode reactor combined with Fenton process was also studied. Experimental results shows that three-dimensional fluid bed electrode reactor combined with Fenton process had better synergic effect, average 17.4% TOC removal rate was improved within an hour. It was found that TOC degradation in coking wastewater followed a pseudo-first-order reaction kinetic model. The optimum degradation efficiencies of TOC were up to 60% as pH3.4, 3.5 mM ofFe2+ andl.2-1.8ml/L H20 2 in 90min reaction period. Furthermore, the integrated process showed a rapid reaction performance at a low temperature within a short reaction time and remained high efficiencies for TOC removal. Overall, the integrated process was proved feasible for coking wastewater treatment in practical applications.IntroductionCoking wastewater is generated from coal coking, coal gas purification, and by-product recovery processes of coking, which is composed of phenolic compounds, heterocyclic compounds, polycyclic aromatic hydrocarbons, ammonia, cyanide, polycyclic nitrogen-containing aromatics, acyclic compounds, etc. Most of these constituents are refractory, poor biodegradability, toxic and carcinogenic['-31. Currently, coking wastewater is usually treated by different forms of A/O biological nitrogen removal process as the primary treatment process, but the aforementioned processes are not efficient enough to meet the requirements from the National Discharge Standard in China (GB13456-1992). According to the continuous requirement on improving environmental protection for coking industry (revised 2008), increasing wastewater utilization ratio and reducing discharge of effluent in the coke industry has to be implemented for cleaner production and sustainable development. Therefore, advanced technologies need to be developed to treat coking wastewater and reutilize the product as industrial cooling water, which would be one of the best choices to achieve zero discharge of wastewater and reduce water consumption per ton of steel [4-51 . In this study, three-dimensional fluidized bed electrode reactor combined with Fenton process was adopted to advanced treatment of coking wastewater, and the effects of operating conditions, including H2O 2 dosage, Fe2+ dosage, initial pH, and reaction time on TOC removal rate, were investigated. Meantime, study of kinetics of reaction was estimated."

Jan 1, 2013

By Robert Hunt

(New York Meeting, February, 1913.) I HAVE frequently stated that while the chemical composition of steel is important, yet even greater importance is connected with the mechanical and heat treatment of the metal. During the past year I encountered such a positive example of that fact that I deem it worth putting upon record. A prominent railway system divided an order for open-hearth steel rails between two steel works, both of which are under the control of the one corporation; giving to one about 18,000 tons, and to the other 7,500 tons of the same section and to be made under the same specifications. The rolling results obtained in the two mills varied so widely that a study of the figures is intensely interesting and serves to illustrate the advantages obtained by careful ingot casting, and, quite as pertinently, the possible benefits of careful subsequent heating and rolling with moderate reductions in the rolling process. The smaller order was rolled complete in four installments during the same months that the larger order was being made in six separate installments; but, to permit of exact comparisons, the totals of the four installments (completing the order with the mill which I will call A) are given with the totals of the first four installments of the larger order, made by the mill designated as B. These rolling results are:

Jan 5, 1913

By Yosep Han

Mechanically-induced chemical reactions between natural beach ilmenite (FeTiO3) and silicon (Si) have been examined by a combination of X-ray diffraction (XRD) and scanning electronic microscopy (SEM) analyses. The effect of various milling time on the phase transformation, crystallite size, and lattice strain of a beach sand ilmenite with silicon, and on their leaching behavior in hydrochloric acid (HCl) has been investigated. For mechanically activated FeTiO3, the crystallite size decreased and lattice strain increased monotonically with time of milling. However, the mechanochemically synthesized ilmenite with silicon showed a relatively smaller crystallite size and greater lattice strain compared with the mechanically activated ilmenite under the same milling condition. In accordance with the elapse of milling time, the intensity of both pure FeTiO3 and mechanically activated FeTiO3 gradually decreased. However, in case of the mechanochemically synthesized ilmenitereduction of FeTiO3 by silicon resulted in formation of rutile TiO2 at the milling time of 20 h and afterwards. Additional leaching experiments were carried out at an HCl/ilmenite (wt%) ratio of 20:1. The concentration of HCl was 3 M and the reaction temperature ranged from 70 to 90 oC. Mechanical activation was observed to significantly enhance the dissolution rates of both iron (Fe) and titanium (Ti) in HCl. Particularly, effects of both milling time and silicon addition on the dissolution rates of titanium and iron were significant, while those of temperature were relatively minor under the conditions investigated in this study. Keywords: mechanochemical treatment, natural beach ilmenite, silicon, leaching behavior

