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By E. Legault-Seguin

The current industrial practice in the processing of nickeliferous laterites involves the precipitation and releaching of Ni and Co to allow separation from the major impurities of Mn, Mg and Ca. A direct solvent extraction process has significant advantages over this practice, which suffers from difficult and costly precipitation steps, lower recovery and inherently complex flowsheets. The present investigation involves the examination of Cyanex 272, Cyanex 301 and Cyanex 302 as extractants for the direct extraction of Ni and Co from major impurities associated with laterite leaching, i.e. Mn, Mg and Ca. For Co extraction, Cyanex 301 and Cyanex 302 are superior to Cyanex 272, because they are able to selectively separate Co from Mn, Mg and Ca. Cyanex 272 offers complete extraction of Co from Ni and Ca, but Mn and Mg pose difficulty. Ni can only be extracted selectively with Cyanex 301, thus another extractant selective for Ni, such as Versatic 10 or Cyanex 301, is needed to recover Ni if Cyanex 302 or Cyanex 272 is used for the initial extraction.

Jan 1, 2004

By Ann M. Hagni

Electric arc furnace (EAF) dust from the secondary steel industry contains lead, cadmium, and chromium that causes it to be classified as a hazardous waste. Pyrometallurgical treatment of EAF dust is directed at recovering zinc and simultaneously rendering the dust non-hazardous. The mineralogy of the EAF dust is important in determining the occurrence and phase relationships of the zinc, lead, cadmium, and chromium contents. The principle phases in EAF dust as determined by reflected light microscopy, SEM-EDS, and XRD are solid solutions of the iron spinels (franklinite, magnetite, and jacobsite), zincite, hematite, and Ca-Fe-Si glass. Chromium is present in small amounts in solid solution in the spinels. Cyclone sizing of the minus 53 pm particles shows that more than 50% of this size fraction are less than 10 pm in diameter. The <I0 pm particles contain zinc as both franklinite in solid solution with magnetite and jacobsite, and zincite as determined by transmission electron microscopy and XRD. Auger electron spectroscopy did not detect coatings of volatile phases on the surfaces of EAF dust particles.

Jan 1, 1994

By OÆNeil G. R

The gold adsorption capacity of ash-char and ion exchange resin Zerolit F.F. (I.P.) was evaluated by obtaining Freundlich isotherms in the presence of selected variables. It was found that the presence of Na , 2+, Ca 2+ cations and SO4 , CN , S Z, 0 2- Zn anions prompted adsorption of gold onto the char and reduced gold adsorption capacity of the resin. Temperature, particle size of adsorbent and pH of solution were found to influence the gold adsorption capacity of char and the resin. The most efficient desorbent for gold adsorbed on the ash char was S2 ions. Optimum sulphide concentrations were found in the region of 1% Na2S. Investigation into the concentration of gold from actual carbon contaminated gold residue dumps in Kalgoorlie area onto ion ex- change resin showed limited success in one case and not so in another. Maximum gold adsorption by the resin appeared when cyanidation and sulphidization treatments were carried out simultaneously in the presence of the resin.

Jan 1, 1979

By Benj. Lazer

Multiple seam mining has been studied and writ- ten about extensively in the past and in the latest review of the subject in 1956 David Stemple covered it exhaustively. The present discussion has to do with only one phase of the problem-"The effects on upper seams when the lower seams have been mined first." The study presented here is based on observations made in mining operations in southern West Virginia and adjoining areas of Virginia and Kentucky during the past 43 years. These observations are largely confined to the Pocahontas coalfields of southern West Virginia which have, since 1883, produced well over one billion tons of coal from an area of about 300 sq miles and where multiple seam mining has been active, or is now active, at more than 40 operations. The observations and conclusions as to the effects on upper seams when lower seams have previously been mined are therefore related only to the local coalfields in the area of the three states named but I believe that they can be applied generally to other coalfields.

