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By B. Anameric

Considerable effort has been directed towards understanding the carbothermic reduction mechanisms of self-reducing, fluxing dried green balls to produce pig iron nuggets. Given the geometry of the situation, some investigators believed that the shrinking core model was applicable. Hence, this study involved investigation of the applicability of the shrinking core model to pig iron nugget production. The experiments involved heat treatment of dried green balls utilizing either a laboratory-scale resistance box furnace or a gas-fired muffle furnace at various furnace temperatures and residence times. The products were analyzed for the following: (i) preferred reaction pattern, (ii) distribution of the metallized areas, (iii) % iron content variation in the pig iron nuggets from surface to center, (iv) carburization pattern and (v) physical and chemical properties of the pig iron nuggets. It was determined that the reduction of iron oxide occurred simultaneously throughout the sample and not beginning at the surface and propagating inward; thus the shrinking-core model was not applicable. Heat transfer and gas diffusion from surface to center were not the rate-limiting steps for reduction and carburization reactions.

Jan 1, 2011

By R. E. Murray

"It is a gloomy moment in the history of our country. Not in the lifetime of most men has there been so much grave and deep apprehension; never has the future seemed so incalculable as at this time. The domestic economic situation is in chaos. Our dollar is weak throughout the world. Prices are so high as to be utterly impossible. The political cauldron seethes and bubbles with uncertainty. Russia hangs, as usual, like a cloud, dark and silent, upon the horizon. It is a solemn moment. Of our troubles, no man can see the end." By now you, no doubt, are asking, 'Where did Murray get this bit of philosophy?' Well, I obtained it from an editorial entitled. "The Worst of Times", which was published in the Harper's Magazine in 1847. That's right, 1847! The parallelism between the situation in our country at this time and in 1847 is un- canny. But wait, there is one major exception the size of government. To my knowledge, the citizens of 1847 were not stifled by the extreme governmental excesses that we are experiencing today.

Jan 1, 1980

By G. H. Keith

The Bureau of Mines determined the mechanism(s) involved in observed anomalous changes in mechanical properties of vanadium-base alloys. Tensile properties of electrorefined and commercial-purity vanadium-base alloys containing up to 5 atomic percent molybdenum or titanium were measured between 77° and 673° K. Snoek oxygen and nitrogen peak heights were measured to determine the changes in dissolved interstitial content caused by increasing quantities of solute. In addition, changes in lattice parameter were followed wit: precision X-ray techniques. Softening, observed in alloys containing titanium, is explained by the formation of a second-phase titanium compound with oxygen or nitrogen. However, because of partitioning of titanium between compound formation and solid solution formation, about five times the stoichiometric amount was required for complete reaction. Addition of 1 percent titanium drastically lowered the strengthening due to strain aging, at 673° K, and 2 percent titanium essentially eliminated it. All alloys were ductile at 77° K. Variations in the tensile properties of the molybdenum-containing alloys are explained by variations in the amounts of interstitial impurities present. The molybdenum did not react with these impurities and had no effect on strengthening due to strain aging. Commercial-purity vanadium alloys containing more than 2 percent molybdenum were brittle at 77° K.

Jan 1, 1969

By B. M. Thethwayo

Graphite blocks are currently used in the concentrate - slag zone in primary PGM smelters, and can possibly be extended to the matte zone. This project evaluates the interaction between synthetic matte and graphite blocks on a laboratory scale. Static crucible tests were performed where graphite crucibles (prepared from standard and high-grade graphite) were filled with synthetic matte (27.7 per cent S ? 46.1 per cent Fe ? 17.0 per cent Ni ? 9.2 per cent Cu) and heated to 1550°C for different time periods (1?5 days). Matte penetration was evaluated using a SEM, while graphite dissolution was evaluated by measuring the carbon content of the matte with a LECO carbon analyser. Matte penetrated into standard grade graphite up to approximately 2 mm, while matte infiltration into the high grade graphite was limited to the immediate hot face. The saturation solubility of graphite in the synthetic matte at 1550°C was 0.43 per cent. Copper, iron, nickel, and sulphur were detected in an accretion that formed in the water-cooled part of the furnace. This accretion consists of mainly Cu-S and Cu-Fe-S based phases.

