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By R. H. Hiltz

The Coal Mine Health and Safety Act of 1969 legislated maximum dust levels for the working place. As the law was implemented, extensive efforts were undertaken to provide the technology necessary to control dust generation. One approach to dust control was the use of high expansion foam in place of the usual water sprays on coal cutting equipment. At the time of the act, high expansion foam had already seen considerable testing for the suppression of dust in underground coal mines. Work by MSA, several coal companies and the Bureau of Mines itself had provided data which showed foam to have some merit as a dust control mechanism. It suffered in a few areas, however, which limited its practical application. Its principal difficulty was persistence which hampered operations due to foam buildup, but problems were also encountered due to equipment size and form.

Jan 1, 1975

By Lifeng Li, Jhon Silva-Castro

In a previous work, the authors analyzed the overlapping probability of two adjacent charges in a single hole for pyrotechnic and electronic detonators. This document extends such work to a complete mine blast where more than two holes are detonated. In a mine blast, all the blast holes are connected as a network by detonators to follow a given initiation sequence. Such initiation sequence’s performance is based on the adequate timing between charges in the mine blast. The analysis of the reliability of a mine blast based on the timing between charges and the initiation type is presented in this document. For a long-run time and under proposed operating conditions, the reliability of the mine blast can be analyzed based on the network which is treated as a system. The failure of the system is defined as no success between any two delays charges either in a single hole or in between two holes.

Jan 1, 2016

By Virgil A. Marple

The objective of this contract was to investigate time-integrated and real-time methods for determining the diesel exhaust particulate concentration in underground mines, in particular, coal mines. The microorifice uniform deposit impactor (MOUDI) is recommended for obtaining the time-integrated measurement of the size distribution. The mass concentration of diesel exhaust particles can be obtained from the particle size distribution of mine aerosols. On a mass basis, diesel exhaust particles are primarily in the submicrometer size range while coal dust particles are larger. Size distribution measurements made in the laboratory and in three underground coal mines exhibited two distinct modes with the diesel exhaust particles in the smaller particle mode and the coal particles in the larger particle mode. The point of separation between the two modes occurred in the 0.7 to 1.0 pm size range. The separation was found to be independent of mass fraction of the diesel exhaust particles, particle concentration and sampling site. Methods recommended for further consideration as real-time monitors of diesel exhaust aerosols in mines are photometers and filter pressure drop techniques. A preclassifier would be required in both cases to separate the larger dust particles from the sample. The Metrex Mineral/Diesel Photometer should also be investigated further once the electronics problems are eliminated.