Jan 9, 1965

By I. M. Charles

Mr. Chairman and Gentlemen: At the request of our Secretary, Mr. Shubart, I am pleased to present the following brief discussion of the Alamo Washery. In order to insure an excellent and uniform preparation of nut coal, the Alamo Coal Company erected last year a modern washery at a cost of about $50,000, in which, since the completion last December, all of the nut coal shipped from the Alamo Mine, has been washed. In part of the workings of the Alamo Mine, the coal is overlaid by a lenticular strata of slate, which invariably falls when the coal is shot down and breaks for the most part into fragments of such size as pass through three-inch round perforations, and are retained on plates having one and a fourth inch round holes with the nut coal. This "draw slate" comprises the principal impurity in the Alamo coal, and to remove it, some bone and a few small fragments of sandstone from the roof and floor, the washery was designed and erected. The few impurities contained in the lamp are readily re-

Jan 1, 1926

By John R. Hoskins

Uniaxial compressive strength of rock is usually determined in the laboratory from cylindrical samples that vary in diameter from 5/8 to 8 inches, using a spherically seated compression head of unspecified size. The Bureau of Mines conducted a series of tests on limestone, marble, sand-stone, granite, and plaster of paris to determine the influence of the spherical head sizes and the specimen diameters themselves on the uniaxial compressive strength. Cylindrical samples of several different diameters of each rock type, all having a length of twice their diameter, were prepared and broken using at least three different diameter spherical heads. Analysis of the data shows that spherical head size does not significantly affect the uniaxial compressive strength of cylindrical rock samples. However, the diameter of the rock specimens does significantly affect the uniaxial compressive strength. Within the range of specimen diameters tested, a coefficient of variation of 6.4 percent for plaster of paris can be attributed to the selection of specimen diameter alone. Similarly, a maximum coefficient of variation of 4.7 percent for the rock types tested can be attributed to the specimen diameter alone.

Jan 1, 1969

By M. D. Cooper

LUCIEN EATON, Ishpeming, Mich.-It is not the custom in the Lake Superior region, as far as I know, to employ shot-firers. Each man, or pair of men (most of the contracts are given to two men) do their own firing; each contractor keeps his powder separately. The general custom is to distribute powder (dynamite only is used) to the mines 2 days a week. The boxes, marked with the contract number and the level, are taken underground and the men take them to their working places. They are kept in boxes, which must not be nearer together than 50 ft. and are usually away from the timber roads or traveling roads. When holes have been drilled, one man usually takes down the machine, and the other man makes up the charge. He cuts the fuse, puts in the caps, etc., at a distance from the powder box. He then carries the powder charges to the working place where both men charge the hole. They do their own firing and warn others coming from any direction that the holes are being fired.

Jan 4, 1917

By K. A. du Preez, P. J. van Staden, M. van Rooyen

Mine-impacted water, including acid mine drainage (AMD), is a global problem. While precipitation of dissolved metals and neutralization of acidity from mine-impacted water is accomplished relatively easily with lime addition, removal of sulphate to permissible discharge limits is challenging. This paper presents a high-level comparison of four sulphate removal technologies, namely reverse osmosis, ettringite precipitation, barium carbonate addition, and biological sulphate reduction. Primarily operating costs, based on reagent and utility consumptions, are compared. Each process is shown to be subject to a unique set of constraints which might favour one over another for a specific combination of location and AMD composition. Access to and cost of reagents would be a key cost component to any of the processes studied. The total cost calculated for each process also depends on the type of effluents that are allowed to be discharged.

Oct 1, 2021

By William Hutton Blauvelt

An official of one of the prominent iron companies of the South recently made the following statement during a discussion of the present conditions of the Southern iron business: " The trouble with us in the South has been that we have been satisfied to buy iron and coal lands, build blast-furnaces, and make pig-iron. We stopped at pig-iron, and as a result we are all poor. The South needs diversified industries, and needs to work up its raw products into articles the Southern market can use. If we had realized this sooner, some of us might now be rich." The South is awakening to this view, and in the Birmingham district alone one basic steel-mill is already in operation, and in a year&apos;s time another and much larger one will be turning out rails and shapes, with rod- and wire-mills in prospect. It is to chronicle another metallurgical step forward in the same district that I have prepared the following description of the new by-product retort coke-oven plant recently put in opera-

Jan 1, 1899

By Tiago Webber

Mineral resources estimation comprises basically two stages: (i) data collection, analysis and validation, and (ii) the estimate of the grades and tones of the deposit. The most applied method for sampling survey in mineral exploration is rotary drilling with total core recovery. High drilling costs make borehole geophysical logging attractive to obtain the maximum possible information from each borehole helping to understand ore intersections, grades variability, limits of the deposits and continuity of the mineralization. In this paper, borehole geophysical logging was used to enhance the sampling survey and to derive grades indirectly (without lab analysis) with a certain amount of uncertainty. Indicator kriging (IK) was the estimation method used, as it is adequate to incorporate the uncertainty associated with the geophysical derived grade values. The results were compared to the conventional procedures using grades determined via core analysis and ordinary kriging. Borehole geophysical logging proved to be efficient to define the essential features of ore deposit and IK provided results with acceptable precision and accuracy if compared to the model provided by ordinary kriging.