Jan 1, 2012

By J. J. Liu

In the Bayer process, control of alumina trihydrate particle size, oxalate stability and morphology and foaming is crucial for improving the yield and quality of alumina trihydrate. One way to economically achieve such control is to employ specifically developed chemical additives, termed, crystal growth modifiers (CGM?s). In this paper, the mechanism of action and practical application of CGM?s in the Bayer process are summarized. The application of CGM additives allows for both enhanced agglomeration and secondary nucleation control, and hence coarsening of the particles. Current research efforts have utilized the information gained from mechanistic studies to enhance the performance of CGM products. It was demonstrated in both laboratory tests and industrial operations that the newly developed CGM formulations have a range of properties with enhanced performance, compared to the current commercial products.

Jan 1, 2014

By A. H. Roberson, L. H. Banning

DURING the past few years, a considerable tonnage of ilmenite has been produced as a byproduct of a monazite dredging operation and stockpiled near Boise, Idaho. This ilmenite has not been marketed because of the long distance from ilmenite-consuming areas and its comparatively low TiO2 content. Production of monazite from the alluvial sand deposits of Idaho is a mar- ginal venture when it is the only marketable product, and it will be necessary to establish a byproduct market before the operation becomes economically stable. Early in 1954, the Bureau of Mines Northwest Electrodevelopment Laboratory at Albany, Ore., conducted a series of tests which demonstrated that arc furnace smelting could be utilized to produce commercial quality pig iron and a high titanium content slag from these ilmenites. Additional studies showed that the slag chlorinated readily to produce a satisfactory yield of TiCl4. The investigation was carried out by two research teams. The Ferrous Metals Branch, with adequate

Jan 1, 1956

By Gerhard Derge

METALLURGISTS have used borax as a fluxing agent traditionally, but until recently elemental boron has played an insignificant role as an alloying element. Neither the metal nor its compounds have been regarded as important metallurgical materials and there is a surprising lack of knowledge concerning their metallurgical behavior. The new applications to steelmaking of both boron and borates, which arose in part from wartime incentives and restrictions, have been seriously handicapped by this lack of data. For example, rasorite, a naturally occurring sodium borate, has been shown to be an effective substitute for aluminum as a ladle deoxidizer in rimming steels.1 Likewise, the effectiveness of boron as an alloying agent has been demonstrated, 2,3 giving deep hardening when used in restricted amounts. The exploitation of both of these uses has been retarded by the difficulty of attaining suitable metallurgical control. Recognizing that the most important information required was a knowledge of the equilibrium between boron and oxygen dissolved in liquid iron, Gurry4 calculated this relation from the best thermal data available. However, estimates of the entropy of melting of boron, the activity coefficient of boron in liquid iron and the activity coefficient of B203 in slag were involved, and experimental work on this problem was obviously desirable. The experiments to be described were planned to establish the boron-oxygen relations in liquid iron and to demonstrate at the same time the ferroborate slag compositions in equilibrium with various amounts of oxygen in liquid iron. Accordingly, slags containing varying proportions of iron and boron oxides were held in contact with molten iron, and samples of both slag and metal were analyzed. The limitations upon the accuracy of the data will be considered, but in a practical sense the oxygen levels that can be attained in iron by iron borate slags, and the amounts of boron in iron at these oxygen levels were established. EXPERIMENTAL PROCEDURE No entirely suitable refractory was found for the mixtures of iron oxide and boron oxide used as slags. Crucibles of silica, magnesia, Ramix, beryllia, and zirconia were all tried unsuccessfully. The most satisfactory method discovered for handling them was the rotating-crucible technique, which creates a parabolic crucible of liquid iron 5,6 Even this was not entirely successful, for at steelmaking temperatures (1600°C.) the slags had such a low surface tension that they crept up to the refractory and slowly dissolved it. These difficulties made it impossible to maintain a constant slag composition for an unlimited period of time. However, by using the rotating