Jan 1, 1986

By E. Martinez

Samples of chrysocolla, a hydrated copper silicate, from several sources were submitted to differential thermal analysis (DTA) and thermal gravimetric analysis (TGA). Pure samples of chrysocolla are difficult to obtain, but comparison of the thermograms revealed that certain reactions occurred in all the samples and it is believed that these are due to chrysocolla. Endothermic reactions occurred at 50' to 175°C, 350° to 650°C, and 980° to 1100°C each of which caused a weight loss. The first was due to loss of absorbed water, the second to a dehydroxyla-tion, and the last to conversion of cupric oxide to cuprous oxide. In addition, two exotherms were detected at 685° to 695°C and 935° to 950°C. Infrared spectra of heated samples indicated the exotherms were due to changes in the Si-O bonds leading to the formation of cristobalite. The results suggest that thermoanalysis may be a more sensitive and reliable method for detection and identification of chrysocolla than X-ray diffraction, infrared spectroscopy, or optical techniques. The recovery of copper from oxide ores has been the subject of much research in recent years. One of the principal oxide copper minerals is chrysocolla, a hydrated copper silicate. The information available indicates that it has widely varying properties depending on the origin of the sample. Chrysocolla usually is found associated with cuprite, malachite, azurite, and native copper. Most of these other minerals are recoverable by present day flotation practice, but chrysocolla is lost in the tailings.1,2 Reagent combinations that are successful in laboratory chrysocolla flotation with ore from one source have been found to be ineffective with another. 3 The copper segregation process offers an altemative to beneficiation of oxide copper ores.4'5 The process is of particular interest in processing ores that cannot be treated by conventional hydrometal-lurgical methods because of high acid consumption.6 Fuller understanding of the properties of chryso- colla may prove of value in the search for improvements in both the flotation and segregation processes. Chrysocolla samples from Arizona, Nevada, Chile, Australia, and South Africa were studied by differential thermal analysis (DTA) and thermal gravimetric analysis (TGA). In addition, a sample from Miami, Ariz., was submitted to X-ray diffraction, infrared spectrophotometry, and surface area determination. EQUlPMENT Differential thermal analysis (DTA) detects, amplifies, and records exothermic-endothermic reactions occurring in a sample as its temperature is raised at a constant rate, usually 10°C per minute. A unit made by the Robert L. Stone Co. was used in this study. The tests can be run if desired with a gas streaming through the sample. A thermobalance records weight losses or gains in a sample as its temperature is raised at a uniform rate. The gravimetric analyses (TGA) were run on a Chevenard thermobalance converted electronically for graphic recording. A heating rate of 5°C per minute up to 1100°C was used in these tests. A Perkin Elmer Infrared Spectrophotometer, Model 221, was used with sodium chloride optics obtaining IR spectra in the 2 to 15 region. A pressed pellet technique with potassium bromide was used in preparing the samples. DESCRIPTION OF SAMPLES Chrysocolla is found in the oxidation zones of copper deposits commonly associated with malachite, azurite, and limonite. It is described as varying in composition and in color from bluish green to brown or black. Inclusions of other minerals are usual so chemical analysis of chrysocolla samples may be suspect. However, it is considered by many to be a solid solution of CuO, SiO2 and H2O with a general formula of CuO.SiO2.2H2O or 2CuO.2SiO2. 3H20. Chukhrov7 has described a sample from the Urals as CU3,5(OH)2 (A1Si3) O10.nH2O and stated that chrysocolla is a montmorillonite-type mineral. On the basis of X-ray analyses, DTA, and infrared spectra of chrysocolla from the Inspiration Mine, Ariz., Sun8 concluded that there was no substantial evidence to classify it as a montmorillonite mineral. Chrysocolla samples from many sources throughout the world were used in this investigation. The following is a brief description of each:

Jan 1, 1963

By W. R. Toeplitz

Probably a more descriptive title would be "Much Ado About Nothing." By "nothing," of course, I refer to the porosity which is the main feature of this type of bearing. Porosity has a decided effect on the manufacturing techniques, the structure and physical properties, the oil content, and on the installation and service of oil-retaining porous bronze bearings. A simple curve can be drawn by plotting specific gravity along the abscissa and percentage of porosity by volume on the ordinate. A bronze composition, analyzing 89 Per cent copper, 9.75 Per cent tin, and 1.25 per cent graphite, has an absolute solid specific gravity of 8.5. At this specific gravity, of course, occurs the point of zero porosity. Conversely, at loo per cent porosity, the specific gravity is zero. A similar curve can be drawn for bearings impregnated with oil; the only change being that the specific gravity at loo per cent oil will be 0.89 if we assume that that is the specific gravity of the lubricant. The curve is useful in determining the oil content by volume for any specific gravity. The normal range of oil content for porous bronze bearings of this composition is from 35 to 16 per cent, which is in the specific gravity range of from 5.8 to 7.3. In addition to the amount of porosity, the type of porosity is important. The first consideration here is that the porosity must be intercommunicating. This can be determined by a number of simple tests. The first method, which is very accurate, is to extract the oil in the bearing by cycling

Jan 1, 1945

The Effect of Bulk Iron Concentration on the Copper Activation of Sphalerite at pH 9

Sep 13, 2010

By Y. Ichihara, H. Matsumoto, K. Itakura, H. Eguchi, G. Deguchi, K. Sato

Mechanical data from a rockbolt drilling machine, such as torque, thrust, revolution and stroke, are useful for understanding the geological and geomechanical conditions around roadways and hence selecting the optimum bolt type and density. Laboratory experiments showed that the level of torque or thrust reflects differences in rock type, with separation of strata and cracks appearing as a specific pattern. Algorithms of neural networks based on adaptive resonance theory and back-propagation were used to extract the pattern and estimate the location of discontinuities. For field testing in an underground coal mine, a prototype data acquisition system was attached to a portable drilling machine. Several sets of logging data from one locality were combined to construct a two-dimensional model of the strata, from which the slope angles of discontinuity faces could be estimated