Sep 1, 2012

By Hong Yong Sohn

On the occasion of this symposium in my name, I reflect upon the contributions of my academic mentors and early associates who helped shape my professional career. I was fortunate to have these people around me during my graduate work and at the start of my professional career. In forming my view of the technical field and career, they represented academia, research institutions, industry, and different parts of the world.

Jan 1, 2006

By Holly J

Mr. Champness: I wish to congratulate the authors on their paper, which covers a large variety of subjects. Not every mine is in the fortunate position to effect cost reductions by the sinking of a new shaft, but, as the authors have endeavoured to show in their paper, with improved techniques further reductions are possible. I would like to ask two questions. Can the authors give me an approximate idea...

Jan 1, 1956

By Hong Yong Sohn

On the occasion of this symposium in my name, I reflect upon the contributions of my academic mentors and early associates who helped shape my professional career. I was fortunate to have these people around me during my graduate work and at the start of my professional career. In forming my view of the technical field and career, they represented academia, research institutions, industry, and different parts of the world.

Jan 1, 2006

By Fernández H. Carlos

Debido que el subproducto en la etapa de lixiviación de las calcinas de zinc, alcanza un 18% de plomo y 40% de plata en la refinería de Cajamarquilla, es necesario la recuperación de sus elementos valiosos a través de un procedimiento hidrometalúrgico donde se obtengan extracciones en plomo y plata del orden de 85% respectivamente. En este sentido, el texto señala la solubilidad del plomo y la plata en una solución con excesos de iones cloruros y así someter al residuo a una lixiviación ácido clorurante de altas temperaturas y con presencia de un agente oxidante. Una vez obtenida la solución, se divide el plomo y la plata por cementaciones sucesivas con polvo de zinc. Finalmente, se determina la factibilidad del procedimiento para la extracción de los elementos valiosos del residuo y se disminuye los costos de la refinación del zinc.

Nov 8, 1984

By Nathaniel Arbiter

The question of automation of concentrator operations with computer control is under increasing consideration. Some of the problems involved will be discussed from the viewpoint of the availability of the requisite, detailed knowledge of the unit operations. The justification for full-scale automation of a mill must ultimately be economic--an increase in profitability over and above the cost of instrumentation and development, Potential savings would be in three probable directions: decrease in operating labor costs by substitution of machine control; improved metallurgy through continuous effective control; and decreased operating costs by achieving higher unit capacities and process efficiencies.

Jan 1, 1962

By Hong Yong Sohn

On the occasion of this symposium in my name, I reflect upon the contributions of my academic mentors and early associates who helped shape my professional career. I was fortunate to have these people around me during my graduate work and at the start of my professional career. In forming my view of the technical field and career, they represented academia, research institutions, industry, and different parts of the world.

Jan 1, 2006

By E. J. Duggan

CLIMAX ore is an altered and highly silicified granite, about half of the gangue being quartz. Molybdenite is the only mineral recovered and most of it is intimately associated with the quartz in fine veinlets. Other minerals are molybdite, pyrite, and chalcopyrite. Although the molybdite may be readily extracted by hydrometallurgical methods, its content is too low to make this profitable. The pyrite ranges from 2 to 5 per cent and the chalcopyrite from 0.03 to 0.05 per cent. There is not enough copper to make its recovery attractive and one of the problems is its elimination, and that of pyrite iron, from the final product. On account of the high degree of dissemination of the molybdenite and the necessity of eliminating the iron and copper, fine-grinding followed by flotation is the only known feasible method of concentration. Two factors, peculiar to Climax ore, have a predominating influence on the metallurgical attack: (1) Molybdenite is one of the most easily floated minerals. High recoveries may be made with pine oil alone if the