Oct 1, 2009

By C. H. Gorski

Evaluation of raw materials for mineral wool is one phase of the Bureau of Mines broad program for the more effective utilization: of our mineral resources. The experimental work and test-evaluation results on several raw materials as useful components for the production of mineral wool are presented in this report. Samples from all sections of the United States, including copper slag from Tacoma, Wash., pebble phosphate slime from Florida, and granites from Massachusetts and Minnesota, have been blown into mineral wool successfully in the laboratory tests. Maximum conservation of the Nation&apos;s mineral and manpower resources requires maximum utility of those resources. Al though the domestic reserves of oil, gas, and coal are tremendous, judicious use of these fuels through the use of proper insulation will insure the highest thermal efficiency. The effectiveness of mineral wool as a heat-insulating material has assumed an increasingly important role in the national economy, and it has become a fuel saver in countless applications. The most immediate concern to many is the use of mineral wool in the home, which promotes uniform temperature and minimizes drafts by reducing heat transfer through the walls, ceiling, and floors. There are, however, many industrial and commercial uses that require large volumes of mineral wool each year.

Jan 1, 1951

By L. A. Jordan, D. van Vuuren

A two-dimensional finite difference model has been developed to describe the reduction of kilogram quantities of dehydrated phosphogypsum. The model’s scope has been limited to focus on the heat transfer and reactions that occur within a mass of material contained in a vessel inside a furnace rather than also including the effects of heat transfer to the vessel. Changes in the heat transfer properties (k, ρ, and Cp) are incorporated as the composition of the mass changes as the chemical reactions progress. The model is validated against experimental data, with samples heated to 1000°C at 3°C min−1 while purging with nitrogen gas. A sensitivity analysis of model predictions to the pre-exponential factor of the reaction rate constant of the main chemical reaction and the thermal conductivity of the powder bed indicated that, at the envisaged process conditions, the behaviour of the system depends much more on the rate of heat transfer than on the rate of the chemical reaction. The model demonstrated a significant increase in accuracy when the thermal conductivity was modelled to increase linearly with temperature compared to assuming a constant value.

Oct 1, 2022

By E Nettleton, A Melkumyan

A probabilistic system for autonomous tracking of excavated ore in mining would be highly valuable. Currently, mine sites can have a vast array of sensors; examples include excavator load cells, bucket volume estimators and haul truck strut pressures which can be used to gather information about the excavated ore at different locations. These sensors can be utilised efficiently to increase the accuracy of mine estimates by introducing a real-time ore tracking system. This requires the introduction of a probabilistic ore tracking framework to consistently fuse information from any sensor input. Current modelling practices are manually intensive, deterministic (no recognition of the quality of data) and generally not a complete end-to-end system. This paper will provide a novel method for tracking extensive ore properties (mass, volume) and intensive ore properties such as chemical composition (eg Fe per cent, SiO2 per cent, Al2O3 per cent). This method is proved to ensure that correct correlations between states are conserved as material is transferred, combined and/or separated at different locations with any configuration of sensor inputs. This ensures that consistency of estimates is maintained and other benefits such as real-time probabilistic reconciliation can be implemented. A method for combining material of different mass and chemical compositions is also developed to enable accurate and efficient operation of the system. Representative experiments on a small-scale and a larger field trial which mimic the mining processes of excavation, haul and unload to ROM Stockpile will be used to verify the approach.