Jan 1, 1946

By D. Harrington

E. H. DENNY (United States Bureau of Mines, Denver, Colorado) In the absence of Mr. Harrington it is my privilege to read his paper, which is in his usual, forcible and sincere style, and it is within the province of this Institute, certainly, to go into it as it concerns safety and efficiency in mining. He brings out some points in his paper that, I think, are well worth the consideration of the Institute. The figures he uses were compiled by Mr. Adams, of the Bureau, and cover a five-year period. However, examination of similar Bureau figures for a ten-year period, or any other long period on other bases brings out similar results. The figures in this paper have been based on the million hours of exposure of accidents, and the figures based on three hundred working-man-day basis, or on tonnage, brings out similar results. This paper is entitled "Accident Record in Western Mines," and it is, in a way, an amplification of Mr. Harrington's letter which was read at the Glenwood Springs Meeting.

Jan 1, 1927

By COURTNEY DE KALB

IRON ore is the cause of the present trouble in Morocco. At least three nations are interested in the outcome and private syndicates have been active. The iron deposits are found in that mountainous northern coast line known as the Rif. This is an uplift that has been cut through, by the northward drainage, representing an ancient land surface. Erosion has produced .a fiordlike coast, which circum- stance has aided contraband' traffic to the tribes dominated by Abd-el-Krim, the chief of the clan of the Beni Urriaguel, near the center of 'the north coast, opposite Alhucemas. The iron deposits are extensive in the territory of the Beni Urriaguel. They were "located," if such a term is permissible, many years ago. The first arrangements, through direct contracts with the tribal chieftains, have been reinforced by compliance with the subsequent code under the Spanish protectorate in 1914. Under those terms, the location had to be made through the Arbitral Commission sitting in Paris. These locations, or "denouncements," were made by the I-louse of Mannesmann, of Hamburg.

Jan 1, 1925

By Guy Crane

I. INTRODUCTION THE geology of the Tintic mining district, fully treated, would occupy an elaborate monograph. This less comprehensive paper is devoted primarily to the occurrence and origin of the orebodies of the district, while space is given to those phases of the general geology only which seem necessary to a proper setting of such a discussion. The first geological report on the Tintic district to be issued was that by Tower and Smith, published in 1899, in the form of a paper in Part III of the Nineteenth Annual Report of the U. S. Geological Survey, and also as Folio No. 65, Geologic Atlas of the United States. About four years ago a second investigation was begun by Waldemar Lindgren and G. F. Loughlin, of the U. S. Geological Survey. With the exception of a paper on the oxidized zinc ores of the Tintic district by Mr. Loughlin, the results of their work are still unpublished. The writer's acquaintance with the district began in the fall, of 1913, and has extended over a period of about two years.

Jan 10, 1915

By Pierre Montrueil, Marcel St-Amant

Within the next few years, underground mobile equipment will be partially automated. Mining methods will integrate more and more automation. Such an evolution will be possible only if adequate underground communication systems are developed. This is expected due to the available competence in Canadian telecommunication, to the economic pressure on the Canadian mining industries for international competitiveness and to the social changes where a better working environment (i.e. less accidents) becomes a major concern. CCARM propose the concept of a Production Area Network for Automated Mobile Units called PANAMU as an intermediate size communication system. It can be implemented using mature present-day technology and it can be integrated in some mine wide communication systems. It can evolve so as to incorporate new technologies because of its modular concepts. In this paper, the communication requirements are estimated, the amtmptions are defined, the concepts of the PANAMU are presented and an over- view of its implementation is described. CCARM presents this article to the mining industry as a document for discussion.