Jan 1, 1946

By Shenghui Guo, Ying Lei, Wei Li, Jinhui Peng, Libo Zhang, Yu Li

"Abstract: In this work, low temperature carbothermic reduction of Panzhihua low grade ilmenite after ball milling were investigated. The ball milling of ilmenite and graphite were processed in a ball mill. The milling process can attenuate the particle of ilmenite, and the ilmenite characteristic peak were broadened and weakened. The reduction temperature and behaviors are studied on the thermo gravimetric apparatus; lower temperature and higher reaction rate were obtained for the reduction of ilmenite with graphite after milled. The reduction temperature and times of ilmenite decreased to 1000-1025°C and 40-60min via milled for 4 or 8h; Low down the reduction temperature can eliminate the solution of Mg2+ and FeTi03 in a certain degree; the reduced ilmenite has an obvious loose structure, can favored the subsequent procedure such as leaching.1 IntroductionThere is about 9.66 billion tons of Vanadic Titan-magnetite deposited in Panzhihua, China. In this reserve, there is about 8.73x108 t ofTi02, Accounting for 90.54% of the Chinese reserves, and 35.17% of the international reserves and ranking first in the world. [JJ Titanium mineral deposits major classified into Rock type and Placer type. Rock type is the igneous mineral, which have great content of FeO (Relative to Fe20 3) and gangue. The rock textures are compact and almost are complex ore. Rock type Titanium mineral major are ilmenite and titan magnetite ore, difficult to separate the metal ore and gangue. l.21 Thus, the Ti02 grade of Rock type ilmenite much lower than the Placer type (Table land 11). Panzhihua ilmenite are the typical Rock-type, due to the higher contents of MgO, CaO and Si02 and the complex mineralogy in ilmenite in Panzhihua region, making its direct reduction progressively more difficult. Mechanical activation, usually carried out by energetic milling or ball milling, was reported to significantly decreased the reduction temperature and accelerate the reaction rate of reduction of ilmenite with carbon, silicon and Magnesium. f3·(>J It reported that the process temperature were decreased to 600-1000°C and the annealing time were reduced to 30-120min after milled for 50-400 h. Shorter milling time involved was imported for else procedure such as direct leaching. 171 Hardly any research had referred to the carbothermic reduction reactivity of ilmeite milled for a short time as 1-1 Oh. In the present work, the aim is to investigate the reactivity and reaction temperature of carbothermic reduction of Panzhihua ilmenite. The Phase composition and micro morphology of samples are characterized."

Jan 1, 2011

By B. R. Queneau

Steel has been chosen as the metal whose solidification will be used to tie in the principles discussed in the previous papers. Although steel is the most important [ ] practical example that could be chosen, its solidification is complicated by the presence of many elements added either intentionally or present as impurities. The liquid steel bath in an open-hearth furnace contains carbon, manganese, phosphorus, sulphur, and many residual alloying elements such as nickel, copper, and molybdenum. The bath also contains oxygen, the concentration of which is a function of the carbon content, as shown in Fig. I. Deoxidizers such as silicon and aluminum may be added either before or after tapping depending on the grade of steel being made. There are four types of steel ingots: Killed, semikilled, capped, and rimmed, and these differ from each other in their state of oxidation. Each type of steel has advantages in the production of specific steel products, and it should be emphasized that no one type should be considered superior to the others. Fully deoxidized steels, known as killed steels, have little or no gas evolution on solidification. When the steel solidifies in the mold, shrinkage occurs which causes a large void known as "pipe." To minimize the amount of metal that has to be discarded on account of pipe, a big-end-up mold is used together with a refractory "hot top" which supplies molten steel to the main body of the ingot while solidification proceeds, Fig. 2. A section through a 32x32 in. ingot is shown in Fig. 3. The "hot top" volume is about 15 pct of the ingot, and the yield from killed steel in billet form is about 8o pct of the ingot weight. High quality machinery and tool steels are rolled from killed-steel ingots, but at the present time this represents less than 20 pct of the total steel production in the United States. In order to reduce cost and to increase