Jun 19, 1905

By H. Tomlinson

"INTR0DUCTIONThis publication is a third of a series devoted to falls of roof and coal in coal mines of the Western States. It gives the results of examinations of the mines of the Rock Springs coal District of Sweetwater County, Wyo., which represent the principal coal beds therein and approximately 75 percent of total production of the State.A study was made of safety conditions at all the producing mines of the district and suggestions were offered the operators regarding methods and practices which would, in the opinion of the writer, provide additional safeguards to prevent accidents from falls of roof and coal.In presenting the subject, consideration must be given to such features as character of the coal beds, depth of cover. methods of mining, timbering practice, roof testing and supervision, and for comparative purposes to certain statistical matter bearing upon relation of accidents to their causes, tonnage produced, men employed, days worked, and lost days due to accidents during the 3—year period covered by this study.ACKNOWLEDGMENTSThe writer acknowledges the cooperation of the officials of the various coal companies, without whose assistance this work could not have been completed.F0UR REPRESENTATIVE COAL OPERATIONSThis report relates to four representative coal operations in the Rook Springs district of Sweetwater County, Wyo., which are referred to as mines A, B, C, and D. This group employs yearly an average of 993 men, representing 37 percent of the men in coal mines of the county, and has an average annual production of 1,484,373 tons, representing approximately 44 percent of the coal produced in the county. Figure 1 is a map of the Rook Springs coal district."

May 1, 1933

By Donald E. Grimes

In conjunction with Inland Steel&apos;s development of lead-bearing steels possessing improved machin-ability because of tellurium and/or selenium additions, it was decided to determine liquidus and solidus temperatures in the Pb-PbTe-PbSe sub-ternary system. With the exception of alloys in the PbTe-PbSe system, it is believed that no previous study of this subternary has been performed. Thermal analysis was employed in a general survey of the subternary. In addition to PbTe, PbSe, and pure lead, ten ternary compositions were selected at intervals of ten at. pct. Sixty-gram alloys were prepared by sealing an appropriate mixture of the elements in quartz crucibles with a central thermocouple-well under a vacuum of less than 10 p. All three elements were 99.999+ pct pure with only trace impurities detected by spectroscopic examination. After the alloys had been heated at least 20°C above the liquidus in a Kanthal furnace, cooling and heating curves were obtained. Two or more cooling curves were employed both for the determination of each alloy liquidus and for the solidus of those al- loys containing greater than 50 at. pct Pb. Cooling rates were 0.5° to 3.5°C per min during the 5 min immediately prior to the start or end of solidification. For those ternary alloys containing 50 at. pct Pb, the solidus was determined from heating curves. Temperatures were measured with a Pt/Pt-10 pct Rh thermocouple which was calibrated in the same apparatus against the freezing points of zinc (A. D. MacKay—99.999 pct), antimony (A. D. MacKay-99.999 pct), and copper (ASARCO—99.999+ pct) both before and after the experimentation. The only interruptions in the continuous strip-chart recording of the temperature occurred for brief periods at significant points of interest when direct readings were made with a Rubicon Type B potentiometer sensitive to * 1 µv. The average liquidus and solidus temperatures obtained in this investigation are listed in Table I together with probable errors based on the accuracy of the thermocouple calibration and the reproduci-bility of the data. No chemical analyses of the alloys were performed because the synthetic or as-charged compositions were felt to be reliable. The melting points obtained for PbTe (924.7° ± 0.7°C) and PbSe (1084.0° ± 0.6°C) compare favorably with recent findings of other investigators.&apos;-&apos; As indicated in Table I, both the liquidus and solidus temperatures increase as selenium replaces tellurium for a constant atomic percent lead. As a result, the ternary liquidus and solidus temperatures for a given percent lead lie between the corresponding binary temperatures published in the literature. It should be noted that those ternary alloys containing 50 at. pct Pb exhibit a relatively narrow liquid-plus-solid region (<80°C) when compared with alloys containing greater than 50 at. pct Pb. Alloys with 60, 70, or 80 at. pct Pb not only have a much wider liquid-plus-solid region (>500°C) but also exhibit considerably lower and approximately constant solidus temperatures which thus form a virtually isothermal solidus "plane" slightly below the melting point of pure lead (327.3°C). For these alloys