Sep 26, 2011

By F. J. Zuiderweg, G. G. Bemer

Results of a study aimed at assessing kinetics and mechanisms of the batch agglomeration process in suspension are discussed. A recently developed light backscatter technique which enables the increase of average particle size from 1 to 5000 µm to be followed, was used to determine agglomeration kinetics. Growth curves and agglomerate size distributions were obtained in a stirred vessel for various model systems and operating conditions. Four distinct growth regimes were identified, i. e. the flocculation regime, the zero-growth regime, the fast growth regime, and the equilibrium regime. Further, it was observed that large differences in the occurrence and duration of these regimes resulted from small variations in parameters, such as size distribution of the initial particles and the binding-liquid to solid ratio. Mechanisms that determine the occurrence of the relevant regimes are discussed. The growth process was described in terms of population balance equations. In this way, the growth rate, the equilibrium agglomerate size distribution, and the evolution of the agglomerate size distribution were generated. The agreement with experimental results is satisfactory.

Jan 1, 1980

By E. T. Hayes, A. H. Roberson, M. H. Davies

ZIRCONIUM has been produced on a pilot-plant scale for only a few years, but the potential uses have led a large number of research establishments to engage in a thorough study of the metal and its alloys. The work described in this paper is part of a cooperative project between the Bureau of Mines and the Air Materiel Command. The Zr-Cr system was one of the first investigated because of the possibilities of improving the properties at elevated temperatures, the chemical corrosion resistance, and the mechanical properties of zirconium in a manner similar to the enhancement of the properties of titanium by additions of chromium. There is no published work on the Zr-Cr system but from the similarity of the metals involved it was expected that it would be similar to the Zr-Fe&apos; and Ti-Cr&apos; systems. The materials used in this investigation were prepared in the Bureau of Mines laboratory at Albany, Ore. Zirconium was produced by magnesium reduction of zirconium tetrachloride, and a typical analysis is as follows: Fe, 0.06 pct; Ox, 0.08; N?, 0.01; C, 0.02; and other impurities such as Al, Pb, Ni, Ti, and Si less than 0.01 pct each. High purity chromium was prepared by treating crushed electrolytic chromium in a stream of dried and purified hydrogen." The resulting powder contained about 0.01 pct 0 and about 0.1 pct total metallic impurities. All alloys were prepared by arc-melting 50 g briquetted compacts of the desired composition in a Kroll-type" arc furnace using an inert atmosphere. The furnace was evacuated twice and backfilled with helium, which was gettered by melting a center zirconium button immediately before the alloys were melted. Alloys were remelted at least once to insure greater uniformity of composition and subsequently were annealed in vacuum at 1250°C for 48 hr. Fairly homogeneous alloys were obtained by this means; a slight loss of chromium from the surface by evaporation during the high temperature homogenization was noted. All alloys were analyzed for chromium and gave results in good agreement with the nominal composition. Spot checks on tungsten and nitrogen showed pick-up of these elements to be negligible. Over 70 alloys were prepared for use in this investigation; only the critical ones are shown in Table I. Alloys containing up to 10 pct Cr were amenable to hot working at 850°C and a number of these were sheath rolled to 1/16 in. thickness. Specimens were cut from the sheet for use as metallographic samples. For the thermal analysis a differential couple was used in conjunction with an X-Y recorder, the temperature of the specimen and the difference in ternperature between it and the standard nickel body were recorded simultaneously. Heating and cooling rates of 5°C per min were used. The sensitivity of the instrument was such that a difference in temperature between the specimen and standard equivalent to 0.1 mv produced a deflection of 1 in. on the recording chart. The chromel-alumel thermocouples were checked against a Bureau of Standards calibrated thermocouple. Melting-point determinations were made in a high vacuum induction furnace using an optical pyrometer. The pyrometer, calibrated against nickel, copper, and zirconium (iodide process) under near black body conditions, was focused on the base of a hole drilled in cylindrical samples. A North American Philips Geiger counter X-ray spectrometer was used for all diffraction studies. This instrument, in addition to supplying precise intensity measurements of planar reflections, has an added advantage in that metallographic specimens mounted in bakelite can be used directly, and this

Jan 1, 1953

By Simon N. Lekakh, D. G. C. Robertson

A new integrated CFD-combined reactors approach is proposed for the description of processes in metallurgical vessels. CFD simulations were used to obtain the melt flow pattern in the vessels (ladle, tundish, and continuous caster mold). From these simulations, the characteristic curves were derived: (i) the residence time distribution curves (RTD) for flow-through systems (at tundish exit or at dendrite coherency surface in the mold) and (ii) the mixing curves for closed systems (ladle). In the next step, the melt flow was represented in a “combined reactors” system consisting of a combination of unit reactors (Plug Flow, Mixer, and Recirculated Volume). An inverse simulation was used to define the volumes of the reactor units and the melt flow rates between them by fitting to the characteristic curves from both methods (CFD and combined reactors). The suggested approach is demonstrated for multiple designs of Ar-stirred ladles, tundish, and SEN. This methodology can be used to enhance traditional post-processing CFD analysis and also as a tool for on-line process control.