Jan 1, 1951

By Richard P. Rothwell

The communication which I hare to lay before my fellow-members of the Institute, is no elaborate paper, nor the statement of any great discovery; it is simply the record of convenient methods of conducting topographical survey?, and of keeping the notes of the same; methods that have grown out of practical experience, and have saved me many a day's labor by facilitating office and field work, and at the same time secured a greater degree of accuracy than is obtained by the methods now in general use. I assume it as granted that no topographical map is worthy of the name, except it represent the elevations and depressions of the surface by means of horizontal or contour lines. In the Ordnance Survey of Great Britain, the contour lines are traced for every fifty feet vertical height, I believe, by running out the line with level and compass through all its meanderings on the surface; this, of course, is a very tedious, though accurate process, but " in the woods," where many of our surveys have to be made, it would be practically impossible. Some time ago, I made an extensive and quite elaborate topographical survey and contour map of the southern portion of the Cahaba coal-field, in Alabama, the object of the survey being to

By NEWTON C. MARSHALL

AS every school boy knows, the Andes mountain range forms the backbone of South America, extending the full length of the continent along its western edge and fairly close to the Pacific coast. But in Colombia these mountains are divided into three distinct ranges known as the Western, Central and Eastern ranges of the Andes. United at the southern end, they spread out like three fingers in a northerly direction across the Republic of Colombia. These great natural barriers have only in recent years been tarried by railroads or wagon roads, and they have had their effect upon the history of the country, both political and ethnological. Each of the three ranges dies out and dwindles away before reaching the boundary of Colombia on the Caribbean Sea. When I studied my geography as a youngster 1 used to think that the

Jan 1, 1935

By ERIK CHARRIER, ADITYA JUGANDA, Jürgen Brune, Gregory Bogin, Patrick Maier

Confined explosions are a major risk in underground coal mine operations. Depending on confinement, ignition location and obstacles in the flame path, methane explosions can transition to detonations. This research focuses on explosion experiments in a reactor with diameter of 71 cm and length of 30.5 m, along with developing the corresponding computational fluid dynamics (CFD) model that captures the observed flame behavior. The results show that the 2D and 3D CFD models are able predict the experimental flame front propagation velocity, but the 3D model shows more explicit conformity than the 2D model.

May 1, 2024

By Donald J. Olson, Thomas J. Lutzenberger, John Ramage

The North Shore Inline Interceptor, Phase IA tunnel is a 8,550-meter (28,000-ft) interceptor tunnel currently being constructed by Traylor Bros./Frontier-Kemper, Joint Venture, using a 9.8-meter (32-ft - 4-in) diameter Robbins tunnel boring machine (TBM). This tunnel is being driven in Silurian age dolomite approximately 91.5 m (300 ft) below ground surface. Significant water inflows were encountered when the tunnel drive penetrated the thinly-bedded Waubakee Formation. Flow increases approaching 0.75 cu m per min per 30 m of tunnel (200 gpm per 100 ft) have occurred in this formation. After driving approximately 2,285 m (7,500 ft) of tunnel (200 m full face in the Waubakee Formation), total flows exceeded 12 cu m per min (3,200 gpm) with about 5.7 cu m per min (1,500 gpm) entering the tun¬nel from the 200 m (600 ft) of exposed Waubakee Formation. Additional water control measures consisting of increased pumping capacity, increased water treatment capacity, surface grouting ahead of the tunnel, grouting ahead of the tunnel face and panning to improve the working environment for installation of tunnel support, were implemented to deal with the large water inflows. Currently (January 24, 1989), 3,400 m (11,000 ft) of tunnel has been driven, total water inflows are in the range of 11.7 cu m per min (3,100 gpm) with only 6.8 cu m per min (1,800 gpm) inflow from about 1,220 m (4,000 ft) of tunnel driven full face through the Waubakee Formation.

Jan 1, 1989