Jan 1, 1965

By Ronald E. Triplett, George K. Burke, Bernard H. Voor

To accommodate larger double-stack rail cars through a tunnel, the existing active tracks were to be lowered. The tunnel is an elliptical, horseshoe-shape with concrete base support, removal of which would jeopardize the tunnel integrity, particularly since the soils beneath part of the tunnel floor included soft, saturated silt overlying rock. Grouted bar anchors combined with a SuperJet soilcrete strut replaced the existing support in situ prior to floor lowering. Close cooperation and detailed timely engineering support provided a quality project. Project design and construction, ground improvement methods, and the performance of the work are described.

Jan 1, 2001

By Rahul Singh, Sunil Kumar, Erich Dohm, Maoming Fan

The rapid increase of P2O5 use for food, biofuels, and LiFePO4 batteries etc. accelerates the depletion rate of phosphate reserves. In the phosphate industry, a significant amount of ultrafine phosphate has been discarded as slime tailing due to processing difficulties. The major problems associated with ultrafine particle flotation are low probability of bubble-particle collision and adhesion, and high probability of unwanted gangue particles entrainment. This paper investigates the enhanced ultrafine phosphate particle flotation probability by Eriez’ CavTube generated fine/ ultrafine bubbles and the improved flotation selectivity by wash water etc. Ultrafine phosphates with various gangue minerals of quartz/muscovite, calcite/dolomite, and iron/ silica were studied. Microscopic observations show that the entrained ultrafine gangue minerals can be minimized by using wash water in column flotation. A three-factor threelevel central composite experimental design was conducted for ultrafine phosphate flotation. For comparison, both benchtop mechanical cell and laboratory column flotation tests were performed at their optimal respective flotation conditions. Using Eriez CavTube column flotation technology for Industries Chimiques du Senegal (ICS) ultrafine slime tailings, a concentrate grade of 36.0% P2O5, was achieved at 89.4% P2O5 recovery. Improved flotation performance was achieved using column flotation as compared to benchtop mechanical cell flotation. The benefits of Eriez’ column flotation technology realized from this study include the high P2O5 grade and recovery.

Feb 1, 2024

By Andréa Lagacé

"The milling of sulphide ores inherently generates “thiosalts”, a series of partially oxidized sulphur oxyanions (S2O3 2-, S3O6 2-, S4O6 2- etc.), which make control of effluent treatment systems difficult because their natural oxidation produces acid with the potential to lower the pH within the treatment system and/or receiving environment.At the Xstrata Copper Kidd Metallurgical Site, thiosalt oxidation in the Tailings Management Area continues after buffer storage Ponds A and C where lime is added to precipitate metals and elevate the pH to within the required range for discharge. If the additional acidity generated during the continued process of thiosalt oxidation is not neutralized there is a risk that the final effluent will be non-compliant with regulated standards.To mitigate this risk, in 2007 a full scale pilot trial was conducted with hydrogen peroxide in order to force the complete oxidation of thiosalts prior to the lime treatment stations. This method of chemical oxidation had been shown to be effective at Xstrata Zinc’s Brunswick Mine. The pilot results indicated that a maximum of 50% of the stoichiometric quantity of hydrogen peroxide is required to reduce the thiosalt concentration in the No. 2 thickener overflow stream (feed to buffer storage Ponds A and C) to less than detection (10 mg/L); however, treatment was only effective in the presence of a 20 mg/L iron (Fe) catalyst. Since the hydrogen peroxide addition point at the No. 2 tailings thickener overflow typically contains <1 mg/L total Fe, a second reagent, ferric sulphate, was used to increase the total Fe concentration to the required level. This paper describes the set-up and results of the pilot trial which were used in the design of the full-scale plant.INTRODUCTIONTailings Management Area OverviewXstrata Copper’s Kidd Metallurgical Site, located in Timmins, Ontario, is an integrated metal refining facility producing copper, zinc, cadmium, indium, liquid sulfur dioxide, and sulfuric acid from third party custom feeds, and mineral concentrates recovered from its 7,800 tonne per day mill."