Jan 1, 2014

By Carter NB

A statistically-designed experimental program has been used to study compositional and processing variables which influence the development of strength and reducibility of iron ore pellets. The effects of chemical composition and processing variables were investigated by indurating laboratory-made green pellets, of known composition, under approximately isothermal conditions in a pot- grate simulator. Some findings from a six- variable study are summarized in the form of contour diagrams and emphasize the importance of interactions between the variables. Production of strong, highly reducible pellets is possible over a considerable range of combinations of temperature and firing time. Abrasion index (AI) and cold compression strength (CCS) improve as both these variables increase, but reducibility (R) declines, so a compromise is required. When the lime level is too low to form enough slag for bonding, the AI and CCS may be inadequate. Larger additions of lime tend to improve AI and CCS, with only slight effects on R. Finer grinding of the balling feed (i.e. higher Blaine index) tends to improve Al and CCS without

Jan 1, 1980

By Michael J. Howes

The nature of business in a free enterprise system is to maximise the return on an investment i.e. to maximise the wealth of the shareholders. This is normally achieved within constraints dictated by many agencies, one of which is the health and welfare of the employees. In the mining industry considerable effort has been expended in improvements in this field, however, the major problem still confronting the practicing ventilation or environmental engineer is the determination of what standards he should design for, which satisfy both the economic and health requirement s. Normally the basic health requirements are satisfied by the minimum standards defined in regulations and codes of practice. These are, however, based on an acceptance of a certain risk or lower production potential. A prime function of the ventilation engineer is therefore to financially justify and implement improvements to both standards and systems. The main purpose of this paper is to examine the basis and techniques of providing this financial justification. Changes in existing methods to achieve the same standards but at lower costs are also covered.

Jan 1, 1980

By M. E. Mellado

In this paper, we present an a posteriori validation of a heap leaching analytical model using sensitivity analysis. The model is suitable to represent the process of heap leaching of solid reactants from porous pellets and is based on a combination of the leaching kinetics at two levels: particle and heap. The validation is simple, and a sensitivity analysis can easily be performed. The simplicity of the analysis provides insight into the control and optimization of the heap leaching process without strong mathematical complexities. The model and the corresponding sensitivity analysis include the effects of heap height, particle sizes, flow rates and several operation-design variables. Using a case study, we discuss the importance of model validation based on sensitivity analysis. We also comment on several choices for optimizing the process. We had three goals in this work: a posteriori validation, highlighting the importance of model validation and providing insight into optimization choices. We can conclude that the model has good internal logic and there are no extra variables; i.e., all of the variables in the model are necessary.

May 1, 2012

By E. A. Metz

Silicon dioxide, silica, is the most common oxide in the earth&apos; s crust. The health effects of silicon dioxide dust have been known since Biblical times. Agricola&apos;s book, published in the mid 1500&apos;s on occupational medicine, described a lung disease that afflicted miners. He observed a disease in miners that caused shortness of breath, coughing and wasting. Add fever, chest pains and fatigue and we have the current symptom complex of silicosis. As we approached the 21stcentury, the Labor Department began an aggressive campaign to combat silicosis-a preventable disease. Unfortunately, many publications do not clearly differentiate the polymorphs of silica known to mineralogists. Crystalline silica, i.e., alpha quartz, tridymite and cristobalite need to be considered differently from the amorphous forms of silica. Freshly fractured surfaces of the silica and host specific responses will be examined. Recent research focuses on the biologic interactions of free radicals generated by mineral particles. This results in cell injury and DNA damage, in turn leading to fibrogenesis and possibly carcinogenesis. In addition to particle-cell interactions, emphasis is given to lung defense mechanisms.

Jan 1, 1998