Jan 1, 1994

By Ali Porbaha

In today's fast-track construction environment, owners are searching for non-conventional technologies to build their projects faster and safer while maintaining traffic flow during construction. To that end designers and contractors are providing solutions that incorporate many unique features to expedite construction processes. In addition to timely delivery of the finished highway products, there is an increasing interest in making the initial investment in applying innovative technologies and thereby minimizing costly maintenance of highway projects. Accordingly, the aim of this paper (along with the accompanying paper) is to examine innovative technologies, developed mostly in Europe, that accelerate construction of highway, runway and railway embankment foundations. For each technology, a basic concept, installation technique(s), and design considerations are discussed, along with the case history of a real-world project. The Geotextile Encased Columns (GEC), AuGeo, and Continuous Flight Auger (CFA) are presented in Part I. Deep Mixing (DM), Cut-Mix-Injection (FMI), Mass stabilization, and Combined soil Stabilization with Vertical columns (CSV) technologies are discussed in Part II.

Jan 1, 2002

Firedamp drainage has become an essential part of many mine environmental systems, and new applications are arising. Installations are evolving further to satisfy ever changing basic requirements, standards, and iniilny needs. In this paper, water seal, vacuum based installations are considered, as well as moni- toring, protective and control systems which have been developed for continuous, manless, and trouble free operation. Some factors affecting plant capacity and extractor per- formance are identified and assessed. INTRODUCTION Firedamp drainage applications are incr- easing world wide as mining engineers strive for improved safety and security, and further concentration of coal output. Fewer and fewer mines are able nowadays to satisfy coal prod- uction and firedamp control requirements solely by air dilution or by air dilution and underground firedamp extraction plants. As a result, dependence on surface extraction plants is increasing. This paper deals with som requirements and applications of such installations. I. DEVELOPMENT AND PRACTICE Firedamp drainage has existed for over 250 years following the early work of Carlisle Spedding at Whitehaven (1730). Some fundamentals of current firedamp drainage systems can be recognised in the

Jan 1, 1982

By Muir D

A review of the various methods of degrad- ing cyanide either from gold processing liquors or electroplating baths is presented with some discussion on their relative merits or problems. Whilst alkaline chlorination is common practice in many U.S. and Canadian plants it poses particular problems for certain plants. Alter- native methods include electrolysis, hydrolysis and air oxidation with activated carbon as catalyst which are also integral steps in the carbon-in-pulp process. A basic study of the degradation of cyanide ion has been carried out therefore to determine the effect of temperature, oxygen and carbon. It is shown that carbon is an excellent catalyst for degradation by air and likely to lead to higher losses of cyanide in a C.I.L. circuit. Degradation by hydrolysis is important at high temperatures and high pH such as employed in the Pressure Zadra or Anglo elution processes. Carbon catalysed degradation of cyanide by oxygen in effluent streams may be an environmentally acceptable alternative to conventional chlorine degradation.

Jan 1, 1987

By J M. Palin

Hydrothermal scheelite precipitated in fault-veins at Paradise, Bonnie Jean, Davidson's and Glenorchy mines display chemical variability involving REE patterns that are transitional between two end-member types. Type I is a MREE-enriched pattern with no or a small positive Eu anomaly. Type II is a flat to MREE-depleted pattern with a strong positive Eu anomaly. The chemical inhomogeneity of these scheelites can be explained by a model of fractional precipitation of REE, with preferential removal of MREE from the fluid during precipitation of scheelite. Irrespective of the mechanism responsible for scheelite precipitation, the source of dissolved constituents is different for scheelites from the Paradise Mine. Bonnie Jean, Davidson's and Glenorchy scheelites formed from LREE-enriched fluids whereas Paradise scheelites precipitated from fluids that were lower in LREE. These inferred fluid characteristics cannot be linked unambiguously to specific source rocks in the region, but could suggest that scheelite deposited in the Paradise fault-vein reflects a more mafic source of REE possibly greenschists, whereas the REE in scheelite from the other mines suggest a more felsic source.

Jan 1, 2003

By L. H. Adami

This paper reports the results of solution calorimetry conducted to obtain the heats of formation of crystalline FeS04?6.952H20 and FeS04?1.008H20, from. which values were derived for the stoichiometric compounds FeS04?H20 and FeS04?H20. Also included are derived values of the free energies of formation and dehydration. This work was undertaken primarily to fill a need for data for pure, easily obtainable ferrous compounds that are suitable for use as calorimetric intermediates, The ferrous sulfate hydrates meet the essential requirements for this use.