Jan 1, 2010

By Sandip K. Mukherjee

This report presents the results of the economic analysis of several applicable alternatives to increase airflow in four underground coal mines. Pressure-quantity surveys were conducted underground and measurements were also made at the main mine fan(s). The existing ventilation networks were modeled using the modified Penn State ventilation simulator. The applicable alternatives were simulated. Performance data obtained from these simulation runs were utilized to conduct the cost-effectiveness analysis. The costs for each of the alternatives included capital, operating and operating costs. These costs were expressed as annual ventilation costs per active section in terms of dollars per cfm taking into account the economic life associated with each of the alternatives. The benefits were expressed as increased airflow quantity in the critical sections. A section of this report also deals with comparison of simulator predicted air quantity values against air quantity values measured under-ground. This volume constitutes Volume II of the report and contains the outputs of the computer simulation runs.

Jan 1, 1983

By Mariana Sizenando Lyrio, Fernanda Nascimento Moreira, Weslley Luiz da Silva Assis, Harison da Silva Ventura, Gabriella Maria Silveira de Sá, Ana Gabriella Conceição dos Santos

surgimento de fases intermetálicas em aços é matéria de grande interesse devido ao caráter nocivo que elas podem conferir às propriedades mecânicas do material. No presente trabalho, foi estudado o efeito do surgimento da fase sigma em um aço inoxidável duplex através de modelamento numérico-computacional. A microestrutura duplex foi obtida via simulação, sendo, então utilizada como matriz para a nucleação e crescimento da fase sigma, também via simulação. O método do Cone Causal foi utilizado para o desenvolvimento da microestrutura e os resultados foram comparados com a metodologia da cinética formal de JMAK para fins de validação do modelo. Os resultados da simulação permitem obter, através da Regra das Misturas, predições sobre as propriedades mecânicas do material, no caso, o limite de resistência à tração, que foi comparado com os dados encontrados na literatura. Foi possível constatar o aumento do limite de resistência à tração para maiores frações volumétricas de sigma, o que traz como resultado a diminuição da ductilidade para o aço.

Nov 17, 2019

By Zhong g. Shui-ping

A new type Pb-Ag (0.8wt%)-Bi (0~5.0wt %) alloy used as anode in electrowinning of zinc from sulphuric acid electrolytes was prepared. The electrochemical properties of this ternary lead alloys have been tested and compared with those of Pb-Ag (0.8wt %) anodes used in industry. Results show the anodic overpotential decreases with the increasing of Bi content in the alloys. When the content of Bi was 1.0 wt% and 5.0 wt%, the anodic overpotential is about 40?50 mV and 60?80 mV lower than that of Pb-Ag (0.8wt %) alloy, respectively. The formation of oxide layers on the surface of these alloys was traced by LSV methods and the composition of the anodic oxide layers was characterized by XRD and SEM analysis. The surface layer on the two type anodes examined is mainly composed of a?PbO2 and ß?PbO2. But different structure of the surface layer was observed, Pb-Ag (0.8wt%)-Bi (1.0wt %) has a more fine-grained structure as compared to Pb-Ag (0.8wt %). But the film on Pb-Ag (0.8wt%)-Bi (3.0wt %) alloy is rather friable, cracked and not tightly attached to the anode.

Jan 1, 2008

By Peter Klaver

Deep tunnels have been used for decades for the temporary storage of large volumes of urban runoff, both storm water and combined sewer overflow (CSO). Tunnels are attractive because they reduce surface disruption and do double duty as storage and conveyance systems, collecting overflows from multiple locations and transporting them for treatment to various facilities. Like any hydraulic system, however, there are dynamic effects that must be fully understood during the design phase so that the final constructed product does not have unintended negative consequences. Preliminary sizing of storage tunnels is typically based on the total volume required. For example, if studies have determined that a volume of 56.8 ML (15 million gal) will provide the intended level of control, then that figure can be used, along with a preliminary idea of the desired tunnel length, to compute the required diameter. Of course, filling a long tube with water from various points along the way is not at all the same as pouring water into a bucket, and these dynamic effects require additional attention from design engineers. The rapid filling of storage tunnels can lead to the formation of bores, which are essentially moving walls of water. An open channel bore can build in height until it reaches the crown of the tunnel, at which point it becomes a pipe-filling bore. Figure 1 depicts both kinds of bores moving upwards in a rapidly filling tunnel. Bores can strike the ends of tun-nels with tremendous force, driving water and entrained air upwards into dropshafts and creating strong pressure surges in portions of the tunnel that are already filled. If the hydraulic surges are high enough to reach grade, they can cause overflows and/or damage structures at the surface. Trapped air pockets can occur through several phenomena, including the reflection of bores off dropshaft structures and the occurrence of ?premature pressurization.? The latter refers to the situation where the inflow to a tunnel is increasing more rapidly than the tunnel can convey it, such that the pipe becomes surcharged at an upstream point while points downstream are still flowing as an open channel. These air pockets are a great nuisance as they migrate toward points in the tunnel where they can rise to the surface, which are often shafts that are already filled with water (Fig. 2). The ?geyersing? that results can be hazardous and costly.

Jan 3, 2010

By J. W. Town

The Bureau of Mines conducted petrographic classification and flotation studies to determine if acid-grade concentrates could be obtained from individual and composite samples from the Meade Peak member of the Phosphoria Formation, Idaho. The petrographic studies were made to determine the effect of compositional features on concentration of phosphates. The ore grade, ovule size, and clay content were the main features affecting grade and recovery of phosphate. Flotation results on roasted ore with a tall oil emulsion scheme showed that beds containing over 10 percent P2O5 could be beneficiated and composited with the two high-grade beds to produce a composite concentrate containing 31.9 percent 05 at 84.3 percent recovery. Treatment of these intermediate-grade phosphate beds by flotation increased ore reserves over 200 percent and increased the ore-to-waste ratio in the ore zone from 1:5.7 to 1:0.27.

Jan 1, 1966

By Marcos Natan da Silva Lima

O aço com alto manganês tem sido estudado como alternativa mais barata em substituição às ligas de aço mais utilizadas, devido as suas propriedades de resistência, ductilidade e tenacidade. Foi alterada a composição de manganês para teores acima dos teores dos aços Hadfield, visando sua aplicação em temperaturas criogênicas. Foram obtidas ligas de aço com alto teor de Manganês através do processo de fundição. O objetivo é avaliar as alterações provocadas pelo aumento do Manganês no aço fundido. Através do estudo realizado no Thermo-Calc®, as amostras da liga fundida foram submetidas à laminação a quente e posterior tratamento térmico de solubilização a 700 ºC, com o intuito de manter a microestrutura austenítica. As mesmas foram analisadas quanto à microestrutura por microscopia ótica (MO) e microscopia eletrônica de varredura (MEV). Os ensaios de dureza realizados confirmaram a elevada dureza das ligas, bem como a variação entre as ligas no estado fundido e solubilizado.

Oct 30, 2017

By Anderson Rosa Pereira

A constante busca pela excelência na qualidade do material produzido tem gerado demanda para métodos precisos e de determinação on-line das características do material. Os métodos hoje utilizados para coleta de dados de rugosidade superficial geram amostras randômicas ou concentradas no início ou fim da bobina, o que não necessariamente mostra com precisão a rugosidade de todo o material produzido, e impossibilitam uma intervenção mais direta, precisa e automática nos parâmetros de laminação, objetivando um melhor aproveitamento dos cilindros, redução de custos e controle sobre este importante parâmetro de qualidade. Esta publicação descreve o funcionamento e a aplicação do sistema de medição de rugosidade on-line EMGSORM 3plus no controle automático de rugosidade desenvolvido para um skin pass mill. Assim, a linha principal deste artigo mostra através de um exemplo prático a aplicação de um sistema de medição de rugosidade on-line e seus benefícios.

Aug 16, 2017