Jan 1, 1963

[Note.—The paper of Mr. Hoffman on " Practical Results in the Magnetic Concentration of Iron-Ore " (page 602); that of Mr. Langdon on "The Use of Magnetic Concentrates in the Port Henry Blast-Furnaaces" (page 599); and those of Mr. Landis on "The Determination of Iron in the Tails from Magnetic Concentration " (page 609) and "Note on Sampling Iron-Ore" (page 611), were all prepared as contributions to this discussion.] The papers of Mr. Langdon and Mr. Hoffman were presented. W. H. Hoffman, Croton Mines, N. Y.: I will add a few remarks, by way of answer to inquiries for further details. The Croton Mines are particularly well located for cheap mining. The ore-bed is very large, and so lies in relation to the railway tracks of the Harlem and other railroads that a very large proportion of our mining for several years to come can be done above these tracks. The concentrating-mill is now 400 feet from where we are working in the quarry. In blasting we never remove less than 2500 tons at a blast,

Jan 1, 1892

By A. J. Hyett, N. Hedrick, J. Blackall

The Garford bulb anchor is a modified cable geometry developed and patented by Garford Ply Ltd. of Australia, and which has recently become widely available in Canada. It is produced by deforming the seven wires (including the central kingwire) of a standard cable into a bulb" (Fig. 1). Laboratory cable pull tests indicate that the bond capacity of the 25 mm Garford bulb anchor is comparable to the nutcase cable, in excess of the birdcage cable, and significantly higher than standard 7-wire strand. Its comparative advantage over the latter is most significant for tests at low radial confinement and high water:cement ratio grout, which corresponds to operational conditions of low quality rock (i.e. weak, highly fractured rock masses, foliated hanging walls, failed ground, etc.) and poor installation quality control (perhaps the most common explanation for cable bolt failures). It is under such conditions that cable bolting is often ineffective. The most impressive result is that for a reduction of the effective rock mass modulus by a factor of five, the Garford bulb cable capacity remains virtually unchanged.

Jan 1, 1995

By R. W. Armstrong, P. C. Jindal

TABOR1 has indicated for a number of polycrystal-line materials that their hardness should be directly related to their yield strength. For a material showing zero work-hardening, the Meyer hardness, MH, may be calculated in terms of the yield stress, sy, by utilizing slip line theory and the result is: The Meyer hardness corresponds to indenting the surface with a spherical indenter and specifying the ratio of load and projected area of the indentation. The correlation indicated by Eq. [I] is not well-established. It has been verified to some degree by performing hardness tests on materials strained to the maximum nominal stress and taking this stress as the (new) yield stress of a nonwork-hardening material. The dependence of hardness on yield strength for an annealed material capable of showing work-hardening has not been theoretically evaluated but, presumably, the hardness should be greater than that specified above. Marcinkowski, Fisher, and szirmae2 measured the dependence of the Vickers Diamond Pyramid hardness, H,, on yield strength for an annealed Fe-Cr alloy which shows work-hardening and found:

Jan 1, 1968

By Jin Liu

To improve value metals recovery, a new operating concept for the Inco flash furnace was investigated, in which the flash furnace coke addition practice would aim at establishing a reducing barrier on the surface of the molten bath. The descending partially oxidized sulfide mineral particles would reach the supernatant coke layer prior to the formation of slag. The key for success depends on the effectiveness of the coke layer to produce a sulfur deficient matte while maintaining furnace production capacity. The mechanism and rate of carbon reduction of the phases formed in the flash flame, i.e. sulfide (matte) and oxysulfide was investigated by means of crucible graphite reduction test work. The objective of these tests was to measure the rate of solid graphite reduction of matte, oxysulfide, slag, and matte+slag mixture at different temperatures. These tests were expected to permit understanding and explaining the reduction mechanism of each material by comparing the respective reaction rates, product reaction gas compositions, reduced material assays, and other relevant parameters. Direct visual inspection of the test crucibles would provide additional information.

Jan 1, 2006